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1. INTRODUCTION
The search for cleaner fuel technology is driven by many factors including lack of
availability of fossil fuels, environment norms and concerns about global warming.
This quest has resulted in a number of technological trials and endeavors for
developing cleaner fuel and engines. In spite of the limitations because of emission
constraints one cannot compromise on the performance and efficiency of the engines.
Among the alternative fuels, biodiesel has received ample attention due to their
attractive characteristics of being renewable in nature and decreasing effect on HC
and CO emissions. On the contrary, major problems associated with the use of
biodiesel are lower engine power, higher BSFC due to their lower calorific values,
higher densities and viscosities. NOx emission also increases with the use of biodiesel
for higher fuel bound oxygen. To overcome some of these difficulties use of ethanol,
n-butanol or diethyl ether in small proportion as additive has come out with great
potential recently. Similarly many researchers have developed new methods for
efficient combustion of fuels. Porous media combustion, also known as filtration
combustion in a packed bed, due to the interaction between two different phases, solid
and gas or liquid. The theory of filtration combustion involves a new type of flame
with exothermic chemical reactions during fluid flow in a porous medium. The term
'filtration combustion' was introduced by Russian scientists for combustion of gas
flow through porous media. This term does not correspond to western scientific
terminology, still it can be found in special literature as a synonym to combustion
within porous media (PM) [1]. This process facilitates a combustion process with
stability in a wide range of reactant fluid velocities, air-fuel ratios, and power density.
PM combustion has some unique characteristics. It gives rise to high radiant output,
low NOx (Oxides of Nitrogen) and CO (Carbon Monoxide) emissions, high flame
speed and higher power density.
In the literature there are a few studies, which are focused on liquid fuel
combustion in PM to prove its advantages in supporting Mixture formation and
improving combustion processes [36]. Martynenko et al. [4] numerically modeled
the fuel droplet collision with a high porosity PM by using a collision probability and
analyzed one-dimensional, self-sustaining combustion in inert porous media with all
modes of heat transfer. Kayal and Chakravarty [3] presented a numerical analysis of
combustion of liquid fuel droplets suspended in air inside an inert PM. A model based
on a combined self-sustained liquid fuel vaporizationcombustion system was
developed. A counter-flow annular heat recirculating burner fueled with kerosene was
designed and experimentally studied by Newburn and Agrawal [4] for lean
prevaporized, premixed combustion to evaluate its heat transfer and combustion
performance. The system was shown to produce low emissions. The latest reviews of
liquid fuel combustion in porous media are provided by Mujeebu et al. [5,6]. Durst
and Weclas [7, 8] proposed the concept of the PM engine and performed a systematic
experimental study on a test engine, which was a modified diesel engine by inserting
a SiC PM into the cylinder head between the intake and exhaust valves. Fuel was
injected into the PM volume, and consequently, all combustion events, i.e., fuel
vaporization, fuelair mixture formation, and homogenization, internal heat
recuperation, as well as combustion reactions occurred inside the PM. Their results
demonstrated many attractive characteristics of the PM engine in comparison with the
original one, such as a very low emission level, high cycle efficiency, and low
combustion noise. In a numerical study, based on a multizone combustion model,
Macek and Polassek [9] modeled the working process of a PM engine fueled with
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methane and hydrogen, respectively, and discussed some important issues concerning
practical applications of the PM engine. Recently, Zhao and Xie [10,11] investigated
the interaction between a pressure swirl fuel spray and a hot porous medium, as well
as the compression ignition and combustion characteristics of a PM engine using a
two-dimensional numerical model, while Liu et al. [12,13] analyzed the heat
regenerative cycle in a PM engine. and evaluated its thermodynamic performance
based on single zone and two-zone thermodynamic models. The above mentioned
studies are all based on the PM engine concept proposed by Durst and Weclas [7, 8],
in which the PM insert is fixed in the combustion chamber. There is another design of
PM engine configuration, namely, the regenerative engine which was proposed by
Ferrenberg [14]. In this regenerative engine, a porous insert, functioning as a
regenerator, is attached to a rod and moves in the cylinder, synchronized but out of
phase with the piston. During the regenerative heating stroke, the porous medium
remains just beneath the cylinder head for most of the period and moves down to the
piston while it reaches the top-dead-center (TDC) position, the intake air arrives in the
cylinder and is then heated by passing through the hot PM insert. During the
regenerative cooling stroke, the regenerator moves up and remains in the original
position until the next regenerative heating stroke. After all the fuel has combusted,
hot exhaust gas flows through the PM insert and delivers part of the reaction heat into
the PM.
In the literature there are a few studies, which are focused on liquid fuel
combustion in PM to prove its advantages in supporting Mixture formation and
improving combustion processes [36]. Martynenko et al. [4] numerically modeled
the fuel droplet collision with a high porosity PM by using a collision probability and
analyzed one-dimensional, self-sustaining combustion in inert porous media with all
modes of heat transfer. Kayal and Chakravarty [3] presented a numerical analysis of
combustion of liquid fuel droplets suspended in air inside an inert PM. A model based
on a combined self-sustained liquid fuel vaporizationcombustion system was
developed. A counter-flow annular heat recirculating burner fueled with kerosene was
designed and experimentally studied by Newburn and Agrawal [4] for lean
prevaporized, premixed combustion to evaluate its heat transfer and combustion
performance. The system was shown to produce low emissions. The latest reviews of
liquid fuel combustion in porous media are provided by Mujeebu et al. [5,6]. Durst
and Weclas [7, 8] proposed the concept of the PM engine and performed a systematic
experimental study on a test engine, which was a modified diesel engine by inserting
a SiC PM into the cylinder head between the intake and exhaust valves. Fuel was
injected into the PM volume, and consequently, all combustion events, i.e., fuel
vaporization, fuelair mixture formation, and homogenization, internal heat
recuperation, as well as combustion reactions occurred inside the PM. Their results
demonstrated many attractive characteristics of the PM engine in comparison with the
original one, such as a very low emission level, high cycle efficiency, and low
combustion noise. In a numerical study, based on a multizone combustion model,
Macek and Polassek [9] modeled the working process of a PM engine fueled with
methane and hydrogen, respectively, and discussed some important issues concerning
practical applications of the PM engine. Recently, Zhao and Xie [10,11] investigated
the interaction between a pressure swirl fuel spray and a hot porous medium, as well
as the compression ignition and combustion characteristics of a PM engine using a
two-dimensional numerical model, while Liu et al. [12,13] analyzed the heat
regenerative cycle in a PM engine. and evaluated its thermodynamic performance
based on single zone and two-zone thermodynamic models. The above mentioned
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studies are all based on the PM engine concept proposed by Durst and Weclas [7,8],
in which the PM insert is fixed in the combustion chamber. There is another design of
PM engine configuration, namely, the regenerative engine which was proposed by
Ferrenberg [14]. In this regenerative engine, a porous insert, functioning as a
regenerator, is attached to a rod and moves in the cylinder, synchronized but out of
phase with the piston. During the regenerative heating stroke, the porous medium
remains just beneath the cylinder head for most of the period and moves down to the
piston while it reaches the top-dead-center (TDC) position, the intake air arrives in the
cylinder and is then heated by passing through the hot PM insert. During the
regenerative cooling stroke, the regenerator moves up and remains in the original
position until the next regenerative heating stroke. After all the fuel has combusted,
hot exhaust gas flows through the PM insert and delivers part of the reaction heat into
the PM.
The primary objective of the proposed work is to model and simulate the
combustion and emission process in direct injection diesel engine in the presence of a
Porous Media (PM) inside the IC engine for different fuel blends. The final ratio of
the improved blends consisted 80% diesel, 15% palm biodiesel and 5% additive. The
idea was to maintain 20% of biofuel into the blends.. In this paper a modified KIVA
3 code is used along with Wiebes combustion model for modeling the combustion.
Similarly emission of NOx and Soot are also suitably modeled. The modeled features
are incorporated in the form of a modified KIVA code and the results of the
simulation are presented. The analysis is specifically carried out in regard to fuel
consumption, brake power delivered and emissions. These analysis were carried out at
a constant speed.
2. FUEL BLENDS
Most of the researchers have concentrated their attention to the density, kinematic
viscosity, flash point, and calorific value to define the quality of fuel [15-18]. Among
them density and viscosity are the most important parameters of fuel because the fuel
has to flow through various pipelines, nozzles and orifices. Furthermore, they have
great influence on the atomization of fuel which governs the quality of combustion as
well as the performance and emission characteristics. As the density and viscosity of
biodiesel are higher than diesel, use of ethanol, n-butanol and diethyl ether as
additives helped to decrease both density and viscosity. Investigations have been
carried out on different proportions of ethanol in the biodiesel - diesel blend to
improve the performance and emission characteristics [19, 20]. n-butanol is a strong
alcohol competitor of ethanol as additive to be used in diesel engine which is also a
biomass-based renewable fuel. n-butanol has higher heating value, higher cetane
number, less hydrophilic tendency and higher miscibility than ethanol. Hence, nbutanol has got superior characteristics than ethanol to be used as additive. Diethyl
ether, another potential additive, can be produced from ethanol. It has got a very high
cetane number, high oxygen content, low autoignition temperature, high miscibility in
diesel and broad flammability limits. The final ratio of the improved blends consisted
80% diesel, 15% palm biodiesel and 5% additive. The idea was to maintain 20% of
biofuel into the blends. For the sake of ease, blends containing ethanol, n-butanol and
diethyl ether were named D80P15E5, D80P15B5 and D80P15DE5 respectively.
These additives have got decreased calorific values than biodiesel, so the blends
showed the less calorific value than DP20. Flash point also showed a decreased
manner. Regarding cetane number, with an exception of D80P15DE5, D80P15B5 and
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D80P15E5 showed lower values than DP20.The characteristics of the fuel are listed in
Table 1.0
Table 1 Characteristics of the Fuels
Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
Kinematic
Viscosity
( @40 0C
mm2/ sec)
3.46
3.62
3.23
3.29
3.27
Density
(Kg/m3)
Calorific
Value
(Kj/g)
Cetane
Number
Flash
Point
(0C)
833
837
833
833
832
44.66
43.71
43.08
43.43
43.41
47
48
46
47
52
69.5
93.5
84.5
85.5
81.5
(1)
W= =
(2)
or the non-dimensional burn fraction x and its derivative w (burn rate) as functions of
time t can be written as
X=1-
(3)
W= =
(4)
The time it takes to reach maximum burn rate tm can be found by differentiating
equation (4) and equating the result to zero
tm=td (
)1/ (m+1)
(5)
(6)
Wiebe suggested the physical meaning of the exponent m which was based on
equation (5), which shows that for a given combustion duration the time it takes for
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(7)
(8)
pn exp
(9)
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5. RESULTS
A modified KIVA 3V code is used to simulate and analyze the performance of the
proposed model. The specifications of the engine modeled are illustrated in the Table
2. The necessary modeling parameters are fed and modeled initially using K3PREP
solved using the code and processed using K3POST.
Table 2 Engine specifications
Bore
Stroke
Length of Connecting Rod
Squish
Compression Ratio ( CR)
RPM
13.716 cm2
16.51 cm
26.3 cm
0.4221 cm
15:1
1600
Similarly other factors that are considered in this model are listed in the Table
(3.0). These parameters are vital for further analysis and modeling of combustion and
emission.
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433.3K
523.3K
553.0K
341.0K
1.96 e+6 dyn/cm2
325.0K
The analysis for performance and emission characteristics has been carried out at
a constant speed of 1600 RPM
Table 4 Engine brake power comparison for different blends without PM inside combustion
chamber at an RPM of 1600
Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
Table 5 Engine Brake Power comparison for different blends with PM inside combustion
chamber at an RPM of 1600
Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
The lowest power for DP20 can be attributed to its lower calorific value and lower
combustion efficiency due to higher density and viscosity. D80P15E5, D80P15B5 and
D80P15DE5 gave higher increment of brake power than DP20 respectively at 1600
rpm. However, in spite of lower calorific value, these blends showed higher brake
power than DP20 which ensures higher combustion efficiency. This higher
combustion efficiency is the result of their decreased density and viscosity which
improved atomization.
Table 6 Brake Specific Fuel Consumption for different blends without PM inside combustion
chamber at an RPM of 1600
Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
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BSFC (g/(kW-hr))
249.45
250.72
251.87
239.63
237.84
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BSFC (g/(kW-hr))
232.60
235.4261
236.3296
224.7729
221.9047
As the comparison of BSFC is effected at a constant speed and constant full load,
which means at a certain engine power, the values of BSFC are then obviously
directly proportional to the fuel mass flow rate. It can be seen that D80P15B5 and
D80P15DE5 has shown lower BSFC corresponding to DP20 as well as diesel.
Though they have got lower calorific values, this kind of result can be attributed to
good atomization and combustion quality. Combining the facts, lower BSFC with
lower calorific value.
Table 8 Brake Thermal Efficiency for different blends without PM inside combustion
chamber at an RPM of 1600
Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
Efficiency %
17.8
18.1
18.4
18.7
18.9
Table 9 Brake Thermal Efficiency for different blends with PM inside combustion chamber
at an RPM of 1600
Type of Fuel
Efficiency %
Diesel
18.2
DP20
18.6
D80P15E5
18.7
D80P15B5
19.0
D80P15DE5
19.2
Table 8 can be easily explained where it shows the brake thermal efficiency
(BTE) of D80P15DE5 and D80P15B5 are higher than DP20 and diesel fuel. As BTE
is simply the inverse of the multiplication of BSFC and calorific value, consequently
they showed this kind of higher BTE. For D80P15E5, though its calorific value was
the lowest among the blends, it showed lower BTE for its higher BSFC which depicts
its lower combustion efficiency than D80P15DE5 and D80P15B5.
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Nox(g/kg-f)
36.5
36.9
34.41
35.12
31.285
Table 11 Quantification of NOx formation for different blends with PM inside combustion
chamber at an RPM of 1600
Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
Nox( g/kg-f)
21.9
22.32
21.56
21.63
20.32
Nox(g/kg-f)- Without PM
36.9
36.5
Diesel
DP20
35.12
34.41
22.32
21.9
Nox(g/kg-f)- With PM
21.56
D80P15E5
31.285
20.32
21.63
D80P15B5
D80P15DE5
Figure 1 Comparison of NOx formation for different blends with and Without PM inside
combustion chamber at an RPM of 1600
Table 12 Quantification Soot formation for different blends without PM inside combustion
chamber at an RPM of 1600
Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
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Soot (g/kg-f)
3.30
3.15
2.75
3.07
3.09
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Soot (g/kg-f)
3.10
2.63
2.52
2.83
2.92
3.3
3.1
3.15
2.63
2.52
2.75
Diesel
3.07
2.83
2.92
3.09
DP20
D80P15E5
D80P15B5
D80P15DE5
Figure 2 Comparison of NOx formation for different blends with and Without PM inside
combustion chamber at an RPM of 1600
Figure (1) and Figure (2) illustrates the improvement in view of the introduction
of porous media inside the combustion chamber. Though ethanol and n-butanol have
got higher oxygen content, D80P15E5 and D80P15B5 showed lower NO which can
be explained by their lower calorific value and higher heat of evaporation which
resulted in lower in-cylinder temperature. In the case of D80P15DE5, lower NO can
be attributed to reduced part of premixed combustion where NO is mainly formed.
Nonetheless, among the blends with additives, D80P15E5 showed the highest amount
of NO which can be attributed to the comparatively higher oxygen content of ethanol.
It can be observed that, oxygenated compounds available in the biodiesel made
the soot emission lower in the case of DP20. In spite of higher oxygen content of
ethanol, n-butanol and diethyl ether blends showed higher amounts of soot emission.
This behavior can be the effect of addition of additives like ethanol, n-butanol and
diethyl ether which make it easier to evaporate the fuel and slipped into the cylinder
especially at low speed during expansion stroke. Another reason can be mentioned
here is the increase of lean outer flame zone. This actually means the envelope of
the spray boundary where the fuel is already beyond the flammability limit because of
over mixing. However, the comparative emission of soot among the blends with
additives can be explained easily with the oxygen content of the additives mentioned
earlier.
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Type of Fuel
Diesel
DP20
D80P15E5
D80P15B5
D80P15DE5
Improvement in
Engine Brake
Power
(%)
7.242474
6.5
6.630004
6.800007
7.500016
Reduction in
BFSC
(%)
-6.75486
-6.09999
-6.17001
-6.20002
-6.70001
Improvement in
Thermal
Efficiency
(%)
2.247191
2.762431
1.630435
1.604278
1.587302
Reduction in
Nox
(%)
-40
-39.5122
-37.3438
-38.4112
-35.0487
Reduction
in Soot
(%)
-6.06061
-16.5079
-8.3636
-7.81759
-5.50162
6. CONCLUSION
In this paper we have simulated the performance of PM inside a combustion chamber
for different types of fuel blends with additives. The PM and the IC engines as whole
was modeled using modified KIVA-3V code. The performances of the engines were
studied to illustrate their capability in terms of brake power, fuel consumption rate,
emission etc. It can be clearly observed from the results the introduction of PM inside
results in increased power deliver at reduced fuel consumption for different fuels. The
introduction of PM reduced the NOx emissions to a great extent.
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Kayal, T. K., and Chakravarty, M., 2007, Modeling of a Conceptual SelfSustained Liquid Fuel VaporizationCombustion System With Radiative Output
Using Inert Porous Media, Int. J. Heat Mass Tran, 50(9), pp. 17151722.
Martynenko, V., Echigo, R., and Yoshida, H., 1998, Mathematical Model of SelfSustaining Combustion in Inert Porous Medium With Phase Change Under
Complex Heat Transfer, Int. J. Heat Mass Tran. 41(1), pp. 117126.
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