The photobooth mode in DSLR Remote Pro for Windows can accept the following key presses:

Esc - exit full screen photobooth or video booth mode and return to the main DSLR Remote Pro
for Windows screen
F2 - switch to B&W mode and start the photobooth sequence
F3 - switch to color mode and start the photobooth sequence
T - switch to B&W (toned) mode and start the photobooth sequence
F4 - start the photobooth sequence using the current B&W or color setting
F5 - same as F4
F6 - reactivate live view and display ready.jpg screen if previously canceled due to inactivity or
cancel live view and display welcome.jpg screen if live view currently active
Ctrl+Alt+F6 - switch from standby to ready mode
F9 - switch to stills photobooth mode and start the photobooth sequence
Ctrl+F1 - select the camera's user 1 picture style
Ctrl+F2 - select the camera's user 2 picture style
Ctrl+F3 - select the camera's user 3 picture style
Ctrl+F4 - select the camera's standard picture style
Ctrl+F5 - select the camera's portrait picture style
Ctrl+F6 - select the camera's landscape picture style
Ctrl+F7 - select the camera's neutral picture style
Ctrl+F8 - select the camera's faithful picture style
Ctrl+F9 - select the camera's monochrome picture style
S - cycle through available picture styles
Ctrl+A - auto focus (only available for camera models that support live view AF)

Ctrl+B - switch to B&W mode but don't start the photobooth sequence
Ctrl+C - switch to color mode but don't start the photobooth sequence
Ctrl+K - switch to color mode but don't start the photobooth sequence (alternative for Ctrl+C)
Ctrl+Alt+P - display the reprint selection dialog
Ctrl+R - reprint the last set of photos without displaying the touchscreen keyboard or print
confirmation screens
Ctrl+Alt+R - reprint the last set of photos with touchscreen keyboard and print confirmation
screens if enabled
Shift+Ctrl+R - fast reprint of the last set of photos (if output option is set to "Print and save
JPEG copy")
Ctrl+T - switch to B&W (toned) mode but don't start the photobooth sequence
Ctrl+W - toggle between B&W and color modes
Ctrl+Z - take photo when the booth is running in clicker mode
A - Accept print when print confirmation window is displayed or in the reprint selection dialog
P - Accept print when print confirmation window is displayed but don't copy JPEG copy
W - cycle through color, B&W and B&W (toned) modes
X - Reject print when print confirmation window is displayed or cancel the reprint selection
dialog
Ctrl+1 - select one copy of prints
Ctrl+2 - select two copies of prints
Ctrl+3 - select three copies of prints
Ctrl+4 - select four copies of prints
Ctrl+5 - select five copies of prints
Ctrl+6 - select six copies of prints
Ctrl+7 - select seven copies of prints

Ctrl+8 - select eight copies of prints

Ctrl+9 - select nine copies of prints
Shift+Ctrl+1 - select profile 1
Shift+Ctrl+2 - select profile 2
Shift+Ctrl+3 - select profile 3
Shift+Ctrl+4 - select profile 4
Shift+Ctrl+5 - select profile 5
Shift+Ctrl+6 - select profile 6
Shift+Ctrl+7 - select profile 7
Shift+Ctrl+8 - select profile 8
Shift+Ctrl+9 - select profile 9
Shift+Ctrl+F1 - select profile 10
Shift+Ctrl+F2 - select profile 11
Shift+Ctrl+F3 - select profile 12
Shift+Ctrl+F4 - select profile 13
Shift+Ctrl+F5 - select profile 14
Shift+Ctrl+F6 - select profile 15
Shift+Ctrl+F7 - select profile 16
Shift+Ctrl+F8 - select profile 17
Shift+Ctrl+F9 - select profile 18
Shift+Ctrl+N - select next profile
Shift+Ctrl+P - select previous profile
CursorLeft - digital zoom out

CursorRight - digital zoom in

Shift+CursorLeft - crop live view display (reduce the amount of cropping)
Shift+CursorRight - crop live view display (increase the amount of cropping)
Shift+rotate mouse wheel - adjust live view display cropping
Ctrl+rotate mouse wheel - adjust focus
Number pad '+' - increase the number copies of prints (up to a maximum of 9 copies)
Number pad '-' - decrease the number copies of prints (down to a minimum of 1 copy)
Ctrl+Page Up - decrease exposure using exposure compensation in auto exposure modes or ISO
in manual exposure
Ctrl+Page Down - increase exposure using exposure compensation in auto exposure modes or
ISO in manual exposure
b - cycle through number of copies of prints: 1,2,3,4,5,6,7,8,9,1,2,3...

Sharing photos by email of Facebook upload

F - select Facebook upload from the sharing screen
E - select email photos from the sharing screen
X - exit the sharing screen
Enter - login to Facebook or authorize the app when the Facebook login screen is displayed
Shift+Ctrl+S - display the sharing screen (only available when the ready screen is displayed)

Video booth keyboard shortcuts:

Ctrl+A - auto focus (only available for camera models that support live view AF)
Ctrl+V - switch from stills photobooth mode to video booth mode
Ctrl+P - switch from video booth mode to stills photobooth mode

Ctrl+S - toggle between video and stills photobooth mode and back again
F4 - start video booth capture sequence in video booth mode or photobooth shooting sequence in
stills mode
F7 - start video booth capture sequence
F8 - switch to video booth mode and start the video booth capture sequence
End - end the video recording now rather than wait for the full duration
Ctrl+F1 - select the camera's user 1 picture style
Ctrl+F2 - select the camera's user 2 picture style
Ctrl+F3 - select the camera's user 3 picture style
Ctrl+F4 - select the camera's standard picture style
Ctrl+F5 - select the camera's portrait picture style
Ctrl+F6 - select the camera's landscape picture style
Ctrl+F7 - select the camera's neutral picture style
Ctrl+F8 - select the camera's faithful picture style
Ctrl+F9 - select the camera's monochrome picture style
Ctrl+rotate mouse wheel - adjust focus
S - cycle through available picture styles
A - accept the video and switch from the playback screen to the ready screen
P - play video from the start when in displaying the playback screen
X - reject the video, delete it from the computer and switch from the playback screen to the ready
screen