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A. J. Ali,
Asst. Prof., Sohar Univ /Oman,
ajali@soharuni.edu.om,
ABSTRACT
Two small scale columns pressure swing adsorption unit (50 mm diameter, and 570 mm bed
length) has been constructed to study the separation of oxygen from air using commercial 13X
zeolite. The effect of adsorption pressure (2, 3, and 4 bar), adsorption time (10, 20, and 30 s), and
purge flow rate (1 to 6 liter/min) on the product oxygen purity were studied. For the case of 2column, 4-step operation, the result show that a product of about 70% oxygen purity was obtained,
whereas a product of about 80% oxygen purity was obtained for 6-step operation. No significant
effect on product oxygen purity was noticed throughout the adsorption pressure range studied, for
both cycle operations. This is confirmed by single bed characteristic results. The effect of the
adsorption time and the purge flowrate on the product oxygen purity show some optimum values for
4-step operation. Single bed characteristic result confirms the range of the adsorption time and the
purge flowrate. Similar trend results were noticed with 2-column, 6-step operation, with air initial
pressurizing, for the effect of purge flowrate at constant adsorption time (30 s). The product oxygen
purity for 6-Steps operation, with pure oxygen initial pressurizing, presents a plateau (of 82% purity)
for purge flowrate from 1 to 1.5 liter/min then decreases when increasing the purge flowrate above
1.5 liter/min. Single column characteristics, using initial intermediate oxygen pressurizing indicated
higher product oxygen purity expected (>90%) than that obtained in the 2-column, 6-step operation.
570
50
. 13X
(
6 -1)
30 20 10)
(
%80
4 3 2)
%70
.
.
.(
/
30 )
1,5
.(
%82
1
/
1,5
.% 90
( %82
203
The 2nd Regional . Conf. for Eng. Sci. /College. of Eng. / Al-Nahrain University /1-2/12/2010
1. INTRODUCTION
At the present time, there are three
different technologies for oxygen production
from air:
1. The cryogenic technology based on
separation
by
low-temperature
distillation.
2. The membrane technology.
3. The adsorption technology
The latter two technologies have been
performed at ambient temperature. A more
and more popular air separation process is
currently pressure swing adsorption (PSA) on
zeolites, which was proposed by Skarstrom[1]
in the middle of the 20th century and is based
on periodic change of modes of selective
adsorption of gases at increased pressure and
their desorption with a decrease in pressure.
According to foreign information sources,
more than 20% of world oxygen production
is by pressure swing adsorption.[1,2]
The first (PSA) unit composed of two
beds and using a zeolite, was patented by
Skarstrom in 1960. Four steps were used in
this unit, as follows:[1,3]
1. Pressurization step, the bed pressure is
increased with feed.
2. Producing step, high pressure feed
through one end with raffinate
withdrawal through the other. Raffinate
means rich in the component with the
lowest adsorption affinity
3. Depressurization or blow down step,
pressure is decreased opening one bed
end, and the resulting flow is
countercurrent to the feed.
4. Purging step, desorption at the lower
operating pressure, which is performed
by purging the bed with the raffinate
product, flows countercurrent to the feed.
A very important improvement was the
introduction of the pressure equalization
stage, prior to the blow down step where two
beds are connected through one end while the
other remaining ends are kept closed. The
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The 2nd Regional . Conf. for Eng. Sci. /College. of Eng. / Al-Nahrain University /1-2/12/2010
(2)
(4)
(5)
tz = 0.21 W qf / NfO2
(6)
3. EXPERIMENTAL WORK
The
schematic
diagram
of
the
experimental arrangement of PSA unit used
in the present work is shown in Fig.2. It
contains two galvanized steel columns. The
length of each column (L) is 0.7 m and its
diameter (D) is 50 mm. The input and output
connections are of 5 mm tubing, fittings and
valves.
The setup is equipped with an automatic
control system for controlling the time of
each cycle. A programmed timer controlled
solenoid valves were used to achieve the
desired operation.
The concentrations of the effluent flows
were analyzed by a portable calibrated
oxygen analyzer (GOX 100 Greisinger
Electronic GmbH).
(1)
205
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The 2nd Regional . Conf. for Eng. Sci. /College. of Eng. / Al-Nahrain University /1-2/12/2010
3.
4.
5.
6.
7.
REFRENCES
1. Ruthven, D. M.; Farooq, S.; Knaebel, K.
S., Pressure Swing Adsorption. VCH
Publishers: New York, 1994.
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The 2nd Regional . Conf. for Eng. Sci. /College. of Eng. / Al-Nahrain University /1-2/12/2010
qs
maximum adsorbent capacity of N2 or
O2 in Langmuir adsorption isotherm, mol/kg
tz
time of the front at position z, s
tads adsorption time, s
tdepress depressurization time, s
teq equalization time, s
tpress pressurization time, s
uH interstitial velocity during adsorption
step, m/s
uL interstitial velocity during purging step,
m/s
W adsorbent weight, kg
yi
mole fraction in gas phase of
component (i)
z axial co-ordinate,or distance traveled by
the front, m
Greek Symbols
ads dimensionless adsorption time
( ads = tads/ B)
purg dimensionless purging time
( ads = tpurg/ Bp)
bed
time constant of adsorption step
B
( B =LB/uH) , s
Bp bed time constant of purging step
( Bp =LB/uL) , s
NOMENCLATURE
A bed cross-section area, m2
bO2 Langmuir adsorption isotherm constant
of O2 , bar-1
bN2 Langmuir adsorption isotherm constant
of N2 , bar-1
Cf solute feed concentration, mol/l
d
bed diameter, mm
dp
adsorbent diameter, mm
LB bed length, m
NfN2 feed mole flowrate of N2, mol/s
NfO2 feed mole flowrate of O2, mol/s
NExN2 exhaust mole flowrate of N2, mol/s
PH, P1 adsorption high pressure ,bar
PL, P2 desorption low pressure, bar
Peq equalization pressure, bar
Qpurg purge flow rate, l/min
Qprod product flow rate, l/min
Qeffluent effluent flow rate, l/min
Qf air feed flow rate, l/min
qN2 adsorbent capacity of N2 , mol/kg
qO2 adsorbent capacity of O2 , mol/kg
Abbreviations
DR
Dryer
F
Filter
PR
Pressure Regulator
CT
Cold Trap
PG
Pressure Gauge
V1 to V5 Solenoid Valves
OA Oxygen Analyzer
OF Oxygen flowmeter
Table 1 Details of PSA Columns and Adsorbent
Adsorbers
Column Length
Column diameter
Adsorbent Type
Shape
Particle diameter
Particle density
Bulk density
Bed porosity
210
L
D
dp
p
B
0.7 m
50 mm
13X zeolite
Sphere
1.7-2.6 mm
1070 kg/m3
670 kg/m3
0.4
The 2nd Regional . Conf. for Eng. Sci. /College. of Eng. / Al-Nahrain University /1-2/12/2010
Adsorbent weight
Adsorbent bed length
Langmuir
isotherm
parameters[4]
Oxygen
Adsorption heat of O2
Nitrogen
Adsorption heat of N2
w
LB
0.75 kg
0.57 m
qsO2
bO2
HO2
qsN2
bN2
HN2
3.091 mole/kg
0.0367 bar-1
12.8 kJ/mole
3.091 mole/kg
0.1006 bar-1
17 kJ/mole
Column 1
1 Pressurizing
(tprs=10 s)
2 Producing
(tads)
3 Depressurizing
(tdeprs=10 s)
4 Purging
(tpur=tads)
(V1)open
(V3)close
(V1)open
(V3)close
(V1)close
(V3)open
(V1)close
(V3)open
Column 2
Depressurizing (V2)close
(tdepr s=10 s) (V4)open
Purging
(V2)close
(tpur=tads) (V4)open
Pressurizing (V2)open
(tprs=10 s) (V4)close
Producing
(V2)open
(tads)
(V4)close
Column 1
Column 2
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