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TECHNICAL REPORT
EUSTOMXRIC INSULATION FCR SOLID PROPELIANT
ROCKET MOTORS
By
D.
H. Sale
IO124401A
5025.11.8
42
03
Copy No.
Date
.
27 October 1964
Repcrt No,
Copy No.
ELASTOMERIC
By
D.
H. Sale
Apprcved by:
A. C. HANSON
Laboratory Dlrector
27 October 1964
DA Projec Nc.
1CO-24401-All0
5025 11.84203
64-3158
ABSTRACT
The development of flexible, elastomeric-based,
solid propellant rocket motor case insulation is discussed.
The effect on insulation properties of type of asbestos,
of liquid versus solid elastomers and of methods of dispersing fibrous compounding ingredients, are reported.
Oxyacetylene torch and static
motor firing test data
for some of the better insulation materials developed,
as well as for souie commercial materials, are presented.
The torch test, the principle screening tool used in this
study, conforms to the test currently being standardized
by the Flame Ablation Test Group of Section III-L of ASTM
Committee D-20.
A material with 40 percent elongation, 1.34 gm/cc
density, performance ind3x of 95 cm2 sec/gm and erosion
rate of 2.0 mils/sec was the most promising insulation
developed.
The material is a 55/45 butadiene/acrylonitrile
compound containing phenol furfural resin, asbestos
and oxyazoline wetting agent.
It has been satisfactorily
bonded to aluminum and to steel by conventional bonding
agent.
The thermal properties of this vulcanizate are
not affected by oven aging for one week at 70 0 C.
64-3158
RECOMMENDAT IONS
project be discontinued.
It is recommended that this
It is believed that the insulation materials developed
investigation represent an
during the course of this
and that further
of the art
advancement in the state
and
inves t lgations under the approaches outlined in this
improvements.
only
marginal
in
would
result
work
earlier
I-- is recommended that the oxyacetylent torch test
eqipment be retained in a usable condition, in order that
promising new commercial insulation materials might be
evaluated and that cooperative work to further improve
might be conducted, if necessary
*his screening test
64-3158
ii
ELASTOMERIC
Object
Inttroduction
Procedure
Literature References
14
Appendix I
16
Appendix II
17
Distribut icn
18
iii
64-3158
ELASTOERIC
ROCKET MOTORS
OBJECT
To develop improved,
flexible,
are concerned,
Earlier work
attainable only It the expense of the other.
at this Arsenal, -8,9) as well as more recent studies, has
led to the development of r-'bber-based insulations having
a compromise In these two properties, namely, the highest
degree of ablative resistance which could be attained
together with flexibility which, when measured in terms of
Results of these
elongation, amounts to 20 to 50 percent.
studies have led to the following conclusions:
combination for
1. By far the cost effective filler
imparting ablation resistance to rubber vulcanizates is a
combination of a phenolic resin and long fiber asbestos.
2.
high nitrile
butadiene/acrylonitrile
elastomer.
64-3158
fillers
64-3158
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TABLE I
TORCH TEST OPERATING CONDITIONS
Oxygen flow rate, standard cubic feet/hour
(SCFH)
123
102
1 2
degrees 90
4 X 4 X 1/4
3/4
Visual
resistance
In static
Corporation
respective
insulations.
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64-3158
11
TABLE V I
EVALUATION DATA FOR THE BEST ROCK
ISLAND ARSENAL
AND COMMERCIAL INSULATIONS
Property Measured
P200- Cm 2 sec/gm
Commercial #I
95
79
Time to backside
temperature of 2000C.
for 1/4" specimen, sec.
127
101
E,
2.0
2.0
mils/sec
Elongaticn,
Density,
gm/cc
Major constituents
40
50
1.34
1.28
Rubber,
Asbestos,
Resin,
Oxyazoline #1
Rubber.
Resin,
Asbestos
12
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LITERATURE REFERENCES
1.
2.
3.
4.
5.
6.
Headrick,
R.
7.
8.
9.
14
Use of Plastic
of the Plastics
Management
Chicago,
64-3158
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64-3158
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