Gases

1. A pressure that will support a column of Hg to a

height of 256 mm would support a column of
water to what height? The density of mercury is
13.6 g/cm3; the density of water is 1.00 g/cm3.
A.
348 cm
B.
1.00 102 ft
C.
18.8 mm
D.
33.8 ft
E.
76.0 cm
2.
Which of the following is/are characteristic(s) of
gases?
A.
High compressibility
B.
Relatively large distances between
molecules
C.
Formation of homogeneous mixtures
regardless of the nature of gases
D.
High compressibility AND relatively large
distances between molecules
E.
High compressibility, relatively large
distances between molecules AND
formation of homogeneous mixtures
regardless of the nature of gases
3.
A sample of a gas occupies 1.40 103 mL at 25C
and 760 mmHg. What volume will it occupy at the
same temperature and 380 mmHg?
A.
2,800 mL
B.
2,100 mL
C.
1,400 mL
D.
1,050 mL
E.
700 mL
4.
A sample of nitrogen gas has a volume of 32.4 L
at 20C. The gas is heated to 220C at constant
pressure. What is the final volume of nitrogen?
A.
2.94 L
B.
19.3 L
C.
31.4 L
D.
54.5 L
E.
356 L
5.
If 30.0 L of oxygen are cooled from 200C to 1C
at constant pressure, what is the new volume of
oxygen?
A.
0.150 L
B.
17.4 L
C.
23.0 L
D.
51.8 L
E.
6.00 103 L
6.
A sample of N2 gas occupies 2.40 L at 20C. If the
gas is in a container that can contract or expand
at constant pressure, at what temperature will
the N2 occupy 4.80 L?
A.
10CB.
40C
C.
146C
D.
313C
E.
685C
7.
The gas pressure in an aerosol can is 1.8 atm at
25C. If the gas is an ideal gas, what pressure
would develop in the can if it were heated to
475C?
A.
0.095 atm B.
0.717 atm
C.
3.26 atm
D.
4.52 atm
E.
34.2 atm
8.
If the pressure of a gas sample is quadrupled and
the absolute temperature is doubled, by what
factor does the volume of the sample change?
A.
8
B.
2
C.
D.
1/4
E.
1/8
9.
If the pressure on a gas sample is tripled and the
absolute temperature is quadrupled, by what
factor will the volume of the sample change?
A.
12 B.
4/3
C.
D.
1/3
E.
4

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

A small bubble rises from the bottom of a lake,

where the temperature and pressure are 4C and
3.0 atm, to the water's surface, where the
temperature is 25C and the pressure is 0.95 atm.
Calculate the final volume of the bubble if its
initial volume was 2.1 mL.
A.
0.72 mL
B.
6.2 mL
C.
41.4 mL
D.
22.4 mL
E.
7.1 mL
The temperature of an ideal gas in a 5.00 L
container originally at 1 atm pressure and 25C is
lowered to 220 K. Calculate the new pressure of
the gas.
A.
1.0 atm
B.
1.35 atm
C.
8.8 atm
D.
0.738 atm
E.
0.114 atm
0.820 mole of hydrogen gas has a volume of 2.00
L at a certain temperature and pressure. What is
the volume of 0.125 mol of this gas at the same
temperature and pressure?
A.
0.0512 L
B.
0.250 L
C.
0.305 L
D.
4.01 L
E.
19.5 L
At what temperature will a fixed amount of gas
with a volume of 175 L at 15C and 760 mmHg
occupy a volume of 198 L at a pressure of 640
mm Hg?
A.
274C
B.
214C
C.
114C
D.
1C
E.
-59C
At what temperature will a fixed mass of gas with
a volume of 125 L at 15C and 750 mmHg occupy
a volume of 101 L at a pressure of 645 mm Hg?
A.
-73C
B.
10.4C
C.
2C D.
34C
E.
200C
Calculate the volume occupied by 35.2 g of
methane gas (CH4) at 25C and 1.0 atm.
R = 0.0821 L atm/Kmol.
A.
0.0186 L
B.
4.5 L
C.
11.2 L
D.
49.2 L
E.
53.7 L
Calculate the volume occupied by 25.2 g of CO2
at 0.84 atm and 25C.
A.
0.060 L
B.
1.34 L
C.
16.9 L
D.
24.2 L
E.
734 L
A gas evolved during the fermentation of sugar
was collected at 22.5C and 702 mmHg. After
purification its volume was found to be 25.0 L.
How many moles of gas were collected?
A.
0.95 mol
B.
1.05 mol
C.
12.5 mol
D.
22.4 mol
E.
724 mol
How many molecules of N2 gas can be present in
a 2.5 L flask at 50C and 650 mmHg?
A.
2.1 10-23 molecules B.
4.9 1022
molecules
C.
3.1 1023 molecules D.
3.6 1025
molecules
E.
0.081 molecules
Calculate the mass, in grams, of 2.74 L of CO gas
measured at 33C and 945 mmHg.
A.
0.263 g
B.
2.46 g
C.
3.80 g
D.
35.2 g
E.
206 g

20.

21.

22.

23.

24.

25.

0.500 mole of ammonia (NH3) occupies a 1.2 L

flask at 150C. Calculate the pressure of the
ammonia inside the flask.
A.
6.91 10-2 atm
B.
5.13 atm
C.
12.2 atm
D.
14.5 atm
E.
22.4 atm
Gases are sold in large cylinders for laboratory
use. What pressure, in atmospheres, will be
exerted by 2,500 g of oxygen gas (O2) when
stored at 22C in a 40.0 L cylinder?
A.
3.55 atm
B.
1,510 atm
C.
47.3 atm
D.
7.56 104 atm
E.
10.2 atm
Calculate the number of kilograms of helium
needed to inflate a balloon to a volume of
100,000 L at an atmospheric pressure of 250
mmHg and a temperature of -35C.
A.
1.68 kg
B.
3.36 kg
C.
5.21 kg
D.
6.74 kg
E.
5120 kg
Calculate the density, in g/L, of CO2 gas at 27C
and 0.50 atm pressure.
A.
0.89 g/L
B.
1.12 g/L
C.
9.93 g/L
D.
46.0 g/L
E.
2.17 kg/L
Calculate the density of CO2(g) at 100C and 10.0
atm pressure.
A.
1.44 g/L
B.
134 g/L
C.
44.0 g/L
D.
53.6 g/L
E.
14.4 g/L
Calculate the density of Br2(g) at 59.0C and 1.00
atm pressure.
A.
27.2 g/L
B.
5.83 g/L
C.
769 g/L
D.
22.4 g/L

26.

27.

28.

29.

E.
3.45 g/L
Calculate the density, in g/L, of SF6 gas at 27C
and 0.500 atm pressure.
A.
3.38 10-3 g/L
B.
2.96 g/L
C.
22.4 g/L
D.
32.9 g/L
E.
3.38 kg/L
Calculate the density, in g/L, of chlorine (Cl2) gas
at STP.
A.
2.13 10-2 g/L
B.
46.9 g/L
C.
1.58 g/L
D.
3.16 g/L
E.
0.316 kg/L
Calculate the density of Ar(g) at -11C and 675
mmHg.
A.
1.52 g/L
B.
1.65 g/L
C.
-39.3 g/L
D.
39.95 g/L
E.
1254 g/L
Which of the following gases will have the
greatest density at the same specified
temperature and pressure?
A.
H2
B.
CClF3
C.
CO2
D.
C2H6
E.
CF4

30.

31.

32.

33.

34.

35.

36.

37.

Which one of the following gases is "lighter-thanair"?

A.
Cl2
B.
SO2
C.
PH3
D.
NO2
E.
Ne
Two moles of chlorine gas at 20.0C are heated to
350C while the volume is kept constant. The
density of the gas
A.
increases.
B.
decreases.
C.
remains the same.
D.
Not enough information is given to correctly
answer the question.
Determine the molar mass of chloroform gas if a
sample weighing 0.389 g is collected in a flask
with a volume of 102 cm3 at 97C. The pressure
of the chloroform is 728 mmHg.
A.
187 g/mol
B.
121 g/mol
C.
112 g/mol
D.
31.6 g/mol
E.
8.28 10-3 g/mol
What is the molar mass of Freon-11 gas if its
density is 6.13 g/L at STP?
A.
0.274 g/mol
B.
3.64 g/mol
C.
78.2 g/mol
D.
137 g/mol
E.
365 g/mol
Determine the molar mass of Freon-11 gas if a
sample weighing 0.597 g occupies 100. cm3 at
95C, and 1,000. mmHg.
A.
0.19 g/mol
B.
35.3 g/mol
C.
70.9 g/mol
D.
137 g/mol
E.
384 g/mol
1.018 g of Freon-113 gas is trapped in a 145 mL
container at 760. mmHg and 50.0C. What is the
molar mass of Freon-113?
A.
21.7 g/mol
B.
28.8 g/mol
C.
46.1 g/mol
D.
186 g/mol
E.
245 g/mol
A 0.271 g sample of an unknown vapor occupies
294 mL at 140C and 847 mmHg. The empirical
formula of the compound is CH2. What is the
molecular formula of the compound?
A.
CH2
B.
C2H4
C.
C3H6
D.
C4H8
E.
C6H12
A gaseous compound is 30.4% nitrogen and
69.6% oxygen by mass. A 5.25-g sample of the
gas occupies a volume of 1.00 L and exerts a
pressure of 1.26 atm at -4.0C. Which of the
following is its molecular formula?
A.
NO
B.
NO2
C.
N3O6
D.
N2O4
E.
N2O5

38.

39.

40.

41.

42.

43.

44.

A mixture of three gases has a total pressure of

1,380 mmHg at 298 K. The mixture is analyzed
and is found to contain 1.27 mol CO2, 3.04 mol
CO, and 1.50 mol Ar. What is the partial pressure
of Ar?
A.
0.258 atm
B.
301 mmHg
C.
356 mmHg
D.
5,345 mmHg
E.
8,020 mmHg
A sample of hydrogen gas was collected over
water at 21C and 685 mmHg. The volume of the
container was 7.80 L. Calculate the mass of H2(g)
collected. (Vapor pressure of water = 18.6 mmHg
at 21C.)
A.
0.283 g
B.
0.572 g
C.
0.589 g
D.
7.14 g
E.
435 g
A sample of carbon monoxide gas was collected
in a 2.0 L flask by displacing water at 28C and
810 mmHg. Calculate the number of CO
molecules in the flask. The vapor pressure of
water at 28C is 28.3 mmHg.
A.
5.0 1022
B.
5.2 1022
C.
3.8 1023
D.
5.4 1023
E.
3.8 1025
Air contains 78% N2, 21% O2, and 1% Ar, by
volume. What is the density of air at 1,000. torr
and -10C?
A.
1.0 g/L
B.
6.1 g/L
C.
1.3 g/L
D.
1.8 g/L
E.
0.56 g/L
What volume of oxygen gas at 320 K and 680 torr
will react completely with 2.50 L of NO gas at the
same temperature and pressure
2NO(g) + O2(g) 2NO2(g)
A.
1.25 L
B.
2.50 L
C.
3.00 L
D.
1.00 L
E.
5.00 L
What volume of CO2 gas at 645 torr and 800 K
could be produced by the reaction of 45 g of
CaCO3 according to the equation?
CaCO3(s) CaO(s) + CO2(g)
A.
0.449 L
B.
22.4 L
C.
25.0 L
D.
34.8 L
E.
45.7 mL
How many liters of chlorine gas at 25C and
0.950 atm can be produced by the reaction of
12.0 g of MnO2?
MnO2(s) + 4HCl(aq) MnCl2(aq) + 2H2O(l) +
Cl2(g)
A.
5.36 10-3 L
B.
0.138 L
C.
0.282 L
D.
3.09 L
E.
3.55 L

45.

46.

47.

48.

49.

50.

How many liters of chlorine gas at 200C and

0.500 atm can be produced by the reaction of
12.0 g of MnO2 with HCl as follows?
MnO2(s) + 4HCl(aq) MnCl2(aq) + 2H2O(l) +
Cl2(g)
A.
10.7 L
B.
3.09 L
C.
4.53 L
D.
0.138 L
E.
0.093 L
How many liters of chlorine gas at 650 mmHg
and 25C can be produced by the reaction of 2.00
L of 2.50 M HCl solution with excess MnO2
MnO2(s) + 4HCl(aq) MnCl2(aq) + 2H2O(l) +
Cl2(g)
A.
1.25 L
B.
24.2 L
C.
35.7 L
D.
88.6 L
E.
143 L
Chlorine gas can be prepared in the laboratory by
the reaction of solid manganese dioxide with
hydrochloric acid. (The other reaction products
are aqueous manganese chloride and water.) How
much MnO2 should be added to excess HCl to
obtain 275 mL of chlorine gas at 5.0C and 650
mmHg?
A.
1.18 10-4 g
B.
0.896 g
C.
1.22 g
D.
49.8 g
E.
8,440 g
How many liters of oxygen gas at 153C and
0.820 atm can be produced by the decomposition
of 22.4 g of solid KClO3? (The other decomposition
product is solid potassium chloride.)
A.
3.0 L
B.
0.085 L
C.
4.20 L
D.
7.79 L
E.
11.7 L
When active metals such as magnesium are
immersed in acid solution, hydrogen gas is
evolved. Calculate the volume of H2(g) at 30.1C
and 0.85 atm that can be formed when 275 mL of
0.725 M HCl solution reacts with excess Mg to
give hydrogen gas and aqueous magnesium
chloride.
A.
3.4 10-3 L
B.
2.2 L
C.
2.9 L
D.
5.8 L
E.
11.7 L
Calculate the volume of H2(g) at 273 K and 2.00
atm that will be formed when 275 mL of 0.725 M
HCl solution reacts with excess Mg to give
hydrogen gas and aqueous magnesium chloride.
A.
0.56 L
B.
1.12 L
C.
2.23 L
D.
4.47 L
E.
3.54 L

2.

1.

Solutions
Which one of the following would be immiscible
with water?
A.
3.

B.
4.

C.

D.
E.

5.
NH3

6.

Which response lists all the following pairs that

are miscible liquids.
Pair # 1. octane (C8H18) and water
Pair # 2. acetic acid (CH3COOH) and water
Pair # 3. octane (C8H18) and carbon
tetrachloride (CCl4)
A.
1, 3
B.
1, 2
C.
3
D.
2
E.
2, 3
Which of the following liquids would make a good
solvent for iodine, I2?
A.
HCl
B.
H2O
C.
CH3OH
D.
NH3
E.
CS2
Which of the following compounds should be
soluble in CCl4?
A.
NaCl
B.
H2O
C.
NaOH
D.
C8H18
E.
none of these
Which of the following gives the molarity of a
17.0% by mass solution of sodium acetate,
CH3COONa (molar mass = 82.0 g/mol) in water?
The density of the solution is 1.09 g/mL.
A.
2.26 10-6 M
B.
0.207 M
C.
2.07 M
D.
2.26 M
E.
2.72 M
What is the molarity of a solution of 10% by mass
cadmium sulfate, CdSO4 (molar mass = 208.46
g/mol) by mass? The density of the solution is
1.10 g/mL.
A.
0.528 M
B.
0.436 M
C.
0.479 M
D.
0.048 M
E.
22.9 M

7.

8.

9.

10.

11.

12.

13.

14.

What is the molarity of a solution that is 26.0% by

mass phosphoric acid (H3PO4) and that has a
density of 1.155 g/mL?
A.
2.30 10-3 M
B.
0.30 M
C.
2.30 M
D.
3.06 M
E.
300 M
What is the percent CdSO4 by mass in a 1.0 molal
aqueous CdSO4 solution?
A.
0.001 %
B.
0.10 %
C.
17.2 %
D.
20.8 %
E.
24.4 %
What is the percent CsCl by mass in a 0.711 M
CsCl solution that has a density of 1.091 g/mL?
A.
3.87 10-4 %
B.
3.87 10-1 %
C.
11.0 %
D.
1.1 %
E.
6.5 10-2 %
Calculate the percent by mass of potassium
nitrate in a solution made from 45.0 g KNO3 and
295 mL of water. The density of water is 0.997
g/mL.
A.
1.51 %
B.
7.57 %
C.
13.3 %
D.
15.2 %
E.
none of these
How many grams of water are needed to dissolve
27.8 g of ammonium nitrate NH4NO3 in order to
prepare a 0.452 m solution?
A
769 g
B.
36.2 g
C.
100. g
D.
0.157 g
E.
157 g
In how many grams of water should 25.31 g of
potassium nitrate (KNO3) be dissolved to prepare
a 0.1982 m solution?
A.
250.0 g
B.
792 g
C.
1,000. g
D.
1,263 g
E.
7,917 g
Calculate the molality of a solution containing
14.3 g of NaCl in 42.2 g of water.
A.
2.45 10-4 m
B.
5.80 10-4 m
C.
2.45 10-1 m
D.
103 m
E.
5.80 m
Calculate the molality of a 20.0% by mass
ammonium sulfate (NH4)2SO4 solution. The
density of the solution is 1.117 g/mL.
A.
0.15 m
B.
1.51 m
C.
1.70 m
D.
1.89 m
E.
2.10 m

15.

16.

17.

18.

19.

20.

21.

22.

23.

Calculate the molality of 6.0 M H2SO4 solution.

The density of the solution is 1.34 g/mL.
A.
4.48 m
B.
7.98 m
C.
8.10 m
D.
8.43 m
E.
10.2 m
The density of a 20.3 M CH3OH (methanol)
solution is 0.858 g/mL. What is the molality of this
solution? H2O is the solvent.
A.
17.4 m
B.
20.8 m
C.
23.7 m
D.
70.0 m
E.
97.6 m
Calculate the molality of a 15.0% by mass
solution of MgCl2 in H2O. The density of this
solution is 1.127 g/mL.
A.
0.157 m
B.
11.8 m
C.
1.86 m
D.
0.0134 m
E.
1.58 m
Which of the following has the greater molal
concentration (molality)?
A.
1.0 m KNO3
B.
1.0 M KNO3
C.
Both have the same molality.
The solubility of gases in water usually decreases
with
A.
increasing pressure.
B.
increasing temperature.
C.
decreasing temperature.
The solubility of nitrogen gas at 25C and a
nitrogen pressure of 522 mmHg is 4.7 10-4
mol/L. What is the value of the Henry's Law
constant in mol/Latm?
A.
6.8 10-4 mol/Latm
B.
4.7 10-4 mol/Latm
C.
3.2 10-4 mol/Latm
D.
9.0 10-7 mol/Latm
E.
1.5 103 mol/Latm
The solubility of oxygen in lakes high in the Rocky
Mountains is affected by the altitude. If the
solubility of O2 from the air is 2.67 10-4 M at sea
level and 25C, what is the solubility of O2 at an
elevation of 12,000 ft where the atmospheric
pressure is 0.657 atm? Assume the temperature
is 25C, and that the mole fraction of O2 in air is
0.209 at both 12,000 ft and at sea level.
A.
1.75 10-4 M
B.
2.67 10-4 M
C.
3.66 10-5 M
D.
4.06 10-4 M
E.
none of these
The solubility of CO2 gas in water
A.
increases with increasing temperature.
B.
decreases with decreasing temperature.
C.
decreases with increasing temperature.
D.
is not dependent on temperature.
The solubility of CO2 gas in water
A.
increases with increasing gas pressure.
B.
increases with decreasing gas pressure.
C.
decreases with increasing gas pressure.
D.
is not dependent on pressure.

24.

25.

26.

27.

28.

29.

At 10C one volume of water dissolves 3.10

volumes of chlorine gas at 1.00 atm pressure.
What is the Henry's Law constant in mol/Latm?
A.
3.8
B.
0.043
C.
36.
D.
3.1
E.
0.13
According to Raoult's law, which statement is
false?
A.
The vapor pressure of a solvent over a
solution decreases as its mole fraction
increases.
B.
The solubility of a gas increases as the
temperature decreases.
C.
The vapor pressure of a solvent over a
solution is less than that of pure solvent.
D.
The greater the pressure of a gas over a
solution the greater its solubility.
E.
Ionic solutes dissociate in solution causing
an enhancement of all colligative
properties.
Consider a solution made from a nonvolatile
solute and a volatile solvent. Which statement is
true?
A.
The vapor pressure of the solution is always
greater than the vapor pressure of the pure
solvent.
B.
The boiling point of the solution is always
greater than the boiling point of the pure
solvent.
C.
The freezing point of the solution is always
greater than the freezing point of the pure
solvent.
The vapor pressure of water at 20C is 17.5
mmHg. What is the vapor pressure of water over
a solution prepared from 2.00 102 g of sucrose
(C12H22O11) and 3.50 102 g water?
A.
0.51 mmHg
B.
16.0 mmHg
C.
17.0 mmHg
D.
18.0 mmHg
E.
19.4 mmHg
A solution is 40.0% by volume benzene (C6H6) in
carbon tetrachloride at 20C. The vapor pressure
of pure benzene at this temperature is 74.61
mmHg and its density is 0.87865 g/cm3; the
vapor pressure of pure carbon tetrachloride is
91.32 mmHg and its density is 1.5940 g/cm3. If
this solution is ideal, its total vapor pressure at
20C is
A.
84.64 mmHg.
B.
84.30 mmHg.
C.
82.96 mmHg.
D.
81.63 mmHg.
E.
165.93 mmHg.
A solution of carbon tetrachloride in benzene,
C6H6, at 20C has a total vapor pressure of 78.50
mmHg. (Assume that this solution is ideal.) The
vapor pressure of pure benzene at this
temperature is 74.61 mmHg and its density is
0.87865 g/cm3; the vapor pressure of pure carbon
tetrachloride is 91.32 mmHg and its density is
1.5940 g/cm3. What percentage of the volume of
this solution is due to carbon tetrachloride?
[Hint: assume that you have 1.000 L of solution.]
A.
75.2%

B.
C.
D.
E.

76.7%
14.3%
24.8%
23.3%

30.

31.

32.

33.

34.

35.

A solution of chloroform (CHCl3) and acetone

((CH3)2CO) exhibits a negative deviation from
Raoult's law. This result implies that
A.
chloroform-chloroform interactions are
stronger than chloroform-acetone
interactions.
B.
chloroform-chloroform interactions are
weaker than chloroform-acetone
interactions.
C.
acetone-acetone interactions are stronger
than chloroform-acetone interactions.
D.
acetone-acetone interactions are weaker
than chloroform-acetone interactions.
E.
chloroform-chloroform interactions are
weaker than chloroform-acetone
interactions AND acetone-acetone
interactions are weaker than chloroformacetone interactions.
F.
chloroform-chloroform interactions are
stronger than chloroform-acetone
interactions AND acetone-acetone
interactions are stronger than chloroformacetone interactions.
Dissolving a solute such as KOH in a solvent such
as water results in
A.
an increase in the melting point of the
liquid.
B.
a decrease in the boiling point of the liquid.
C.
a decrease in the vapor pressure of the
liquid.
D.
no change in the boiling point of the liquid.
What is the freezing point of a solution that
contains 10.0 g of glucose (C6H12O6) in 100. g of
H2O? Kf for water is 1.86C/m.
A.
-0.186C
B.
+0.186C
C.
-0.10C
D.
+0.10C
E.
-1.03C
Which of the following aqueous solutions has the
highest boiling point?
Kb for water is 0.52C/m.
A.
0.2 m KCl
B.
0.2 m Na2SO4
C.
0.2 m Ca(NO3)2
D.
0.2 m KCl AND 0.2 m Na2SO4
E.
0.2 m Na2SO4 AND 0.2 m Ca(NO3)2
Which of the following aqueous solutions has the
highest osmotic pressure at 25C?
A.
0.2 M KBr
B.
0.2 M ethanol
C.
0.2 M Na2SO4
D.
0.2 M KCl
During osmosis
A.
pure solvent diffuses through a membrane
but solutes do not.
B.
pure solutes diffuse through a membrane
but solvent does not.
C.
pure solvent and a solution both diffuse at
the same time through a membrane.
D.
gases diffuse through a membrane into a
solution and build up pressure.

36.

37.

38.

39.

40.

41.

42.

Calculate the freezing point of a solution made

from 22.0 g of octane (C8H18) dissolved in 148.0 g
of benzene. Benzene freezes at 5.50C and its Kf
value is 5.12C/m.
A.
-1.16C
B.
0.98C
C.
6.66C
D.
12.2C
E.
5.49C
What is the freezing point of a solution prepared
from 50.0 g ethylene glycol (C2H6O2) and 85.0 g
H2O? Kf of water is 1.86C/m.
A.
17.6C
B.
-176C
C.
-1.50C
D.
1.50C
E.
-17.6C
A solution that contains 55.0 g of ascorbic acid
(Vitamin C) in 250. g of water freezes at -2.34C.
Calculate the molar mass (in units of g/mol) of
the solute. Kf of water is 1.86C/m.
A.
1.26
B.
10.9
C.
43.6
D.
175
E.
277
What is the molar mass of toluene if 0.85 g of
toluene depresses the freezing point of 100. g of
benzene by 0.47C? Kf of benzene is 5.12C/m.
A.
92.6 g/mol
B.
78.0 g/mol
C.
10.7 g/mol
D.
81.8 g/mol
E.
927 g/mol
What mass of ethanol, C2H5OH a nonelectrolyte,
must be added to 10.0 L of water to give a
solution that freezes at -10.0C? Assume the
density of water is 1.0 g/mL. Kf of water is
1.86C/m.
A.
85.7 kg
B.
24.8 kg
C.
5.38 kg
D.
2.48 kg
E.
1.17 kg
When 24.0 g of glucose (a nonelectrolyte) are
dissolved in 500. g of water, the solution has a
freezing point of -0.47C. What is the molar mass
of glucose? Kf of water is 1.86C/m.
A.
41.9 g
B.
47.5 g
C.
54.9 g
D.
178 g
E.
190. g
What is the osmotic pressure of a solution that
contains 13.7 g of propyl alcohol (C3H7OH)
dissolved in enough water to make 500. mL of
solution at 27C?
A.
0.014 atm
B.
0.037 atm
C.
0.456 atm
D.
0.01 atm
E.
11.2 atm

43.

44.

45.

46.

47.

48.

What is the freezing point of an aqueous solution

of a nonvolatile solute that has a boiling point of
102.5C?
[For water Kf = 1.86C/m and Kb = 0.52C/m.]
A.
-8.94C
B.
-366C
C.
-0.99C
D.
0.99C
E.
8.94C
What volume of ethanol (density = 0.7893 g/cm3)
should be added to 450. mL of water in order to
have a solution that freezes at -15.0C?
[For water, Kf = 1.86 C/m.]
A.
371 mL
B.
470 mL
C.
212 mL
D.
132 mL
E.
167 mL
What volume of water should be added to 600.
mL of ethanol in order to have a solution that
boils at 95.0C?
[For ethanol, Kb = 1.22C/m, density = 0.789
g/cm3, boiling point = 78.4C]
A.
186 mL
B.
245 mL
C.
518 mL
D.
116 mL
E.
322 mL
Pure benzene, C6H6, freezes at 5.5 and boils at
80.1C. What is the boiling point of a solution
consisting of cyclohexane (C6H12) dissolved in
benzene if the freezing point of this solution is
0.0C?
[For benzene, Kf = 5.12C/m, Kb = 2.53C/m; for
cyclohexane, Kf = 20.0C/m, Kb = 2.79C/m]
A.
82.8C
B.
91.2C
C.
80.9C
D.
77.4C
E.
83.1C
When 12.1 g of the sugar sucrose (a
nonelectrolyte) are dissolved in exactly 800 g of
water, the solution has a freezing point of
-0.082C. What is the molar mass of sucrose?
Kf of water is 1.86C/m.
A.
426 g
B.
99.2 g
C.
178 g
D.
266 g
E.
343 g
What is the boiling point of an aqueous solution
of a nonelectrolyte that has an osmotic pressure
of 10.50 atm at 25C? Kb of water is 0.52C/m.
Assume the density of the solution is the same as
that of pure water.
A.
0.22C
B.
0.429C
C.
100.43C
D.
99.78C
E.
100.22C

Answers

49.

50.

0.102 g of an unknown compound dissolved in

100. mL of water has an osmotic pressure of 28.1
mmHg at 20C. Calculate the molar mass of the
compound.
A.
663 g/mol
B.
0.872 g/mol
C.
1.15 g/mol
D.
727 g/mol
E.
1.10 102 g/mol
An aqueous dextrose solution having a density of
1.04 g/cm3 freezes at -1.15C. Find the osmotic
pressure of this solution at 25C.
[Given: for water Kf = 1.86C/m; molecular mass
of dextrose = 180.16 g/mol]
A.
B.
C.
D.
E.

13.8 atm
14.1 atm
15.1 atm
12.9 atm
120 atm

Gases

1.A

2.E

3.A

4.D

5.B

6.D

7.D

8.C

9.B

10.E

11.D

12.C

13.D

14.A

15.E

16.C

17.A

18.B

19.C

20.D

21.C

22.D

23.A

24.E

25.B

26.B

27.D

28.B

29.B

30.E

31.C

32.B

33.D

34.D

35.D

36.B

37.D

38.C

39.B

40.A

41.D

42.A

43.D

44.E

45.A

46.C

47.B

48.E

49.C

50.B
Solutions
1.D

2.E

3.E

4.D

5.D

6.A

7.D

8.C

9.C

10.C

11.A

12.D

13.E

14.D

15.B

16.E

17.C

18.B

19.B

20.A

21.A

22.C

23.A

24.E

25.A

26.B

27.C

28.B

29.D

30.E

31.C

32.E

33.E

34.C

35.A

36.A

37.E

38.D

39.A

40.D

41.E

42.E

43.A

44.C

45.D

46.A

47.E

48.E

49.A

50.B