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Cade of Federal Regulations
Code of Federal Regulations
Title 40 - Protection of Environment
Volume: 27
Date: 2012-07-01
Original Date: 2012-07-01
Title: Section 261.33 - Discarded commercial chemical products, off-specification species,
container residues, and spill residues thereof.
Context: Title 40 - Protection of Environment. CHAPTER | - ENVIRONMENTAL PROTECTION
AGENCY (CONTINUED). SUBCHAPTER | - SOLID WASTES (CONTINUED). PART 261 -
IDENTIFICATION AND LISTING OF HAZARDOUS WASTE. Subpart D - Lists of Hazardous
Wastes.
§ 261.33 Discarded commercial chemical products, off-specification species, container
residues, and spill residues thereof,
The following materials or items are hazardous wastes if and when they are discarded or intended
to be discarded as described in § 261.2(a)(2)i), when they are mixed with waste oil or used oil or
other material and applied to the land for dust suppression or road treatment, when they are
otherwise applied to the land in lieu of their original intended use or when they are contained in
products that are applied to the land in lieu of their original intended use, or when, in lieu of their
original intended use, they are produced for use as (or as a component of) a fuel, distributed for
use as a fuel, or bumed as a fuel
(@) Any commercial chemical product, or manufacturing chemical intermediate having the generic
ame listed in paragraph (e) or (f) of this section.
(b) Any off-specification commercial chemical product or manufacturing chemical intermediate
which, if it met specifications, would have the generic name listed in paragraph (e) or (f) of this
section.
(6) Any residue remaining in a container or in an inner liner removed from a container that has held
any commercial chemical product or manufacturing chemical intermediate having the generic
name listed in paragraphs (e) or (f) of this section, unless the container is empty as defined in §
261.7(b) of this chapter.
[ COMMENT: UNLESS THE RESIDUE |S BEING BENEFICIALLY USED OR REUSED, OR LEGITIMATELY
RECYCLED OR RECLAIMED: OR BEING ACCUMULATED, STORED, TRANSPORTED OR TREATED PRIOR TO
SUCH USE, RE-USE, RECYCLING OR RECLAMATION, EPA CONSIDERS THE RESIDUE TO BE INTENDED FOR
DISCARD, AND THUS, A HAZARDOUS WASTE. AN EXAMPLE OF LEGITIMATE RE-USE OF THE RESIDUE
WOULD BE WHERE THE RESIDUE REMAINS IN THE CONTAINER AND THE CONTAINER IS USED TO HOLD
‘THE SAME COMMERCIAL CHEMICAL PRODUCT OR MANUFACTURING CHEMICAL INTERMEDIATE IT
PREVIOUSLY HELD. AN EXAMPLE OF THE DISCARD OF THE RESIDUE WOULD BE WHERE THE DRUM IS SENT
TO.ADRUM RECONDITIONER WHO RECONDITIONS THE DRUM AUT DISCARDS THE RESIDUE.)
(a) Any residue or contaminated soil, water or other debris resulting from the cleanup of a spill into
or on any land or water of any commercial chemical product or manufacturing chemical
intermediate having the generic name listed in paragraph (e) or (f) of this section, or any residue or
contaminated soil, water or other debris resulting from the cleanup of a spill, into or on any land or
water, of any off-specification chemical product and manufacturing chemical intermediate which, if
it met specifications, would have the generic name listed in paragraph (e) or (f) of this section
[ COMMENT: THE PHRASE “COMMERCIAL CHEMICAL PRODUCT OR MANUFACTURING CHEMICAL
INTERMEDIATE HAVING THE GENERIC NAME LISTED IN...” REFERS TO A CHEMICAL SUBSTANCE WHICH IS
MANUFACTURED OR FORMULATED FOR COMMERCIAL OR MANUFACTURING USE WHICH CONSISTS OF
‘THE COMMERCIALLY PURE GRADE OF THE CHEMICAL, ANY TECHNICAL GRADES OF THE CHEMICAL THAT
ARE PRODUCED OR MARKETED, AND ALL FORMULATIONS IN WHICH THE CHEMICAL IS THE SOLE ACTIVE
INGREDIENT. IT DOES NOT REFER TOA MATERIAL, SUCH AS A MANUFACTURING PROCESS WASTE, THAT
CONTAINS ANY OF THE SUBSTANCES LISTED IN PARAGRAPH (E) OR (F). WHERE A MANUFACTURING,
PROCESS WASTE IS DEEMED TO BE A HAZARDOUS WASTE BECAUSE IT CONTAINS A SUBSTANCE LISTED IN
PARAGRAPH (E) OR (F), SUCH WASTE WILL BE LISTED IN EITHER § 261.31 OR § 261.42 OR WILL BE
IDENTIFIED AS A HAZARDOUS WASTE BY THE CHARACTERISTICS SET FORTH IN SUBPART C OF THIS
PART]
(€) The commercial chemical products, manufacturing chemical intermediates or off-specification
commercial chemical products or manufacturing chemical intermediates referred to in paragraphs
(@) through (4) of this section, are identified as acute hazardous wastes (H) and are subject to the
iepiwww.gpo.goulsysipkICFR-2012-tle40-vol27imlICFR-2012-ttleH0-vol27-s6c261-33.xml 4372s2016
Cade of Federal Regulations
small quantity exclusion defined in § 261.5(e)..
[ COMMENT: FOR THE CONVENIENCE OF THE REGULATED COMMUNITY TH
-RIMARY HAZARDOUS
PROPERTIES OF THESE MATERIALS HAVE BEEN INDICATED BY THE LETTERS T (TOXICITY), AND R.
(REACTIVITY). ABSENCE OF A LETTER INDICATES THAT THE COMPOUND ONLY IS LISTED FOR ACUTE
TOXICITY, WASTES ARE FIRST LISTED IN ALPHABETICAL ORDER BY SUBSTANCE AND THEN LISTED AGAIN
IN NUMERICAL ORDER BY HAZARDOUS WASTE NUMBER }
‘These wastes and their corresponding EPA Hazardous Waste Numbers are!
Mazardous | Speuacts Substance
Wo
pas [Tor00 [Ronan aioe
Pooz 591-08-2 Acetamide, N-(aminothioxomethy!)-
post | 9-7 | enn ve
poss [e078 [Reno ro satan
oor so-082 [amy tiwren
po0s [sor 08 asobin
pore fneaes [are
aos 16a8a84 | naar stone
poo | so8-002 [wer
pos [ror [Aina
0s) 0886-73. [Auman hose AT)
ee ee
pos (seas [sannopine
Poos 131-74-8 Ammonium picrate (R)
Prig| 7008-656 [Anon vrate
oes [s0e.i-8 [genate( beyano Opals
pow [rire sea |reenc ats 80,
oie wares [Nemonte Ano,
ee
orn | 08282 | Aone pein
poe [wars | wemictnaie
poss [osea.2 [wane ao
poss [6062-8 | penn ie phon
poss | 6-864 [Aare
post [16868 [parne ma
ows |sae-se1 _|eomeynde
pas [1067-8 | Bonsante, Saar
rorr [1000-8 | beerarine, ve
pos [100.7 | Bonzo (ert
Pod 51-43-4 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, (R)-
pois [1220-8 Bozoeatonarie, be abe det
pote [108985 |Bonereia
iar [1680-882 | 7Benatranal 23 anyaro 22 Greys webyarbanala
rice favour | Brameaal zoe cede 2g aa Rmirteaem
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Po4s 39196-18-4 | 2-Butanone, 3,3-dimethyl-1-(methylthio)-,O-(methylamino)carbonyl] oxime
roo [sons | get gagiaspee ome atest maven
vo [wors _ [Rarer nes ames aang
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Post 1 7220-8 | odahycro», (tape beta 2abeta abn Saba Seta Theta, Taapha). &
Pos 6051-5 | Dimethoate
046 122-09-8 | alphailpha-Dimetiybhenethyamine
Prat 644-544 | Dimetian
Poar 1534-52-4 [4.6-Dinivo-o-creso,& sats
Poss 51-285 [24Dintrophenol
ozo 88-85-7 | Dinoseb
Poss 152-169 _[ Diphosphoramide, octamethyk
Pm 107-49-3 | Diphosphorc acid, tetrasthytestor
Pose 298.04-4 | Disufoton
Poss 541-587 | Dithiobiuret
Pras 26419-73-8 | 1.3-Dihiolane-2-carboraldehyde, 2.4-dmothyb, O- [(methylamino)-carbonyfoxime
oso 118-297 _ | Endosutan
Poss 145-73.3 | Endothal
Post 7220-8 [Endrin
Post 7220-8 | Endrin, & metaboltes
042 5143-4 [Epnephrine
Po3t 460-195 | Ethanedinitrie
pio 2310622. | Eniidobiot 2c, 2dmetifamino)-N-imebyaming) caronyon
P88 16752-77-6 | Ethanimidothioic acd,N-[(methylamino)earbonyoxy)-, methyl ester
Prot 107-120 __[Ethyleyanide
Pos 151-564 _ | Ethyleneimine
oar 5285-7 [Famphur
oss 7782-41-4 | Fluorine
Pos7 640-197 | Flureacetamide
P58 62-748 | Fluoroacete acid, soaium sak
prs 23422-53-9 | Formetanate hydrochloride
P97 17702-57-7_| Formparanate
oes 628-86-4 | Fulminie acd, mercuryi24) sat (RT)
Pose 76-44-8 | Heptachlor
082 757-584 | Hexaethyltetraphosphate
Pie 79619-6 __[ Hytrazinecarbothioamige
Pose 60-344 | Hydrazine, methyk
063 7490-8 [Hydrocyanic acid
068 74-90-8 [Hydrogen oyanide
Pose 7803.51-2 _| Hydrogen phosphide
060 465.73-6 | Ison
192 11-38-0 _[Isolan
202 64-006 _ | 3-1sopropyoheny! N-methyarbamate,
007 2763-96-4 | 3(2H)-Isoxazolone, 5-(aminomethy)-
P96 1339-36-3._| Manganese, bs(cimethycarbamodithioato-S.S)-,
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Pige 15999.36-3._| Manganese dimethylithiocarbamate.
092 62-384 | Mercury, (acetato-O)pheryk
085 628-86-4 | Mercury fulninate (R.T)
082 62-759 | Methanamine, N-mathyLN-nivoso-
Pose 624-83-9 | Methane, socyanato-
Pore 542-88-1 | Methane, oxpbisichore-
Pita 509-14-8 | Methane, totraniro- (R)
Pie 7570-7 __| Methanettiol tehioro-
pig zoazzene |Metanindenie NNanetnW-f(mahyamine)-crbonyonfehenA
Pa7 17702-57-7_ | Methanimidamide, N.N-cimetnytN-{2-methy+-4[\¢methylamino)carbonylonylphenyt-
ps0 nis2a7 | 2Mehane bencodorahiepn 6.7.8.9.10,10-herachine-15 86860
O59 7644-6 __[47-Methano-iH-indene, 14.5,6,7.88-heplachloro-3a,4,7,7a-lovahyaro-
Pra 2032-65-7 | Mathiocar
066 16752-77-5. | Methomyl
P68 60-34-4 | Methyl hydrazine
Pos 624-83: | Methylisooyanate
Po6a 75.88-5 | 2-Mothylactontie
Port 298-00-0 _ | Methyl parathion
P90 1129-645 | Motolear
P28 Mexacarbate.
Po72 abpha-Naphihythiourea
Po73 13463-39-3_ | Nicke carbonyl
Po73 49463-39-9_| Nickel carbonyl N{CO), (T-4)-
ora 567-19-7 _ | Nickel cyanide
Pore 557-19-7 | Nekeleyande N(CN),
Po75 184.11-5 | Neotine, & sats
a7 10102-43.9_ [Nic onde
Po77 100.01-6 —[peNitroaniine
Po7a yoro2.4a.o | Nitrogen dioxide
Po76 10102.43-9 | Nirogen oxide NO
Pore 10102-44-0 | Nirogen oxide NO,
oat 55-63-0_| Nivoglyoorine (R)
P82 62-759 | N-Nirosodmethylamine
Poss 4549-40-0 | N-Nirosomethykinylamine
08s 152-169 [ Octamethyloyrophosphoramide
Po87 20816-12-0 | Osmium oxide O50, (T=4)-
087 720816-12-0 | Osmium tetroxide
oa 146-733 | 7-Oxabieyco(2.2.‘]neplane-2,3-dicarvonyle acd
Prat 23135-22.0 | Oxamy
ose 56-38-2 | Parathion
Pos 131-685 | Phenol. 2-cycoheny+4.6-dintro-
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Pode 51-28-5 | Phenol, 2,4-initro-
Poa7 1.534-52-1 | Phonol, 2-mothyi-4.6-diniro-, & salts
020 88-85-7 | Phenol, 2-(1-methyipropy!)-4,6-dintro-
Poo 131-748 | Phenol, 2.46-trntro-, ammonium salt (R)
ize 315-18-4 | Phenol, 4-(dimethyamino)-3,5-dimethyt, methykcarbamate (ester).
Pi99 2032-68-7 _| Phenol, (3,5-