Chemical Engineering 317 — 2016: Additional Notes Topic 3 class examples not in Dahm and Visco Example 3.4: 2015 Tut test 1 Consider a turbine and the work that it can deliver. A 236.67 kmol/h gas stream enters the turbine, The stream contains 2.11 % Hz, 71.13 % Nz and 26.76 % NHs (mole basis) and it enters at a pressure of 413 bar and a temperature of 250 °C. Assume the gas is well described by the equation of state given below (Note, although very similar this is not the SRK or Redlich-Kwong equation of state), (@) Your thermodynamics textbook gives you the following general expression for the residual enthalpy for a pressure explicit equation of state: Hre® = fo, Derive the above equation from first principles. Only thermodynamic definitions, fundamental property relations and Maxwell equations can be used as is. [18] (0) Develop an expression for the residual enthalpy, in terms of temperature and volume, for conditions where the given equation of state is valid (13) (C) What is the specific volume (in m3/mol) of the inlet and outlet gas stream if it is assumed that the given equation of state is valid? The outlet pressure is 70 bar and the outlet temperature is 70 °C. (15) (d) How much work (in kW) can expansion Cee [6] ci hi a 76 Tere where Pe Omix = LiL) YiYjaij where ayy = {fajay a Dynix = Li yiebi Ques tion(ay He F(T, PD => di = (QH\ dP + oH) dT Gr, . ($1, ® Fundamental property relation. dH = Tdg + vdP * Boke TGR Moxwel M8) _- Gi, °F). v Page 1 of 7OH) oo 7 PX Substitute ® unt @: d= G#),0" + (v- TGR) er But, For residuals, Tis censcant -0 dT=0 = eee oe ) > dd =(v 1(32), ) dP peer eee) Residtial enthalpy UE— = Hyp ~ His 7 (H5,0 - Are 20) 7 (Hr ~Hy,e-0) But at P=0 the Fluid behaves Kte an ideal gas. Aeldittonaly, Une enthatpy of cn idecl gas is pressuute dependent . The last term uy above equation is Unis 2D > Ube = Ure - ree Unteg rate equation @ freur P- % to P-P e » Ure = Spo (v (&),)e __— put P= f(T) => dP = (22) aT + (2) dy. av ly av lr ASMSiduUals are at combant T, dT teem falls away aP = (2) av Wr SubseMUle unto G curd change integration Units P20, Ve , PEP, Vev He {4 (8 “1@4),) (),% + Mow (Y Gale -* GF) ( So) (Gz), +1 GA.) —__© *\ovJy * ! \or Ve yy “vem Question (0): GOS! P= he _ 4 vb ” Vr) ca . _&T_ _ =o _ 4 IIT (u-bR V7(urb) — v(v +b)? Page 2 of 7v (5). * Tl a wv), @-b)2 Var * Wee —— © ay 2 RL apy. or < GH, yo Te V0 —e (OP) yey = RT er CW: Verh 5th? webs Wb viveb)* Es vo» _@ -RT A. B ace _ AL Conside Vo Vb * WF oy > RTV = AV-Ab+B => A=-RT, B=~-RTb ~» -8TV_) | -RT _ Rb (w-b)* ~ Wb) W-by @ a _¢c, Dd Consider (aby avs ae - O=Cv+Cht oy weed, o- $ a a a ee ©) W+bv py b(v+by —____9 Subsntute @ and @ mw®: (oP OU ei a RO a4 (Clare v5), 157), (v-b)” -oF * by ~ be rb) * Goh" Vb Rib rit q@ a a ~v-oy oy ~ BU) * DF — Subsnitutd @ unto © : R pv Rt q a oad " wr wa (Uy be ~ vue)” wo) oY y Rb . Vayfv \_ 4 v + y- -b) 5 Eo) vi+tb Ike aoe _ a v-b > inlay) ~ O45 Guesuicn ©) : E0%: P= eT _ O mix - BOS. Pee Dam” Ven Wn + Dain) Need values for Ame and bax Page 3 of 7Oma = BO Acxy ay = UPAn + AF Mae + LF gs 4 2X2 Met 2 Us %z Aat2Aes bmx = Dax bi = Yb, + X2bs +X3 ds Te ‘ Gwen a au =0.42a¥s SE ond ay -aiay am Pawe and bi = 08oe4 en bin inet, Q) = Qu = 0.02441 on = 0.053647 bi = 820764 = hg = DABEH) Quy = 0.10334 Da 2, 67 ES 7L5qO1 E-5 a a, 2033 2 G-43ib Aw = oO. 244249 3 => Cui = 019084 , bmx = 2,6335€-5 Inlet: P2uIZ bar =UIZEFPa, T= 250°C = 523.15k USING EOS MED Ainm GNA vin =D Vinx > 1.OU4 E-Hinge OulleL: P= TObarz FEGPa , T= FO = 343,15K => Vins ous = 3,676 EE MB 7 met Questicn (d) W-N- Ad Od AH = HE -HR + SP ACRAT van cae WU Vein Calouatid th (cd: -TAT. 15 Vine ye = = ~ 2182. bo Ymot SE Cp9dT = Ce mic AT AS CoS Is T ende pendent CHI ome = SEL CD = 36.51 Het.) » (BopsdT = -6592 3 iy Pw = 236.04 «(9492.46 —(-11F.99) - 53 Bree x(-2182.60 —(-1 )- 09723) =-U62 SKN = 4o2 kw delivered Page 4 of 7Class Example 3.5: Example 3.4 (c) using compressibility charts Consider a turbine and the work that it can deliver. A 236.67 kmol/h gas stream enters the turbine. The stream contains 2.11 % Hz, 71.13 % No and 26.76 % NH; (mole basis) and it, enters at a pressure of 413 bar and a temperature of 250 °C. ‘What is the specific volume (in m?/mol) of the inlet and outlet gas stream? The outlet pressure is 70 bar and the outlet temperature is 70 °C. Use Kay's nue te get Mdticed properties. However, Hz Needs ct Temper tere depencence evinectton 43.6 20.5 bar ho pHee Oe ee Tein Ky Pe Dew CT 1+ 2G Oe oe 6 oir) = Using Above and values th Dam + Visco Hainer Heater No Ni3 Maxine Mx adet % ~ Oo2il GQ 6.7NZ 0.2676 Tek) 42.4 42.3 (26.2 Yow. 194.4 19946 Pe(UPa) 1,44 1,93 3393 41.27 54a 6.49% 2 -G.21 - 0.2) 40034 0.252 0.0882 0.0882 Unt: Tee Yre = 523.18 /ag.ya = 2.62 Poe Ye = 3/5.4% = 7.b4N fram Charts. 2° = 1.0F na see 5o opp ft? “arte = 1.488 Fram Vi = 2RYp Vo in = | 1oT E+ Znet Outel: Tr = 1,42 , Pr= 1,299 cu Charts ena oe de 0.939 3 > Vmnm,our = 3,829 €-¥ Ymee (Kay's (ule: Mun = ShareMe ) Page 5 of 713 cueet inte ae I L uw 1 09 0.8 |. a in | Jyepor tie 06 b= 0s - 04 I eo i | 02 - ot . - 08 ° 0.01 on FIGURE 7-14 Compressibility ‘equation. 1 factor for a compound with @ = 0 for F use in the Lee-Kesler Out ine 03 FIGURE 7-15 Compressibility correction factor for a compound with a = 1 for use in the Lve-Kesler equation. Page 6 of 7Example 3.6: Example 3.4 (d) using Lee-Kessler Tables Consider a turbine and the work that it can deliver. A 236.67 kmol/h gas stream enters the turbine, The stream contains 2.11 % Hz, 71.13 % Nz and 26.76 % NHs (mole basis) and it enters at a pressure of 413 bar and a temperature of 250 °C. The outlet pressure is 70 bar and the outlet temperature is 70 °C. How much work (in kW) can expansion of the gas produce? Use Tem, Pew And Wm Oi for Fx .3.5 Consicler the Lmet: T= 2022 , Pr = 4.944 USING double Unear Unterpelation : HE AQ Te) = -0.4543 H/ (R.Te) = 40.4066 DYR/(R Te) = ~ 6.9543 + 0.0882+ (0, 7066) = - 0.6920 = Hears -0,0120% 8.34199 YF = 1149 Soy Consider the Mbt Te i420, Pre |2a¢ HORT) = = 0.4934 HPP TZR TE) = 40.0519 > HART) = -0.4689 Mus 45 Be Freud VAMUPIE 3.4 AWS = - 6592 inet, Aus HR- Ye + AM'S = (-799.5)-(-1149) - 6972 = -b2602 Wen dH= 256-64 (6202) = ~403. 9 MO 3600 =) YOR KW delivered Page 7 of 7