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Abstract
The steady-shear and small-amplitude oscillatory rheological properties of tamarind (Tamarindus indica L.) juice concentrate (TJC)
were studied in the temperature range of 1090 1C using a controlled-stress rheometer. Under steady-shear deformation tests, shear
stressshear rate data were adequately tted to the Herschel-Bulkley and Casson model at lower (1030 1C) and higher (5090 1C)
temperature range, respectively. The Carreau model was applied to describe the shear-thinning behaviour of the concentrate, and the
model parameters estimated empirically showed temperature dependence. Oscillatory shear data of TJC revealed predominating viscous
behaviour (G00 4G0 ) at lower frequency range while the elastic modulus predominating over the viscous one (G0 4G00 ) at higher frequency
range. The CoxMerz rule that relates steady shear and dynamic material functions was tested and not followed by most of the
temperatures. The specic heat of TJC increased with temperature and the glass transition temperature of the product was found to be
70.74 1C.
r 2005 Swiss Society of Food Science and Technology. Published by Elsevier Ltd. All rights reserved.
Keywords: Tamarind juice concentrate; Herschel-Bulkley model; Casson model; Carreau model; Apparent viscosity; Complex viscosity; CoxMerz rule
1. Introduction
Tamarind (Tamarindus indica L.) is a versatile fruit,
which can be used for many purposes. Tamarind pulp has
been used for many medicinal purposes and continues to be
used by many people in Africa, Asia and America
(Gunasena & Hughes, 2000). The pulp is believed to
improve loss of appetite and is used as a gargle for sore
throats, dressing of wounds (Benthal, 1933; Dalziel, 1937)
and is said to aid the restoration of sensation in cases of
paralysis. The unique sweet/sour avour of the pulp is
popular in cooking and avouring. Tamarind juice
concentrate (TJC) is a convenient product due to its ease
to dissolve and reconstitute in warm water. The product
can also be stored for long periods due to its moderate
water activity. TJC is manufactured by extracting pulp
with boiling water using the counter current principle,
Corresponding author. Tel.: +15146314390; fax: +15143987977.
0023-6438/$30.00 r 2005 Swiss Society of Food Science and Technology. Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.lwt.2005.11.002
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Table 1
Selection of ow models based on standard errors
Model
Standard error at
10 1C
Standard error at
70 1C
Casson
Herschel-Bulkley
Bingham
Newtonian
Power
11.58
3.82
29.42
48.12
7.45
6.62
9.76
38.14
151.9
47.24
_ 0:5 ,
t0:5 t0:5
0c K c g
(3)
where t is the shear stress (Pa), t0 and t0c are the yield stress
(Pa) and Casson yield (Pa0.5), g_ is the shear rate (s1), K is
the consistency coefcient (Pa sn), Kc is the Casson constant
(Pa s)0.5 and n is the ow behaviour index (dimensionless).
The TJC samples exhibited denite yield stress due to
signicant particleparticle interactions and crowding.
Yield stress is an important quality control parameter to
process industries, particularly for comparing the overall
characteristics of products made on different production
lines (Ahmed, 2004). A true value of the yield stress could
be benecial for the optimal design of food-processing
systems such as those required during thermal processing
(Steffe, 1992). The yield value obtained from both the
Herschel-Bulkley and the Casson model decreased
(Po0.05) with temperature since the stress level in the
uid is increased, the structure responsible for the yield
stress is destroyed. The literature on concentrated suspensions and materials which exhibit a yield stress is
voluminous. Manohar et al. (1991) reported TJC sample
(621Brix) did not exhibit any yield stress. This behaviour is
contrary to the present study. The differences in observation could be due to variation in soluble solids content,
type of instruments used and variation in shear rates.
Both the Herschel-Bulkley and the Casson model
parameters are presented in Table 2. The n values ranged
between 0.43 and 0.78 which indicate shear-thinning nature
of TJC. However, there is no trend for n values with
temperature. The consistency index decreased systematically with temperature (except 90 1C for Casson model).
The applicability of Casson model at elevated temperatures
indicated strong gel characteristics of TJC (possibly due to
protein and starch component); however, the strong
interaction among the molecules disrupted at 90 1C.
(2)
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Table 2
Rheological parameters of (a) Herschel-Bulkley and (b) Casson models of TJC at selected temperatures
Temperature (1C)
K (Pa sn)
SE
3.88
1.46
0.69
0.53
0.91
9.28
4.32
0.52
0.49
0.27
0.78
0.59
0.59
0.43
0.51
3.82
14.78
7.234
10.20
31.68
Temperature (1C)
K (Pa sn)
SE
6.07
2.32
0.73
0.70
1.79
2.63
0.29
0.06
0.03
0.21
100
11.58
33.72
4.43
6.62
14.75
Table 3
Carreau model parameters for tamarind paste
Temperature
Z0
(Pa s)
ZN
(Pa s)
K (s)
n
(dimensionless)
SE
10
30
50
70
90
447.5
275.5
21.96
13.15
18.28
3.82
0.26
0.12
0.05
6.07E-6
625.2
578.0
34.38
20.43
24.54
0.60
0.81
0.84
0.86
0.84
5.93
1.78
0.72
0.73
17.32
10
0.1
0.01
0.1
10
100
(4)
(5)
(6)
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100
1000
10
R2 = 0.8195
100
()
100
229
10
1
R2 = 0.7061
10
0.1
0.1
0.0025
0.0027
0.0029
0.0031
1/T (K-1)
0.0033
0.0035
0.0037
1
(Hz)
10
(7)
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10
(Pa.s)
0.1
1
100
0.1
100
100
70C
10
1
0.1
0.1
1
1
, (s-1)
10
10
(Pa.s)
(Pa.s)
(Pa.s)
10
10
1
, (s-1)
100
50C
0.1
0.1
10
30C
10
10
, (s-1)
(Pa.s)
10
10
1
0.1
10
100
10C
(Pa.s)
100
Complex viscocity(Pa.s)
230
1
100
100
100
90C
10
(Pa.s)
(Pa.s)
10
0.1
0.1
10
0.1
100
, (s-1)
Fig. 4. Shear viscosity and complex viscosity date of tamarind juice concentrate at selected temperature (&: Apparent viscosity and n: complex viscosity).
Z CZa jog .
(8)
Table 4
Coefcients of generalized CoxMerz rule Z CZa
Temperature (1C)
R2
SE
10
30
50
70
90
0.86
2.71
28.13
30.82
2.82
1.05
1.06
0.67
0.76
0.91
0.987
0.967
0.972
0.964
0.997
0.071
0.126
0.191
0.170
0.061
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0.05
2.5
References
1.5
1
0.5
-0.1
-0.05
-0.15
-0.5
-0.2
-100
-50
50
Temperature (C)
100
231
-1
150