Professional Documents
Culture Documents
Separation process - I
(Mass Transfer)
8/11/2015
8/11/2015
Liquid Liquid:
Extraction: Sep. involving contact of two
immiscible liquid phases. Mix of
(Acetone+H2O)+CCL4 rich phase (CCl4)
containing large amount of acetone and other is
lean phase.
Fractional extraction:
Sol. of (HAc+Acetone) + insoluble mix. of (CCl4+H2O)
shaking & settling two phases, each containing HAc
and Acetone, but in different proportion.
Two liq. phase sol. may be produced from a single
phase sol. by cooling the later below critical sol. temp.
(CST). Two phases will have diff. comp.
Liquid solid:
Fractional crystallization: all constituents are
present in both phases at equilibrium.
Leaching: selective solution of a comp. from solid
mix. by a liq. solvent. Ex. leaching of gold from its
ore by cyanide sol. and of cottonseed oil from
seed by hexane.
Adsorption: Removal of color material which
contaminate impure cane sugar can be removed
by contacting liq. sol. with activated carbon.
8/11/2015
Membrane Separation
Gas Gas:
Gaseous diffusion/ Effusion: Microporous membrane is
used. Doff. comp. of the gas passes through pores by
diffusion, the rate of which depends on molecular weight
Permeation: non-porous membrane solute first dissolve
in the membrane and then diffuses through it. Sep. of He
from natural gas by selective permeation through
flourocarbon polymer membrane.
Basic concept
Equilibrium: There exist for all combination of
phases a condition of zero net interchange of
properties (usually mass or energy, in chem.
eng.)called equilibrium.
Driving force: For all such combination not in
equilibrium, the diff. in conc. of some property
between one in existing condition and one that
would exist at equil. cond. is a driving force
tending to alter the system toward equil. state.
8/11/2015
Flow pattern:
co-current
counter-current
8/11/2015
Molecular diffusion
Concentration difference or chemical potential
difference
Pressure diffusion
Motion of solute resulting from pressure difference
Thermal diffusion
Motion of a solute due to thermal (temperature)
gradient
Forced diffusion:
Motion of A due to unequal external forces on A and B
8/11/2015
=Molar flux
8/11/2015
Some relationship:
+
+
=1
=1
+
=
=
=
=
+
+
+
8/11/2015
Concentrations
Velocities
8/11/2015
and
=
Ficks law of diffusion for constant total concentration
(c),
10
8/11/2015
11
8/11/2015
12
8/11/2015
13
8/11/2015
14
8/11/2015
15
8/11/2015
16
8/11/2015
17
8/11/2015
18
8/11/2015
Problem:
O2 (A) is diffusing through CO (AB) under s.s. condition with CO non-diffusing. Total
pressure is 1105 N/m2 and temperature 0oC. The partial pressure of O2 at two planes
2mm apart is respectively 13000 and 6500 N/m2. The diffusivity for the mixture is
1.8710-5 m2/s. Calculate the diffusion flux of O2.
Solution:
Here,
=
= 1.87 10
= 27
= 13000
= 10
,
, = 0.00
=
= 8314
= 87000
.
.
= 6500
93500
=
= 90200
= 2.97 10
19
8/11/2015
Problem:
Recalculate the diffusion of O2 (A) assuming that non-diffusing gas is a mixture of CH4
(B) and H2 (C) in the volume ratio 2:1. The diffusivities are estimated to be
=
1.86 10
&
Solution:
Here,
= 90200
= 6.99 10
So,
=
= 3.91 10
Problem:
Water at 25oC is flowing in a covered irrigation ditch below ground. Every
30m, there is a vent line 2.5cm inside diameter and 30cm long to the outside
atmosphere at 25oC. There are 10 vents in 300m ditch. The outside air can be
assumed to be dry. Calculate the total evaporation loss of water in kg/day.
Vapor pressure of water at 25oC is 23.76mm Hg and diffusivity of water vapor
through air at 25oC is 0.26 cm2/s.
Problem:
A spherical gas bulb of volume 500cc contains air NH3 mixture in the
volume ratio of 4:1 at 40oC and 1atm pressure. It is exposed to the
atmosphere at the same temperature and pressure through a capillary of
length 5cm and diameter 1.0mm. If this gas bulb is left open as such, find the
ammonia concentration in the bulb after 15 minutes. Given: DAB for air NH3
at 0oC and 1atm pressure is 0.19810-4 m2/s.
20
8/11/2015
21
8/11/2015
22
8/11/2015
23
8/11/2015
24
8/11/2015
25
8/11/2015
26
8/11/2015
27
8/11/2015
28
8/11/2015
29
8/11/2015
30