Professional Documents
Culture Documents
(Page # 2)
1.
Sol.
[PHYSICS]
5h
8
(2)
3h2
8R
(3)
h2
4R
(4)
3h
4
z0
2 0.1 9 109
1 1 3 108
1.8 109
18
3
3 108
1 /2
Mg
TM = T 1
A
'
TM2
Mg
Mg
TM2
2 =1+
T 2 1 =
A
A
T
Intensity P 1 0E2C
A 2
P
1
0E2C
4R 2 2
2P
40R 2C
2
1
A TM 1
Mg T
4.
(1)
PE
E
PE
E 6 2.45 V / m
3.
'
g
Also:
; TM = 2
g
Mg / A
Mg
Mg
'
'
=
=
=1+
/
A
A
TM
=
T
3h
4
(From class theory)
Sol.
3
T = 2
4
z0
2.
Sol.
A pendulum made of a uniform wire of crosssectional area A has time period T. When an
additional mass M is added to its bob, the
time period changes to TM. If the Young's
modulus of the material of the wire is Y then
1/Y is euqal to : (g = gravitational acceleration)
2
TM A
1
(1)
T Mg
T A
(2)
TM Mg
T 2
A
M
(3) T 1 Mg
T 2
Mg
M
(4) T 1 A
(2)
KE
(3)
KE
PE
d
(4)
PE
KE
d
4
KEmax at mean position.
U=0
KE=0
(Page # 3)
7.
U=0
KE=0
(1) 2
Extreme
MP
V=max
=0
Extreme
(2)
Sol.
Sol.
i x
0i2
2d
Change is ~
12%
tan =
V
= neAVd
R
VA
= neAVd
5
= 8 1028 1.6 1019 2.5 104
0.1
{R
gL
(4) 2 sin cos
0
320
f2 = 1000
= 941 Hz
300 20
Sol.
gL
(3) sin cos
0
320
f1 = 1000 300 20 = 1066 Hz
6.
gL
tan
0
l
}
A
0i2
2d
.g.
.g. sin
i2 = . cos (2) d
0
i = 2 sin
8.
[d = 2L sin]
gL
0 cos
= 1.56 105 m
5
~
1.6 10 m
(Page # 4)
Sol.
Sol.
i0 =
15
0.15 103
= 0.1A
Rt
9V
i = i0 e L
= 0.1 e
x9
x6
x
+
+
=0
5
3
1
3x 27 5x 30 15x
=0
15
3
A
23
from Q to P
x=
9.
Sol.
D
500 10 9 25 102
d
2 0.25 102
y 30m
10.
V
R
P0
2
According to given conditions:
0.15103 10 3
0.03
= 0.1 e5 =
11.
0.1
= 0.67 mA
150
C
If a student plots graphs of the square of
maximum charge (Q2max) on the capacitor with
time (t) for two different values L1 and L2
(L1 > L2) of L then which of the following
represents this graph correctly ? (Plots are
shematic and not drawn to scale)
L1
Max
(1)
L2
t
(2)
(1) 6.7 mA
(3) 100 mA
(2) 0.67 mA
(4) 67 mA
Max
Q0
Alternative solution
The value of Qmax reduces because of energy
dissipation in resistor. As the value of inductor
increases the time taken for capacity to
discharge or charge increases therefore heat
dissipation time decreases. Hence corrcect
graph is 3.
12.
In the given circuit, charge Q2 on the 2F
capacitor changes as C is varied from 1F to
3F. Q2 as a function of 'C' is given properly
by : (figure are drawn shematically and are
not to scale)
L1
Max
(3)
(Page # 5)
L2
t
1F
Max
L2
L1
(4)
2F
E
Sol.
Charge
R
(1)
KVL
Q2
3F
Q2
1F
Charge
dI q
0
dt C
d2q
dq q
R
dt 2
dt C
comparing with equation of damped oscillation
(3)
(2)
1F
IR L
Charge
Sol.
d2 y
dy
ky
dt 2
dt
bt
(4)
3F
Q2
1F
4
3C
q
E
C 3
q = CV
q C
where b
2m 2L
qmax q0e
q2max q20e
Rt
2L
Rt
R
time constant =
L
since L1 > L2
1 < 2
Hence correct graph is 3.
Charge
Q2
1F
3F
3C
2
q2
E
C
3
2C
q2
E
C 3
2C
q2
E
1 3
C
q = CV
C q2
If C , q = constant value.
3F
(Page # 6)
13.
(1)
(2)
9 3
MR2
(3)
Sol.
(4)
32 2
4MR
Sol.
dT 1 dL 1 dg
T
2 L
2 g
90
1
100 100
3 3
1 dg 1 dL dT
2 g
2 L
T
MR2
16 2
1 0.1
1 /100
1
1
2 20 90 /100 400 90
1
I=
Mx2
6
1 dg
1
1
2 g
400 90
dg 490
2
g
400 90
3x
2R
490
= 0.20272
200 90
Now,
mass of cube :
M
4
m = R 3
3
3M
3
4R
m=
I=
14.
2R
8R 3
3 3
15.
R
R
2M
3
1
3
2M 4R 2
3 3
Sol.
4MR 2
9 3
is T 2
16.
Sol.
1
Frequencies are
FC, FC FS
17.
Sol.
(Page # 7)
Consider a spherical shell of radius R at
temperature T. The black body radiation inside
it can be considered as an ideal gas of photons
with internal energy per unit volume
1U
U
T 4 and pressure p . If the
3V
V
Sol.
1
R
(3) T e R
1
u
U
T4
V
1U
3V
(2) T
1
R3
(4) T e3R
Adiabatic expansion
TV1 = K
TV 4 C
150
(i) s1
200
dQ
dT
dT
ms
ms
T
T
T
100
150
r 1
4
3
1
4
150
200
ln
ln
100
150
4
3
4
3
ln ln
2
3
TV 4 C
s1 ln2
TV 3 C
(ii) s2
dQ
T
112.5
100
125
dQ
dQ
......
T
T
112.5
4
3
T R 3 C
3
112.5
125
ln
ln 112.5 .....
100
19.
9
10
16
ln ln
ln
8
9
15
16
ln
= ln2
8
1
R
(Page # 8)
(The figures are schematic and not drawn to
scale)
sr = vr t = 30 8 = 240 m
(y2y1)m
(y2y1) m
t=8sec
240
240
`
(1)
12
t=1sec
t(sec)
t(s)
8 sec < t 12 sec
vr increases in magnitude and relative
acceleration is g downwards
(y2y1) m
240
(y2y1)m
240
(2)
8
12
t(s)
8
12
t(sec)
(y2y1) m
240
20.
(3)
240
12
t(s)
(y2y1) m
3V0
,
2
5V0 3V0
V
,
and 0 have radius R1, R2, R3
4
4
4
(4)
Sol.
t(s)
(2) 2R < R4
(3) R1 = 0 and R2 > (R4 R3)
1
Ist stone
Sol.
0 t 8 sec
vr = 40 10
= 30 m/s
ar = 0
t=2sec
r=R
t=6sec
R1
3V0
5V0
3V0
V
; R2
; R3
; R4 0
2
4
4
4
rR
v
KQ
3R2 r2
2R 3
(Page # 9)
21.
3V0
, R1 0
2
5V0
KQ
3R 2 R 22
4
2R 3
R2
3
r2 < c
r2 < sin1 (1/)
sin r2 < 1/
sin = sin r1
r1 = sin1 (sin/)
sin (A r1) < 1/
A
r1
r2
1
1 sin
R
2
r>R
sin
A sin1 < sin1
3V0 KQ
4
R3
R3
1
A sin1 < sin1
4KQ KQ R R
3V0
3 KQ 3
V0 KQ
4
R4
4KQ 4KQ
R 4R
V0
KQ
1 1
sin1 sin A sin m <
On comparing we get
(1) or (2)
22.
21.
z
I
(a)
I
x
(1) >
sin
sin
1 1
sin A sin <
R4
cos1
1 1
sin A sin
1 1
(2) < cos1 sin A sin
1 1
sin A sin
1 1
(4) > sin1 sin A sin
I
y (b)
(c) I
I
I
I
z
I
B
I
B
I
B
y (d)
I
x
y
I
(Page # 10)
Sol.
23.
Sol.
For equilibrium = 0
= MB sin n
If, sin = 0; = 0
(3) F1 = F2 = 0
24.
Sol.
(1) 56%
(2) 62%
(3) 44%
1
(4) 50%
2v
v
2m
before collision
Px = 2mv i
Py = 2mvj
outwards
3
Cross-sectional view
V'
3m
i1
i2
After collision
Px = 3mv'cos
Py = 3 v' sin
By momentum conservation ;
in horizontal 2mv = 3mv' cos
in vertical 2mv = 3mv' sin
from (i) and (ii) tan = 1; = 45
...(i)
...(ii)
2 2v
3
initial K.E. ; 1/2 (m) (2v)2 + 1/2 (2m) (v)2 = 3mv2
2 2v
= 4/3 mv2
final K.E. ; 1/2 (3m)
F1 0
F2 0
% loss
(KE)i (KE)f
100%
(KE)i
= 55.55 ~
56%
(Page # 11)
Sol.
CP
of q is : C
V
(1)
(3)
Sol.
1
2
(2)
3 5
6
(4)
1
2
R/2
C
3 5
6
1
mean free path
1
2d n
no. of molecules
volume
T.V-1 = C
vavg.
T
V
C
vr 1
vq v
q
v avg.
v is volume
1
2
1
2
1
2
2GM
(1)
3R
(3)
GM
2R
2GM
(2)
R
(4)
GM
R
3G (M / 8)
GM
GM 3R 2 R
+
=
3
2
2 (R / 2)
2R
27.
Sol.
26.
4
Solid sphere is of mass M, radius R.
Spherical portion removed have radius
R/2, therefore its mass is M/8.
(Page # 12)
28.
Sol.
ETotal = 13.6 eV
PE = 2 Etotal
As n decreases, Total energy decreases,
potential energy decreases and kinetic energy
increases.
++
++
Z2
n2
KE = |ETotal|
++++
+
(1)
30.
(2)
++
+
+
++++
+
ListI
(A)
FranckHertz
Experiment
(B)
Photo-electric
ListII
(i) Particle nature of
Experiment light
(ii) Discrete energy
experiment
Davison-Germer
levels of atom
(iii) Wave nature of
Experiment.
++++
(3)
electron
(iv) Structure of atom
++
++
(C)
(1) A ii ; B i ; C iii
(2) A iv ; B iii ; C ii
(4)
++++
+
++
++
(3) A i ; B iv ; C iii
Sol.
3
Tangent to the electrical field lines will give
us the direction at a given point.
29.
An an electron makes a transition from a excited state to the ground state of a hydrogenlike stom/ion :
(1) Kinetic energy decreases, potential energy increases but total energy remains same
(2) Kinetic energy and total energy decrease
but potential energy increase
(3) Its kinetic energy increases but potential
energy and total energy decrease.
(4) Kinetic energy potential energy and total
Sol.
(4) A ii ; B iv ; C iii
1
Photoelectric experiment is linked with particle
nature of light
energy decrease
Let and be three non- zero vectors such that no two of them are collinear and () =
If q is the angle between vectors and , then a value of sin is :
(1)
(2)
(3)
(4)
32.
Let O be the vertex and Q be any point on the parabola, x2 = 8y. If the point P divides the
line segment OQ internally in the ratio 1 : 3, then the locus of P is
(1) y2 = 2x
(2) x2 = 2y
(3) x2 = y
(4) y2 = x
33.
If the angles of elevation of the top of a tower from three collinear points A, B and C, on a
line leading to the foot of the tower, are 30, 45 and 60 respectively, then the ratio, AB :
BC, is :
(1)
(2) 2 : 3
(3)
(4)
34.
The number of points, having both co-ordinates as integers, that lie in the interior of the
triangle with vertices (0, 0), (0, 41) and (41, 0), is
(1) 820
(2) 780
(3) 901
(4) 861
35.
36.
Let A and B be two sets containing four and two elements respectively. Then the number of
subsets of the set A B, each having at least three elements :
(1) 275
(2) 510
(3) 219
(4) 256
37.
is equal to
(1) 2
(2)
(3) 4
(4) 3
39.
The distance of the point (1, 0, 2) from the point of intersection of the line = = and the
plane x y + z = 16, is
(1)
(2) 13
(3)
(4) 8
40.
41.
Th e
su m
+ + + ..... is :
(1) 142
of
f i rst
(2) 192
t erms
(3) 71
of
the
seri es
(4) 96
42.
The area (in sq. units) of the region described by {(x, y) : y2 2x and y 4x 1} is
(1)
(2)
(3)
(4)
43.
The set of all values of l for which the system of linear equations :
2x1 2x2 + x3 = x1
2x1 3x2 + 2x3 = x2
x1 + 2x2 = x3
has a non-trivial solution,
(1) contains two elements.
(2) contains more than two elements..
(3) is an empty set.
(4) is a singleton.
44.
A complex number z is the said to be unimodular if |z| = 1. Suppose z1 and z2 are complex
number such that is unimodular and z2 is not unimodular.
Then the point z1 lies on a :
(1) circle of radius 2.
(2) circle of radius .
(3) straight line parallel to x-axis
(4) straight line parallel to y-axis
45.
46.
The number of integers greater than 6,000 that can be formed, using the digits 3, 5, 6, 7
and 8, without repetition, is :
(1) 120
(2) 72
(3) 216
(4) 192
47.
Let y(x) be the solution of the differential equation (x log x) + y = 2x log x, (x 1). Then
y(e) is equal to :
(1) 2
(2) 2e
(3) e
(4) 0
48.
If A = is a matrix satisfying the equation AAT = 9I, where I is 3 3 identity matrix, then the
ordered pair (a, b) is equal to
(1) (2, 1)
(2) ( 2, 1)
(3) (2, 1)
(4) ( 2, 1)
49.
If m is the A.M. of two distinct real numbers l and n(l, n > 1) and G1, G2 and G3 are three
geometric means between l and n, then equals.
(1) 4 lmn2
(2) 4 l2m2n2
(3) 4 l2mn
(4) 4 lm2n
50.
(4) s ^ (r ^ ~ s)
(4)
51.
(2)
(3)
52.
53.
Let
t an 1 y
=
where |x| < . Then a value of y is :
(1)
(2)
54.
t an 1 x
(3)
t an 1 ,
+
(4)
(4)
55.
The mean of the data set comprising of 16 observations is 16. If one of the observation
valued 16 is deleted and three new observations valued 3, 4 and 5 are added to the data,
then the mean of the resultant data, is :
(1) 15.8
(2) 14.0
(3) 16.8
(4) 16.0
56.
(3) 2
(4) 4
57.
58.
(3) 8
(4) 4
59.
The area (in sq. units) of the quadrilateral formed by the tangents at the end points of the latera
recta to the ellipse + = 1, is :
(1)
(2) 27
(3)
(4) 18
60.
If 12 identical balls are to be palced in 3 identical boxes, then the probability that one of the
boxes contains exactly 3 balls is :
(1)
(2)
(3)
(4)
Let and be three non- zero vectors such that no two of them are collinear and () = .
If is the angle between vectors and , then a value of sin is :
(1)
(2)
(3)
(4)
3
31.
Sol.
,
bc cos =
cos =
32.
Sol.
sin =
Let O be the vertex and Q be any point on the parabola, x2 = 8y. If the point P divides the
line segment OQ internally in the ratio 1 : 3, then the locus of P is
(1) y2 = 2x
(2) x2 = 2y
(3) x2 = y
(4) y2 = x
2
Let P : (h, k)
33.
Sol.
34.
Sol.
(,) on Parabola
2 = 8 (4h2) = 8.4 k
16h2 = 32k
x2 = 2y
If the angles of elevation of the top of a tower from three collinear points A, B and C, on a
line leading to the foot of the tower, are 30, 45 and 60 respectively, then the ratio, AB :
BC, is :
(1)
(2) 2 : 3
(3)
(4)
3
The number of points, having both co-ordinates as integers, that lie in the interior of the
triangle with vertices (0, 0), (0, 41) and (41, 0), is
(1) 820
(2) 780
(3) 901
(4) 861
2
x + y < 41
1 to each
x + y < 39 x + y 38 x + y + z = 38
38 + 3 1
C31 = 40C2 = .
35.
Sol.
36.
Sol.
37.
Sol.
38.
Sol.
39.
Sol.
(3) 4
(4) 3
(3 + 1) = 2
The distance of the point (1, 0, 2) from the point of intersection of the line = = and the
plane x y + z = 16, is
(1)
(2) 13
(3)
(4) 8
2
P(3 + 2, 4 1, 12 + 2)
3 + 2 4 + 1 + 12 + 2 = 16
11 = 11
=1
40.
Sol.
41.
Sol.
42.
Sol.
=
43.
Sol.
The set of all values of for which the system of linear equations :
2x1 2x2 + x3 = x1
2x1 3x2 + 2x3 = x2
x1 + 2x2 = x3
has a non-trivial solution,
(1) contains two elements.
(2) contains more than two elements..
(3) is an empty set.
(4) is a singleton.
2
= (2 ) (2 + 3 4) + 2 ( 2 + 2) + 1 (4 3 ) = 0
3 2 + 6 + 8 3 8 = 0
3 2 + 5 3 = 0
3 + 2 5 + 3 = 0
( + 1) (2 + 2 3) = 0
( + 1) ( + 3) ( 1) = 0
= 1, 1, 3
44.
Sol.
A complex number z is the said to be unimodular if |z| = 1. Suppose z1 and z2 are complex
number such that is unimodular and z2 is not unimodular.
Then the point z1 lies on a :
(1) circle of radius 2.
(2) circle of radius .
(3) straight line parallel to x-axis
(4) straight line parallel to y-axis
1
(z1 2z2)
45.
Sol.
46.
Sol.
47.
Sol.
48.
Sol.
|z1| = 2
The number of common tangents to the circles x2 + y2 4x 6y 12 = 0 and x2 + y2 + 6x
+ 18y + 26 = 0, is :
(1) 3
(2) 4
(3) 1
(4) 2
1
x2 + y2 4x 6y 12 = 0
C1 (2, 3)
r1 = = 5
x2 + y2 + 6x + 18y + 26 = 0
C2 (3, 9), r2 = = 8
C1C2 = = 13
The number of integers greater than 6,000 that can be formed, using the digits 3, 5, 6, 7
and 8, without repetition, is :
(1) 120
(2) 72
(3) 216
(4) 192
4
6/7/8
3 4C3 3! = 72
= 120
Total = 192
Let y(x) be the solution of the differential equation (x log x) + y = 2x log x, (x 1). Then
y(e) is equal to :
(1) 2
(2) 2e
(3) e
(4) 0
1
+ .y=2
I.F. =
y log x = dx
y log x = 2 (x log x x ) + c
x=1
c=2
x=e
y = 2(e e) + 2 = 2
If A = is a matrix satisfying the equation AAT = 9I, where I is 3 3 identity matrix, then the
ordered pair (a, b) is equal to
(1) (2, 1)
(2) ( 2, 1)
(3) (2, 1)
(4) ( 2, 1)
2
AAT = 9 I
49.
Sol.
50.
Sol.
51.
Sol.
52.
Sol.
a + 4 + 2b = 0 a + 2b = 4 ....(i)
2a + 2 2b = 0 a b = 1 ....(ii)
From i and ii
3b = 3 b = 1
a=2
If m is the A.M. of two distinct real numbers l and n(l, n > 1) and G1, G2 and G3 are three
geometric means between l and n, then equals.
(1) 4 lmn2
(2) 4 l2m2n2
(3) 4 l2mn
(4) 4 lm2n
4
m=
2m = + r4
G1
G2
G3
n
2
3
r
r
r
r4 = n
4 4
4 8
4 12
r + 2 r + r
4r4(1 + 2r4 + r8)
4r4 (1 + r4)2
4r4
n 3
4m2n
The negation of ~ s v(~ r ^ s) is equivalent to :
(1) s v (r v ~ s)
(2) s ^ r
(3) s ^ ~ r
(4) s ^ (r ^ ~ s)
2
~ S V (~ r ^ S)
The integral equals :
(1)
2
(2)
(3)
= = ...(1)
put
1 + x4 = T4
4x5 d x= 4T3 dT
(1) become
=T+C
= (1 + x4)1/4 + C =
The normal to the curve, x2 + 2xy 3y2 = 0, at (1, 1) :
(1) meets the curve again in the third quadrant.
(2) meets the curve again in the fourth quadrant.
(3) does not meet the curve again.
(4) meets the curve again in the second quadrant.
2
x2 + 2xy 3y2 = 0
diff. w.r.t. x
2x + 2x (y) + 2y 6yy = 0
2 + 2y + 2 6y = 0
4y = 4
y = 1
slope of normal = 1
So equation becomes
y 1 = 1 (x 1)
x+y=2
(4)
53.
Sol.
y = 1, 1
thus second point of intersection is (3, 1) is in 4th qud.
Let
t an 1 y
=
t an 1 x
where |x| < . Then a value of y is :
(1)
(2)
(3)
3
tan1 y = tan1 x + tan1
|x| <
tan1 = 2 tan1 x
54.
Sol.
t an 1 ,
+
(4)
y=
g(3) = g (3+)
= 3m + 2
2k = 3m + 2 ......(1)
(4)
Again
g(3+) = g (3)
m=
4m = k.....(2)
55.
Sol.
k+m= =2
The mean of the data set comprising of 16 observations is 16. If one of the observation
valued 16 is deleted and three new observations valued 3, 4 and 5 are added to the data,
then the mean of the resultant data, is :
(1) 15.8
(2) 14.0
(3) 16.8
(4) 16.0
2
......(1)
(1)
(2)
......(2)
a1 + a2 + a3 +.....+ a15 = (16)2 16
now
56.
Sol.
57.
Sol.
58.
Sol.
= = = 14
mean = 14
The integral dx is equal to :
(1) 1
(2) 6
(3) 2
(4) 4
1
.....(1)
using
I = ....(2)
(1) + (2) gives
2I =
I=1
Let and be the roots of equation x2 6x 2 = 0. If an = n n, for n 1, then the value
of is equal to :
(1) 3
(2) 3
(3) 6
(4) 6
1
x2 6x 2 = 0 2 6 2 = 0
26 2 = 0 .....(1)
an = n n n 1
a40 298 = 10 10 28 +28
= 8 (a2 2) b8 (b2 2)
= 8(6) 8(6)
(using (1)
= 69 69
= 6a9
now
59.
Sol.
4a + 3b = 4
32a + 12b = 8
32a + 24b = 32
The area (in sq. units) of the quadrilateral formed by the tangents at the end points of the latera
recta to the ellipse + = 1, is :
(1)
(2) 27
(3)
(4) 18
2
a=3b=
e2 = 1
=1
e=
now the quadrilateral formed will be a rhombus with area =
60.
Sol.
=
= 27
If 12 identical balls are to be placed in 3 identical boxes, then the probability that one of the
boxes contains exactly 3 balls is :
(1)
(2)
(3)
(4)
3
Success (p) =
Failure (q) =
Acc. to binomial distribution, we have to find,
P(x = 3) = .
=.
(Page # 20)
61.
[CHEMISTRY]
CH3
CH3
Sol.
(1)
NH2
Sol.
N2Cl
CN
CuCN/KCN
+ N2
5
4
1 CHO
3
CH3
CH3
65.
Sol.
Sol.
67.
In the reaction
NH2
NaNO2/HCl
0 - 5C
CuCn/KCN
CH3
E + N2
CH3
(D)
(E)
r=
CH3
3a = 4r
CH3
0-5C
66.
63.
(3)
CH3
NaNO2/HCl
CH3
CH3
Sol.
(2)
CH3
ozonolysis
62.
(1)
(4) H3C
(4)
CH3
COOH
CH 3
(4)
CH3
Sol.
CN
CH3
CH3
(3)
Sol.
1.732 4.29
= 1.86
4
compounds is not
= Yellow
= Yellow
= White
= Yellow
13.6
for hydrogen ; z = 1 2
n
n2
Possible is 13.6, 3.4, 1.5 etc.
Sol.
69.
Sol.
70.
Sol.
71.
KMnO4
SOCl2
(Page # 21)
72.
Sol.
73.
Sol.
74.
H2/Pd BaSO4
Sol.
(2) C6H5CHO
(4) C6H5CH3
COOH
Sol.
75.
KMnO4
(A)
SOCl2
CHO
COCl
Sol.
H2/Pd
BaSO4
(C)
(B)
(Page # 22)
76.
Sol.
2
309
(2)
1
412
(3)
1
103
(4)
1
206
(2)
2C8H7SO3Na + Ca7+ (C8H7SO3)2Ca
2 mole
1 mole
2 206 gm take 1 mole of Ca2+
1gm takes
77.
Sol.
78.
78.
79.
Sol.
1
mole of Ca2+.
412
Sol.
81.
Sol.
141 103
80
188
82.
Sol.
RF + AgCl/AgBr
0.9 103 60
103
3
54
= 18 mg
3
The vapour pressure of acetone at 20C is
185 torr. When 1.2 g of a non-volatile
substance was dissolved in 100 g of acetone
at 20C, its vapour pressure was 183 torr.
The molar mass (g mol1) of the substance
is:
(1) 128
(2) 488
(3) 32
(4) 64
(4)
P = 185
83.
141 103
188
141 103
80
100
188
250 103
= 24%
% of Br =
80.
Sol.
n
P0 P
=
N
P
M = 64
1.2 / M
185 183
=
100
/ 58
183
Sol.
85.
Sol.
1
reaction mixture is [A] = , [B] = 2 and [C]
2
1
. The reaction proceeds in the :
=
2
[R = 8.314 J/K/mol, e = 2.718]
(1) forward direction because Q < KC
(2) reverse direction because Q < KC
(3) forward direction because Q > KC
(4) reverse direction because Q > KC
(4)
G at 300K = 2494.2 J
2A
(Page # 23)
87.
Sol.
88.
Sol.
89.
(1) 86600
B+C
G = RT n K
2494.2 = 8.314 300 n K
K = 10
Sol.
1
2 4
=
.
Q=
2
[A]2
1
2
Q > KC reverse direction.
[B][C]
86.
Sol.
0
0
= Gr = 2GNO2 2GNO
90.
Sol.