SMK KEPONG

SKEMA JAWAPAN PEPERIKSAAN PERCUBAAN SPM

TAHUN 2013
MARKING CRITERIA
1a

ii
i

ii
iii
i
ii
iii

MARK
S
1

To heal wounds/ skin dieases// To treat diabetes/ asthma/epilepsy/osteoarthritis/

sunburn
ginger
X: analgesic
Y:antibiotic
To make sure all bacteria are killed
Penicillin
preservative
To draw the water out of the cells of bacteria or fungi, thus retarding the growth
soy lecithin-stabiliser
ethyl butanoate-flavouring
Total

2a
b

i
ii
i
ii

iii
iv

proton number
18
group 17, period 3
-size of sodium atom is bigger than chlorine atom
-number of protons in chlorine atom is more than sodium atom
-attraction force between nucleus and electron in chlorine atom is stronger
Ionic

1
1

-Number of electron occupied with electron and symbol

-Charge of Na+ and Cl-

Total
3a

b
c

i
ii
iii
iv
i
ii
i
ii

1
1
1
1
1
1
1
1
1
10
1
1
1
1
1
1
1

Number of proton at the nucleus of atom

Electron
14
+1
6
same number of valence electron
X-any monoprotic acid
QX2 : any correct answer
1 mol,2 mol
1 mol, 1 mol
Na2SO4 + BaCl2 BaSO4 + 2 NaCl
Total

9
1
1
1
1
1
1
1
1
1
1
10

4a
b
c

i
ii

d
e
f

Alkene
correct structure of propanol
2C3H6 + 9O2 6CO2 +6 H2O
-Channel gas to lime water
-Lime water turns cloudy
- functional diagram
-label
Acidified potassium dichromate (VI) solution

1
1
1
1
1
1
1
1
1

i
chemical formula not structural formula
ii

float on water
Total

5a

A reaction where oxidation and reduction occur at the same time

ii

Set
1
2
Change in oxidation
number of iron
+2 +3
+2 0
Perubahan nombor
pengoksidaan bagi ferum
Half equation
Fe2+ Fe 3+ + e
Fe2+ + 2e Fe
Setengah persamaan
Type of reaction
Oxidation
reduction
Jenis tindak balas
X: copper/silver/(other metals situated lower than iron in the electrochemical series)
Y: magnesium/zinc/(other metals situated higher than iron in the electrochemical
series)
iron atoms lost electrons to form iron (II) ions//(Iron atom undergoes oxidation
- Iron (II) ions // Fe2+ is present
Total
- functional diagram
-label
-A glowing wooden splinter is placed at the mouth of text tube filled with gas released
-Gas relights the glowing wooden splinter
-Hydroxide ions attracted to anode
-Discharge to form oxygen molecules
Cl- , OH-chloride ions/ Cl-Chloride ions more concentrated than hydroxide ions
2Cl- Cl2 + 2e
Total
Heat released when 1 mole of metal copper is displaced from copper
(II) sulphate solution by a metal
Zn + Cu2+ Zn2+ + Cu
Reactant : Zn & CuSO4
Product : Cu & ZnSO4
Total enegy of Zn and CuSO4 is higher/more than total energy

ii

6a

i
ii
iii

i
ii
iii

7a

i
ii
iii

1
10
1
6

1
1
1
1
11
1
1
1
1
1
1
1
1
1
1
10
1
1
1
1
1

iii

v
b

ii

8a

i
ii

of Cu & ZnSO4
The reaction is exothermic reaction
P kJ is released when 1 mol off copper is displaced
Heat released=25 X 4.2 X 10//1050J//1.05kJ
No. of moles of Cu2+ =0.2X25.01000 //0.005 mol
H = -1.050.005 //-210kJ mol-1
Correct sign and unit
Heat is lost to the surrounding
Thermometer and container absorb some heat
HCl is stong acid//CH3COOH is weak acid
HCl ionises completely// CH3COOH ionises partially
Some heat is released are absorbed by the CH 3COOH
molecules to break down the O-H bonds
HCl is monoprotic acid//H2SO4 is a diprotic acid
Number of H+ in H2SO4 is twice
In experiment I, 1 mol of H+ reacts with 1 mol of OHproduced 1 mol of water, heat released is 57kJ
In experiment II, 2 mol of H+ reacts with 2 mol of OHproduced 2 mol of water, heat released is 114kJ

Total
Catalyst provide an alternative path with lower activation
energy
More colliding particles able to achieve activation energy
Frequency of effective collission increases
Rate of decomposition/reaction increases
Diagram with label
Functional diagram
label
volume of gas/cm3

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
20
1
1
1
1
1
1
1

time/s

iii
iv

shape & total volume same

axis and unit
Experimen I: 50/40 //1.25 cm3 s-1
Experimen II: 50/20 //2.5 cm3 s-1
Experiment II:
Concentration of hydrogen peroxide solution higher

1
1
1
1
1

Number of particles per unit volume higher

Number of collision of particles higher
Number of effective collision higher
Rate of reaction higher
2H2O2 2H2O + O2

2 mol hydrogen peroxide produce 1 mol of oxygen

Number of moles of oxygen= 5024000//0.0021 mol//

Number of moles ofhydrogen peroxide=2X0.0021 //0.0042
mol
MX50 = 0.0042 // 0.084
1000

Total

9a

% of nitrogen in ammonium sulphate

=(2X14)[(2X14)+8+32+(16X4)]X100%//21.2%
% of nitrogen in urea
= (2X14)[(2X14)+4+12+16]//46.7%
% of nitrogen in urea is higher
Urea is better fertilizer
i
ii

tin
Pure metal
Atoms are packed in orderly manner
When force is applied, layers of atom slide over each other
Alloy
Mixture of different metal
Foreign atoms // tin atoms and copper atoms - differnet
atomic size
Foreign atom//tin atoms in alloy disturb the orderly
arrangement of copper atoms
Reduce the layers of atoms from sliding
Polymer-long chain molecules made up of many (small
repeating units)//(monomer molecules)
One example of polymer
Polymerisation-the process of joing together the monomers to
form polymer
Equation
Named monomer
Non biodegradeble-improper disposal will clot drains, causes
flash floods
Open burning of plastics releases toxis gas that is harmful to
our body
(Any two correct answers)
Two methods:
Use biodegradeble plastics

ii

1
1
1
1
1
1
1
1

20
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

10
a

Reduce, reuse, recycle

Pyrolysis
(Any two correct answers)
Total
% of carbon in hexane = (6x12)[(6X12)+14]X100%//83.7%
% of carbon in hexene = (6x12)[(6X12)+12]X100%//85.7%
% of carbon in hexane is higher
Combustion of hexene produce more soot
Ethanol exists as molecules//no freely moving ions
Ethanoic acid ionises partially in water to produce freely
moving ions

II

CH3COOH + H2 O

Add spatula of (Zn powder)/(magnesium powder)/(calcium

carbonate)/(any suitable chemical) into two separate test
tubes that contain aqueous solution of ethanol and aqueous
solution of ethanoic acid
Correct observation for aqueous solution of ethanol
Correct observation for aqueous solution of ethanoic acid
(pH paper or litmus paper test not accepted)
P- ethanol
Q-propanoic acid
R-ethyl propanoate
Process S-esterification
Fermentation
10g Yeast is added into 200 cm3 pineapple juice
Left in a warm place for one week
After one week, the content of the conical flask is filtered
Pure ethanol is collected through distillation
Esterification
Pour 4 cm3 of ethanol and 2 cm3 propanoic acid into a test
tube
A few drops of concentrated acid are added
Mixture is heated for 2 minutes .The product is R.

20
1
1
1
1
1
1
1

CH3COO- + H3O+

Total

1
1

1
1
1
1
1
1
1
1

1
1
1
(Max
10
mark
s)
20