Professional Documents
Culture Documents
Table of contents
CHEMISTRY OF SACCHARIDES
Objectives
Introduction
History of Sugar
Uses and Applications of Sugar
Properties of Sugar
I.
Physical Properties
II.
Chemical Properties
Raw Materials for Industrial Manufacture of Sugar
Sugar Mills in the Philippines
Sugar Substitutes
Manufacturing Process
I.
Industrial Sugar
a. Manufacturing Process
b. Process Layout
c. Equipment Layout
II.
Refined Sugar
a. Manufacturing Process
b. Process Layout
c. Equipment Layout
By-Products of the Sugar Industry
References
OBJECTIVES
General objective:
CHEMISTRY OF SACCHARIDES
Specific objectives:
To present the history of sugar, uses, properties and sugar mills in the
Philippines
To identify major and minor sources/raw materials of sugar
To identify the step by step process of manufacturing industrial sugar
To enumerate and evaluate the step by step process of manufacturing
table sugar
SUGARS
Carbohydrates, sugar and starches are the most widely distributed and
abundant organic chemical on earth. They have a central role in the metabolism
of animals and plants. These serve as the basic food, accounting for a large
CHEMISTRY OF SACCHARIDES
400 B.C
10TH CENTURY A.D
1493
1600
1747
1800
EVENT
Ancestry of sugar cane traced in New
Guinea, migration to the southern Asia,
Indonesia, Philippines, Malay, Indochina
and eastern India
Knowledge of sugar prevalent in India
Sugar cultivation and manufacturing had
become important industries in Persia
and Egypt.
The early Islamic movement spread the
knowledge of the sugar industry
throughout the Mediterranean sea
Christopher Columbus took the sugar
cane to the Caribbean islands of Santo
Domingo for trial planting
The sugar industry was the largest in
tropical America; sugar was then treated
as luxury. Referred to as white gold
General chemist, Andrea Sigismund
Margraf and his pupil Achard, established
that sugar from sugar beets was the
same with sugar cane
Sugar beet had replaced sugar cane as
the main source of sugar in continental
Europe
In the Philippines, the industry of sugar started two to four thousand years
CHEMISTRY OF SACCHARIDES
before the Christian era wherein vessels from the Celebes came to Mindanao with
sugarcane cuttings. According to Spaniard writings, in 1521 when Magellan
arrived, Filipinos already know how to extract juice from the sugar cane but
through a primitive way.
USES/APPLICATION OF SUGAR
1.
Food-Sugar is now a highly valued food and sweetener and also serves as
an edible preservative
2.
3. Aid for dehydration -Table sugar can be used to make oral rehydration
solution (ORS), which can help prevent dehydration in children who have
infantile diarrhea or vomiting in developing countries.
5.
Hair removal - Sugar is used for hair removal, in a practice that is thought
to date back to the ancient Egyptians. A warm paste of sugar, water and lemon
juice is applied to the skin. Strips of cloth are then pressed over the paste and
torn off quickly, taking the hair with them. Sugar is also used in soap-making and
as an abrasive scrub to exfoliate skin.
CHEMISTRY OF SACCHARIDES
6.
Chemical Properties
Antioxidant Activity
Sucrose has been reported to exhibit antioxidant properties
which help to prevent the deterioration of textures and flavours
in canned fruits and vegetables. These effects may be partially
attributed to sucrose's ability to lower water activity.
In addition, the products of the hydrolysis of sucrose (glucose
and fructose) appear to have the ability to block the reactive
sites of ions such as copper and iron and, to a lesser extent,
cobalt. This characteristic of monosaccharides aids in food
preservation by impeding catalytic oxidation reactions.
(C12H22O11)
CHEMISTRY OF SACCHARIDES
RAW MATERIALS
Major sources
SUGAR CANE
(Saccharum officinarum L. ) is a member of the
grass family (Poaceae) and is widely cultivated,
providing around 70% of the worlds sugar.
Sugar cane yields the highest number of
calories per unit area of cultivation of any plant.
It contains 11 to 15% sucrose by weight.
Description:
Overview: A tall grass, which looks rather like a bamboo cane, and grows
3-6 m high with culms (stems) 20-45 mm in diameter.
The thicker-stemmed forms are commonly known as 'thick' or 'noble' canes
CHEMISTRY OF SACCHARIDES
SUGAR BEET
(Beta vulgaris) is a large pale brown
root crop similar to parsnip, and has a
sugar content of 16% when it is
harvested. It grows in the temperate
climate of Europe and North America.
Sugar beet differs from the ordinary
table beet in that it is much larger and
is not red. Sugar beets contain 13 to 17 %
sucrose and 0.8% ash.
Description:
The sugar beet has a conical, white, fleshy root (ataproot) with a flat crown.
The plant consists of the root and a rosette of leaves.
Minor sources
1. Maple tree
2. Sugar palm trees
CHEMISTRY OF SACCHARIDES
3. Insects
4. Sweet sorghum
SUGAR MILLS IN THE PHILIPPINES
1. Central Azucarera Don Pedro Inc. (Region IV-A)
Lumbungan, Nasugbu, Batangas
Capacity: 12,000 TC/day
2. Biscom Inc. (Region VI)
Brgy. San Vicente, Binalbagan, Negros Occidental
Capacity: 14,000 TC/day
CHEMISTRY OF SACCHARIDES
10
RSB,
Lacarlota
city,
5.
Acesulfame-K
Is
the
potassium
salt
of
6-methyl-1,2,3-
oxathiazin-4(3H)-one-2,2-dioxide.
Discovered
Alitame
Is a sweeter based on amino acid. It is a
very
intense
sweetener,
possessing
Aspartame
Cyclamate
4.
I.
-
INDUSTRIAL SUGAR
Raw sugar or the sugar that does not undergo the refining process
EQUIPMENT
PROCESS
Washing
At the mill, the cane must be clean
as possible. Truck loaders unload the
cane into a receiving table and into a
conveyor belt that takes it into two
phases of water
Shredding
The washed cane is then
into cutters to decrease
make shredding easier.
passed to a shredder
decreased the bulk size
Milling Train
transported
the bulk to
It is then
to further
Milling
Shredded can passes through a
series of roller mills to extract the
cane juice. The bagasse or cane pulp
and the raw cane juice is collected.
Filtration
The raw cane juice is filtered to
remove any unwanted particulates. It
is then clarified for quality purposes
Evaporator
Evaporation
The juice is reduced via evaporation
of
moisture
to
increase
the
concentration of sugar by up to 60
percent
Crystallization tank
Crystallization
After evaporation, the resulting
concentrated
cane
juice
is
transported to a crystallization tank,
where seed crystals are added to
induce crystallization.
Centrifuge
Centrifugation
After the crystallization process, it is
to
Drying
The crystals are then dried and then
stored, ready for distribution
II.
Refined Sugar
Sugar cane is the most common raw material used in the production of
sugar. It grows in almost all types of soil, from sandy loams to clay loams and
from volcanic soils to calcareous sedimentary deposit s. At least 17 provinces
located in 8 regions of the Philippine archipelago have grown sugarcane
crops, of which the two on Negros island account for half of the countrys
total production. As of Crop Year 2009-2010, 29 mills are operational divided
as follows: 6 mills on Luzon, 13 mills on Negros, 4 mills on Panay, 3 mills in
Eastern Visayas and 3 mills on Mindanao. The harvest period is from October
to December and ends in May.
B. PROCESS LAYOUT
EQUIPMENT
Affination Centrifuge
PROCESS
Affination
The first step in refining is removing the adhering
film of molasses from the crystals of raw sugar by a
washing process known as affination. This is done by
mingling the raw sugar with hot raw syrup in a large
trough containing a mixer paddle and scroll. Surface
impurities (molasses) dissolve in this syrup are
removed. The affination process yields a palecolored sugar, which is discharged by ploughs into
continuous- melter tanks.
Melting Tanks
Melting
The washed sugar is melted in hot water in the
melter tank where it meets a stream of hot sweet
watersfrom the process. The melted liquor is
strained through a plain screen to remove insoluble
debris.
Clarification
The melted sugar liquor is then purified, utilizing
either the carbonation or phosphatation process.
These processes trap suspended impurities in larger
particles which are easier to separate from the sugar
liquor. It is the complete removal of the undesirables
Bleaching Unit
Decolorization
The clear but tan colored sugar solution is pumped
through a series of columns containing an ion
exchange resin which absorbs the remaining color to
produce a clear and colorless solution known as fine
liquor.
Crystallizer
Decolorization
Thick liquor is transferred to boiling vessels known
as pans where under controlled vacuum the liquor is
boiled at low temperature to further concentrate the
solution. As water evaporates and the liquor
concentrates, sugar crystals begin to form,
their growth being controlled by careful
adjustment of the boiling conditions. When the
crystals are large enough, the crystals and syrup are
discharged from the pan. This mixture of crystals
and syrup is called
"massecuite".
Granulator
Drying
The refined sugar crystals are dried by tumbling
them through a stream of air. The dryers are called
granulators because they rotate and keep the
crystals from sticking together.
C. EQUIPMENT LAYOUT
Filtration
The most-straightforward, probably the oldest form of sugar liquor
clarification process. Carbonated liquor (solution) is pumped through a series
of leaf filters which retain the calcium precipitate in the filter and discharge a
clear but colored sugar solution.
Molasses
is the final effluent obtained in the preparation of sugar by
repeated crystallization. The sugar it contains cannot be removed
economically. The molasses from cane sugar is most commonly known
as backstrap and that from beet is called beet molasses. Molasses is
mainly used for the manufacture of ethyl alcohol (ethanol).
2.
Bagasse
a fibrous residue of the cane stalk that
is obtained after crushing and
extraction of juice. It consists of water,
fiber, and relatively small quantities of
soluble solids. Bagasse is usually used
as fuel in the furnaces to produce
steam in sugar factories. It is also used
as a raw material for production of
paper and feedstock for cattle.
3.
Mud
The material removed from the filters
during clarifications of the juice
contains the settled insoluble solids.
The mud is returned to the fields as
fertilizer. Some sugar factories extract
a crude wax from the filtered mud,
which is used in the manufacture of
polishes.
4.
Pulp
The pulp produced after the extraction of sugar is pressed in screwtype presser to remove water. The pressed pulp is enriched by the
addition of molasses or concentrated steffen filtrate and is dried in
rotary driers. Molasses dried beet pulp is an excellent cattle feed.
REFERENCES
Ali, Mohammad F. (2005). Handbook of industrial chemistry: organic
chemicals
Riegel, Emil R. (1983). Riegels handbook of industrial chemistry, 8th
ed.