Professional Documents
Culture Documents
2
|!| = 1
Yx =
41
$ d
i dx
ikx
Re e = cos kx
ikx
Im e = sin kx
= c1 1 + c 2 2 + $ =
c
k
with )k = kk
= *) d
Complementary observables
The fact that particles are described by wavefunctions and that
the outcome of observations depends on the properties of operators and eigenvalues leads to profound dierences between
quantum mechanics and classical mechanics. We can begin to
appreciate these dierences by considering the wavefunction for
a particle travelling in one dimension towards positive x with
linear momentum k$. As we saw in Section 1.7, the wavefunction is Neikx, where N is the (real) normalization factor.
Where is the particle? To answer this question, we use
Postulate II to calculate the probability density:
| |2 = (Neikx)*(Neikx) = N2(eikx)(eikx) = N2
(1.18)
42
!
Location
of particle
x
Fig. 1.16 The wavefunction for a particle at a well-defined
location is a sharply spiked function which has zero amplitude
everywhere except at the particles position.
of locations (Fig. 1.17). However, as the number of wavefunctions in the superposition increases, the wavepacket becomes
sharper on account of the more complete interference between
the positive and negative regions of the individual waves. When
an infinite number of components is used, the wavepacket is
a sharp, infinitely narrow spike, which corresponds to perfect
localization of the particle. Now the particle is perfectly localized.
!
x
5
21
In this expression p is the uncertainty in the linear momentum parallel to the axis q, and q is the uncertainty in position
along that axis. These uncertainties are precisely defined, for
they are the root mean square deviations of the properties from
their mean values:
p = {p2 p2}1/2
[1.19b]
px
py
pz
x
y
z
px
py
k=1
pz
q = {q2 q2}1/2
(1.19a)