01-04-14 - SR - Iit All Streams & Lt-Iit - Phase-Ii - Jee-Main - gtm-4 - Final Key & Sol

NARAYANA IIT ACADEMY
INDIA
Sec: Sr.IIT ALL STREAMS & LT-IIT
PHASE -II
Date: 01/04/14
GRAND TEST-4
Max Marks:360
KEY SHEET
PHYSICS :1) 4
2) 3
3) 3
4) 3
5) 2
6) 3
7) 4
8) 4
9) 2
10)4
11) 4
12)2
13)1
14) 1
15)1
16)1
17)3
18) 2
19)3
20)4
21) 3
22)2
23)4
24) 3
25)3
26)4
27)2
28) 1
29)1
30)2
CHEMISTRY :31) 2
32)2
33)2
34) 3
35)1
36)1
37)2
38) 3
39)2
40)3
41) 1
42)1
43)2
44) 3
45)1
46)3
47)4
48) 3
49)2
50)1
51) 3
52)3
53)3
54) 2
55)3
56)4
57)3
58) 4
59)3
60)3
MATHEMATICS:61) 2
62)2
63)2
64) 4
65)2
66)3
67)2
68) 1
69)1
70)2
71) 2
72)4
73)1
74) 2
75)1
76)1
77)3
78) 3
79)1
80)3
81) 1
82)1
83)4
84) 1
85)2
86)1
87)2
88) 4
89)3
90)4
Narayana IIT Academy
01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4
PHYSICS
1.
Vm 3i
Let VR ai bj
VRM VR Vm
= 3iai bj
VRM3 ai bj
VRM. Vertical
i.e 3 a 0
a3
If Vm 6i
VR1M 6iai bj
VR1M6 aibj
It is 450 with vertical

i.e , 6 a b
63 b
b3
VR 3i 3 j
VR 3 2 kmph
2.
Given vR 36
V 2 369 ; V18V
Equivalent of 6
&9
69 18
3.6
15
5
3.6 and
2
Are in series
So vR
3.
1 8 3 .6
V2
2
V2 10V
x 3t2t3
V1
R1
V2
R2
When x is maximum dxt 0 d

d
x
t3t 2 0
dt
6t 3t2
3t 6 t2
x 0. 3t 2 t3
t 3 s ec
When t 4sec
maximum x
x 348
4m
x 316 6416m
Sr.IIT ALL STREAMS & LT-IIT_JEE-MAIN
Page 2
So distance travel . 4 416 24m

4.
P1000kw103103 J / sec
Energy in one hour 1063600J
36108 J
mass decay E2 36106 8
C
9101
410 kg 40g 8
5.
PE at the top of the inclined plane

= work done against friction
mgh mg L cosmg L
cos
hL
cos1
13 2
h cos
3
L
2
3
s
i
n
cos 2 tan
2
6
.
E l El 1
l 5 3l / 2
l 2 l1
53
l1 3l
10
F ks1/3
7.
m d ks1/3
dt
m d ds ks1/3
s dt
m d ks1/3ds
ds
m ks 2
2
2/3
1/3
s
2/3
P FV
P s1/3s1/3
P s0
8.
9.
8q 2q
x 2 x L2
2 1
x xl
2 x 2L x
x 2L
F f Ma translational motion

FR fR I I a Rotational motion
R
F
I 2 MR 2
5
F f Ia2 (1)
R
F f Ma (2)
Solving
a 10 F
7
M
10.
Mean square value2
v dt
dt
For T
4
v at ( up to T/4increases with time)
At t T / 4, V v0
v0 aT
4
4v0
a
T
T /4
v2dt
Page 3
t 2 dt
T /4
dt
dT
16v2t /
30
0
T /4
T /4
T
V0 2
3
v
v0
r
m
s
11.
Equation of the particles are

x1 Asinwt
x2 Asinwt
When they meet AsinwtAsinwt
2Asinwt / 6 0
wt 5
6
t 5 5T
5T
t
6
Page 4
6w 6.2 12
Altier
A to A T
01/04/14_ Sr.IIT ALL STREAMS &
LT-IIT _Phase-II_JEE-Main_GTM-4
They meet at the mean position

-AA 0 T so T T 5T
4
12.
4 6 12
No.of beats 220 10

If tuning fork frequency is n.
n10 10.2 n
1
0
9
.
2
n
194Hz
dF
Gm.dx
x2
Gma bx2dx
dF
x2
la
F= Gm xa2 dx Gmb dx
dx
=
Gmax 1
Gmbl

Gma 1 1bl
1
4
.
l
I4
x
I0 cos2 / 2 3 I0
4
cos
/ 2 3
2
/
2
3
0
60
x 6
As it is formed between 5th maxima and 6th minima

x
5 31
6
6
31t
6
31
t 3
2
1
15.
substituting t=9.3m
When separation occurs

2
mg m r
g w2 r
Page 5
r g2
w
T1sec , w 2
r g 2 1 0.25m
4
4
16.
surface tensional force wt.of the liquid column

2 d1 d2T d2 d1hg
2
2
4T
h
d2d1g
17.
4R2x
4R3w
3
R
x
w1
x R
3
18.
19.
2 2
h r w 25104222 m 0.02m
2g
210
T
2m1m2g
m1 m2
S T2
2.m.2mg
3
m
r 4mg
3
s
20.
Stoping potential 1.1V

i.e. KEma 1.1eV
h
w0 KEma
4000A0
12400 w1.1eV w 2eV

4000
T
s
21.
0 12400 6200A0 620nm

2
at at 2
d e a 2at
dt
2
dt e dt R
H P
H
0
1a
2at2 dt
R
1a22 4a t 4a . t
2 3
2 0
Page 6
1a23 4 a23
2a23
3
R
a3 43 23
3
R
a 413
R 3
a3 2
3R
22.
In FM Band width is less
23.
Boi0 e
2
2r T
T r
3/ 2
r
Br13/2 15/2
.r
r
rn 2
24.
B 15
n
Voltage gain = Av V0IIc

Roi v
5mA
6k50
A 600
in
bR
=1000
25.
After two hours

F
o
u
r
h
x : y No : No 1 : 1
22
ours
o : 3 No 1 : 3
4
4
Six hours 8 8
No : 7No1: 7
26.
Here it is 1 : 4
So t > 4 hrs
If u x
< 6 hrs
10 x
f12cm
11 1
u
f
1 1 1 solving
x 10 x 12
u x 20cm
30
M 1 5
M v / u 1.5
2
7
.
Y A BA
B
A B A
B
AA AB AB BB
O AB AB O
Page 7
2
8
.
AB ABOR gate
dQ mSdT
dQ
mA T
dt
20
= mA T4
2
9
.
mA204 mA16104 4mA104

4
4
h R 1 2 12
n
1
R n2n 2n21 if n >>1

nn1
R42n 13
n
n
3
0
.
Initial int ernal energy 4CvdiaT 4 5R T

2
final int ernal energy 2Cvdia T 4Cvmono T
2 5 R T 4 3R T
1
R
Then Q11RT10RT RT
CHEMISTRY
31. Volume strength 5.6 Normality

32.
M gBr
COOM gB r
C OOH
Mg
CO2
33.
H2O
5 f 14, 6d 3 Total 17e

5 f 14 (n l) 5 3
8
34.
35.
6d 3 ( n l ) 6 2
8
Page 8

CH 3
CH 3
CH 3
Br
Br
r2
Sn/
HCl
HB
NO2
NO2
NH 2
(B)
(A)
C
O
O
H
CH 3
CH 3
Br
B
r
MO
K n 4
(E)
O
H2
OH
Br
(D)
H3 2
PO
2-bromobenzic acid
2Cl
(C)
36.
V H 2 V He 1 1
H2He
R 12 12 Rz2 12 12
n1
4
n2
n1 1 &
n2 2
39.
Vender wall's equation for 1 mole gas is p a2 (v b) RT
AT low p,
volume is
High. so (Vb)=V
p a2 v RT
(or) PV + a RT
V
PV RT a
V
40. Work done 1 (4P1 P1)(3V1 2V1)

2
4
4
.
= 3 P1V1
It is a basic buffer
pH = 8.65
pOH 14 8.65 5.35
POH=
pkb
log [NH4 ]
[NH4OH ]
Page 9
5.35 = 4.75 log [NH4 ]
[NH4OH ]
[NH4 ] anti log(5.35 4.75)

[NH4OH ]
[NH4 ] 0.2 30 4
[NH4OH ] 0.3V1
V= 5 ml
45. 1-alkyl halides follows SN2 path and walden Inversion takes place
46. B2H6+6H2O 2H3BO3+6H2
3B2H6+6NH3a0b0o
2B3N3H6+12H22vCe
4
7
.
A2B3 2A3+ + 3B2-
Ksp 108x5
4 58.5g - No. of unit cells 61023
1 gram = ?
48.
1 61023 2.561021
458.5
Al2(SO4)3 2Al3 3SO42
0
.
Initially let
After
1
1
i 1 2 3 4.2
1
1 4 4.2
4 3.2 3.2 0.8 80%
4
TfA 2
52. Given
1 e
TfB 1 1 / 2
B should associate to show lower inT
54. Cell reaction : 2Fe3++Fe 3Fe2+

E0ell 0.77 (0.44)1.21 spon tan eous c
Fe3 & Fe will reduce
55.
Al3++3e- Al
1 mol Al = 27g = 3F
13.5 gr of Al = ? F= 1.5F
Page 10
57.
Order with respect to A 0.03x 45

5
0
.
0
1
3 3 x 2
x
Order with respect to B 0.02x 5

0.01
2.5
2 2 y = 1
y
Rate = K
A2B1
59.
I order 100%t1/2 50%H2 25%
Given 2t1/2 1hr

t1/2 1 hr
2
28VN2 at STP100
60. %N
22400WoC
28 22.4100 11.2%
22400 0.25
6
1
.
6
2
.
MATHEMATICS
Tr 100cr (51/6)100 (21/8 )r As 5 and 2 are relatively prime, Tr+1will be rational if 100 r
r
r are both integers 100-r is a multiple of 6 and r is a multiple of 8, 100-r is
and 8
multiple of 6 if r = 4, 12, 20 100 of which 12, 36, 60, 84 are divisible by 6. Hence,
there are just four rational terms. no. of irrational terms is 101 - 4 = 97.
2
Z = rei Then
2
12
r cos 3 r
=r=3
3
3
(ei ei )2 1 r3 r2
3 r2
3 max value of |z|
1 cos2
63.
If the lines a1 x +b1 y+c1 = 0 and a2x +b2y+c2 = 0 meets the axes is concyclic points
then a1a2 = b1b2
64.
Sol : A (x1, y1) be any point on parabola y2 = 4x and B (h,k) is its image w.r.t
x-y+13
h x1 k y113 0
= 0 then
k y1 (1)1 x h13, yk13

1
hx
1
h132 4k13
65.
66.
and
Formula application
Taking the coordinates of vertices O,P,Q,R as (0,0), (a,0), (a,a), (0,a) respectively we
get the coordinates of M as a, a and of
a ,a
N as
Area
2 h 2 ab
.
68.
Shortest distance is 0.
69.
foot of the perpendicular A (1,0,2) to the line is B 1 ,1, 3 /
2
Page 11
70.
we find dxt when x 1 and y 23 given that dyt3 units/s and x2 y2 1

d
Differentiating x2 y2 1, we have 2x dxt 2 y dyt 0

d
Putting x 1 , y 23 and dyt3 , we have 1 dxt 23 (3) 0 dxt 3 3

2
L
t
7
1
.
Clearly
x
0
1
1
x x
xe
2d
0 f0 Continuous at x = 0
1 1
x x
L
t
x
e
L
e
t
L
t
x
Lt
x0
x0
x0
x0
1 1
x x
fx f0 Lt xe
x0
01
x0
0 = Lt
x0
Not differentiable at x = 0
72.
1 , 1 are the roots of cx2 bx a 0
cx 2 b x a c x 1 x 1
e2 / x 0
73.
T : x -x = 0 is integers reflexives y - x is integer symmetric (x-y) + (y-z) = x -z is

integers transitive T is equivalence and S : y - x = 1 x - x 1 not reflexive.
cos
7
4
.
x dx cos2 x cos2x dx
1 a
1 a x
0
/2
1 ax
cos2 x dx
cos2 x
dx2
75.
[2sin
(1)dx
(2)dx
(2)dx
x]dx
11
2
(1 )dx
11
6
dy x2 xy y2 is a homogeneous differential equation, put y = vx.
6
.
dx
7
7
x2
We have ex cos xdx 1 exsin x cos x2
.
Therefore, I x. 1 exsin x cos x
2
exsin x cos xdx e

2
x exsin x cos x 1 excos x sin x dx

2
2
x exsin x cos x 1ex cos x c
2
78.
1 ex x sin x x cos x cos x c

2
from truth table pq p p p q
We have
9
.
100
c50 100!
50!50!
sin xdx
Page 12
The exponent of 7 in 50! is57050 71 8
72
And the exponent of 7 in 100!

10017020 14 2 16 ,
Thus, exponent of 7 in C50 is 16 28 0 100
80.
total no of ways of answering is 15. Out of 15 combinations only one is correct. The
probability of ticking the answer at the first .. is 115 , that of 2nd is 14 .114 115 and that
of 15
third is 14 .13.113 115 probability that the student will get marks for the question if
15 14
he is allowed into 3 chances

3115 1 .
8
1
.
Let f x x 2ax a a 3 0
Then (i)
(ii) sum of root <6
(iii) f3 0
82.
b 2ac ; c 2bd
ac
bd
c
(a c)(b d) 2ac . 2bd 4 ad ab bc cd ad 4ad

b
x
2
8
3
.
84.
i
1
400
n 16 hence, possible value of n = 18.
80
n
n
n
cot tan m sec2. m tan1
sec cos n tan2. n sec2
tan2 nnm2
1/3
from (1) & (2) similarly sec2 mn2m1/3 eliminate

85.
8
sin1sin 3 3
sin1sin 4 4
AD 2BC x 2
sin1sin 5 5 2
sum2
xy 4
CF 2BA y 2
E
87.
for no solution or infinitely many solutions

1
1
1
1 012 2 0
1
1,1, 2
but for = 1, there are infinite solutions when = -2, we have

2 x y z 3,
x 2 y z3 x 2 y 2z3 adding 0 = - 9, which is not true no
solution.
Page 13
88.
AA ' I
0
0 1 0
0
00
1 0 1 0
0 0 1
0 0 0 1
0
0
1
0
0 1 0
0
(-1, 2)
C (2 , 1 )
89.
01
The two shaded areas are congruent

Area = The area ACEF
1
area of circleOAD
4
9
0
.
5 1 5 2 .
42
4
2
2
Differentiating x 2 y y c, 2x 4 yy1 y1 0 2x4y1 y1
Replacing y by 1 , 2xdy 4y1

y1 dx
44ydy1
2
dxx
ln4 y1 lnx ln c1
2
4 y1 c1x2
y cx2 1 , 4c c1.
4
Page 14

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