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Biodiesel
CHAPTER 1
INTRODUCTION
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It helps to reduce carbon dioxide and other pollutants emission from engines.
Engine modification is not needed as it has similar properties to diesel fuel.
It comes from renewable sources whereby people can grow their own fuel.
Diesel engine performs better on biodiesel due to a high cetane number.
High purity ofbiodiesel would eliminate the use of lubricant.
Biodiesel production is more efficient as compared to fossil fuels as there will be no
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South Western Railway general manager P.K. Saxena flagging off the train in
Hubballion Thursday.
1.4 OBJECTIVES
To determine the yield of biodiesel from waste oil.
To optimize the process parameters (Methanol to oil ratio, Quantity of catalyst,
Reaction time) for the biodiesel production.
To determine the physicochemical properties of the neem biodiesel using standard
methods, while the fatty acid profile is to be determine using gas chromatography.
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CHAPTER 2
LITERATURE REVIEW
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Optimization of Biodiesel production from mixed oil (Karanja &Dairy waste Scum
oil) using Homogeneous Catalyst.
Here, crude mixed oil was used as feedstock for biodiesel production by Homogeneous Catalyst.
The reaction in the presence of KOH as catalyst was carried out to investigate the optimum
conditions and study the effect of variables on the reaction. The variables included methanol to
oil molar ratios, catalyst concentrations, reaction temperature and reaction times. Gas
chromatography was used to determine the fatty acid composition of mixed oil. The optimum
conditions for mixed oil biodiesel production were a catalyst concentration of 1.0% w/w of oil, a
reaction temperature of 70oC, a reaction time of 30minutes 6:1 methanol to oil molar ratio at
400rpm. The methyl ester content under these optimum conditions was 95.10%, and all the
measured properties of mixed oil biodiesel met the ASTM standards.
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Synthesis of Biodiesel Synthesis of Biodiesel from neem oil using Sulfated Zirconia
via transesterification
Sulfated zirconia (SZ) is a widely used catalyst, which is synthesized by a solvent free method
and the synthesized catalyst has been characterized. Neem Methyl Ester (Biodiesel) was
prepared by a two-step process of esterification and transesterification from Neem oil with
methanol in the presence of catalyst. Acid catalyst was used for the esterification and alkali
catalyst (KOH) for the transesterification reaction. Optimal Free Fatty Acid (FFA) conversion
was achieved using 1 wt% SZ as an acid catalyst with a methanol-to-oil molar ratio of 9:1,
temperature of 65C and reaction time of 2 h. The acid value was reduced to 94% of the raw oil
(24.76 mg KOH/g), which confirmed the conversion. Consequently, this pretreatment reduces
the overall complexity of the process and a conversion efficiency of 95% is achieved when
pretreated oil reacts with methanol in the presence of KOH.
Department of Chemical Engineering
KLE Dr. M.S. Sheshgiri College of Engineering & Technology, Belagavi
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Calcium oxide from Pomacea sp. shell as a catalyst for biodiesel production
Heterogeneous catalysts are promising catalyst for the transesterification reaction of vegetable
oils to produce biodiesel. In this study, the Pomacea sp. shell was used as the raw material for
CaO catalyst. The calcination of Pomacea sp. shell was conducted at 900C for 2 h. The raw
material and the resulting CaO catalyst were characterized using X-ray diffraction, X-ray
fluorescense spectrometry, and Fourier transform infrared spectroscopy analysis. From the
experimental results, it was found that the maximum yield of fatty acid methyl esters was
95.61% at the following reaction conditions: reaction temperature of 60C, a reaction period of 4
h, a ratio of methanol-oil at 7:1, and amount of catalyst at 4% w/w. The physical and chemical
properties of biodiesel were determined based on ASTM standard, and the values obtained were
confirmed with the Indonesian National Standard (SNI-04-7182-2006) and (B100)-ASTM
D6751-07b.
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The various species exist in equilibrium, and the product distribution depends on the relative
energies of the reactant and product.
The stoichiometry requires 1 mol of triglyceride and 3 moles of methanol to give 3 moles of fatty
acid methyl esters (FAME, Biodiesel) and 1 mol of glycerol. Diglycerides and monoglycerids are
the intermediates in this process. The glycerol is separated by setteling or centrifugation
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CHAPTER 3
MATERIALS
&
METHODOLOGY
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Sulfuric acid is a diprotic acid and shows different properties depending upon its concentration.
Its corrosiveness on other materials, like metals, living tissues or even stones, can be mainly
ascribed to its strong acidic nature and, if concentrated, strong dehydrating and oxidizing
properties.
3.1.3 METHANOL
Methanol, also known as methyl alcohol, wood alcohol, wood naphtha or wood spirits, is a
chemical with formula CH3OH (often abbreviated MeOH). It is the simplest alcohol, and is a
light, volatile, colorless, flammable, liquid with a distinctive odor that is very similar to but
slightly sweeter than ethanol (drinking alcohol). At room temperature it is a polar liquid. Most
methanol today is produced from the methane found in natural gas, but methanol is also
produced from all types of biomass, coal, waste, and even CO2 pollution from power plants.
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3.2 METHODOLOGY
3.2.1 PREPARATION OF BIODIESEL:
Biodiesel production is carried out using a two step transesterification process
Acid catalyzed transesterification process followed by base catalyzed transesterification process.
This process has been used to convert vegetable oils with free fatty acids value.
1. Cooking oil is collected from restaurants.
2. Transesterification reaction uses H2SO4 (Catalyst) and methanol as reactant.
3. Initially oil is heated strongly around 80 for 30mins using magnetic stirrer to reduce
the viscosity of oil.
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CHAPTER 4
TESTING AND ANALYSIS
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Procedure:
Materials Required:
Palm oil (used and unused)
Conical Flask
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Reagents Required:
Aalcoholic KOH(95% ethanol, v/v)
Potassium hydroxide [0.5N]
Hydrochloric acid[0.5N]
Phenolphthalein indicator
Procedure:
A known weight of the given sample of oil is taken and then transferred into
iodine flask.
Add 25ml of 0.5N alcoholic KOH and 25ml of alcohol into the flask through
pipette and mix well.
Add the same amount of alcohol and 0.5 KOH in another flask for blank
determination.
Fill the flask with water condensers and reflux the contents on a water bath for a
period of 1 hour.
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4.4 VISCOSITY
The viscosity of a fluid is a measure of its resistance to gradual deformation by
shear stress or tensile stress. For liquids, it corresponds to the informal concept of
"thickness"; Viscosity is a measure of an oil's resistance to flow. It decreases (thins)
with increasing temperature and increases (or thickens) with decreased
temperature. An oil's viscosity is measured most commonly by kinematic viscosity
and reported in a unit called the centistoke (cSt). Kinematic viscosity is measured in
the time it takes for a specific volume of oil to flow through a special device called a
capillary tube.
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CHAPTER 5
RESULTS
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Time
(Hours)
2.5
Time
(Hours)
2.5
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Time
(Hours)
2.5
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Time
(Hours)
2.5
Time
(Hours)
2.5
Time
(Hours)
2.5
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Time
(Hours)
2.5
Time
(Hours)
2.5
Time
(Hours)
2.5
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Time
(Hours)
2.5
Time
(Hours)
2.5
Time
(Hours)
2.5
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Catalyst
NaOH
NaOH
NaOH
Methanol : oil
4:1
4:1
6:1
Time (hours)
3
4
4
Flash point
42
42
40
Fire point
46
45
43
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Properties
Flash point (oC)
Viscosity
Specific Gravity
Pour pint
Standard
Range
Obtained
GC/MS analyses of feed oil and the product oil were performed at Shivaji University, Kolhapur.
Gas chromatography analysis of biodiesel prepared from NaOH and CaO is shown in table . The
percentage of unsaturated fatty acid is 80.27 % for NaOH catalyst and 79.01% using CaO
catalyst. Biodiesel fuel with more unsaturated fatty acid composition has more density but has
less viscosity, lower cetane number and heating value. It has lower thermal effiency compared to
high saturated fatty acid composition. It emits lower HC and CO and less smoke compared to
highly saturated biodiesel fuel (Olugbenga Olufemi Awolu).
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Fatty acid
Percent composition %
Unsaturated fractions
Oleic acid (C18:1)
19.1
57.1
.11
Hexadecanoic acid
2.7
Saturated fractions
Palmitic acid (C16:0)
11.1
9.9
Total
100%
Fatty acid
Percent composition %
Unsaturated fractions
Oleic acid (C18:1)
18.1
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