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Boronising
(Boronizing, Boriding)
Boronising and Diffusion Alloys
Boronising, sometimes referred to as boriding, is a thermochemical surface hardening method in
which boron atoms are diffused into the parent metal, forming a hard interstitial boron compound
at the surface. The resulting surface boride may be in the form of either a single phase or a double
phase boride layer. The case layer has a hard, slippery surface capable of performing at higher
temperatures than most surface treatments. Diffusion Alloys has extended its boronising
qualifications in the demanding turbomachinery market (for example of steam turbine tripin
blades and nozzle rings) into more general industrial applications such as cast iron glass
bottle moulds, plungers, tooling and dies.
Properties and Uses of Boronising
Boronising can be carried out on most ferrous materials e.g. structural steels, case hardened,
tempered, tool and stainless steels, cast steels, ductile and sintered steels and also air hardened
steels. The exceptions to these are steels containing aluminium and silicon. In addition, materials
such as nickel-based alloys, cobalt-based alloys and molybdenum can be boronised. Nickel alloy can be
boronised without sacrificing corrosion resistance, as well as producing extreme hard surface wear
resistance.
Boride Coating Properties:
50
Microstructure of a DAL
Boride diffusion coating on
an alloy steel component
Due to wear/performance benefits provided by the boronised layer, combined with the broad
range of compatible substrates and the cost-effective nature of the process, boronising is used
successfully for general wear resistance of carbon steel components. Additionally, due to its
temperature and wear resistance, boronising is also a good choice for certain tooling applications.
Typical parts for boronising include:
Ferrous materials
Nickel alloys
Titanium alloys
Sintered tungsten carbides
Slurry Process
Diffusion Alloys boride diffusion coating slurries
consist of a reactive pack powder mixture to
which water is added until the desired viscosity is
achieved. Dependent upon the latter, the slurries
can be applied to components either by painting
or by pasting. The slurry process is utilised both
for carrying out local diffusion coating repair and
for diffusion coating specific areas of components.
After application, slurries are dried overnight.
Masking of areas not to be diffusion coated is a
simple case of ensuring that no slurry is applied
to these areas. This is readily achieved using
inexpensive tape which is removed prior to the
slurry diffusion coating thermal cycle.
Summary
In our Hatfield factories, we have fifteen reducing/inert gas atmosphere retorts with six associated
furnaces suitable for applying boronising. Various coating compounds are available enabling DAL
to offer tailor-made solutions for customer requirements. Stringent quality control procedures
are in place to guarantee product quality with representative and strategically located test pieces
accompanying every diffusion coating run to facilitate in-process control and certification.
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