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KEBANGSAAN
MALAYSIA
The National University
of' Malaysia
PEPERIKSAAN AKHIR
SEMESTER II SESI AKADEMIK 2012-2013
IJAZAH SARJANAMUDA DENGAN KEPUJIAN
JUN 2013
KOD KURSUS
STKK1032
TAJUK KURSUS
AMALI KIMIA AM
ARAHAN
1.
2.
No.Pendaftaran :
(dengan perkataan)
Kertas soalan ini mengandungi 14 muka surat bercetak, tidak termasuk muka surat ini.
STKK1032
Choose the best answer for each question in this section and mark the corresponding
letter in the OMR form CLEARLY with 2B pencil.
Each question carries 1 mark.
1.
4H3AsO3
H3As04 + 3I- + 2H+
A.
B.
C.
D.
E.
0.167 x 10-3 M
0.503 x 10-3 M
0.1034 M
0.167 M
0.3101 M
2.
I.
II.
III.
IV.
As a titrant
KI improves the solubility of iodine
KI will reduce the analyte
KI as a catalyst
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3.
I.
Which of the following describe the reaction involved in the determination of ascorbic
acid using iodometric titration?
IV.
The iodine is formed by the reaction of excess amount of iodate ion in the presence of
iodide ion
The solubility of iodine formed is increased and oxidised to form triiodide as long as
any ascorbic acid present
Once all the ascorbic acid has quantitatively reacted with iodine, the excess iodine is
free to react with the starch indicator forming the blue-black starch-iodine complex
The removal of blue colour marks the endpoint of the titration
A.
B.
C.
D.
LH, IV
I, III, IV
II, III, IV
I, II, III, IV
4.
II.
III.
A.
HO
B.
HO
HO
OH
C.
HO
D.
HO
E.
HO
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Consider the following chemical reaction to answer questions 5-7.
OH
+ HOH
5.
Which reagent and condition could be used to carry out this synthesis?
A.
B.
C.
D.
E.
6.
A.
B.
C.
D.
E.
Elimination reaction
Subtitution reaction
Rearrangement reaction
Acid-base reaction
Polymerization reaction
7.
I.
II.
III.
IV.
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8.
A.
+ Mn 02
OH
OH
B.
+
Mn02
OH
C.
+ Mn02
OH
0
D.
+
Mn02
OH
E.
+ Mn02
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F
9.
F///
I \\
"'S'"
F
F
F
F
Based on the structure of sulfur hexafluoride shown above, how many pairs of fluorinesulfur-fluorine bonds lies in a straight line?
A.
B.
C.
D.
E.
2
3
4
5
6
10.
A.
B.
C.
D.
E.
11.
A.
B.
C.
D.
E.
Tetrahedron
Trigonal planar
Bent
Trigonal pyramid
Square planar
12.
How many pairs of sulfur-fluorine bonds are perpendicular to the electron pair on the sulfur
atom?
A.
B.
C.
D.
E.
1
2
3
4
None
5
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13.
A.
B.
C.
D.
E.
0.24 M
0.34 M
0.44 M
0.54 M
0.64 M
14.
Which of the following methods can be used for the determination of chloride ion in
an acidic solution?
I.
II.
III.
Mohr method
Gravimetric method
Volhard method
15.
A.
B.
C.
D.
E.
Chloride ion
Iodide ion
Silver ion
Chromate ion
Ascorbic acid
16.
In the experiment of titration using Mohr's method, the end point indicator is
A.
B.
C.
D.
E.
potassium chromate
silver chloride
calcium carbonate
silver nitrate
potassium iodide
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17.
A.
B.
C.
D.
E.
140,000 kJ
2,800 kJ
57.1 kJ
420,000 kJ
2,500 kJ
18.
The heat in kilojoules that is released or absorbed in a chemical reaction where the
number of moles of reactant indicated in the balanced equation react completely, is
known as
A.
B.
C.
D.
E.
heat of combustion
heat of solution
heat of reaction
kilogram calorific value
heat of diffusion
19.
"The heat change of a reaction depends only on the initial and final states of the
reaction and is independent of the route taken" is known as
A.
B.
C.
D.
E.
Avogadro's Law
Hess's Law
Boyle's Law
Joule's Law
Charles's Law
20.
Find the AH for the reaction below, given the following reactions and
subsequent AH values: 2CO2(g) + H20(g) --- C 2H2(g) + 5/202(g)
A.
B.
C.
D.
E.
AH = -94.5 kJ
20
AH = 71.2 kJ
AH = -283 kJ
235 kJ
452 kJ
361 kJ
174 kJ
198 kJ
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21.
A.
B.
C.
D.
E.
Temperature
Concentration
Size of flask
Catalyst
Pressure
22.
Why does increasing the temperature of the reactants increase the rate of a chemical
reaction?
A.
Heat energy causes some of the reactants to evaporate, increasing the concentration of
the reactants
Heat energy helps to lower the amount of overall energy that is required for the
reaction to occur
Heat energy increases the size of the molecules of reactants, and therefore the
molecules react more frequently
Heat energy causes the particles of the reactants to move faster, and therefore react
with each other more frequently
Heat energy causes the solvent to evaporate, increasing the concentration of the
reactants
B.
C.
D.
E.
23.
Which of the following would cause the rate of chemical reaction to slow?
A.
B.
C.
D.
E.
24.
A.
B.
C.
D.
E.
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25.
I.
II.
III.
IV.
26.
A solution that is capable of dissolving more solute than it already contains at the
same temperature is called
A.
B.
C.
D.
E.
insoluble
unsaturated
saturated
soluble
dehydrated
STKK1032
Use the solubility curve provided below to determine the answers for questions 27 and 28.
150
140
130
120
110
2 0 100
Vi
90
80
0 a
70
60
50
40
30
20
10
0
0 10 20 30 40 50 60 70 80 90 100
Temperature (C)
27.
What information that can we derive from the solubility curves for selected solutes as
above?
A.
B.
C.
D.
E.
28.
A.
B.
C.
D.
E.
2g
4g
7g
17 g
100 g
10
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solution must be prepared.
29.
A.
B.
C.
D.
E.
saturated.
unsaturated.
concentrated.
supersaturated.
hydrated.
30.
Use the solubility curve provided below to determine the answers to the following
questions:
100
90
80
70
60
50
40
30
20
10
0
10 20 30 40 50 60 70 80 90 100
Temperature (C)
placated
hydrated
saturated
supersaturated
unsaturated
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31.
I.
II.
III.
IV.
32.
A.
The melting point of solvents is lower than the melting point of pure compounds that
make up the mixture
The melting point of impurities is higher than the melting point of the solvents
The melting point of pure compounds that make up the mixture is lower than the
melting point of the mixture
The melting point of mixtures is lower than the melting point of pure compounds that
make up the mixture
The melting point of solvents is higher than the melting point of pure compounds that
make up the mixture
B.
C.
D.
E.
33.
The following are the precautions that can be taken to avoid or minimize the lost of
acetanilide during the experiment, EXCEPT
A.
B.
C.
D.
E.
Make sure the filter paper and filter funnel are hot
Use excess amount of charcoal
Take out the dry acetanilide completely
Make sure the washing water is chilled
Use minimal chilled water to wash the acetanilide
12
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34.
I.
II.
III.
IV.
35.
A.
B.
C.
D.
E.
36.
The following steps may be taken to induce recrystallization if the solid fails to
separate, EXCEPT
A.
B.
C.
D.
E.
Reheat the solution and boil it for a few of minutes to reduce the solvent
Add a seed crystal of the compound to the solution
Add more solvent
Cool to induce the recrystallization
Scratch the bottom of the recrystallization flask to induce recrystallization
37.
In drawing Lewis structures, a single line (single bond) between two elements
represents
A.
B.
C.
D.
E.
13
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38.
A.
B.
C.
D.
E.
Nitrogen
Hydrogen
Carbon
Potassium
Chlorine
39.
A.
B.
C.
D.
E.
109.5
90
102
180
145
40.
Based on the diagram below, which letter corresponds to the activation energy of the
reaction?
A.
B.
C.
D.
E.
I
II
III
IV
None of the above
14