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doi:10.14355/ijer.2014.0302.01
AnExperimentalStudyonaDensityDriven
SolarWaterHeatingSystemUsing
SupercriticalCO2asWorkingFluid
RuchiShukla1,K.Sumathy*2,M.RaisulIslam3
DepartmentofMechanicalEngineering,NorthDakotaStateUniversity,Fargo,NorthDakota,58108,U.S.A
Ruchi.Shukla@ndsu.edu;*2Sumathy.Krishnan@ndsu.edu;3Mohammad.r.Islam@ndsu.edu
Received17September2013;Accepted10October2013;Published15May2014
2014ScienceandEngineeringPublishingCompany
Abstract
An experimental study was performed to investigate the
feasibility and performance of thermosyphon solar water
heating(SWH)systemusingR744(CO2)astheworkingfluid.
Theuniquenessofthesystemwastheuseofcarbondioxide
as a working fluid; which is one of the most promising
alternative natural refrigerants. For supercritical carbon
dioxide,asmallchangeintemperatureorpressurecanresult
in a large change in density, especially close to its critical
point. At this pseudo critical region, density decreases
rapidly with increase in temperature which aids the
thermosyphonflow.Anexperimentalsetupinwhich1.15m2
evacuated tube (Upipe)solar collector acting as a source as
well as an evaporator for the refrigerant, was designed and
tested based on this principle. Experimental results have
shown that it is possible to induce the natural convective
flowevenduringsolaradverseconditions.Althoughduring
winteritwasnotpossibletoextractanyusefulheatgain,the
system did show some promising results when operated
duringspring.Thetimeaveragedcollectorandheatrecovery
efficiencies for summer were about 58% and 45%,
respectively.
Keywords
Solar Water Heating; Thermosyphon; Refrigerant; R744;
EvacuatedTubeCollector;HeatRecoveryEfficiency
Introduction
EcologicalproblemsandPotentialenergycrisesinthe
world have encouraged the development of new
sustainableenergyoptions.Solarwaterheating(SWH)
is widely used throughout the world and a large
varietyofsystemsarecommerciallyavailable.
The growing popularity of SWH systems is fueled by
their environmentally friendly operations with
minimal system maintenance and operation costs as
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RefrigerantType
NaturallyOccurring
ODP
GWP
CriticalPointTemp
CriticalPoint
Pressure
TriplePointTemp
TriplePointPressure
Flammable/Explosive
Toxic
SeveralstudieshavebeeninitiatedutilizingCO2asthe
working fluid. Recently, Zhang et al. have made a
detailedstudyonthecollectorcharacteristicswithCO2
as the working fluidandinvestigated the influenceof
CO2 in a Upipe inserted glass evacuated tube solar
collector. It has been reported that the annually
averagedcollectorefficiencywasabove60%inthecase
of supercritical CO2 as the working fluid, which is
muchhigherthanthatofwaterbasedcollectorswhere
annuallyaveragedefficiencyreachedonlyupto50%.
Literature shows that most of the CO2 utilized SWH
systems are active systems. In this study, an attempt
has been made to design and fabricate a simple
thermosyphon solar water heater using supercritical
CO2asworkingfluidtoinvestigateforitsfeasibilityin
operating in harsh winter regions like those found in
NorthDakota,USA.
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FIG.1SCHEMATICDIAGRAMOFASIMPLETHERMOSYPHON
SWHSYSTEM
InternationalJournalofEnvironmentandResourceVolume3Issue2,May2014www.ijer.org
) is defined
The instantaneous collector efficiency
astheratiooftheusefulheatgain(
deliveredtothe
availablesolarenergyatthesolarcollector( .
(5)
by the storage tank can
Heat quantity recovered (
beexpressedintheformoffollowingequation:
(6)
Criticalpoint
FIG.2PRESSUREENTHALPYDIAGRAMOFCARBODIOXIDE[30]
Governing Equations
(7)
Experimental Set-up
Finally,theheatrecoveryefficiency
ofthesystem
canbeevaluatedbasedontheratiooftheheatquantity
recovered by the water flow through the heat
exchanger
totheusefulheatgain
(1)
(2)
(3)
(4)
Themainobjectiveofthestudyistodevelopareliable
andacosteffectiveSWHsystem,whichcouldoperate
when exposed to low ambient temperatures and low
solar radiation intensity conditions. Accordingly, the
main components of a SWH system, such as the
collector and the storage tank were appropriately
chosenanddesigned.
With regard to the type of collector, for the desired
passive SWH system, both a evacuated tube collector
(ETC) and a flatplate collector (FPC) are more
commonly employed. For the given constraint of low
ambientandsolarinsolationconditions,ETChasbeen
chosen in this study. ETC has proven to aid inherent
maximumoperatingtemperaturesandlowheatlossat
hightemperaturesrelativetotheambienttemperature.
In addition, it has a lower absorber plate area to the
gross area ratio compared to FPC. The efficiency of a
collector is also dictated by the shape of the absorber
tube.Forinstance,Perezetal.confirmedthattheglass
ETC with a semicylindrical shaped absorber tube
couldabsorbapproximately16%moreenergythanan
ETC with a flatplate shaped absorber tube. Kim and
Seo [31] introduced several potential designs of the
absorbertubeandinvestigatedtheperformanceofthe
four different shapes of absorber tubes. The shapes
include(i)afinnedtube,(ii)anUtubeweldedinside
a circular fin, (iii) an Utube welded on a copper
plate. Among the four different designs, an Utube
placed inside a circular fin provided the best heat
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16
StorageTank
Solar Collector
Data
Acquisition
FIG.3FRONTVIEWOFSWHSYSTEM
InternationalJournalofEnvironmentandResourceVolume3Issue2,May2014www.ijer.org
(a)
(b)
FIG.4EVACUATEDTUBESOLARCOLLECTOR(a)FRONTVIEW
(b)CROSSSECTIONALVIEW[30]
TABLE2THEPARAMETERSFORTHEGLASSEVACUATED
TUBESOLARCOLLECTOR
Material
Absorbingcoating
Outerglasstube
Airlayer
Copperfin
Utube
Parameters
Value
Absorptivity
Emissivity
Outerdiameter(m)
Innerdiameter(m)
Thickness(m)
Conductivity(W/mK)
Thickness(m)
Conductivity(W/mK)
Thickness(m)
Conductivity(W/mK)
Outerdiameter(m)
innerdiameter(m)
Thickness(m)
0.92
0.19
0.04
0.03
0.0015
1.2
0.001
0.03
0.0006
307
0.0063
0.0031
0.015
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FIG.5VARIATIONOFSOLARRADIATIONANDAMBIENT
TEMPERATUREVSTIMEOFDAY
Thermocoupleswereusedtomonitorthetemperature
of CO2 refrigerant. Initially, the system was charged
with CO2 until the initial pressure of 5.5 MPa was
achieved,itwasexposedtosunlight.Duringtheinitial
hours of exposure, a steady rise in CO2 temperature
and pressure was noticed. Measured values of CO2
temperature both at the inlet and the outlet of the
collector are plotted in Fig. 6. During the test period,
theCO2temperatureatthecollectoroutletvariedfrom
17Cto80C.Atsuchhightemperatures,supercritical
CO2canserveasausefulsolarthermalsourceforhot
watersupply in cold regions.Literature shows that,it
is difficult to achieve such temperature gain, with
conventional flat plate collectors. This improved
design has successfully generated approximately a
60 C rise in the CO2temperature. It is due to the fact
that,whenCO2temperatureisclosetoitssupercritical
state,evenasmallchangeinpressureandtemperature
results in dynamic changes in its thermophysical
properties.
Figure 6 also shows the variation in pressure of CO2,
both at inlet and outlet conditions of the collector.
During test hours, it was noticed that not only CO2
temperature,butalsoCO2pressureinthecollector,was
influenced by solar radiation. The changes in the CO2
pressure at the collector inlet and outlet have similar
trends. It could be seen that the CO2 pressure at the
solar collector rises from 5.5 MPa to 9.5 MPa within
07:30 to 13:30 hours. Even during cloudy periods,
though there was a reduction in CO2 pressure, it
stabilizedtoabout7.5MPa,whichisabovethecritical
point of CO2 (7.3 MPa). Beyond 15:00 hours with
furtherdecreaseintemperatureandpressure,theCO2
fluidentersasubcriticalzone.
The relationship between temperature, pressure,
enthalpy,andentropyareshowninpressureenthalpy
diagram in Figure 7. In this figure, the critical point
C.P. is located at the peak of the vapor dome. As
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FIG.6VARIATIONOFCO2TEMPERATUREANDPRESSUREVS
TIMEOFDAY
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CO2fluidstate
atthecollector
CO2fluidstateatthe
collectoroutlet
FIG.7CO2PRESSUREENTHALPYDIAGRAMSHOWINGCO2
FLUIDSTATESDURINGTHETESTPERIOD
FIG.9VARIATIONOFCOLLECTORUSEFULHEATGAINAND
RECOVEREDHEATQUANTITYVSTIMEOFTHEDAY
FIG.8VARIATIONOFSTORAGETANKWATERTEMPERATURE
VSTIMEOFDAY
FIG.10VARIATIONOFCOLLECTOREFFIECNCYANDHEAT
RECOVERYEFFICIENCYVSTIMEOFDAY
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usedforthestoragetankcouldnoteffectivelyprevent
the heat losses. Based on the test data collected, it is
suggested that thermosphoning system is not suitable
in solar adverse regions. It should be noted, the
preliminary results have proven that, even in extreme
winter conditions, it is possible to affect CO2 heating;
theenergygaincanbeeffectivelyharnessedforwater
heating purposes through heat pump technique.
However, as shown in Fig. 11, during spring season
(AprilMay), the system did show some promising
results.
Results obtained from the present study are
encouraging as it signifies that the environmental
benignrefrigerantCO2(R744),canserveasanefficient
working fluid compared to water when exposed to
solar adverse conditions. There are several
characteristics of CO2 that contribute to the high
efficiency of CO2based collector compared to
traditionalcollectorsusingwaterasworkingfluid.The
collector efficiency could further be improved by
implementingheattransferthroughforcedconvection
thannaturalconvention.
needtobeoperatedinsolaradverseregions.However,
thermosyphon based SWH system is not
recommended for winter conditions. A suggestion for
further studies is to investigate the heat pump based
CO2 driven SWH system when subjected to solar
adverse condition (very low Ta and wind chill
temperature).
Nomenclature
Ac
Cb
d
F
F
hf
Qu
Qw
Ta
Tf
UL
W
IT
Mw
Cp
theoutersurfaceareaofabsorbertube,(m2)
bondconductance,(Wm1K1)
diameteroftheUtube,(m)
finefficiencyofstraightfin
collectorefficiencyfactor
the heat transfer coefficient between the fluid and the U
tubewall,(Wm1K)
usefulenergygain,(W)
heatquantityrecovered,(W)
ambienttemperature,(K)
meantemperatureoftheworkingfluid,(K)
overalllosscoefficient,(Wm2K1)
thecircumferentialdistancebetweentheUtubes,(m)
totalsolarradiation
massofwaterinstoragetank,(kg)
specificheatofwater(kJkg1K1)
Greek
thethicknessofthecopperfin,m
solarcollectorefficiency
conductivityofcopperfin,W/(mK)
Absorptance
Subscripts
FIG.11CO2TEMPERATUREANDTHECORRESPONDENCE
AVERAGERISEINTANKTEMPERATUREFORTYPICALDAYS
OFDIFFERENTMONTH
Conclusion
A CO2 assisted water heating system using Utube
evacuated tube collector has been investigated for
Fargo, ND, weather conditions. The thermal
performanceofthesystemisdeterminedbasedonthe
measured collector temperature and water
temperature in the storage tank, under different
weatherconditions.Theresultsindicatethat,thetime
averaged collector efficiency (col) and heat recovery
efficiency (RE) are calculated around 58% and 45%
respectively.Experimentshaveshownthepotentialof
usingCO2astheworkingfluidinSWHsystemswhen
20
col
RE
w
i
f
u
o
collector
heatrecovery
water
inlet
fluid
useful
outlet
ACKNOWLEDGEMENT
Thisresearchwaspartlysupportedbyagrantfromthe
PakistanUS Science and Technology Cooperation
Program,USDepartmentofState(jointlyadministered
by the National Academics and Higher Education
CommissionofPakistan).
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http://en.wikipedia.org/wiki/Hotwater_storage_tank