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Basis:
H2O
100
mol S1
SO3
H2SO4
mol SO3
Composition of S2
SO3 = 0.001303
Inerts = 0.998697
Basis:
S1 =
28
MW H2SO4 =
MW H2O =
98
18
lb/ lb mol
lb/ lb mol
Overall
H2SO4
H2O
F
0.959
0.041
P
-0.98
-0.02
constant
-216.2272
39.7152
F=
P=
2059.307
2235.819
lb/hr
lb/hr
P2
1
0.98
constant
-2059.307
-1974.875
6177.92
4118.613
lb/hr
lb/hr
at B
Total
H2SO4
-1
-0.973
G=
P2 =
lb mol/hr
% SO3 absorbed =
-216.2272
39.7152
-2059.307
-1974.875
0.985
S2
SO3
Inerts
S1
SO3
Inerts
0.0013
0.9987
28
0.08
0.92
lb mol / hr
a.
b.
c.
F=
G=
P=
ABSORPTION
TOWER
P1
A
24.71168
74.13504
26.82982
ton/day
ton/day
ton/day
G
H2SO4
H2O
P2
4118.613
P
H2SO4
H2O
2235.819
0.98
0.02
6177.92
0.973
0.027
lb/hr
lb/hr
F
H2SO4
H2O
2059.307
0.959
0.041
lb/hr
Problem 1
Given that the vapor pressure of n-butane at 350 K is 9.4573 bar, find the
molar volumes of (a) saturated-vapor and (b) saturated-liquid n-butane at
these conditions as given by the Redlich/Kwong equation.
T=
Tc =
Tr =
350
425.1
0.823336
=
=
0.42748
0.08664
q=
=
6.604378
0.026217
K
K
Saturated-Vapor
Z
0.83049
Z'
0.83049
V=
2555.319 cm3/mol
Saturated-Liquid
Z
0.043312
Z'
0.043312
V=
133.2663 cm3/mol
P=
Pc =
Pr =
9.4573
37.96
0.249139
R=
83.14
bar
bar