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Ideal
Prctica 3:
X2
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
V1
0
1.4
2.9
4.6
6.5
8.6
11.1
13.8
17
20.7
25
V2
25
23.6
22.1
20.4
18.4
16.4
13.9
11.2
8
4.3
0
nliq
1.3740
1.3709
1.3683
1.3661
1.3628
1.3584
1.3528
1.3486
1.3415
1.3321
1.327
T
76
74
73
71
68.9
67.4
66
63.8
61.5
59
59.7
T(K)
349.15
347.15
346.15
344.15
342.05
340.55
339.15
336.95
334.65
332.15
332.85
nvap
1.3744
1.3650
1.3590
1.3567
1.3511
1.3430
1.3405
1.3341
1.333
1.3285
1.3270
Y
0
0.32
0.455
0.51
0.63
0.77
0.8
0.865
0.88
0.94
1
Equilibrio
Ideal
Prctica 3:
3.
T exp vs x
T exp vs Y
G
raficar en el eje de las x, la composicin de la fase vapor en equilibrio y
fase liquida en equilibrio con las temperaturas de burbuja
experimentales.
Metanol (1)
Isopropanol (2)
P sat= A
ln
B
T +C
A
18.5875
18.6924
donde:
B
3626.55
3640. 20
T = K , P = mm Hg
C
-34.24
-53.54
Equilibrio
Ideal
B1
T1 = ( A 1ln( P) C 1 ) ;
3626.55
T1 = ( 18.5875ln (585) (34.24) )
B2
T2 = ( A 2ln(P) C 2 )
Prctica 3:
3640.20
T2 = ( 18.6924ln(585)(53.54) )
T1 = 331.1115 K ;
T2= 348.9918 K
6.
X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
T sup1
X2
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
348.9918
347.20377
345.41574
343.62771
341.83968
340.05165
338.26362
336.47559
334.68756
332.89953
331.1115
Calcular
las
B1
+C
T 1
ln
Donde: T = K , P = mm Hg
( A 1
P1 sat=e
Ejemplo para X1= 0.1
B1
)
+C
T 1
( A 2
P2 sat=e
B2
)
+C
T 2
Equilibrio
Ideal
(18.5875
P1 sat=e
3626.55
)
347.20377+(34.24)
P2 sat =e
P1 sat = 1096.3448
(18.6924
Prctica 3:
3640.20
)
347.20377 +(53.54)
P2 sat= 542.7186
X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
P1 sat
P2 sat
1170.9426
585
1096.3448
542.7186
1025.7232
503.0323
958.9124
465.8117
895.7517
430.9341
836.0848
398.2809
779.7599
367.7378
726.6295
339.1947
676.5508
312.5457
629.3851
287.6889
585
264.5264
P= 585 mm Hg
Suma= y1 + y2
1096.3448
585
X1
0
0.1
0.2
0.3
0.4
= 0.18741;
Y1
0
0.18741
0.35067
0.49175
0.61248
y 2=0.9
Y2
1.00000
0.83495
0.68791
0.55738
0.44198
542.7186
585
Suma 1
1.00000
1.02236
1.03858
1.04913
1.05446
= 0.83495
Equilibrio
Ideal
0.5
0.6
0.7
0.8
0.9
1
0.71460
0.79975
0.86947
0.92520
0.96828
1.00000
0.34041
0.25144
0.17395
0.10685
0.04918
0
1.05501
1.05120
1.04342
1.03205
1.01746
1.00000
Prctica 3:
T sup2
X2
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
351.15
349.347
347.544
345.741
343.938
342.135
340.332
338.529
336.726
334.923
333.12
B1
T +C 1
2
ln
Donde: T = K , P = mm Hg
( A 1
P1 sat=e
B1
)
2
T +C 1
( A 2
P2 sat=e
B2
)
2
T +C 2
Equilibrio
Ideal
Prctica 3:
P1 sat=e
3626.55
)
349.347 +(34.24)
P2 sat =e
P1 sat= 1186.2499 mm Hg
X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
(18.6924
3640.20
)
349.347+(53.54 )
P2 sat= 593.7172 mm Hg
Psat 1
1266.5225
1186.2499
1110.2279
1038.2816
970.2404
905.9387
845.2154
787.9142
733.8833
682.9755
635.0479
Psat 2
639.6724
593.7172
550.5599
510.0645
472.0995
436.5382
403.2583
372.1420
343.0757
315.9501
290.6603
P= 585 mm Hg
Suma2= y1 + y2
1186.2499
585
X1
0
0.1
0.2
0.3
y 2=0.9
= 0.20277
Y1
0
0.202777
76
0.379565
11
0.532452
09
Y2
593.7172
= 0.91341
585
Suma 2
1.09346
1.09346
0.91341
1.11619
0.75290
1.13247
0.61033
1.14279
Equilibrio
Ideal
0.4
0.5
0.6
0.7
0.8
0.9
1
0.663412
22
0.774306
55
0.866887
61
0.942803
37
1.003601
16
1.050731
52
1.085552
02
Prctica 3:
0.48420
1.14762
0.37311
1.14742
0.27573
1.14262
0.19084
1.13365
0.11729
1.12089
0.05401
1.10474
0.00000
1.08555
11. Con las dos temperaturas supuestas, realizar una interpolacin para
conocer la temperatura real de aplicacin.
2
(T T )
T = T sup2 + (1-suma2)*( suma 2suma 1 )
X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
(349.347347.20377)
)
1.116191.02236
X2
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
T = 346.692994 K
T
348.991875
346.692994
344.541139
342.519066
340.612865
338.811294
337.105274
335.487502
333.952158
332.494677
331.111576
Equilibrio
Ideal
Prctica 3:
P1 sat= A 1
B1
T +C 1
P2 sat= A 2
ln
B2
T +C 2
ln
Donde: T = K , P = mm Hg
Ejemplo para x1= 0.1
3626.55
346.692994+(34.24)
ln
= 1075.7723 mm Hg
3640.20
346.692994+(53.53)
ln
= 531.1227 mm Hg
P1 sat = 18.5875
P2 sat= 18.6924
X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
Psat1
1170.9458
1075.7723
992.5772
919.3305
854.4457
796.6661
744.9849
698.5871
656.8070
619.0962
584.9999
Psat2
584.9999
531.1227
484.5258
443.9180
408.2973
376.8756
349.0252
324.2406
302.1110
282.2994
264.5274
Donde:
P 1 sat
P
P= 585 mm Hg
y 2=x 2
P 2 sat
P
Suma2= y1 + y2 = 1
Equilibrio
Ideal
X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
Y1
Y2
Suma
0
0.183892
71
0.339342
62
0.471451
56
0.584236
4
0.680911
21
0.764087
08
0.835916
23
0.898197
64
0.952455
7
0.999999
89
1.00000
1.00000
0.81711
1.00100
0.66260
1.00194
0.53118
1.00264
0.41877
1.00300
0.32212
1.00303
0.23865
1.00274
0.16628
1.00219
0.10329
1.00148
0.04826
1.00071
0.00000
1.00000
Prctica 3:
TABLA DE RESULTADOS
X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
Datos Experimentales
T
Y1
349.15
347.15
346.15
344.15
342.05
340.55
339.15
336.95
334.65
332.15
332.85
0
0.32
0.455
0.51
0.63
0.77
0.8
0.865
0.88
0.94
1
Datos Tericos
T
Y1
348.991875
346.692994
344.541139
342.519066
340.612865
338.811294
337.105274
335.487502
333.952158
332.494677
331.111576
0
0.18389271
0.33934262
0.47145156
0.5842364
0.68091121
0.76408708
0.83591623
0.89819764
0.9524557
0.99999989
Equilibrio
Ideal
Prctica 3:
Temperatura vs X,Y
T vs X
T vs Y
Equilibrio
Ideal
Prctica 3:
x vs y
T burbuja exp vs X
T burbuja exp vs Y
T burbuja teorica vs X
T burbuja teorica vs Y