5.

1.

2.

The rate at which a substance reacts depends

on its
(A) atomic mass

(B) equivalent mass

(C) Molecular mass

(D) active mass

6.

Which of the following rate law has an overall

order of 0.5 for the reactions involving
substances x,y,z?

0.5

(B) Rate = k (Cx) (Cy) (Cz)

(D) Rate =
3.

Cy 2

7.

(B) activation energy

(C) activation energy + average energy of the
reactants

4.

Select the rate law that corresponds to the

data shown for the following reaction
A+B

C.
Experiment
[A]
[B]
Initial Rate
0.10
0.012
0.035
0.80
0.024
0.070
0.10
0.024
0.035
0.80
0.012
0.070

(D) 12

The concept of mechanical velocity or speed

cannot be used in measuring the rate of
reactions, because

(D) Both (A) & (B)

(A) average energy of the reactants

(D) activation energy average energy of the

reactants

(C) 9

(C) rate of reaction depends on molar

concentration of products and it decreases with
time

In a reaction the threshold energy is to equal to

(B) 10

(B) rate of reaction depends on molar

concentration of reactants and it decreases
with time.

0.5

(C) Rate = k(Cx)1.5 (Cy)1(Cz)0

R Cx Cz

(A) 8

(A) rate of reaction depends on active mass of

reactants and it decreases with time

(A) Rate = k(Cx) (Cy) (Cz)

0.5

For a first order reaction, the ratio of time for

the completion of 99.9% and half of the
reaction is

8.

A certain radioactive element A, has a halflife

= t seconds. In (t/2) seconds the fraction of the
initial quantity of the element so far decayed is
nearly
(A) 25%

(B) 29%

(C) 21%

(D) 17%

For the reaction CaCO3(s)

CaO(s)

+CO2(g), the pressure of CO2(g) depends on

(A) the mass of CaCO3(s)
(B) the mass of CaO(s)
(C) the masses of both CaCO3(s) and CaO(s)
(D) temperature of the system
9.

In melting of ice, which one of the condition

will be more favourable?
(A) high temperature and high-pressure

(A)Rate=k[B]4
(B) Rate = k [A] [B]3
(C)Rate=k[A]2[B]2
(D) Rate = k [B]3

(B) low temperature and low pressure

(C) low temperature and high pressure
(D) high temperature and low pressure

10.

For the decomposition reaction:

NH2COONH4 (s)

2NH3(g) + CO2(g)

The KP = 2.9 105 atm3. The total pressure of

gases at equilibrium when 1 mole of
NH2COONH4(s) was taken to start with would
be

11.

(A) 0.0194 atm

(B) 0.0388 atm

(C) 0.0582 atm

(D) 0.0766 atm

14.

would be its value in the presence of a catalyst in

the forward reaction?

For the reaction

A+B

1
2

for the reaction 2N2O5(g)

O2(g) would be

(B) 1000

1000
concentration of catalyst

4NO2(g) +
(C)

K p2

(D) impossible to tell

(A)
15.

(B) 2/Kp

(B) 6.76

(C) Undefined (D) 7.47

(C) 1/
16.

1 Kp

(D)
If pressure is applied to the
followingequilibrium, liquid
boiling point of liquid

pH value of pure water at 0C can be

(A) 7

K p2

vapours, the

(A) will increase

17.

(B) will decrease

(C) may increase or decrease
(D) will not change
13.

C + D + 38 Kcal

(A) 1000 concentration of catalyst

2NO2(g) + O2(g)
N2O5(g) if the equilibrium
constant is Kp, then the equilibrium constant

12.

The equilibrium constant at 323C is 1000. What

If CuSO4.5H2O(s)
CuSO4.3H2O(s) +
2H2O(l) Kp = 1.086 104 atm2 at 25C. The
efflorescent nature of CuSO4.5H2O can be
noticed when vapour pressure of H2O in
atmosphere is

18.

A certain buffer solution contains equal

concentration of X and HX. The Kb for X is
1010. The pH of the buffer is
(A) 4

(B) 7

(C) 10

(D) 14

The degree of hydrolysis of a salt of weak acid

and weak base in its 0.1M solution is found to
be 50%. If the molarity of the solution is
0.2M, the percentage hydrolysis of the salt
should be
(A) 100%

(B) 50%

(C) 25%

(D) none of these

What would be the pH of an ammonia solution

if that of an acetic acid solution of equal

(A) 7.29mm

strength is 3.2? Assume dissociation constant

(B) 7.92 mm

for NH3 & acetic acid are equal.

(C) 7.92 mm

(A) 3.2

(B) 6.4

(D) None

(C) 9.6

(D) 10.8

19.

At 30oC, the solubility of Ag2CO3 (Ksp = 8 x

1012) would be greatest in one litre of
(A) 0.05M Na2CO3

(B) 0.05M AgNO3

(C) Pure water

(D) 0.05 M K2CO3

22.

20.

The ratio of dissociation constant of two weak

acids HA and HB is 4. At what molar
concentration ratio, the two acids will have

same pH

21.

HB
HA ?

(A) 2

(B) 0.5

(C) 4

(D) 0.25

In a saturated solution of calcium phosphate,

PO3
4

the concentration of
ions is 3.3 107
M. The Ksp of Ca3(PO4)2 will be
(A) 1.32 1031
(B) 1.321032
(C) 1.32 1033
(D) 1.32 1035

pH of a mixture of 1M benzoic acid (pKa =

4.20) and 1M sodium benzoate is 4.5. In
300ml buffer, benzoic acid is
(A) 200ml

(B) 150ml

(C) 100ml

(D) 50ml