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1.
PHYSICALCHEMUNITTESTMARKS:35
(b) 18M
(c) 9M
(d) 6M
Amount of K2Cr2O7 (aq. wt. 49.04) required to prepare 100 ml of its 0.05 N solution is
(a) 2.9424 g
3.
35MIN
The molarity of a solution made by mixing 50ml of conc. H2SO4 (36N) with 50 ml. o0f water is
(a) 36 M
2.
(b) 0.4904 g
(c) 1.4712 g
(d)0.2452 g
A solution of Al2 (SO4)3 {d=1.253 gm/ml} contain 22% salt by weight. The molarity, normality
and molality of the solution is
(a) 0.805M,4.83N,0.825M (b) 0.825M,48.3N,0.805M
4.
(b)19.8 N
(c) 39.6 N
(d) 98 N
Volume of water needed to mix with 10 ml 10N HNO3 to get 0.1 N HNO3
(a) 1000 ml
6.
(d) None
conc. H2SO4 has a density of 1.98 gm/ml and is 98% H2SO4 by weight. Its normality is
(a) 2 N
5.
(c) 4.83M,4.83N,4.83M
(b) 990 ml
(c) 1010 ml
(d) 10 ml
(b) 20 mL
(c) 10 mL
(d) 60 mL.
A solution has a 1:4 mole ratio of pentane to hexane. The vapour pressure of the pure
hydrocarbons at 20oC are 440 mmHg for pentane and 120 mmHg for hexane. The mole fraction
of pentane in the vapour phase would be
(a) 0.549
(b) 0.200
(c) 0.786
(d) 0.478
The vapour pressure of benzene at a certain temperature is 640mm of Hg. A non-volatile and
non-electrolyte solid weighing 2.175g is added to 39.08g of benzene. The vapour pressure of the
solution is 600mm of Hg. What is the molecular weight of solid substance
(a) 49.50
9.
(b) 59.6
(c) 69.5
(d) 79.8
A solution boils at 90 C at 760 mm pressure. At this temperature if the partial V.P. of solute is
th of that of solvent the partial V.P. of the solvent is
a) 608 mm
b) 760 mm
c) 540 mm
d) 152 mm
10. A metal has bcc structure and the edge length of its unit cell is
in
cm 3
If
NaCl
(a)
12
will be
(a)
11
3 .04 .
1 . 6 10 21 cm 3
is doped with
1 10 3 mol %
(b)
2 . 81 10 23 cm 3
10 3 mol % SrCl 2 ,
(b)
(c) 6 .02 10 23 cm 3
(d)
2 10 3 mol %
(c) 3 10 3 mol %
508 pm .
(d)
285 pm
(b)
398 pm
(c) 144
pm
4 10 3 mol %
6 . 6 10 24 cm 3
(d)
618 pm
110 pm ,
the
PHYSICALCHEMUNITTESTMARKS:35
35MIN
(b) Orthorhombic
(c)Cubic (d)
2 .165 10 3 kg m 3
(a)
15
Triclinic
while its X-rays density is
5 . 96 10 3
(b)
In a catalytic conversion of
N2
(c) 5 .96 10 2
5 .96
to
NH 3
5 . 96 10 1
(d)
60 10 3
(b)
20 10 3
(c)1.200
(in mol
litre1 s 1 )
10 . 3 10 3
(d)
25 o C
35 o C
and
The decomposition of
N 2 O5
O2
100 o C
25 o C
1o C
produced is
9 ml
N 2 O5 N 2 O4
35 ml
1
O2 .
2
After 15
is equal to
(a)
18
1
35
ln
15 44
(b)
1
44
ln
15 26
(c)
1
44
ln
15 35
(d)
1
35
ln
15 26
increasing the pressure on it. If the reaction is of first order with respect to O 2 and second order
with respect to
19
NO
(b)
(d)
75% of a first order reaction was completed in 32 minutes when was 50% of the reaction
completed
(a) 16 min.
20
t1
(b) 24 min.
4 min.
can be taken as the time taken for the concentration of a reactant to drop to
, the
t1
(a)
0 .10 / K
(b)
0 .29 / K
(c)
0 .69 / K
(d)
0 .75 / K
3
4
of its initial
21
PHYSICALCHEMUNITTESTMARKS:35
(Ea ) 0
(K ) 3 . 2 10 6 s 1 at
35MIN
22
3 . 2 10 12 s 1
(b)
(K)
3 . 2 10 6 s 1
(c) 6 .4 10 12 s 1
6 . 4 10 6 s 1
(d)
(K )
the relationship between the corresponding activation energies of the two reactions ( Ea and
Ea
will be
(a)
23
Ea Ea
(b)
(b) 41010
(d)
Ea 4 Ea
(c) 4105
25
(c) E a Ea
24
Ea Ea
(b) 5
BrO 3
(d) 11010
to Br
(c) 6
(d) 4
During electrolysis of fused aluminium chloride 0.9 gm of aluminium was deposited on the
cathode. The volume of chlorine liberated at the anode will be
(a) 2.24 litres
26
Cr = 52).
according to the
28
30
(c) 21.6
(d) 23.2
NH 4 Ag Na Li
(b)
Na NH 4 Ag Li
(c)
Li Na Ag NH 4
(d)
Ag Li Na NH 4
(c)
[Cr ( NH 3 )5 Cl ]Cl 2
29
(b) 2.16
[Cr ( NH 3 )3 Cl 3 ]
The reaction
(b)
[Cr ( NH 3 )4 Cl 2 ]Cl
1
H 2 (g) AgCl (s) H (aq ) Cl (aq ) Ag (s)
2
(d)
[Cr ( NH 3 )6 ]Cl 3
(a)
(b)
(c)
(d)
Which of the following reactions occurs at the cathode during the charging of a lead storage
battery
(a)
Pb 2 2 e Pb
(b)
Pb 2 SO 42 PbSO 4
(c)
Pb Pb 2 2 e
(d)
PbSO 4 2 H 2 O 2 PbO 2 4 SO 42 2 e
31
PHYSICALCHEMUNITTESTMARKS:35
and
ox 1 / red 1
ox 2 / red 2
may be denoted by
35MIN
red 1 , ox 1 || red 2 , ox 2
red 1 ox 1 red 2 ox 2
(b)
red 2 ox 2 red 1 ox 1
(c)
The relationship between standard reduction potential of cell and equilibrium constant is shown
by
(a)
33
0
Ecell
n
log K c
0 . 059
(b)
0
Ecell
0 . 059
log K c
n
(c)
0
Ecell
0 . 059 n log K c
(d)
0
Ecell
log K c
n
Electrode potentials of five elements A, B, C, D and E are respectively 1.36, 0.32, 0, 1.26 and
0.42. The reactivity order of these elements are in the order of
(a) A, D, E, B and C
(b) C, B, E, D and A
(c) B, D, E, A and C
(d) C, A, E, D
and B
34
For a cell reaction involving a two-electron change, the standard emf of the cell is found to be
0.295 V at
(a)
35
25 o C .
1 10 10
(b)
29 . 5 10 2
25 o C
will be
(c) 10
(d)
1 10 10
The technique of protecting a metal from corrosion by connecting it to a second metal (that is
more easily oxidised) is called
(a) Cathodic protection
(c) Galvanisation
(d) Annealing