Sol - 3

1
FIITJEE
JEE(Main)-2016
ANSWERS, HINTS & SOLUTIONS
CONCEPT RECAPITULATION TESTIII
(Main)
ALL INDIA TEST SERIES
FIITJEE Students From Classroom / Integrated School Programs have secured to 2 Zonal, 6 State & 18 City Topper Ranks. 33 in Top 100, 78 in Top 200 and 205 in
Top 500 All India Ranks bagged by FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
AITS-CRT-III-PCM (Sol)-JEE(Main)/16
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
D
C
C
D
C
C
C
D
C
D
C
D
C
C
D
A
B
B
A
C
A
C
A
C
D
B
A
A
D
C
A
C
B
C
C
A
C
C
C
B
B
B
A
C
B
B
C
B
D
B
C
B
B
D
C
B
B
A
C
D
A
A
C
D
B
A
A
A
B
A
C
B
B
A
C
B
C
B
A
C
C
A
C
C
C
A
B
D
D
B
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
1.
For V1 < 5 volt the diode is forward biased output will be fixed at 5V and V1 > 5 volt the diode is
reverse biased, and output will follow V1.
2.
Direction of impulse = ( j /2) i

Unit vector along impulse =
j 2i
5
j 2i
2
va = velocity of approach = i .
=
5
5
j j 2i
1
vs = velocity of separation = .
2 5 2 5
e = vs/va = 1/4
3.
d2 a 1 d2F 1
kd2 x
k
2
= a = 2(a a0)
2
2
2
m dt
m
m
k
dt
dt
4.
v=
RT
M
RC
MV 2
v 1/V
v=
5.
RC 1
M
V
y = t3/3, x = t2/2
y = (1/3)(2x)3/2 =
1 3 2
2x
8 32
x
9
dy 3
8

x1 2 = 0, x = 0
dx 2
9
6.
7.
8.
1
x2
g 2
2 u cos2
put y = 0, x = u2/2g
Solve and get tan = 2
y = x tan
L ML2 3 g
= /I = Mg
2
3 2L
Mg N
acm = L/2 = 3g/4 =
M
Mg
N=
4
R
R
2R
1 1 x
x = 1
3
9.
The effective emf due to batteries connected between A and C is zero while the effective
2 2
16
resistance of the circuit is 4
3 3
3
24
9
I=
= 4.5 A
16 3 2
10.
= d/dt
I = /R = (1/R)(d/dt)
dQ/dt = (1/R)(d/dt)
dQ = (1/R)d
1
or, Q = [No role of velocity]
R
11.
dEcurved =
Rd
40R2
dEstraight =
dx
40 (R sec )2
x = R tan dx = R sec2 d
dEcurved = dEstraight
12.
There is a need of potential difference for current to flow
13.
T sin = mg/2
T = T cos
T = mg/(2 tan )
1 1
gh = 2T
r1 r2
14.
15.
T sin
T cos
mv = 5 mv
v = v/5
2
1
1
3
v
mv 2 5m nRT
2
2
5
2

16.
17.
vp sin = v
cos = 4/5 sin = 3/5
vp 5v
=
(v p = 5v/3)
R 3R
v
O
vp
y = 2 sin(kx + ) cos t,
k = 2/ = 2/8 = /4
x = 1, A = 0 (1) + =
4
= (3/4)
5
3
y = 2sin x
t
cos
4
4
2
3 5
3 5
y = sin x
t + sin x
t
4
4
2
4
4
2
4
18.
U = Q/2 dU = dW
CvdT = PdV
3
(PdV + VdP) = PdV
2
PdV + 3VdP = 0
PV
1/3
= constant
R
C = Cv +
= 3R
1 1 3
19.
20.
21.
22.
24.
a2
a
sin sin
sin = 2 sin
= sin1(2 sin )
e = B(dA/dt) = B(2r)(dr/dt)
x 10 x 6 x x 10
=0x=6V
10
20
10
5
66
I20 =
= 0.6 Amp
20
3RT M0 GMp
4
and use Mp = R3p

2
Rp
3
Q A rA
QB rB
If QT is total charge present on the spheres (A+B) at any time
rB
r
constant.
QB = QT B kQT
k
rA rB
rA rB
rB
rA
S
QB
QA
1st connection q = Qk k = q/Q

(i + 1)th connection qi+1 = (qi + Q)k = (qi + Q)q/Q
For i , qi = qi+1
q = (q + Q)(q/Q)
q = Qq/(Qq)
25.
Force acting on the wedge to the left = p0(ah)

= p0ax
a
a3
K = p0a xdx p0
0
2
p0 2p0
h
x
26.
=
=
1 r
2rdr
2 0 0
R
1 22 2
2 R 3
r
dr
=
2 0 0
30
r
dr
5
v2
v0x
u2
v
v
vIY = v OY , viZ = v OZ
u
u
27.
vIx =
28.
Ndt = (v/2) + v cos

Ndt = v v sin
29.
Nuclear reactions are spontaneous reactions.
30.
Component of force parallel to axis of rotation produces no torque.
6
Chemistry
PART II
1.
H3PO2 H3PO3
1
H3PO2 P H3
M
2
M
Eq .mass
4
Eq .mass
The equivalent mass of H3PO2 in the process of disproportion =
M M
3M
=
2 4
4
PV
10 1
= 365.4 K = 92.4C
10
nR
0.0821
30
2.
3.
4.
Critical temperature Tc
5.
PE = 2 KE
3
RT (Kinetic energy of 1 mole gas)
2
3
3
3
3
E R T 50 RT = R 50 8.314 50 623.55 J
2
2
2
2
8a
27Rb
Greater is the value of (a/b) more is the critical temperature of gas.
For gas X, Tc will be maximum
8a
Tc
27bR
6
a/b for X
240 , for all other gases, (a/b) is lesser.
0.025
2x
4
2x
Change in potential energy = 2x
4
x
3x
= 2x
2
2
PE will change from 2x to
6.
Magnetic moment =
1.73 =
n n 2 BM
n n 2
3 n n 2
n = 1 (number of unpaired electrons)

3
2
V23 3d 4s
4+
1
0
V 3d 4s (has one unpaired electron)
7.
rn n2r1
r3 = 9r1 = 9x
h
mvr = n
2
7
mv9x = 3
h
2
h
6x
mv
= 6x
8.
The redox reaction is = Cr2O72 14H 3Sn2 2Cr 3 7H2O 3Sn4

2+
1 mole of Sn
9.
will reduce 1/3 mole of K2Cr2O7.
150 ml N/10 HCl = 150 ml N/10 CaCO3

CaCO3 2HCl CaCl2 H2 O CO2
Mol. Mass 2g Eq.
40 12 48 100
50
2
2
Mass of CaCO3 present in 150 ml N/10 solution
1 150
= 50
0.75g
10 1000
0.75
Purity =
100 75%
1
Eq. mass of CaCO3 =
10.
HgI2 although insoluble in water but shows complex formation with KI as, 2KI HgI2 K 2HgI4
and thus, number of particles decreases in solution.
11.
rin k A B
Now as the volume is halved the concentration would get doubled

r
2
3
2
3
rnew k 2A 2B 32k A B = 32rin new 32
rin
12.
H Eaf Eab 22 70 Eab

Eab 70 22 92Kcal
13.
Rate of increase in [B] = k1[A]

Similarly rate of decrease in [B] = k2[B]
d B
net rate of formation of B i.e.
= k1[A] k2[B]
dt
W = nRT or W = PV
nRT2 nRT1
= 1 8.314 1 = P
P
P
= 8.314 J
14.
15.
W = ZIt
W
It
Z
1 = It = I 0.25
I = 4 amp
8
16.
F
EtO / EtOH
1-pentene major product

(Less substituted alkene)
17.
H
Li / Liq NH
H
(X) can exist as geometrical
isomers
18.
Alkali will be formed during reaction, so pH will increase gradually.
19.
NBS gives free radical intermediate.
20.
H /
O
21.
Zn dust
2CH3CHO
H O
OH
O
N
CH3
Re duction
22.
2o A min e
In this case, 1 carbocation is more stable than 2 carbocation, because at 2 a powerful EWG is
attached.
O
23.
H
O
CH3
OH
OH
CH3
24.
4Ag 8KCN 2H2O O2 4K Ag CN2 4KOH
25.
FeO SiO2
FeSiO3
9
26.
ClO has sp
27.
SO23 aq 2HCl aq 2Cl aq SO2 aq S s H2O
28.
Coordination number of Cu , Zn and Fe are 4, 4 and 6 respectively.

(i) Cu H2 O 4 SO4 .H2 O
hybridisation.
2+
2+
2+
(ii) Zn H2O 4 SO4 .H2O

(iii) Fe H2 O 6 SO 4 .H2O
29.
Ni shows sp , dsp and sp hybridisation in Ni(CO)4.
Ni CN
and NiBr4
respectively
CN being strong field ligand pairsup unpaired electron in Ni2 .

30.
PA PA0 X A and PB PB0 XB

PA PM YA and PB PM YB
PA
P
B
YA
YB
P0 1 X A
PA0 X A PB0 XB
P0 P0
= B
B A PB0 PA0
YA
YB
XA YA
1 YA
1
1 PA0 PB0 PA0
X A YA PB0 PB0
Y = mx + C
Slope = m =
PA0
PB0
and intercept c =
0
B
PA0
PB0
10
Mathematics
1.
ecot x
PART III
[lncos ec 2 x 2sin x cos x]
sin2 x
2
cosec x dx = dt
1
dx =
dt = et
1 t2
2.
dx (put cot x = t)
2t
t
2
cotx
2
dt = e ln (1 + t ) + c = 2e ln (cosec x) + c.
ln(1 t )
2
1
Consider g(x) = f(x) x
1
2
for any x = a
g(a) = f(a) a
1
2
g(f(a)) = f(f(a)) f(a)
1
1
1
= 1 + a f(a)
=
+ a f(a)
2
2
2
g(f(a)) = g(a)
between any point a and f(a) there lies a root of g(x)
.... (1)
g(f(x)) = g(x) g(f(x)) + g(x) = 0
g(f(f(x)) + g(f(x)) = 0
g(f(f(x)) = g(x) g(1 + x) = g(x)
g is periodic function with period 1
..... (2)
Considering any n, n + 1 interval, we can see from (1) and (2) that g(x) is identically zero.
1
g(x) = 0 f(x) = x + .
2
100
3.
100
x dx =
2 3/2
x
3
100
x x

dx =
0
0
dx
100
100
102
dx 1 dx 2 dx .....
x dx
dx
19
2
= 103 0 1 22 12 2 32 22 2 32 22 3 4 2 3 2 ..... 9 10 2 9 2
3
9 9 118 1
2
2
2000
9 10 19
= 102 9 102 12 22 .... 92 = 103 900
=
900
3
3
6
3
6
2000
1710
2000 3690 310
=
900
=
.
3
6
3
6
6
4.
Put x = y
1
y
1
1
1 = f y 1 2 dy =
y
y
1
Putting z = =
y
1
1 dy
f y dy f y 2
y
yy
1
1
f y dy f z dz = 1.
y
11
5.
A
B

and
lie strictly between 0, and sin x is always increasing in
2
2
2

0, where as cos x is always decreasing in 0, .
2
2
A
B
So if
>
2
2
A
B
sin
> sin or x1 > x2
2
2
1
1
and
as x3 < x4
x3 x 4
In given ABC both
x1
2007
2006
2007
2006
= x2 .x3
is not valid
A
B
similarly for
<
2
2
x1 < x2 and x3 > x4
1
1
x3 x 4
so again equality for x12007.x42006 = x22007.x32006 is not possible.
1
1
A B
So only one possible case exist for x1 = x2 and x3 = x4 or
or
x3 x 4
2 2
BAC is isosceles with ABC = CAB so BC = AC = 1 unit.
6.
.x4
1 1 1 2
=
2
2
h1>
2
h>1+1
h>2
7.
Let P (, ), 2 + 2 = 5 and image of P(, ) with respect line x y + 1 = 0 be Q lies on

7x + y + 3 = 0
x y 2 1
1
1
2
x = 1, y = + 1
7( 1) + + 1 + 3 = 0
= 3 7
2 + 9 + 49 2 42 = 5
2
50 42 + 4 = 0
8.
S(1,1)
42
42 2 800
100
2, 2, 1
2ae = 4
8e=4
e=
|Z 4| [1, 9]
12
9.
a 2b c and b 3c a , where a, b and c are non collinear vectors
a 6c c 2a
a 1 2 6 c
1
and = 6 as a and c are noncollinear.
2
| a 2b 6c | | 6c 6c | | 0 | 0
10.
The required numbers for given m and k is 2k m1, as for given m and k the set will comprise of
(k m + 1) elements and each subset has to have at least 2 elements (m and k), hence the
required number of sub sets = 2k m 1
11.
S = 22 + 42 + 62 + .. + (100)2 + 50 2(2 + 4 + 6 + .. + 100)

22 + 42 + 62 + .. + (100)2 = S + 5050
12.
cos 70 4cos 70 sin70

cos 60 40
3
3
sin70
cos 20
13.
x R then k
a b c 2
a 2 b2 c 2
2
3 ab bc ca 3 ab bc ca 3
2
2
2
a b c 2 ab bc ca
a2 b2 c 2
2
<
3 ab bc ca
3
4
k
3
14.
Let sin x = s and cos x = c then

then (1 + 2sc)(sc + 1)2 = (7sc 1)2
A2 44A + 36 = 0 as A = 2sc
A = 22 8 7
15.
9.10.10.5 {9.8.7.1 + 8.8.8.4}
16.
f(x) = 6x2 + 6 > 0, x R
17.
9 8 C5 504
18.
a b c 2
19.
P(A)
20.
Clearly, (x, y) R x W,
So, R is reflexive.
Let (x, y) R the (y, x) R and x and y have atleast one letter in common. So R is also
symmetric.
But R is not transitive.

2 a b c
9
1
216 24
13
21.
Required area = 4 = 3
(0, 0)
S1
S2
22.
u(x) = 7v(x) u(x) = 7v(x) p = 7(given)

u x
u x
pq 70
7
Again
1
0 q = 0 ; now
v x
pq 70
v x
23.
f(x) = ax3 + bx2 + cx + d

d2 y
b
x
is possible point inflexion also since
changes sign as we move from left to right of
3a
dx 2
b
x
it is a point of inflexion.
3a
24.
y2 = 4ax, 4a = 2p > 0 and t1t2 = 1

4a2 t t
Ratio = 2 21 22 4
a t1 t 2
25.
lim
(dividing Nr and Dr by 3n)
x 2
3n
1
n
n
For lim to be equal to

n
26.
27.
28.
1
1
x2
; lim 0 (which is true) and lim
0.
n
3
n
3
For f to be one-one f(x) > 0 and f(x) < 0 for all x

clearly f is continuous at x = 0 and f(0) = 1
for x 0, f(x) = 2(x + m) if m > 0 then nothing definite can be said
about f(x)
hence m < 0
but m 0 as for x > 0, f is constant and m < 0, f(x) < 0, x > 0
i
3
3
2 3
= 8 3()3 = 24.
2

Let C151 = q. C150 where q 1

n!
q.n!
151! n 151! 150 ! n 150 !

1
q
n 150 = q.151 or n = 151q + 150

151 n 150
Smallest n will be when q = 2
n = 302 + 150
n = 452 sum of the digit = 11.
14
29.
Coefficient of A in nth term = 8 + (n 1) (2)

Coefficient of B in nth term = 2 + (n 1) (1)
10 2n = 2(3 n) 10 = 6
Which is absurd
30.
dx ; let x 9 = t2 dx = 2t dt
x 9
3 t2 9 2
Fx
.2t dt 2 29 3t 2 dt 2 29t t 3
3 /2
F x 2 29 x 9 x 9 C
Given F(10) = 60 = 2[29 + 1] + C C = 0

3/2
F x 2 29 x 9 x 9
F(13) = 2[29 2 + 4 2] = 4 33 = 132

F x
3x 2

Sol - 3

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1

ALL INDIA TEST SERIES

Direction of impulse = ( j /2) i

There is a need of potential difference for current to flow

and use Mp = R3p

1st connection q = Qk k = q/Q

Force acting on the wedge to the left = p0(ah)

Ndt = (v/2) + v cos

Nuclear reactions are spontaneous reactions.

Component of force parallel to axis of rotation produces no torque.

The equivalent mass of H3PO2 in the process of disproportion =

PE will change from 2x to

n = 1 (number of unpaired electrons)

The redox reaction is = Cr2O72 14H 3Sn2 2Cr 3 7H2O 3Sn4

will reduce 1/3 mole of K2Cr2O7.

150 ml N/10 HCl = 150 ml N/10 CaCO3

Eq. mass of CaCO3 =

Now as the volume is halved the concentration would get doubled

H Eaf Eab 22 70 Eab

Rate of increase in [B] = k1[A]

1-pentene major product

Alkali will be formed during reaction, so pH will increase gradually.

NBS gives free radical intermediate.

4Ag 8KCN 2H2O O2 4K Ag CN2 4KOH

SO23 aq 2HCl aq 2Cl aq SO2 aq S s H2O

Coordination number of Cu , Zn and Fe are 4, 4 and 6 respectively.

(ii) Zn H2O 4 SO4 .H2O

Ni shows sp , dsp and sp hybridisation in Ni(CO)4.

CN being strong field ligand pairsup unpaired electron in Ni2 .

PA PA0 X A and PB PB0 XB

[lncos ec 2 x 2sin x cos x]

Consider g(x) = f(x) x

g(f(a)) = f(f(a)) f(a)

In given ABC both

Let P (, ), 2 + 2 = 5 and image of P(, ) with respect line x y + 1 = 0 be Q lies on

a 2b c and b 3c a , where a, b and c are non collinear vectors

S = 22 + 42 + 62 + .. + (100)2 + 50 2(2 + 4 + 6 + .. + 100)

cos 70 4cos 70 sin70

Let sin x = s and cos x = c then

9.10.10.5 {9.8.7.1 + 8.8.8.4}

f(x) = 6x2 + 6 > 0, x R

u(x) = 7v(x) u(x) = 7v(x) p = 7(given)

f(x) = ax3 + bx2 + cx + d

y2 = 4ax, 4a = 2p > 0 and t1t2 = 1

(dividing Nr and Dr by 3n)

For lim to be equal to

For f to be one-one f(x) > 0 and f(x) < 0 for all x

Let C151 = q. C150 where q 1

151! n 151! 150 ! n 150 !

n 150 = q.151 or n = 151q + 150

Coefficient of A in nth term = 8 + (n 1) (2)

Given F(10) = 60 = 2[29 + 1] + C C = 0

F(13) = 2[29 2 + 4 2] = 4 33 = 132

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