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Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around

project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)
Photographs of AAQM station installations

Vav Village - Primary School

Padariya Village - Gram Panchayat

Koliyad Village - Gram Panchayat

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 1 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Galenda Village - Panchayat Office

Project Site

Jolva Siddhi Green Excellence Office terrace

Ambetha Final Pumping Station

Security cabin of Sunshine industries - Dahej

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 2 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)
Geo Engineering Survey photographs

Plate3.1 and 3.2: Measurement of water level

Plate 3.3: Location marking with hand held GPS

Plate 3.4: Measurement of curbing length

Photographs of water sampling

Ambheta Village Pond

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Dahej Village Pond

Page 3 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Jolva Village Pond

GIDC Reservoir

Koliad Village Pond

Padariya Village Pond

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 4 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Vadadla Village Pond

Vav Village

Photographs of soil sampling

Plate 4.1: soil sampling with the help of spiral auger

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 5 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Plate 4.2: Soil sampling with spiral auger


Photographs of noise monitoring

Ambheta Village - Noise

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 6 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)
Janiyadra Village - Noise

Koliad Village

Jolva Village- Noise near internal village road

Jolva Village- Noise near temple

Padariya Noise

Project Site

Vadadla Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 7 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Vav Village
Photographs of water sampling for aquatic studies

Jolva Village Pond

GIDC Reservoir

Koliad Village

Vadadla Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 8 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Padariya Village

Vav Village
Photographs of Flora observed

Galenda Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Janiyadra Village

Page 9 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Project Site

Water Lily - Jolva Pond

Narmada River Bank


Photographs of Fauna survey

Koliad Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Indian Flying Fox - Janiyadra Pond

Page 10 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Padariya Village

Skittering Frog

Dragonfly

Guppy Fish

Indian Flap Shell turtle

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 11 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Eutrophicated Pond - Padariya Village

Dragon Fly - in Vav village pond

Potter Wasps - Ambheta Village Pond

Water Striders - Ambheta Village Pond

Stone Chat

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 12 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)
Photographs of Plankton species

Balantidium sp - GIDC Reservoir

Calanus Sp - GIDC Reservoir

Daphnia sp - Koliad Village

Rotifer sp - Padariya Village

Phytoplankton & debris - Vadadla Village

Cyclops sp - Vav Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 13 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Euglena sp - Vav Village


Photographs of sampling of marine water and sediments

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 14 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 15 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Photographs of Benthos

Gomphonema sp.

Scripsella sp.

Thallasiosira sp.

Euglena

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 16 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Chaetoceros sp.

Tetrastrum sp.

Photographs of Socio-economic survey

Ambheta Village

Vadadla Village

Vadadla Village

Jolva Villaje

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 17 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Jolva Village Gram Panchayat & Bank Facility

Jolva village Post Office

Project Site

Galenda Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 18 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Janiyadra Village

Koliad Village

Vav Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Dahej Villaje

Page 19 of 20

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around
project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,
India for EIA for proposed synthetic resin manufacturing unit.
(Duration Oct 2014 to Dec 2014)

Padariya Village

Dahej Village

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 20 of 20

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

Affected Area

SN 1. Leakage from the 10 KL Tank - Stability Class D (8.33)


Damage distances for toxic effect from Evaporating puddle
Acrylonitrile- 10 KL (1 Tank of 10 KL at site)

Red : 49 meters --- (333 ppm)


Orange: 108 meters --- (85 ppm = IDLH)

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

Affected Area

SN 2. Leakage from the 10 KL Tank - Stability Class F (2.2)


Damage distances for toxic effect from Evaporating puddle
Acrylonitrile- 10 KL (1 Tank of 10 KL at site)

Red : 26 meters --- (333 ppm)


Orange: 91 meters --- (85 ppm = IDLH)

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India

Predominant Wind
Direction - SW to NE

SN 3. Leakage from the 10 KL Tank - Stability Class D (8.33)


Damage distances for Thermal Radiation from Pool Fire

Acrylonitrile- 10 KL (1 Tank of 10 KL at site)

Red : 11 meters ----- (37.5 kW/(sq m))


Orange: 23 meters -----(4.0 kW/(sq m))
Yellow: 31 meters ----- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 4. Leakage from the 10 KL Tank - Stability Class F (2.2)


Damage distances for Thermal Radiation from Pool Fire

Acrylonitrile- 10 KL (1 Tank of 10 KL at site)

Red : < 10 meters(10.9 yards)(37.5 kW/(sq m))


Orange: 24 meters ------ (4.0 kW/(sq m))
Yellow: 36 meters ------- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

Affected Area

SN 5. Leakage from the 50 KL Tank - Stability Class F (2.2)


Damage distances for Toxic Area from Vapor Cloud

Formaldehyde - 100 KL (2 nos. 50 KL Tank at site)

Yellow: 162 meters --- (20 ppm)

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 6. Leakage from the 10 KL Tank - Stability Class D (8.33)


Damage distances for Thermal Radiation from Pool Fire

Methyl Ethyl Ketone - 10 KL (1 Tank of 10 KL at site)

Red : 12 meters --- (37.5 kW/(sq m))


Orange: 26 meters --- (4.0 kW/(sq m))
Yellow: 35 meters --- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 7. Leakage from the 10 KL Tank - Stability Class F (2.2)


Damage distances for Thermal Radiation from Pool Fire

Methyl Ethyl Ketone - 10 KL (1 Tank of 10 KL at site)

Red : <10 meters (10.9 yards) --- (37.5


kW/(sq m))
Orange: 25 meters --- (4.0 kW/(sq m))
Yellow: 39 meters --- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 8. Catastrophic Failure of Hydrogenation reactor - Stability Class D (8.33)


Damage distances for Overpressure (blast force) from vapor cloud explosion

Hydrogen - 2 Cylinders bank of 30 cylinders

Red : LOC was never exceeded (8.0 psi =


destruction of buildings)
Orange: LOC was never exceeded (3.5 psi
= serious injury likely)
Yellow: 24 meters --- (0.5 psi)

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 9. Catastrophic Failure of Hydrogenation reactor - Stability Class F (2.2)


Damage distances for Overpressure (blast force) from vapor cloud explosion

Hydrogen - 2 Cylinders bank of 30 cylinders

Red : LOC was never exceeded --- (8.0 psi =


destruction of buildings)
Orange: LOC was never exceeded --- (3.5 psi
= serious injury likely)
Yellow: 75 meters --- (0.5 psi)

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India

Predominant Wind
Direction - SW to NE

SN 10. Leak from hydrogen cylinders through instrument tubing- Stability Class F (2.2)
Damage distances for Overpressure (blast force) from vapor cloud explosion

Hydrogen - 2 Cylinders bank of 30 cylinders

Red : LOC was never exceeded --- (8.0 psi =


destruction of buildings)
Orange: LOC was never exceeded --- (3.5 psi
= serious injury likely)
Yellow: 25 meters --- (0.5 psi)

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 11. Leakage from 20 KL storage tank- Stability Class D (8.33)


Damage distances for Thermal radiation from pool fire

Styrene - 40 MT (20 KL - 2 nos. of tank at site)

Red : 15 meters --- (37.5 kW/(sq m))


Orange: 31 meters --- (4.0 kW/(sq m))
Yellow: 42 meters --- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 12. Leakage from 20 KL storage tank- Stability Class F (2.2)


Damage distances for Thermal radiation from pool fire

Styrene - 40 MT (20 KL - 2 nos. of tank at site)

Red : less than 10 meters(10.9 yards) --(37.5 kW/(sq m))


Orange: 29 meters --- (4.0 kW/(sq m))
Yellow: 46 meters --- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 13. Leakage from 20 KL storage tank- Stability Class D (8.33)


Damage distances for Thermal radiation from pool fire

Xylene- 20 MT (20 KL - 1no. of tank at site)

Red : 17 meters --- (37.5 kW/(sq m))


Orange: 35 meters --- (4.0 kW/(sq m))
Yellow: 48 meters --- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 14. Leakage from 20 KL storage tank- Stability Class F (2.2)


Damage distances for Thermal radiation from pool fire

Xylene- 20 MT (20 KL - 1no. of tank at site)

Red : less than 10 meters(10.9 yards) --(37.5 kW/(sq m))


Orange: 32 meters --- (4.0 kW/(sq m))
Yellow: 51 meters --- (1.6 kW/(sq m))

Plot Plan:
M/s. POLYOLS AND POLYMERS
at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra,
Dist - Bharuch, State Gujarat, India
Predominant Wind
Direction - SW to NE

SN 15. Leakage from 200 meters length Natural Gas pipeline -Stability Class F (2.2)
Damage distances for Thermal radiation from jet fire

Natural Gas - pipeline supply

Red : 10 meters --- (37 kW/(sq m))


Orange: 32 meters --- (4 kW/(sq m))
Yellow: 49 meters --- (1.6 kW/(sq m))

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

TABLE OF CONTENTS
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

TOLUENE ................................................................................................................................................................................. 2
METHYL ISOBUTYL KETONE (MIBK) ..................................................................................................................................... 3
CYCLOHEXANONE.................................................................................................................................................................. 4
METHYL ETHYL KETONE........................................................................................................................................................ 5
ETHYL ACETATE ..................................................................................................................................................................... 6
ACRYLO NITRILE ..................................................................................................................................................................... 7
ETHYL ACRYLATE................................................................................................................................................................... 9
ETHYLENE DIAMINE................................................................................................................................................................ 10
HYDROGEN-HYDROGENATION REACTOR .......................................................................................................................... 11
HYDROGEN-HYDROGEN CYLINDER BANK.......................................................................................................................... 12
ISOPROPYL ALCOHOL (IPA) .................................................................................................................................................. 13
METHYL METHACRYLATE...................................................................................................................................................... 14
BUTYL ACETATE ..................................................................................................................................................................... 15
BUTANOL ................................................................................................................................................................................. 16
STYRENE ................................................................................................................................................................................. 17
ACETIC ACID............................................................................................................................................................................ 18
BUTYL METHACRYLATE......................................................................................................................................................... 19
FORMALDEHYDE..................................................................................................................................................................... 20
XYLENE .................................................................................................................................................................................... 22
PHENOL.................................................................................................................................................................................... 23
SULFURIC ACID ....................................................................................................................................................................... 24

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 1 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

TOLUENE

Scenario
Most Credible Scenario of Toluene,leakage through 10mm hole
Input Data
Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s
Atmospheric Temperature,degC
Amount of Toluene,KL
pool Area,m2

D
atm
4
8.33
45
20
58.7

F
atm
4
2.2
10
20
57.3

Output
Flash Fire Envelope,m
<10
<10
Pool Fire
4.4
Burn Rate of Pool fire ,kg/s
4.983
Distance to radiation level 37.5kw/m2,..m
16
<10
30
Distance to radiation level 4kw/m2,..m
34
48
Distance to radiation level 1.6 kw/m2,..m
46
Assumptions
Stability class is D and F.
For MCS 10mm hole diameter is considered. (For 3 pipe this is ~10% of pipe diameter ) (Ref 3.A.2.4,Purple Book).
The line feeding Toluene to the reactor will be isolated after detection & identification of leak. The release time is taken
as 15mins.
The leak will form an evaporating puddle. Puddle height is 25mm.
No fire water spray system in process area.
No gas detection is available in process area.
Flammable effects will be analysed.
Area is classified area.
Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.28kg/s.The total material released is 1267kgs.
The evaporating pool will release Toluene vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 5mins.
In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 16/less than 10m respectively. But
the total spilled material will be burnt within 5 mins.
4.0 & 1.6 kw/m2 distances are 34 & 46m for atmosphere condition D and 30 & 48 m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 2 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

METHYL ISOBUTYL KETONE (MIBK)

Scenario
Most Credible Scenario of MIBK,leakage through 10mm hole
Input Data
D

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of MIBK,KL

20

20

60.9

60.9

<10

<10

4.21

3.71

Distance to radiation level 37.5kw/m2,..m

14

Distance to radiation level 4kw/m2,..m

29

<10
27

Distance to radiation level 1.6 kw/m2,..m

39

42

Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s

pool Area,m2
Output
Flash Fire Envelope,m
Pool Fire
Burn Rate of Pool fire ,kg/s

For all 10mm leak MCS scenarios assumptions are covered in general assumptions and similar to Toluene scenario.
Hence these are not repeated for each such scenarios.
Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.23kg/s.The total material released is 1221kgs.
The evaporating pool will release MIBK vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 6mins.
Although for atmospheric stability class F, the temp (10degC) is below flash point of MIBK (14degC), the
consequence is calculated considering the fire initiated due to other source.
In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 14/less than 10m respectively. But
the total spilled material will be burnt within 6 mins.
4.0 & 1.6 kw/m2 distances are 29 & 39m for atmosphere condition D and 27 & 42m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 3 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

CYCLOHEXANONE

Scenario
Most Credible Scenario of Cyclohexanone,leakage through 10mm hole
Input Data
Stability Class
Temperature,degC
Pressure,barg

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of Cyclohexanone,KL

20

20

pool Area,m2

56

56

<10

<10

Burn Rate of Pool fire ,kg/s

3.1

2.88

Distance to radiation level 37.5kw/m2,..m

12

Distance to radiation level 4kw/m2,..m

24

<10
25

Distance to radiation level 1.6 kw/m2,..m

33

38

Wind Speed,m/s

Output
Flash Fire Envelope,m
Pool Fire

Flammable Effects:

Atmosphere Stability Class D

Atmosphere Stability Class F

Discussion:
The discharge rate through leak is 1.34kg/s.The total material released is 1328kgs.
The evaporating pool will release Cyclohexanone vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 8mins.
In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 12/<10m respectively.But the total
spilled material will be burnt within 8 mins.
4.0 & 1.6 kw/m2 distances are 24 & 33m for atmosphere condition D and 25 & 38m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 4 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

METHYL ETHYL KETONE


Scenario
MEK Leak Through 10mm hole
Input Data

Stability Class

Temperature,degC

Atm

Atm

Pressure,barg

Atm

Atm

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Leak Size,mm

10

pool Area,m2

60.7

10
61.5

<10

<10

Burn Rate of Pool fire ,kg/s

3.7

3.28

Distance to radiation level 37.5kw/m2,..m

12

Distance to radiation level 4kw/m2,..m

26

<10
25

Distance to radiation level 1.6 kw/m2,..m

35

39

Output
Flash Fire Envelope,m
Pool Fire

Flammability Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The pool fire due to this spill will last for 5mins and all 1223kgs of spilled MEK will burn within this time.
The radiation of 37.5kw/m2 will experienced at 12m for atmospheric class D.
The total spilled material will be burnt within 5 mins.The radiation will experience for this time only.
4.0 & 1.6 kw/m2 distances are 26 & 35m for atmosphere condition D and 25 & 39m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 5 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

ETHYL ACETATE

Scenario
Most Credible Scienario of Ethyl Acetate,Spillage from 200Lit Drum
Input Data
Stability Class

atm

atm

Pressure,barg

atm

atm

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of Ethyl Acetate,Lits

200

200

pool Area,m2

20

20

<10

<10

Burn Rate of Pool fire ,kg/s

1.09

0.95

Distance to radiation level 37.5kw/m2,..m

<10

<10

Distance to radiation level 4kw/m2,..m

14

13

Temperature,degC

Output
Flash Fire Envelope,m
Pool Fire

Distance to radiation level 1.6 kw/m2,..m


18
19
Assumptions:
The damage of drum is happened during handling.
There can be 10 events of handling.
Due to damage total material of the drum is spilled on the ground.
Due to the adjacent drums the pool height is considered as 10mm.Hence the pool area is considered as 20m2.
The consequence is evaluated assuming that the spill will get an ignition immediately.
Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The pool fire due to this spill will last for 3mins and all 175kgs of spilled ETHYL ACETATE will burn within this time.
The burn rate is 1.09kg/s.
The radiation of 37.5kw/m2 will not experienced due to this fire.
Due to these reasons there is unlikely that other drums will get damaged and additional ETHYL ACETATE will be
spilled.
If the explosive mixture is not ignited immediately then the spilled material will be evaporated at rate of 0.29kg/s and it
will take 16 mins to evaporate all the spilled material.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 6 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

The storage area shall be well ventilated.

ACRYLO NITRILE

Scenario
Most Credible Scenario of ACN,Leakage from 10mm hole
Input Data
Stability Class

Temperature,degC

atm

atm

Pressure,barg

atm

atm

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of ACN,KL

10

10

IDLH,ppm

85

85

LD50,ppm

333

333

Evaporation Rate ,gm/s

0.62

0.0455

Flash Fire Envelope,m

<10

<10

Output

Pool Fire
Burn Rate of Pool fire ,kg/s

2.95

2.667

Distance to radiation level 37.5kw/m2,..m

11

<10

Distance to radiation level 4kw/m2,..m

23

24

Distance to radiation level 1.6 kw/m2,..m

31

36

Distance to LC50,m

49

26

Distance to IDLH,m

108

91

Assumptions
The line feeding ACN to the reactor will be isolated after detection & identification of leak. The release time is taken as
15mins.
The leak will form an evaporating puddle.
Puddle height is 25mm.
ACN Pump should having double mechanical seals.
No fire water spray system in process area.
Toxic and flammable both effects will be analysed.
Area is classified area.
Toxic Effect:

Atmospheric Stability Class D

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Atmospheric Stability Class F

Page 7 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.23kg/s.The total material released is 1225kgs.
The evaporating pool will release ACN vapors to atmosphere which will disperse in downwind direction.
LC50 distances are 49 & 26m for atmospheric condition D & F respectively.
The cloud will reach these distance within 3 mins of release. The concentration at this point will be 333ppm for 1-2
mins and subsequently it decreases below IDLH value.(As seen in below fig)

A part of the emergency plan considers the evacuation of (parts of) the plant, the neighboring plants and people in
further surroundings to minimize exposure in case of an Acrylonitrile vapour cloud
ACN detectors can be installed at the strategic locations in the plant and battery limit which helps in alarming that ACN
is escaping to offsite.
To minimize the effects it is suggested that the area where ACN is handled may have bund wall of 300mm.This will
limit the spread of ACN spill and reduce the pool area. Eventually evaporation rate and ACN evaporated & released to
air can be minimized.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 8mins.
4.0 & 1.6 kw/m2 distances are 23 & 31m for atmosphere condition D and 24 & 36 m for F.
ACN is Highly reactive and reacts violently with strong oxidising agents.ACN emits toxic fumes of hydrogen cyanide
and nitrogen oxide when heated to decomposition.
In the event of a fire involving acrylonitrile, use alcohol resistant foam, or normal foam if not available, and
liquid tight protective clothing with breathing apparatus

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 8 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

ETHYL ACRYLATE

Scenario
Most Credible Scenario of Ethyl Acrylate,Leakage from 10mm hole
Input Data
Stability Class

Temperature,degC

atm

atm

Pressure,barg

atm

atm

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of Ethyl Acetate,KL

10

10

Evaporation Rate ,gm/s

0.405

0.0271

Flash Fire Envelope,m

<10

<10

Burn Rate of Pool fire ,kg/s

3.28

2.91

Distance to radiation level 37.5kw/m2,..m

<10

<10

Distance to radiation level 4kw/m2,..m

23

22

Distance to radiation level 1.6 kw/m2,..m

31

33

Output

Pool Fire

Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.32kg/s.The total material released is 1310kgs.
The evaporating pool will release Ethyl Acrylate vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 8mins.
4.0 & 1.6 kw/m2 distances are 23 & 31m for atmosphere condition D and 22 & 33m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 9 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

ETHYLENE DIAMINE
Scenario

Most Credible Scenario of Ethylene Diamine one drum damage


Input Data
Stability Class

Temperature,degC

atm

atm

Pressure,barg

atm

atm

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of Ethylene Diamine,KL

10

10

Output
Evaporation Rate ,gm/s

0.038

Flash Fire Envelope,m

<10

Pool Fire
Burn Rate of Pool fire ,kg/s

0.65

Distance to radiation level 37.5kw/m2,..m

<10

Distance to radiation level 4kw/m2,..m

11

Material Solidify

Distance to radiation level 1.6 kw/m2,..m


14
Assumptions:
The damage of drum is happened during handling.
There can be 50 events of handling.
Due to damage total material of the drum is spilled on the ground.
Due to the adjacent drums the pool height is considered as 10mm.Hence the pool area is considered as 20m2.
The consequence is evaluated assuming that the spill will get an ignition immediately.
Flammable Effect:

Atmospheric Stability class D


At 10degCatmospheric temperature, ethylene diamine is near to solidification state(MP 8.5degC) hence it will solidify once
released to atmosphere. Hence no hazardous scenario will be created. It can be handled as per normal plant practices.
Discussion:
The pool fire due to this spill will last for 4mins and all 175kgs of spilled Ethylene Diamine will burn within this time.
The burn rate is 0.65kg/s.
The radiation of 37.5kw/m2 will not experienced due to this fire.
Due to these reasons there is unlikely that other drums will get damaged and additional Ethylene Diamine will be
spilled.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 10 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

If the explosive mixture is not ignited immediately then the spilled material will be evaporated at rate of 0.038kg/s
The storage area shall be well ventilated

HYDROGEN-HYDROGENATION REACTOR
Scenario
Hydrogenation Reactor Catastrophic Failure
Input Data

Stability Class

Temperature,degC

atm

atm

Pressure,barg

300

300

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Volume of reactor,m3

10.7

10.7

Distance to overpressure level 8.0psi,..m

Distance to overpressure level 3.5psi,..m

<10

<10

Distance to overpressure level 0.5psi,..m

24

75

Output
Released Quantity,Kg
Explosion

Assumptions:
The catastrophic failure will release all the contents to atmosphere almost instantaneously. The 50% of reactor volume
contains hydrogen which is available for explosion.
The release will catch fire immediately as MIE of hydrogen is very less (0.017mJ) and result in explosion.
Total released material is 10.7 kg.
Flammable Effect (Explosion):

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The failure of hydrogenation reactor will result in release of reactants and the content will splash with force exerted
due to 100barg pressure.
Almost instantaneously the released hydrogen will explode as hydrogen do not need any separate ignition source as
its required minimum ignition energy is very low (0.017mJ).
The explosion will result in overpressure. The analysis results shows that overpressure wave more than 8psi will not
be experienced.
At distance of 24/75 m, the overpressure experienced is 0.5psi for stability class D/F respectively.It can cause injuries
due to glass shattering of windows. It can be protected by applying safety laminates on the windows which come
under this area

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 11 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

10 HYDROGEN-HYDROGEN CYLINDER BANK


Scenario
Hydrogen Cylinders Tubing Leak,(Leak Size 0.75 in)
Input Data
Stability Class
D
Temperature,degC
300
Pressure,barg
100
Wind Speed,m/s
8.33
Atmospheric Temperature,degC
45
Volume of cylinder,m3
0.047
Output
Released Quantity,Kg
1.08
Explosion
Distance to overpressure level 8.0psi,..m
Distance to overpressure level 3.5psi,..m
Distance to overpressure level 0.5psi,..m
Jet Fire
Flame Length,m
1
Distance to radiation level 37.5kw/m2,..m
<10
Distance to radiation level 4kw/m2,..m
<10
Distance to radiation level 1.6 kw/m2,..m
<10

F
300
100
2.2
10
0.047
1.22
25
1
<10
<10
<10

Assumptions:
Atmospheric stability class F & D.
Leak is from instrument tubing which is disconnected and of size .
The leak will cat fire immediately as MIE of hydrogen is very less(0.017mJ).A jet fire will sustain at the leak.
The leak is assumed to be for 15mins before detection and isolation.
Flammable Effect Explosion
No Explosion

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
At the release rate of 0.018 & 0.0203 kg/s for stability class D & F .The burning will occur and it will end within 20 secs
(completely burning 1.08 / 1.22 kgs in one cylinder).
At this rate the radiation effect of Jet Fire are maximum. All radiation effects are within less than 10m from jet source.
The flame length is 1m at start. This is due to high pressure inside of the cylinder.
Practically it will take more time but with less release rate. As pressure will reduce inside cylinder the release rate will
also reduced.
In case of stability class F, the explosion effects are also experienced.0.5 psi overpressure is experienced upto
25m.This overpressure can shatter glasses.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 12 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

11 ISOPROPYL ALCOHOL (IPA)


Scenario
Most Credible Scenario of IPA,leakage through 10mm hole
Input Data
D

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of IPA,KL

20

20

61.5

61.5

<10

<10

Burn Rate of Pool fire ,kg/s

2.4

2.21

Distance to radiation level 37.5kw/m2,..m

<10

Distance to radiation level 4kw/m2,..m

20

<10
21

Distance to radiation level 1.6 kw/m2,..m

27

32

Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s

pool Area,m2
Output
Flash Fire Envelope,m
Pool Fire

Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.23kg/s.The total material released is 1208kgs.
The evaporating pool will release IPA vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 9mins.
Although for atmospheric stability class F,the temp (10degC) is below flash point of IPA (11.67degC), the
consequence is calculated considering the fire initiated due to other source.
4.0 & 1.6 kw/m2 distances are 20 & 27m for atmosphere condition D and 21 & 32m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 13 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

12 METHYL METHACRYLATE
Scenario
Most Credible Scenario of Methyl Methacrylate,leakage through 10mm hole
Input Data
D

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of Methyl Methacrylate,KL

10

10

56.4

56.4

<10

<10

Burn Rate of Pool fire ,kg/s

3.21

2.87

Distance to radiation level 37.5kw/m2,..m

<10

Distance to radiation level 4kw/m2,..m

23

<10
22

Distance to radiation level 1.6 kw/m2,..m

30

33

Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s

pool Area,m2
Output
Flash Fire Envelope,m
Pool Fire

Flammable Effects:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.33kg/s.The total material released is 1319kgs.
The evaporating pool will release Methyl Methacrylate vapors to atmosphere which will disperse in downwind
direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 8mins.
4.0 & 1.6 kw/m2 distances are 23 & 30m for atmosphere condition D and 22 & 33m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 14 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

13 BUTYL ACETATE
Scenario
Most Credible Scenario of Butyl Acetate,leakage through 10mm hole
Input Data
D

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of Butyl Acetate,KL

10

10

57.5

57.5

<10

<10

Burn Rate of Pool fire ,kg/s

3.4

Distance to radiation level 37.5kw/m2,..m

11

Distance to radiation level 4kw/m2,..m

24

<10
23

Distance to radiation level 1.6 kw/m2,..m

32

35

Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s

pool Area,m2
Output
Flash Fire Envelope,m
Pool Fire

Flammable Effects:

Atmospheric Stability class D

Atmospheric Stability class F

Discussion:
The discharge rate through leak is 1.307kg/s.The total material released is 1294kgs.
The evaporating pool will release Butyl Acetate vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 7mins.
Although for atmospheric stability class F,the temp (10degC) is below flash point of butyl acetate (23.9degC), the
consequence is calculated considering the fire initiated due to other source.
In case of stability class D,radiation of 37.5kw/m2 is experienced up to distance 11m.But the total spilled material will
be burnt within 6 mins.
4.0 & 1.6 kw/m2 distances are 24 & 32m for atmosphere condition D and 23 & 35m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 15 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

14 BUTANOL
Scenario
Most Credible Scenario of Butanol,leakage through 10mm hole
Input Data
D

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of Butanol,KL

10

10

60.6

60.6

<10

<10

Burn Rate of Pool fire ,kg/s

2.6

2.41

Distance to radiation level 37.5kw/m2,..m

11

Distance to radiation level 4kw/m2,..m

22

<10
23

Distance to radiation level 1.6 kw/m2,..m

29

34

Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s

pool Area,m2
Output
Flash Fire Envelope,m
Pool Fire

Flammable Effects:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.24 kg/s. The total material released is 1227 kgs.
The evaporating pool will release Butanol vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 8 mins.
Although for atmospheric stability class F, the temp (10degC) is below flash point of Butanol (28.9degC), the
consequence is calculated considering the fire initiated due to other source.
In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 11/less than 10m.But the total
spilled material will be burnt within 9 mins.
4.0 & 1.6 kw/m2 distances are 22 & 29m for atmosphere condition D and 23 & 34m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 16 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

15 STYRENE
Scenario
Most Credible Scenario of styrene,leakage through 10mm hole
Input Data
D

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of styrene,KL

20

20

57.3

57.3

<10

<10

4.35

3.98

Distance to radiation level 37.5kw/m2,..m

15

Distance to radiation level 4kw/m2,..m

31

<10
29

Distance to radiation level 1.6 kw/m2,..m

42

46

Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s

pool Area,m2
Output
Flash Fire Envelope,m
Pool Fire
Burn Rate of Pool fire ,kg/s

Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.31kg/s. The total material released is 1298kgs.
The evaporating pool will release Styrene vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 5 mins.
Although for atmospheric stability class F, the temp (10degC) is below flash point of Styrene (31.1degC), the
consequence is calculated considering the fire initiated due to other source.
In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 15/less than 10 m.But the total
spilled material will be burnt within 5 mins.
4.0 & 1.6 kw/m2 distances are 31 & 42m for atmosphere condition D and 29 & 46m for F.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 17 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

16 ACETIC ACID
Scenario
Most Credible Scenario of Acetic Acid,leakage through 10mm hole
Input Data
D

atm

atm

4
8.33

4
2.2

Atmospheric Temperature,degC

45

10

Amount of Acetic Acid,KL

10

10

53.27

Solid

Stability Class
Temperature,degC
Pressure,barg
Wind Speed,m/s

pool Area,m2
Output
Flash Fire Envelope,m

<10

Pool Fire
Burn Rate of Pool fire ,kg/s

1.28

Distance to radiation level 37.5kw/m2,..m

<10

Distance to radiation level 4kw/m2,..m

12

Distance to radiation level 1.6 kw/m2,..m

15

Solid at 10degC

Flammable Effect:
Acetic acid will solidify below
16degC at atmospheric pressure.
Hence no hazardous scenario is
analysed

Atmospheric Stability Class D

Atmospheric Condition F:.

Discussion:
The discharge rate through leak is 1.41kg/s. The total material released is 1397kgs.
The evaporating pool will release Acetic Acid vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 18 mins.
Although for atmospheric stability class F, at temp (10degC) acetic acid will solidify(below 16degC)
In case of stability class D,radiation of 37.5kw/m2 is not experienced
4.0 & 1.6 kw/m2 distances are 12 & 15m for atmosphere condition D

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 18 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

17 BUTYL METHACRYLATE
Scenario
Most Credible Scienario of Butyl Acrylate,Spillage from 200Lit Drum
Input Data
Stability Class

Temperature,degC

atm

atm

Pressure,barg

atm

atm

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of Butyl Acrylate,Lits

200

200

pool Area,m2

20

20

Output
Flash Fire Envelope,m

<10

Pool Fire
Burn Rate of Pool fire ,kg/s

1.19

Distance to radiation level 37.5kw/m2,..m

<10

Distance to radiation level 4kw/m2,..m

16

Distance to radiation level 1.6 kw/m2,..m

21

Non flammable(flash point52.2degC, is quite higher


10degC)

Assumptions:
The damage of drum is happened during handling.
There can be 10 events of handling.
Due to damage total material of the drum is spilled on the ground.
Due to the adjacent drums the pool height is considered as 10mm.Hence the pool area is considered as 20m2.
Although the flash point 52.2degC is higher than atmospheric temperature,the consequence is evaluated assuming
that the spill will get an ignition immediately.
The consequence is evaluated for class D only.
Flammable Effect:

Atmospheric Stability Class D


Discussion:
The pool fire due to this spill will last for 2 mins and all 175kgs of spilled BUTYL METHACRLATE will burn within this
time.
The burn rate is 1.196 kg/s.
The radiation of 37.5kw/m2 will not experienced due to this fire.
Due to these reasons there is unlikely that other drums will get damaged and additional BUTYL METHACRLATE will
be spilled.
If the explosive mixture is not ignited immediately then the spilled material will be evaporated at rate of 0.29kg/s and it
will take 16 mins to evaporate all the spilled material.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 19 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

The storage area shall be well ventilated.

18 FORMALDEHYDE
Scenario
Most Credible Scenario of Formaldehyde,Spillage from 10mm hole
Input Data
Stability Class

Temperature,degC

45

10

Pressure,barg

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of Formaldehyde,KL

50

50

IDLH,ppm

20

Wind Speed,m/s

Output
Solution Release rate,kg/hr

1.44

1.44

0.0133

0.0133

Flash Fire Envelope,m

<10

<10

Distance to IDLH,m

45

162

Formaldehyde release rate,kg/hr

Discharge Calculations
The discharge is modeled as liquid flow through sharp edged orifice
The Discharge Rate of Formaldehyde Soln.
: 1.44 kg/s
The release rate of formaldehyde from solution can be done in following two basis,
1. There is certain volume over the pool whose composition can be found out by vapor pressure (0.34psi) of
formaldehyde solution at ambient conditions. This formaldehyde is available for dispersion. It can be modeled as direct
source in ALOHA as instantaneous release.
2. The emission rates of formaldehyde from 37% solution are available in literature. (Ref: Estimating Formaldehyde
Emission in Air by EPA;1991) For different process and storages rates are reported. Maximum of these rates
(0.35kg/Mg) can be used in ALOHA and modeled in ALOHA as direct source with continuous rate.
Based on vapor pressure,on conservative side it is assumed that from the released solution 2.5% of the amount of
formaldehyde gas is released to atmosphere.
The release rate of formaldehyde gas

: 1.44*0.37*2.5% = 0.0133kg/s

This much formaldehyde is available to disperse in downwind direction.It is modeled as direct source - continuous in ALOHA.
Flash Fire Envelope:
The envelope diameter is <10m for both atmospheric stability classes.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 20 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

Toxic Effect:
The Area is patchy hence not
shown.

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
It is assumed that after isolation and control of the formaldehyde solution leak(ie 15mins) still there will be release of
formaldehyde gas from spilled solution but it is assumed that it will be negligible as all 37% formaldehyde is released
during the leak.
The IDLH distance for stability class D & F is 45 and 162m. For atmospheric class D the area of dispersion is not
wide and it is patchy ,hence ALOHA has not given the map. For class F also the spread of area along the line of
concentration is not more than 5m.
At these distances the horizontal spread of vapour cloud is not more than 10m maximum.
The toxic effect is more severe than flammable effects.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 21 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

19 XYLENE
Scenario
Most Credible Scienario of xylene,Spillage from 10mm hole
Input Data
Stability Class

Temperature,degC

atm

atm

Pressure,barg

atm

atm

Wind Speed,m/s

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of xylene,KL

20

20

58.7

58.7

<10

<10

5.167

4.65

Distance to radiation level 37.5kw/m2,..m

17

<10

Distance to radiation level 4kw/m2,..m

35

32

Distance to radiation level 1.6 kw/m2,..m

48

51

pool Area,m2
Output
Flash Fire Envelope,m
Pool Fire
Burn Rate of Pool fire ,kg/s

Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Discussion:
The discharge rate through leak is 1.28kg/s.The total material released is 1268kgs.
The evaporating pool will release Xylene vapors to atmosphere which will disperse in downwind direction.
If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material
will burnt out in 4mins.
Although for atmospheric stability class F,the temp (10degC) is below flash point of xylene (24degC), the
consequence is calculated considering the fire initiated due to other source.
In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 17/less than 10m.But the total
spilled material will be burnt within 4 mins.
4.0 & 1.6 kw/m2 distances are 35 & 48m for atmosphere condition D and 32 & 51m for F

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 22 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

20 PHENOL
Scenario
Most Credible Scenario of Phenol,Spillage from 10mm hole
Input Data
Stability Class

Temperature,degC

45

10

Pressure,barg

8.33

2.2

Atmospheric Temperature,degC

45

10

Amount of Phenol,KL

40

40

IDLH,ppm

250

250

LD50,ppm

2500

2500

Wind Speed,m/s

Output
Evaporation rate,kg/hr

0.01026

Distance toLD50,m

<10

Distance to IDLH,m

<10

Burn Rate of Pool fire ,kg/s

2.48

Distance to radiation level 37.5kw/m2,..m

11

Distance to radiation level 4kw/m2,..m

21

Distance to radiation level 1.6 kw/m2,..m

28

Material Solidify

Flammable Effect:

Atmospheric Stability Class D

Atmospheric Stability Class F

Toxic Effect:
All the toxic endpoint distances are less than 10m.
Discussion:
LD50 and IDLHconcentration will not reach more than 10m.
The flash point (79degC) is more than atmospheric temp. Then also the radiation effects are analyzed considering it
will burning due to fire.
The 37.5 kw/m2 radiation will experienced upto 11m. 4 & 1.6 kw/m2 will experienced up to distance of 21&28m.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 23 of 24

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY


For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.
At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

21 SULFURIC ACID
Scienaro 1
Catastrophic Failure of Sulfuric acid Tank
Input Data
Stability Class
Temperature,degC
Pressure,kg/cm2g

atm

atm

8.33

2.2

Atmospheric Temperature,degC

45

10

Volume of vessel,m3

10

10

Diameter,m

Height,m

ERPG2,mg/m3

10

10

Evaporation Rate,kg/min

1.5

0.105

LC50 Distance,m

<10

<10

ERPG2 Distance,m

13

<10

Wind Speed,m/s

Output

Assumptions
For this worst-case analysis, it was conservatively assumed that the sulfuric acid stored in the tank contains 4% sulfur
trioxide (oleum). However, the actual amount of oleum in 96% sulfuric acid is negligible. Nevertheless, to be
conservative, a 4% oleum concentration was used as input into the ALOHA model to simulate a release of sulfuric
acid
The release is instantaneous.
The release will be modeled as burning / evaporating puddle.
Atmospheric stability class is D (Wind velocity 8.33m/s).This is worst case for pool formation, evaporation. With the
heat available from ground and atmosphere is at these conditions, the pool evaporation rate is maximum.
The dyke around sulfuric acid tank is not designed to contain total volume of tank.
The pool height is 10mm(1cm)
Toxic Effect:
All toxic endpoints distances are less than 10m.
Discussion:
ERPG 2 concentration will not reach more than 13m.
The release rate of SO3 from sulfuric acid is 1.5gm/s and amount released in air is 5.39kgs.(for stability class D)
The release rate of SO3 from sulfuric acid is 0.12gm/s and amount released in air is 368gms.(for stability class F)
It is suggested to have 300mm bund wall around sulfuric acid tank and pumping area. This will help to restrict sulfuric acid spill
to minimum area.The area inside bund can be of acid resistant material.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 24 of 24

Project: Baseline Environmental Studies


Client: Polyols & Polymers
Conducted by: Siddhi Green Excellence Pvt Ltd, Ankleshwar
Duration for Baseline Environmental Studies Oct 2014 to Dec 2014 (Post monsoon)
AAQM monitoring dates for stations Jolva, Vadadla, Galenda, Dahej, Ambetha

OCTOBER

NOVEMBER

DECEMBER

WK SUN MON TUE WED THU FRI SAT

WK SUN MON TUE WED THU FRI SAT

WK SUN MON TUE WED THU FRI SAT

50

41

45

10

11

46

51

10

11

12

13

43 12

13

14

15

16

17

18

47

10

11

12

13

14

15

52 14

15

16

17

18

19

20

44 19 20

21

22 23 24 25

48 16

17

18

19

20

21

22

53 21 22 23 24 25 26 27

42

45 26 27 28 29 30

31

49 23 24 25 26 27 28 29

54 28 29 30

31

50 30

Project: Baseline Environmental Studies


Client: Polyols & Polymers
Conducted by: Siddhi Green Excellence Pvt Ltd, Ankleshwar
Duration for Baseline Environmental Studies Oct 2014 to Dec 2014 (Post monsoon)
AAQM monitoring dates for stations Janiyadra, Padariya, Koliyad, Vav, Project site

OCTOBER

NOVEMBER

DECEMBER

WK SUN MON TUE WED THU FRI SAT

WK SUN MON TUE WED THU FRI SAT

WK SUN MON TUE WED THU FRI SAT

50

41

45

10

11

46

51

10

11

12

13

43 12

13

14

15

16

17

18

47

10

11

12

13

14

15

52 14

15

16

17

18

19

20

44 19 20

21

22 23 24 25

48 16

17

18

19

20

21

22

53 21 22 23 24 25 26 27

42

45 26 27 28 29 30

31

49 23 24 25 26 27 28 29
50 30

54 28 29 30

31

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
List of Partners for proposed project

List of Partners:
Sr.No. List of partners

Contact No.

Address

Prabir Kumar Dutt


Bhupendra Mohan Dutt
Mrs. Archana Dutt
Kali Bhusan Sadananda Dutt
Mr. Supratik Dutt
Prabir Kumar Dutt
Patel Navnitbhai Durlabhbhai
Patel Durlabhbhai Zinabhai

9377001193

81, Bhagyoday Society Chala,


Vapi:396191
81, Bhagyoday Society Chala,
Vapi:396191
81, Bhagyoday Society Chala,
Vapi:396191
At & Po. Kalwada, Dist. Valsad
I.T. PAN No. :
AHNPP7136L/Ward-2, Valsad

Patel Gitaben Navnitbhai


Dayabhai Ghelabhai Patel

(02632) 273708

2
3
4

(0260) 2462985
9824141616
9427870258

Page 1 of 1

At & Po. Kalwada, Dist. Valsad


I.T. PAN No. :
ASGPP&031C/Ward-2, Valsad

Area Profile of Vagra sub-district of Bharuch district, Gujarat state


Number of Households

16,767 Average Household Size(per Household)

Population-Total

82,647 Proportion of Urban Population (%)

Population-Rural
Population-Urban
Population(0-6Years)
SC Population

82647 Sex Ratio


0 Sex Ratio(0-6 Year)

5.0
0
913
962

12,813 Sex Ratio (SC)

940

4,459 Sex Ratio (ST)

932

ST Population

21,276 Proportion of SC (%)

5.0

Literates

50,838 Proportion of ST (%)

26.0

Illiterates

31,809 Literacy Rate (%)

73.0

Total Workers

35,269 Work Participation Rate (%)

43.0

Main Worker

28,201 % of Main Workers

34.0

Marginal Worker
Non Worker

7,068 % of Marginal Worker


47,378 % of non Workers

9.0
57.0

CL (Main+Marginal)

8,939 Proportion of CL (%)

25.0

Al (Main+Marginal)

13,801 Proportion of AL (%)

39.0

HHI (Main+Marginal)

328 Proportion of HHI (%)

1.0

OW (Main+Marginal)

12,201 Proportion of OW (%)

35.0

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L,,.rr.:.'.... 11:t !.. \.rt:ir i;!r., .r .r )ti
lirl Ii-r:.,.r*l,er:tt!tl:t li.r \i) i,r.
ir.rr" . r. i . .r,:1i,.,,

s*tss ( ,.tR't rl L t_tt;.

;:,'

Jt\,ts!

.i.tir:0ii
l\j);_.1

P2
(FOR
CAR)

26.5

Lab on FF

48.00

Tank
farm
area

8
Utility

30.0

COMMON
OPEN PLOT

10.00

38.33

20.00

1
2

4
3

20.00

5
6

7
Petroleum
Class A U/g
tankfarm

20.00

18.00

1. HYDROGEN TROLLY
2. HYDROGEN REACTOR
3. RM STORAGE BAGS
4. RM STORAGE DRUMS
5. FG STORAGE DRUMS
6. FG STORAGE BAGS
7. EXPLOSIVE RM STORAGE AREA
8. BOILER, THF, CP, DG, ALL UTILITIES
GREEN BELT AREA

Proposed Plant Layout: M/s. POLYOLS AND POLYMERS


at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India

M/s. POLYOLS & POLYMERS


Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch
List of Raw Material (For proposed New Unit)
Sr No

Product Name

1 (a)

Acrylic resin

Proposed
production
capacity
MT/Month
60

1 (b)

Acrylic Polyols

150

1 (c)

Acrylic emulsion

150

Hydrogenated ketonic
resin

150

Raw materials

Consumption
Kg/kg of
MT/Month
product

Methyl methacrylate
Butyl methacrylate
Acrylic Acid
Poly Vinyl Alcohol
Benzoyl peroxide (Initiator)

0.330
0.460
0.240
0.0003
0.021

19.80
27.60
14.40
0.02
1.26

Toluene
Acrylic monomers
Benzoyl peroxide (Initiator)

0.50
0.49
0.01

75.0
73.5
1.5

Methyl methacrylate
0.396
59.40
Sodium lauryl sulphate
0.008
1.20
Ammonium persulphate
0.001
0.15
Other acrylic monomers which shall be used in product no. 1 (a), (b), (c) as per product spec. are :
Acrylonitrile, Methyl Acrylate, Ethyl Acrylate, Butyl Acrylate, 2 ethyl Hexyl Acrylate, Methoxyethyl
Acrylate, Dimethyl amino Acrylate, Methacrylic Acid, Ethyl methacrylate, Isobutyl methacrylate, 2
ethyl hexyl methacrylate, Lauryl methacrylate, Stearic methacrylate, Di methyl amino methacrylate,
Allyl methacrylate, 2 Hydroxy ethyl Acrylate, 2 Hydroxy Propyl Acrylate, 2 Hydroxy ethyl
methacrylate, 2 Hydroxy Propyl methacrylate, Acryl amide, Methacrylamide, Glycidyl Acrylate,
Styrene

Ketonic Resin

300

Ketonic resin
Butyl acetate /Ethyl
acetate/MEK/IPA/butanol
Hydrogen gas
Raney nickel (catalyst)

0.882
0.021

132.4
3.15

0.098
0.002

14.7
0.30

Cyclohexanone
Optional components :
Methyl Cyclohexanone
Acetophenone
Methyl Ethyl Ketone
MIBK
Formaldehyde (37%) /
Paraformaldehyde
Caustic soda flakes

0.800

240.0

1.200

360.0

0.056

16.8

Page 1 of 3
Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Raw materials list for proposed project

M/s. POLYOLS & POLYMERS


Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch
Sr No

Product Name

Oil based polyester


Polyols (L)

Proposed
production
capacity
MT/Month
1500

Raw materials

Consumption
Kg/kg of
MT/Month
product

Castor oil

0.800

1200.0

Ketonic Resin
0.199
298.5
Di butyl tinoxide
0.001
1.5
Optional raw materials which shall be used in product no. 4 as per product spec. are :Acrylic Polyols, Glycerol,
Trimethylolpropane Propoxylate
5 (a)

5 (b)

6 (a)

Phenol formaldehyde
resin
(a) Phenol
formaldehyde / alkyl
phenol formaldehyde
resin NOVOLACS

750

Phenol formaldehyde
resin (b) alkyl Phenol
formaldehyde resin
resole

300

Polyamide resin
(a) Co solvent grade
polyamide resin

600

Phenol /
Para tertiary butyl phenol/
Nonyl phenol
Formaldehyde (37%) /
paraformaldehyde
Oxalic acid / hydrochloric
acid - catalyst

0.970

727.5

0.672

504.0

0.020

15.0

Para tertiary butyl phenol


Formaldehyde (37%) /
paraformaldehyde
Caustic Soda flakes
Sulphuric acid
Toluene

1.000
0.730

300.0
219.0

0.018
0.030
0.005

5.4
9.0
1.5

Dimer acid /
Fatty acid (Soya fatty acid/
Tall oil fatty acid)
Ethylene Diamine / TETA

0.850
0.134

510.0
80.4

0.107

64.2

6 (b)

Polyamide resin
(b) Alcohol soluble
polyamide resin

600

Dimer acid
Acetic acid
Ethylene Diamine / TETA

0.816
0.146
0.155

489.6
87.6
93.0

6 (c)

Polyamide resin
(c) Reactive poly
amide resin

600

Dimer acid
Soya Fatty Acid
Ethylene Diamine / TETA

0.79
0.154
0.074

474.0
92.4
44.4

Polyester Resins Saturated/ Unsaturated


/ polyester Polyols

300

*Hexanediol
#Adipic Acid
Tri methylolpropane(TMP)/
Glycerol/ Tri
methylolethane(TME)
#Iso Pthalic Acid

0.690
0.425
0.007

207.0
127.5
2.10

0.009

2.70

Page 2 of 3
Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Raw materials list for proposed project

M/s. POLYOLS & POLYMERS


Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch
Sr No

Product Name

Proposed
production
capacity
MT/Month

Raw materials

Consumption
Kg/kg of
MT/Month
product

*Other optional diols :


Ethylene Glycol( EG ), Propylene Glycol ( PG), 1,4Butanediol (BD), 1,5Pentanediol (PD), Di ethylene Glycol
(DEG ), 3 Methyl -1,5pentanediol(MPD), 2,2,4 Trimethyl-1,3 Pentanediol ( TMPD), Tri ethylene glycol (TEG),
Hexyleneglycol (HG), Tri ethylene glycol (TEG), NPG ester,esterdiol, Bisphenol A, Propoxylated Bisphenol A
#Other optional difunctional acids :Maleic Anhydride, Succinic Anhydride, 1,2,3,6 Tetra hydro Pthalic acid anhydride , Fumaric Acid, Succinic
Acid, Di glycolic Acid, Adipic Acid, Pthalic Anhydride, Iso Pthalic Acid, Terepthalic Acid, Azelaic Acid
Sebacic Acid, Trimellitic Anhydride (TMA) ,Citric Acid ,Tri mellitic Acid, Styrene, Xylene\
Other High Functionality Alcohols: Pentaerythritol Sorbitol Di pentaerythritol &
Mono functional acids Benzoic Acid Pelargonic Acid p-Tertiary butyl benzoic Acid
8 (a),9

Rosin Based Resins (a)


Modified Phenolic
Resin &
Turpentine

600

Gum Rosin
Para Tertiary butyl Phenol/
Nonyl phenol
Para Formaldehyde
Pentaerythritol

0.7
0.325

420.0
195.0

0.173
0.135

103.8
81.0

8 (b),9

Rosin Based Resins


(b) Maleic Resin &
Turpentine

600

Gum Rosin
Pentaerythritol
Fumaric Acid

0.8
0.125
0.295

480.0
75.0
177.0

10

Styrene Maleic
Anhydride Resin

300

Styrene
Maleic Anhydride
Toluene

0.45
0.55
0.05

135
165
15

11

Xylene
Formaldehyde Resin

90

Xylene ( L )
Formaldehyde 37% / Para
formaldehyde
Sulphuric Acid
Sodium Carbonate solution

0.800
0.970

72.0
87.3

0.290
0.100

26.1
9.0

Page 3 of 3
Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Raw materials list for proposed project

Project:
Proponent:
Project site:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Documents:

Product-1: (a) Acrylic resins:


Acrylic Resins are formed by addition polymerization reactions.. Unlike condensation
polymerization , addition polymerization leads to high mol weight polymers. There is also no
release of water or other small molecules characteristic of condensation polymers.

Thermoplastic Acrylic Resins


Process:
Reaction:
Process consists of charging DM water in the reactor and dissolving the PVA under stirring.
On completion of the dissolution the contents of the reactor are heated to the desired
temperature. MMA , n-BMA and acrylic acid are slowly added along with the initiator at a
measured rate, taking care not to let the temperature rise beyond a certain required level..
When the required temperature level is reached the reactants are maintained at that
temperature for the required time.
Cooling & Washing:
At the end of the reaction period the contents are cooled and discharged into a neutch filter
and drain the water. The resin is further washed with water to free the resin of any
impurities.
Packing:
The filtered resin is then dried and packed. Filterate is given electrochemical oxidation
treatment followed by Biomass treatment

Chemical reaction:
C5H8O2

C8H14O2

C3H4O2

INITIATOR

C5H8O2
C8H13O2
CH2=CH-COOH

Methyl methacrylate n- butyl methacrylate acrylic acid


Mol. Wt. 100
Mol. Wt. 142
Mol. Wt. 72

Page 1 of 29

acrylic resin
Mol. Wt. 314

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Poly vinyl alcohol 0.300kg
DM water 1000kg

Dissolution
1000.3kg

Methyl Meth Acrylate 330 kg


n- Butyl Meth Acrylate 460 kg
Acrylic acid 240 kg
Benzyl peroxide 21 kg

Heating

2051.3 kg

Cooling
2051.3 kg

Filtration

Filtrate 1021 kg sent to ETP

1030.3 kg
Water 500 kg

Washing

Effluent 500 kg sent to ETP

1030.3kg

Drying

Thermo plastic acrylic resin 1000 kg


INPUT = OUTPUT
2551.3
2551.3

Proposed production capacity

60 MT/month

Freshwater Consumption

90 KL/month

3.0 KL/day

Wastewater generation

91.26 KL/month

3.042 KL/day

Page 2 of 29

Project:
Proponent:
Project site:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Documents:

Product-1: (b) Acrylic polyols


Process:
Reaction:
In this process of manufacture the reactions are taken in a solvent in which the produced resin
is soluble. Solvent (toluene/ MEK/ Butanol). This is an addition polymerization reaction. The
acrylic monomers required along with the initiator are added slowly in the solvent in the
reaction vessel fitted with stirrer system and reflux condenser.
Cooling & Packing:
As this is an exothermic reaction the temperature of the contents of the reactor rises and is
controlled by jacket cooling as and when required When the required temperature is reached,
the reactants are allowed to be maintained for a required time and then cooled and packed in
barrels.

Chemical reaction:

Methyl Methacrylate
Mol. Wt 100

2- OH Ethyl Acrylate
Mol. Wt 116

CH3
H2 C

H
CH2

COOCH3

C
COOCH2CH2OH

Ethyl Hexyl Acrylate


Mol. Wt 200-400

Page 3 of 29

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Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:

Acrylic monomers 490Kg


kg k kg Toluene 500 Kg
Benzyl peroxide 10 Kg

Polymerization
10100
1000kg

Reflux
1000kg

Cooling
1000 kg

Packing in barrels

Acrylic polyols 1000 kg


INPUT = OUTPUT
1000 kg
1000kg
1000kg
Proposed production capacity

150 MT/month

Freshwater Consumption

NIL

Wastewater generation

NIL

Page 4 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product-1: (c): Acrylic Emulsion:


Process: A typical MMA Emulsion Polymers:
Mix 8 Kg sodium lauryl sulphate in 595 Kg DM water is SS reactor fitted with a stirrer,
reflex condenser, thermometer nitrogen inlet tube and two liquid addition inlets. Solution
ammoniums per sulphate in DM water is prepared and of this solution and methyl
methacrylate monomer are added to the flask. The stirrer and nitrogen flow are switched on
and the flask slowly heated to 75C. The emulsion is maintained at 75C for 40 minutes after
the end of the monomer addition to complete the reaction. The non-volatile content is
determined and further initiator added if below theoretical, and the hold is continued for a
further hour.

Chemical reaction:

MW: 100-200

Page 5 of 29

Project:
Proponent:
Project site:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Documents:

Flow sheet:
DM Water 595kg

Polymerization

Sodium lauryl sulphate 8 Kg


kkkgkg
Ammonium
persulphate 1 Kg
kg
Methyl methacrylate 396 kg

10100
1000 kg

Reflux
1000 kg

Cooling
1000 kg

Packing in barrels

Acrylic emulsion 1000 kg


INPUT = OUTPUT
1000 kg
1000kg

Proposed production capacity

150 MT/month

Freshwater Consumption

89.25 KL/month

Wastewater generation

NIL

Page 6 of 29

2.975 KL/day

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product-2 : Hydrogenated Ketonic Resin:


Process:
Reaction:
Process consists of dissolving ketonic resin in the solvent (Butyl acetate/ MEK / ethyl acetate/
IPA/ butanol) and charging the solution along with the catalyst in the Hydrogenation reactor.
Necessary amount of hydrogen is charged in the reactor and the reactor will be under
pressure. Temperature of the reactants is increased to the required level. As the reaction
progresses there will be reduction of the pressure in the reactor indicating consumption of
Hydrogen.
Filtration:
At the end of the reaction the solution of hydrogenated ketonic resin is filtered to recover the
catalyst which shall be used in the next batch. The solution is then distilled in a separate
reaction vessel
Distillation, Cooling & Packing:
The solvent is distilled out and is condensed and is to be used in the next batch. When the
solvent is distilled out, molten resin is left in the reactor which is poured in trays for cooling
and solidification.

Chemical reaction:
O

CH2 OH

KETONIC RESIN

H2
H2
O

H2
O

CH2 OH

n
HYDROGENATED KETONIC RESIN

Page 7 of 29

Project:
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Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Ketonic resin 900 kg
Butyl acetate 400 kg

Dissolution
1300 kg

Hydrogen gas 100 kg


Raney nickel 2 kg

Cooling
1402 kg

Filtration

Spent catalyst 3 kg
(Recovered & reuse in next batch)

1399 kg

Distillation

Butyl acetate 379 kg


(Recovered & reuse in next batch)

1020 kg

Cooling

Hydrogenated ketonic resin 1020 kg


INPUT = OUTPUT
1402
1402

Proposed production capacity

150 MT/month

Freshwater Consumption

NIL

Wastewater generation

NIL

Page 8 of 29

Project:
Proponent:
Project site:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Documents:

Product-3 : Ketonic resin:


Process:
Reaction:
Process consists of charging water, suspension agent, Ketone (e.g. Cyclohexanone ),
Formaldehyde in the reaction kettle fitted with a stirrer system , condenser. Caustic soda
(flaks/lye) is added as a catalyst to start the reaction. It is an exothermic reaction. The temp
rises after addition of the catalyst and is controlled by jacket cooling and is maintained at the
required temp level for required time.
Cooling & washing:
At the end of the reaction the contents of the reactor are cooled and then discharged on a
neutch filter. The resin is then washed with water to free the resin from adhering & catalyst
impurities.
Packing:
Then the resin is dried and packed in bags.

Chemical reaction:
H2
O

H2
O

7 CH2O

CH2OH

CYCLOHEXANONE
(M.Wt. 98)

37 % FORMALDEHYDE
(M.Wt. 30)

KETONIC RESIN STRAIGHT CHAIN


(M.Wt. 600 - 800 Approx )

Page 9 of 29

4H2O

Project:
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Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Cyclohexanone 800 kg
37%Formaldehyde 1200 kg
Caustic soda 56 kg
Water 1400 kg

Reaction

3456kg

Cooling

3456kg

Filtration

ML

Filtration

Effluent 2406 kg
sent to ETP

1030kg

Washing

Water 5000 kg

Resin waste 20 kg
Sent to co processing or incineration
Effluent 5000 kg sent to ETP

1030 kg

Drying & Packing


in bags

Ketonic resin 1000 kg


INPUT = OUTPUT
8456
8456

Proposed production capacity

300 MT/month

Freshwater Consumption

1920 KL/month

64KL/day

Wastewater generation

2221.8KL/month

74.06KL/day

Page 10 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product-4: Oil Based Polyester Polyols:


Natural oil based polyols- castor oil based polyols
Process:
Reaction:
This product is prepared by mixing different polyols e.g Glycerol, Trimethyl prapanol,ketonic
resin polyols or others in castor oil. Castor oil which is a fatty acid containing hydroxyl
groups is taken and mixed with different polyols to impart required properties to the oil based
polyol. This is just a mixing operation and does not involve any reaction.

Chemical reaction:
CH3 (CH2)5 CH (OH) CH2 CH = CH (CH2)7 COOH + HO-R1---(-----OOC-R-COOR1 ---)----OH
CASTOR OIL

POLYESTER RESIN

Mol. Wt 934

Mol. Wt 650

CH3 (CH2)5 CH (OH) CH2 CH = CH (CH2)7 COO


R1---(-----OOC-R-COOR1 ---)----OH

+ H2O

POLYESTER POLYOLS

Mol. Wt 18

1570
Mol. Wt 1584

Flow sheet:
Castor oil 800 kg
Ketonic resin 199 kg
Di butyl tin oxide 1 kg

Mixing

Oil based polyester polyols 1000 kg


INPUT = OUTPUT
1000
1000
Proposed production capacity

1500 MT/month

Freshwater Consumption

NIL

Wastewater generation

NIL

Page 11 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product-5: Phenol Formaldehyde Resins:


(A) Phenol formaldehyde / Alkyl phenol formaldehyde resin NOVOLACS:
Process:
Reaction:
Process consists of charging Formaldehyde (37%) and Phenol in a reactor provided with a
stirrer system and a condenser. After completion of charging the raw materials acid
(catalyst) is added and the contents are heated slightly.
Reflux & cooling:
This is a exothermic reaction and the temperature starts rising slowly. The water in the
formaldehyde gets evaporated and is refluxed . After reaction Reactants are cooled by jacket
cooling.
Distillation:
At the end of the reaction , the condenser is set for distillation and the contents of the reactor
are heated by passing steam in the reactor jacket. The water is evaporated and condensed and
collected in a receiver tank.
Melting, Cooling & Packing:
When the desired melting point of the resin is obtained the molten resin is discharged in
trays. When the molten mass cools down the resin is broken into lumps and packed in
bags.

Chemical reaction:

Page 12 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
37%Formaldehyde 672 kg
Phenol 970 kg
Oxalic acid 20 kg

Reaction
1662 kg

Reflux
1662 kg
Cooling
1662 kg

Distillation

Distillate mainly water 662 kg


sent to ETP

1000 kg

Melting & cooling


1000 kg

Breaking in lumps
& Packing in bags

INPUT = OUTPUT
1662
1662

Phenolic resin 1000 kg

Proposed production capacity

750 MT/month

Freshwater Consumption

NIL

Wastewater generation

496.5KL/month

Page 13 of 29

16.55KL/day

Project:
Proponent:
Project site:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Documents:

(B) Alkyl phenol formaldehyde resin RESOLE :


Process:
Reaction:
Process consists of Charging Formaldehyde in the reactor followed by PTBP (Para tertiary
butyl phenol) and catalyst - caustic soda ( flaks/ lye). After some time the exothermic takes
place and the temperature of the reactants rise.
Cooling & Neutralization:
The temp is maintained within the required temperature range by jacket cooling and the
reactants are then maintained at a particular temp range for the required amount of time and
the resin formed is checked for completion. At the end of the reaction the contents of the
reactor are neutralized by sulphuric acid . Toluene is added to get a solution of the resin and
the contents are allowed to settle.
Layer separation & Distillation:
The water layer is drained and is sent to the ETP. The remaining solution of the resin in
toluene is heated to distill out the toluene in a receiver. This toluene can be used in the
subsequent batches.
Cooling & Packing:
When the toluene is almost stipped the molten resin is poured in trays and allowed to cool.
After cooling and solidification of the resin, it is broken into small lumps and bagged.

Chemical reaction:
H2
OH

NaOH
2 C6H4OHC(CH3)3
PARATERTIARY
BUTYL PHENOL
(M.Wt.150)

CH2O

(CH3)3C

OH
C(CH3)3

FORMALDEHYDE

H2 O

(M.Wt.30)
R
PHENOLIC RESIN
[M.Wt. 312)

Page 14 of 29

M. Wt. 18

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Formaldehyde 730 kg
p- tertiary butyl phenol 1000 kg
NaOH 18 kg

Reaction

1748 kg

Cooling
1748 kg
Sulphuric acid 30 kg
Toluene 100 kg

Neutralization
1878 kg

Layer separation

Aq. Layer 783 kg sent to ETP

1095 kg

Distillation

Toluene 95 kg recovered &


reuse in next batch

1000 kg

Cooling
1000 kg

Breaking of lumps
&Packing in bags

Phenolic resin 1000 kg

Proposed production capacity

300 MT/month

Freshwater Consumption

NIL

Wastewater generation

234.9 KL/month

Page 15 of 29

INPUT = OUTPUT
1878
1878

7.83 KL/day

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product-6 : Polyamide Resins


Process:
Esterification:
Basically this is a Esterification reaction between a dimer acid and di-amine resulting in the
formation of a polyester and water of reaction Process consists of charging all the raw
materials in a stirred reaction vessel fitted with a condenser.
Heating & Distillation:
The contents of the reaction vessel is heated and after about couple of hours the acid value
and the amine values are checked at periodic intervals till the required acid value and amine
value is achieved. The water of reaction is distilled at the high reaction temperature and
condensed in the condenser. The distillate consists mainly of water and traces of impurities
which is sent to ETP
Cooling & Packing:
The molten resin is poured in trays and allowed to cool. After cooling and solidification of
the resin, it is broken into lumps and packed in bags.

Chemical reaction:
HOOC-R-COOH + CH3-COOH + C2H4(NH2)2

Dimer acid

acetic acid

M.Wt.: 560

M.Wt: 60

HOOC-R-CONHR1-NH2 +H2O

ethylene diamine
M.Wt: 60

Where R & R1 are aliphatic hydrocarbons

Page 16 of 29

polyamide resin Water


M. Wt : 662

M. Wt : 18

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

(a) Flow sheet for co solvent grade polyamide resins:


Dimer acid 850 kg
Fatty acid 134 kg
Ethylene diamine/ Tri ethylene
tetra amine 107 kg

Reaction
1091 kg

Heating
1091 kg
Cooling
1091 kg

Distillation

Distillate mainly water 91kg


sent to ETP

1000 kg

Cooling
1000 kg

Breaking of lumps
& Packing in bags

Co solvent grade polyamide resin 1000 kg


INPUT = OUTPUT
1091
1091

Proposed production capacity

600 MT/month (max.)

Freshwater Consumption

NIL

Wastewater generation

54.6 KL/month

Page 17 of 29

1.82 KL/day

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

(b) Flow sheet for Alcohol soluble polyamide resins:

Dimer acid 816 kg


Acetic acid 146 kg
Ethylene diamine/ Tri ethylene
tetra amine 155 kg

Reaction
1117 kg

Heating
1117kg
Cooling
1117kg

Distillation

Distillate mainly water 117kg


sent to ETP

1000 kg

Cooling
1000 kg

Breaking of lumps
& Packing in bags

Alcohol soluble Polyamide resin 1000 kg

INPUT = OUTPUT
1117
1117
Proposed production capacity

600 MT/month (max.)

Freshwater Consumption

NIL

Wastewater generation

70.2 KL/month

Page 18 of 29

2.34 KL/day

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

(c) Flow sheet for reactive polyamide resins:

Dimer acid 790 kg


Soya fatty acid 154 kg
Ethylene diamine/ Tri ethylene
tetra amine 74kg

Reaction
1000 kg

Heating
1000 kg
Distillation

Distillate mainly water 18kg


sent to ETP

1000 kg

Packing in barrels
INPUT = OUTPUT
1018
1018

Reactive Polyamide resin 1000 kg

Proposed production capacity

600 MT/month (max.)

Freshwater Consumption

NIL

Wastewater generation

10.8 KL/month

Page 19 of 29

0.36 KL/day

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product- 7: Polyester resin saturated / unsaturated / polyester polyols:


Process:
Basically this is a Esterification reaction between a di acid and diol resulting in the formation
of a polyester and water of reaction
Reaction:
Process consists of charging all the raw materials in a stirred reaction vessel fitted with a
condenser. The contents of the reaction vessel is heated and after about couple of hours the
acid value is checked at periodic intervals till the required acid value is achieved.
Distillation:
The water of reaction is distilled at the high reaction temperature and condensed in the
condenser. The distillate consists mainly of water and traces of impurities which is sent to
ETP & reaming in product is packed in barrels.

Chemical reaction:

Page 20 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Adipic acid 425 kg
Hexane diol 690 kg
Tri methylol propane 7 kg
Isophthalic acid 9 kg

Esterification

1131 kg

Heating
1131 kg
Distillation

Distillate mainly water 131 kg


Sent to ETP

1000 kg

Packing in barrels
INPUT = OUTPUT
1131
1131

Polyester polyols 1000 kg


Proposed production capacity

300 MT/month

Freshwater Consumption

NIL

Wastewater generation

39.3 KL/month

Page 21 of 29

1.31 KL/day

Project:
Proponent:
Project site:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Documents:

Product-8 : Rosin based Resins & Product no. 9: Turpentine:


(A) Modified Phenolic Resin:
Process:
Rosin based resins are made by basically Esterification process wherein the yield is 90%. The
distillate is around 10 % which consists of distilled terpene oil and reaction water. This
effluent (distillate) consists of 80% Turpentine is recovered in turpentine recovering system
and 20% Effluent is sent to bio treatment plant for treatment.

Chemical reaction:
CH2OH CH2OH

ADDITION
REACTION
R-COOH

M.wt: 323

R-OH

M. Wt: 150

HCHO

-OH Ph - CH2 Ph O ADDUCT

M.Wt: 30

R-COOH

ESTERIFICATION WITH PENTAERYTHRYTOL


REDUCTION
C5H12 O4 - R1 (OH)4
R1 = C5H8

C
R1OOC

CH2 - Ph - CH2OH

[ O - Ph - CH2 -

Ph

+ 2H2O

CH2OH
MODIFIED PHENOLIC RESIN
M.Wt: 467

Water
M.Wt : 18

R-COOH -Rosin (Lavopemeric acid)


R-OH - Alkyl phenol (alkyl phenol can be para tertiary butyl phenol, nonyl phenol
etchere it is PTBP )
HCHO - Formaldehyde

Page 22 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Pentaerythritol 135 kg
Gam rosin 700 kg
para tertiary butyl phenol 325 kg
p- Formaldehyde 173 kg

Reaction

1333 kg

Condensation

Heating
Layer
separation

1000 kg

Cooling

Turpentine 67 kg

Effluent 266kg sent to ETP

1000 kg

Packing
INPUT = OUTPUT
1333
1333

Modified phenolic resin 1000 kg

Modified phenolic resin proposed production


capacity
Turpentine Proposed production capacity

600 MT/month
40.2MT/month

Freshwater Consumption

NIL

Wastewater generation

159.6KL/month

Page 23 of 29

5.32 KL/day

Project:
Proponent:
Project site:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Documents:

(B) Maleic Resin:


Chemical reaction:
O
R-COOH

CH - C -

OH

CH - C -

OH

REACTION AT
ELEVATED
TEMPERATURE

O
R-

CH - C

M.Wt : 323

CH - C

ADDUCT OF LAEVOPIMARIC ACID


AND FUMARIC ACID

M.Wt : 125

ESTERIFICATION WITH PENTAERYTHRYTOL


REDUCTION
C 5H12 O4 - R1 (OH)4
R1 = C 5H8

FUMERIC ACID

M.Wt : 136
CH3

COOH

O
R1OOC - R-

CH - C

CH3
CH3

CH - C

R = ABIETIC ACID
CH3

Page 24 of 29

H2 O

M.Wt : 430
Maleic resin

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Pentaerythritol 125 kg
Gum rosin 800 kg
Fumaric acid 295 kg

Reaction

1220 kg

Condensation

Heating
Layer
separation

1000 kg

Turpentine 44 kg

Cooling
Effluent 176kg sent to ETP
1000 kg

Packing
INPUT = OUTPUT
1220
1220

Maleic resin 1000 kg

Maleic resin proposed production capacity

600 MT/month

Turpentine Proposed production capacity

26.4 MT/month

Freshwater Consumption

NIL

Wastewater generation

105.6KL/month 3.52 KL/day

Page 25 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product-9: styrene Maleic Anhydride Resins:


Process:
Reaction:
Process consists of charging requisite quantities of toluene, styrene, and maleic anhydride
along with initiator in the reaction vessel fitted with a stirrer system and reflux condenser.
The contents are stirred till a homogenous solution is achieved.
Heating & Cooling:
The mixture is then heated to the required temperature and stirred for a required time to
complete the reaction. At the end of the reaction the contents are cooled to room temp and the
SMA co polymer is precipitated.
Filtration, Drying & Packing:
The copolymer is filtered, dried and is then packed. The filtered toluenes along with the
residual monomers are reused in the next batch and necessary adjustments are made for the
maleic anhydride and styrene present in the toluene.

Chemical reaction:

ADDITION
POLYMERISATION

STYRENE
Mol. Wt 104

MALEIC ANHYDRIDE
Mol. Wt 98

SMA RESIN
Mol. Wt 200-400

Page 26 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:
Styrene 500 kg
Maleic anhydride 550 kg
Toluene 1000 kg

Reaction

2050 kg

Reflux
2050 kg

Heating
2050 kg

Cooling
2050kg

Filtration
1050 kg

Filtrate contain toluene 950 kg


& 50kg unreacted styrene
recovered & reuse in next batch

Drying

SMA resin 1000 kg


INPUT = OUTPUT
2050
2050

Proposed production capacity

300 MT/month

Freshwater Consumption

NIL

Wastewater generation

NIL

Page 27 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Product-10: Xylene- Formaldehyde Resins:


Process:
Reaction:
In the basic process xylene as a solvent is added, followed by the calculated amount of
aqueous formaldehyde solution. Than sulfuric acid is added directly into the lower aqueous
phase under smooth agitation. The reaction temperature of the slightly exothermic process is
around 100C. Therefore the quality of formalin solution is important (concentration, amount
of methanol). The reaction is carried out under reflux for min. 6h. The reaction temperature is
in that time increasing up to 105C while the formaldehyde get consumed and reacted with
Xylene.
Layer Separation & Neutralization:
After that the aqueous phase is going to be separated, neutralized and disposed. The organic
phase has to be neutralized after that with aqueous sodium carbonate solution followed by a
phase separation again.
Packing:
Organic solution is a product & Packing in barrels.

Chemical reaction:
H2SO4

Xylene + formaldehyde

Reflux 7hrs

Xylene formaldehyde

CH3-C6H4-CH3 + HCHO

C9H12O

Mol. Wt 106

mol. Wt 136

mol. Wt 30

Page 28 of 29

Project:
Proponent:
Project site:
Documents:

Proposed new manufacturing unit for synthetic organic products


M/s. Polyols & Polymers
Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate
Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India
Manufacturing Process for proposed project

Flow sheet:

Sulphuric acid 290 kg


Xylene 800kg
Formaldehyde (37%) 970 kg

Reaction
2060 kg

Layer separation
1020kg

Neutralization

Sodium carbonate sol.100 kg

Sodium carbonate sol.100 kg


Neutralization
Aqueous layer 1140kg
Sent to ETP

1120kg

Layer separation

Aqueous layer 120 kg


Sent to ETP

Packing
1000kg
Xylene- Formaldehyde resin 1000 kg

INPUT = OUTPUT
2260
2260
Proposed production capacity

90 MT/month

Freshwater Consumption

NIL

Wastewater generation

113.4 KL/month, 3.78 KL/day

Page 29 of 29

Sr.No

Chemical Name

CAS No.

Type of
Hazard

Hazards

Health Fire

Toxicological
information
Reacti ERPG,ppm
vity

LD50
(LC50)
ppm

Flash Point

degC

BP

Sp
LEL
Gravity

degC

UEL

Solubility With Incompeteble Material


Water

NFPA

Hazardous
Combustion Products
R

reactive with oxidicing


insoluble in cold agent and reducing
and hot water agent ,acids ,alkali. And
with moisture.

Carbon Dioxide
Carbon Monoxide

Butyl Methacrylate

97-88-1

Flammable /
Toxic

Butyl Acetate

123-86-4

Flammable

Yes

yes

No

10768

23.9

126.5

0.9

1.7

7.6

Partially soluble
in cold water

Not Available

Carbon Dioxide
Carbon Monoxide

Ethyl Acetate

140-78-6

Flammable

Yes

yes

No

5620
(LC50
45000)

open cup 7.2 close


cup -4.4

77

0.902

2.2

Soluble in cold
and hot water

Reactiv with oxidising


agents, acid and alkali

Carbon Dioxide
Carbon Monoxide

Formaldehyde 37%

50-00-0

Flammable

Yes

yes

No

100

open cup 60 close


cup 50

98

1.08

36.5

Easily Soluble in reactive with oxidicing


hot and cold
agent and reducing
water
agent ,acids ,alkali.

Carbon Dioxide
Carbon Monoxide

Phenol

108-95-2

Flammable

Yes

yes

No

270

open cup 85 close


cup 79

182

1.057

1.7

8.6

Soluble in cold
water

reactive with oxidicing


agent, metals, acids
,alkali.

Carbon Dioxide
Carbon Monoxide

Not Available

Carbon Dioxide
Carbon Monoxide

Yes

yes

yes

16000

52.2

160

0.894

Sulphuric Acid

7664-93-9

Non
Flammable

Yes

No

yes

2140

Not Applicable

270

1.84

NA

NA

reactive with oxidicing


agent, Reducing
Easily Soluble in agents, Cumbustible
cold water
material, Organic
material, metals, acids
,alkali, moisture.

Styrene

100-42-5

Flammable

Yes

yes

yes

2650

open cup 36.7


close cup 31.1

145.2

0.906

1.1

6.1

Very slightly
Soluble in cold
water

Xylene

1330-20-7

Flammable

Yes

yes

No

4300

open cup 37.8


close cup 24

138.5

0.864

insoluble in cold Reactive with oxidicing


and hot water
agent, acids .

Carbon Dioxide
Carbon Monoxide

Acetic Acid

64-19-7

Flammable

Yes

yes

No

3310

open cup 43 close


cup 39

118.1

1.049

19.9

Easily Soluble in Reactive with oxidicing


Hot and cold
agent, metals, acids
water
,alkali.

Carbon Dioxide
Carbon Monoxide

Easily Soluble in
cold water

10

Ethylne Diamine

107-15-3

Flammable

Yes

yes

No

500

34

117.2

0.9

4.2

11

Cyclohexanone

108-94-1

Flammable

Yes

yes

No

1516

open cup 46 close


cup 43.889

155.6

0.948

1.1

9.4

12

Toluene

108-88-3

Flammable

Yes

yes

No

636

open cup 16 close


cup 4.4444

110.6

0.864

1.1

7.1

Not Available

Not Available

Partially Soluble
Reactive with oxidicing
in Hot and cold
agent, acids ,alkali.
water
Practically
insoluble in
water

Reactive with oxidicing


agent.

Carbon Dioxide and


nitrogen oxides
NO,NO2
Carbon Monoxide

Carbon Dioxide
Carbon Monoxide

Carbon Dioxide
Carbon Monoxide

Sr.No

Chemical Name

CAS No.

Type of
Hazard

Hazards

Health Fire

13

Hydrogen Gas

Toxicological
information
Reacti ERPG,ppm
vity

LD50
(LC50)
ppm

degC

BP

Sp
LEL
Gravity

degC

Yes

Yes

No

STEL 10

333

77

0.806

3.1

No

-252.8

UEL

Solubility With Incompeteble Material


Water

Extreamly
Flammable

yes

No Information
Available

1333-74-0

No

Not
Available

Flash Point

14

Acrylonitrile

1017-13-1

Flammable /
Toxic

15

Methyl Ethyl
Ketone(MEK)

78-93-3

Flammable/To
xic

Yes

Yes

No

STEL:300ppm

6480

-9

79.6

0.805

1.8

16

IPA (Isopropyl
Alcohol)

67-63-0

Flammable

Yes

Yes

No

NA

NA

11.67

82.5

0.785

NFPA

Hazardous
Combustion Products
R

Reactive with oxidicing


agent.

Not Available

17

Very slightly
incompatible with
soluble in cold
oxidizing agents, such
water, hot
as metals, acids, alkalis
water

Carbon Dioxide
Carbon Monoxide

10

Soluble in cold
water

Reactive with oxidizing


agents, metals, acids,
alkalis.

Carbon Oxides
( CO2,CO)

Easily soluble in
Reactive with oxidizing
12.7 cold water, hot
agents, acids, alkalis.
water,

Carbon Oxides
( CO2,CO)

Carbon Oxides
( CO2,CO)

75

soluble in water

17

Ethyl Acrylate

140-88-5

Flammable/To
xic

Yes

yes

yes

TWA 25ppm

(1414)

99.4

0.923

1.4

13

The product may


undergo hazardous
decomposition,
Partially soluble
condensation or
in cold water polymerization, it may
react violently with
water to emit
toxic gases

18

Methyl
Methacrylate

80-62-6

Flammable/To
xic

Yes

yes

yes

TWA 100 ppm

7872mg/
kg

19

100

0.936

2.1

12.5

Partially soluble Reactive with metals,


in cold water
acids, alkalis

Carbon Oxides
( CO2,CO)

Carbon Oxides
( CO2,CO)

Carbon Oxides
( CO2,CO)

19

Butanol

71-36-3

Flammable

Yes

yes

no

NA

NA

36.1

117.7

0.81

1.4

Easily soluble in
Highly reactive with
methanol,
oxidizing agents,
diethyl ether.
reducing agents.
11.2 Partially soluble
Slightly reactive to
in cold water,
reactive with organic
hot water, nmaterials, acids, alkalis
octanol

20

MIBK

108-10-1

Flammble

No

yes

No

NA

NA

14

115.9

0.8

1.4

7.5

Imiscible

Avoid oxidizing &


reducing agents

Rapid EIA for Proposed Synthetic Organic Chemicals Manufacturing unit


at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch
Sr. No. Full name of the raw
material

State i.e,
solid /
Liquid /
Gas

Inventory

Details of Hazardous Chemicals Inventory, hazardous properties

Equipment consider No. of container


MAH
& Size at site
threshold
qty.MT
No. of
days
3

No.

MT

Storage Parameters

B.P.C, M.P.C

Fl. P.C

LD50 mg/Kg or
LC50 mg/l

Vapour
pressure

1.5 kPa@
20C
0.5 kPa@
20C
NA
11.1 kPa@
20C
NA
NA

Source

Acetic acid

Consumption
MT/Month
87.6

Al or SS Tank - AGT

10

Pressure
kg/cm2
Atm.

30-40C

BP 118.1C MP 16.6C

39

Acrylic Acid

14.4

Drum

0.2

Atm.

30-40C

BP 141 C MP 14C

50

3
4

Acryl amide
acrylonitrile

S
L

73.5
73.5

5
8

1 MT Jumbo bag
CS Tank - AGT

15
1

15
20

Atm.
Atm.

30-40C
30-40C

BP 125 C MP 84.5C
BP 77.3C MP -82C

138
-1.11

5
6

Benzoyl peroxide
Bisphenol-A

S
S

2.76
207

5
3

50 kg bag
1 MT Jumbo bag

10
20

0.5
20

Atm.
Atm.

30-40C
30-40C

BP 103C MP-104.5C
BP 220C MP 158-159C

NA
227

Butanol

3.15

95

10

Atm.

30-40C

BP 117.7C MP -89.5

28.9

Butyl acetate

3.15

95

CS or SS Tank AGT
CS or SS Tank AGT

LD50- 3310 mg/kg LC505620 mg/l-1h


LD50-33500 mg/kg LC505300 mg/l- 2h
LD50- 124 mg/kg
LD50- 78 mg/kg
LC50333 mg/l-4h
LD507710 mg/kg
LD50- 2000-5000 mg/kg
LC50- 170 mg/l-6h
LD50- 790 mg/kg

10

Atm.

30-40C

BP 126.5, MP -77.9

23.9

LD50- 10768 mg/kg

9
10

butyl acrylate
Butyl methacrylate

L
L

73.5
27.6

8
22

Drum
Drum

100
100

20
20

Atm.
Atm.

30-40C
30-40C

BP 145C MP -64.6C
BP 160C MP -75C

29
52.2

LD50- 900 mg/kg


LC50- 2730
mg/l-4h
LD50-16000
mg/kg

10
11

Caustic soda flakes


Cyclohexanone

S
L

22
240

68
5

50
2

50
40

Atm.
Atm.

30-40C
30-40C

BP 1388C MP 323C
BP 155.6C MP -31C

NA
43.89

12
13

Di butyl tinoxide
Ethyl acetate

S
L

1.5
3.15

4
19

Jambo Bag
CS or SS Tank AGT
Drum
Drum

1
10

0.2
2

Atm.
Atm.

30-40C
30-40C

MP >300C
BP 77C, MP -83C

NA
-4.4

14

ethyl acrylate

73.5

20

Atm.

30-40C

BP 99.4C MP -72C

-2

15

Ethyl methacrylate

73.5

CS or SS Tank AGT
Drum

100

20

Atm.

30-40C

BP 118-119C MP -60C

19

16

Ethylene Diamine

93

Drum

50

10

Atm.

30-40C

BP 117.2C MP 8.5C

34

17

ethylene glycol

207

Drum

100

20

Atm.

30-40C

BP 197.6C MP -13C

111

18

Formaldehyde (37%)

1083

100

Atm.

30-40C

BP 98C MP -15C

50

19
20

Hydrogen gas
Iso Propyl Alcohol

G
L

14.7
3.15

10
190

30
1

5
20

150-200
Atm.

30-40C
30-40C

BP -252.8C MP -259C
BP 82.5C MP -88.5C

NA
11.7

21

methacrylic acid

73.5

CS or SS Tank AGT
Cylinder
CS or SS Tank AGT
Drum

100

20

Atm.

30-40C

BP 163C MP 16C

77

22
23

methyl acrylate
methyl cyclohexanone

L
L

73.5
240

8
3

Drum
Drum

100
100

20
20

Atm.
Atm.

30-40C
30-40C

BP 80.5C MP -76.5C
BP 162-163C MP -13.9C

-3.89
48

24

Methyl Ethyl Ketone

240

CS Tank - AGT

10

Atm.

30-40C

BP 79.6C, MP -86C

-9

25

methyl isobutyl ketone

240

CS Tank - AGT

20

Atm.

30-40C

BP 115.9C MP -84C

14

26

Methyl methacrylate

79.2

20

Atm.

30-40C

BP 100C MP -48C

13

27

Paraformaldehyde

1083

CS or SS Tank AGT
Jambo Bag

50

50

Atm.

30-40C

MP 120-170 C

70

28

Phenol

727.5

CS Tank - AGT

40

Atm.

30-40C

BP 182C, MP 42C

79

0.5 kPa@ indigenous


0.720C
kPa@ indigenous
20C
NA
NA
indigenous
LD50- 1516 mg/kg
0.7 kPa @ imported / indigenous
26.7C
oral-LD50-44.9 mg/kg
NA
indigenous
LD50- 5620 mg/kg, LC50- 12.4 kPa@ indigenous
16000 mg/l -6h
20C
LD50- 800 mg/kg
29 mm Hg indigenous
LC50- 1414 mg/l-4h
@ 20C
LD50- 13424 mg/kg
20hPa @ indigenous
LC50- 8300 ppm-4h
20C
LD50- 500 mg/kg, LC50- 10.7 mm Hg indigenous
424.3 mg/l-4h
@ 20C
LD50- 4700 mg/kg
6 mm Hg @ indigenous
LC50- 200 mg/m-4h
20C
LD50-100 mg/kg, LC50- 2.4 @ 20C indigenous
64000 mg/l -4h
NA
NA
indigenous
LD50- 5045 mg/kg
4.4 kPa@ indigenous
20C
LD50- 1250 mg/kg
0.975 mm indigenous
Hg @ 20C
LD50- 277 mg/kg
NA
indigenous
LD50- 1980 mg/kg
1hPa @ imported / indigenous
20C
LD50-2737 mg/kg, LC50- 10.3 kPa@ imported / indigenous
23500 mg/m -8h
20C
LD50- 1600 mg/kg
15.7 mm Hg imported / indigenous
LC50- 8000 mg/l-4h
@ 20C
LD50-7872 mg/Kg LC50- 29 mm Hg indigenous
5303.3 mg/l-4h
@ 20C
LD50-800 mg/kg, LC50NA
imported / indigenous
1070 mg/m-4h
LD 50-dermal- 630 mg/kg
NA
imported

29
30

Poly Vinyl Alcohol


propylene glycol

S
L

0.02
207

750
3

50 kg bag
Drum

10
100

0.5
20

Atm.
Atm.

30-40C
30-40C

MP 200C
BP 188C MP -59C

79
99

LD50->20000 mg/kg
LD50- 20000mg/kg

31

Styrene

336

CS Tank - AGT

40

cool

15-21C

BP 145.2C MP -30.6C

31.1

32

Sulphuric acid

35.1

CS Tank - AGT

10

Atm.

30-40C

BP 270-340C, MP -35C

NA

33

Toluene

91.5

13

CS Tank -UGT

40

Atm.

30-40C

BP 110.6C, MP -95C

4.44

34

Xylene

199.5

CS Tank -UGT

20

Atm.

30-40C

BP 138.5C MP -47.4C

24

35

Terpentine-Product
AGT - Aboveground Tank

67

CS Tank -AGT
1
UGT - Underground tank

20

20

Temp C

Polyols Polymers

Atm.
30-40C
HF - Highly flammable

BP 165C

LD50-2650 mg/kg,
LC50-12000 mg/l-4h
LD50- 2140 mg/kg,
LC50-510mg/m -2h
LD50-636 mg/kg, LC5049000 mg/m-4h
LD50- 4300 mg/kg

35
LD50- 5760 mg/kg
VHF - Very Highly flammable

indigenous

Sch-1,part-I(b)-HF & Part-II

indigenous

Sch-1,part-I(a)-Toxic & Part-II

indigenous
indigenous

Sch-1,part-I(a)-Toxic & Part-II


Sch-1,part-I(b)-VHF

indigenous
indigenous

Sc-I, part-II
Sc-I, part-II

0.6 kPa@ indigenous


20C
1.3 kPa@ indigenous
20C

NA
0 kPa@
20C
4.5 mm Hg
@ 20C
NA

As per Haz. Chemicals rules,2000

Sch-1,part-I(b)-HF
Sch-1,part-I(b)-HF
Sch-1,part-I(b)-HF
Sch-1,part-I(b)-HF
Sc-I, part-II
Sch-1,part-I(b)-HF
Sch-1,part-I(a)-highly Toxic
Sch-1,part-I(b)-VHF, Sc-I, part-II
Sch-1,part-I(b)-VHF
Sc-I,part-I(b)-VHFpart-II
Sch-1,part-I(b)-HF, Sc-I, part-II
Sc-I, part-II
Sch-1,part-I(b)-HF, Sc-I, part-II
Sc-I, part-II
Sc-I, part-II
Sch-1,part-I(b)-F
Sch-1,part-I(b)-VHF
Sch-1,part-I(b)-HF
Sch-1,part-I(b)-VHF
Sch-1,part-I(b)-VHF
Sch-1,part-I(b)-VHF, Sc-I, part-II
Sch-1,part-I(b)-F

indigenous
indigenous

Sch-1,part-I(a)- Toxic, Sch-1,part-I(b)-F,


Sc-I, part-II
Sch-1,part-I(b)-F
Sc-I, part-II

imported/ indigenous

Sch-1,part-I(b)-HF, Sc-I, part-II

indigenous

Corrosive,Sc-I, part-II

3.8 kPa @ indigenous


25C
0.9 kPa@ indigenous
20C
-

Sch-1,part-I(b)-VHF, Sc-I, part-II


Sch-1,part-I(b)-HF, Sc-I, part-II
-

EIA & EMP and Risk Assessment & DMP report


For proposed unit of Polyols & Polymer.
at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate,
Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India
SAMPLING AND ANALYTICAL METHODS ADOPTED
FLOW CHART FOR MEASUREMENT OF SULPHUR DIOXIDE
Place 30 ml of absorbing media in an impinge
Connect it to the gas-sampling manifold of gas sampling device
(RDS/HVS).
Draw air at a sampling rate of 1 lpm for four hours
Check the volume of sample at the end of sampling and record it
Transfer the exposed samples in storage bottle and preserve
Prepare calibration graph as recommended in method
Take 10/20 ml. aliquot of sample in 25 ml. Vol. Flask
Take 10/20 ml. of unexposed sample in 25 ml. Vol. Flask (blank)
Add 1 ml Sulphamic acid. Keep it 10 minutes
Add 2 ml formaldehyde
Add 2 ml working PRA
Make up to mark (25 ml.) with distilled water.
Keep it 30 minutes for reaction
Set Zero of spectrophotometer with Distilled water
Measure absorbance at 560 nm
Calculate concentration using calibration graph
Calculate concentration of Sulphur Dioxide in g/m3
FLOW CHART FOR MEASUREMENT OF NITROGEN DIOXIDE
Place 30 ml of absorbing media in an impinge
Connect it to the gas sampling manifold of gas sampling device
(RDS/HVS).
Draw air at a sampling rate of 1 lpm for four hours
Check the volume of sample at the end of sampling and record it
Transfer the exposed samples in storage bottle and preserve
Prepare calibration graph as recommended in method
Take 10 ml. aliquot of sample in 50 ml. Vol. Flask
Page 1 of 7

EIA & EMP and Risk Assessment & DMP report


For proposed unit of Polyols & Polymer.
at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate,
Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India
SAMPLING AND ANALYTICAL METHODS ADOPTED

Take 10 ml. of unexposed sample in 50 ml. Vol. Flask (blank)


Add 1 ml hydrogen peroxide,
Add 10 ml sulphanilamide
Add 1.4 ml NEDA
Make up to mark (50 ml.) with distilled water.
Keep it 10 minutes for reaction
Set Zero of spectrophotometer with Distilled water
Measure absorbance at 540 nm
Calculate concentration using calibration graph
Calculate concentration of Nitrogen Dioxide in g/m3
FLOW CHART FOR MEASUREMENT OF PM10
Check the filter for any physical damages
Mark identification number on the filter
Condition the filter in conditioning room / desiccator for 24 hours
Record initial weight
Place the filter on the sampler
Run the sampler for eight hours
Record the flow rate on hourly basis
Remove the filter from the sampler
Keep the exposed filter in a proper container
Record the total time of sampling & average flow rate
Again condition the filter in conditioning room / desiccator for 24 hours
Record final weight
Calculate the concentration of PM10 in g/m3

Page 2 of 7

EIA & EMP and Risk Assessment & DMP report


For proposed unit of Polyols & Polymer.
at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate,
Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India
SAMPLING AND ANALYTICAL METHODS ADOPTED

FLOW CHART FOR MEASUREMENT OF PM2.5


Check the filter for any physical damages
Mark identification number on the filter
Condition the filter in conditioning room / desiccator for 24 hours
Record initial weight
Place the filter on the sampler
Run the sampler for eight hours
Record the flow rate on hourly basis
Remove the filter from the sampler
Keep the exposed filter in a proper container
Record the total time of sampling & average flow rate
Again condition the filter in conditioning room / desiccator for 24 hours
Record final weight
Calculate the concentration of PM2.5 in g/m3

FLOW CHART FOR MEASUREMENT OF BENZO(A)PYRENE


EPM 2000 filter paper
Ultrasonic extraction with Toluene (50 ml 3 times)
Filter & dry with Anhydrous Sodium Sulphate
Concentration with Rotary Evaporator
Clean up with Silica Gel Column Chromatography
Elution with Cyclo-Hexane (5 ml 3 times)
Evaporate to nearly dryness under Nitrogen
Re-dissolved in 0.5 to 1.0 ml Toluene

Re-dissolved in 2.5 ml Methanol

Capillary GC-FID or GC-MS

HPLC/UV-Fluorescence Detector

Page 3 of 7

EIA & EMP and Risk Assessment & DMP report


For proposed unit of Polyols & Polymer.
at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate,
Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India
SAMPLING AND ANALYTICAL METHODS ADOPTED
Analysis of Ground water and surface waters
Sr. No. Test
1
TemperatureC
2
Colour Pt Co Colour units
3
Odour
4
Turbidity
5
Total Solids
6
Total Dissolved Solids
7
Total Suspended Solids
8
Dissolved Oxygen
9
Biochemical Oxygen Demand

Test Method
APHA 21st ed. 2550B
APHA 21st ed. 2120B Visual Comparison
APHA 21st ed. 2150B Thresold odour
IS 3025 (Part 10) 1984 reaffirmed 2002 Nephlometric
A PHA 21st ed. 2540 B TS dried at 103-105c
APHA 21st ed. 2540C TDS dried at 180 c
APHA 21st ed. 2540D TSS dried at 103-105 c
IS 3025 (part 38) : 1989 reaffirmed Azide Modification
3-days BOD test(IS 10-1000mg/l
3025(part44)1993 Reaffirmed 1999)
IS method Open Reflux
IS:3025 (Part-11)-1983
IS -3025-Part 26-1986)
IS -3025-Part 22-1986)
APHA 21st ed. 4500 NH3 C Titration
APHA 21st ed. 4500-N org B Macro-kjedhal method
IS 3025 (Part 34) : 1988 Devadas alloy reduction
APHA 21st ed. 4500C vanadomolybdophosphoric acid
APHA 21st ed. 4500E Turbidimetric
APHA 21st ed. 4500B Argentometric
APHA 21st ed. 4500B Iodometric
APHA 21st ed. 4500C Molybdo silicate
APHA 21st ed. 3500-Ca B EDTA Titrametric
APHA 21st ed. 3500-Mg B calculation method
APHA 21st ed. 2340C EDTA Titrimetric
APHA 21st ed. 3500-Na B Flame Emission Photometric
APHA 21st ed. 3500-K BFlame Emission Photometric
IS 3025 (part 53) 2003 Phenanthroline method
APHA 21st ed. 4500S2- F Iodometric method
APHA 21st ed. 4500F-D SPADNS method
APHA 21st ed. 3500-Mn AAS
APHA 21st ed. 3500 pb AAS
APHA 21st ed. 3500 Zn- AAS
APHA 21st ed. 3500 Cr- AAS
APHA 21st ed. 3500 Cr-B - colorimetric
APHA 21st ed. 3500 Cu-B-Neocuproine Method
APHA 21st ed. 3500 As-AAS
APHA 21st ed. 3500 Hg-cold vapour AAS
APHA 21st ed. 3500 Cd-AAS
APHA 21st ed. 3500 Ni-AAS
IS 3025 (Part 39) : 1991 liq-liq Partition Gravimetric
APHA 21st ed. 5530 D Direct photometric

10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42

Chemical Oxygen Demand


PH Value
Alkalinity
Acidity
Ammonical Nitrogen
Total Kjedhal Nitrogen
Nitrates
Phosphates
Sulphates
Chlorides
Residual Chlorine
Silica
Calcium
Magnesium
Hardness
Sodium
Potassium
Iron
Sulphide
Flourides
Manganese (as Mn)
Lead (as Pb)
Zinc(as Zn)
Chromium(as Cr)
Hexavalent Chromium(as Cr+6)
Copper(as Cu)
Arsenic( as As)
Mercury (as Hg)
Cadmium(as Cd)
Nickel
Oil & Grease
Phenolic Compounds
Microbiological Analysis
(Total bacterial count, MPN/100ml , E.coli, APHA 21st ed. 9000 Microbiological Examination
Coliform,)

43

Biological analysis (Benthos and plankton)

APHA 21st ed. 9000 Microbiological Examination

Page 4 of 7

EIA & EMP and Risk Assessment & DMP report


For proposed unit of Polyols & Polymer.
at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate,
Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India
SAMPLING AND ANALYTICAL METHODS ADOPTED
METHOD EMPLOYED FOR FLORAL DOCUMENTATION:
A road survey in all the accessible areas and in addition on foot surveys were conducted to document the flora. The
local floral was identified by visual cues, such as its size and shape, morphology of the leaf and stem, phenology,
flowering and fruiting status and with all these characters the flora was classified broadly into five categories Trees,
Shrubs, Herbs, Climber and Aquatic Plants or Hydrophytes. The plants that were not identified were collected,
brought to the laboratory and identified using standard herbarium references. Photo documentation of some of the
key species present in the study area was also done.
METHODS EMPLOYED FOR FAUNAL DOCUMENTATION:
Terrestrial Fauna:
The major terrestrial fauna in the area consisted of higher invertebrates and vertebrates. These groups were
identified and mainly documented through Visual Encounter Method. Minor combing operations were done at some
of the sites for documenting the fauna which otherwise remains concealed with the environment and could be
missed out. The combing process included upturning of stones, small rocks, fallen logs, boulders and disturbing
small shrubs and sweeping of leaf litter. Indirect evidences were used as cues for documenting mammalian fauna.
Secondary data for the entire region was procured from Environment Information Centre (A centre with MoEF) and
the same was validated through ground reality. For validating the secondary data coloured pictures of animals were
shown to the villagers and their presence in the area was confirmed. Wherever possible, photo documentation was
done using Digital Camera of sufficiently high resolution.
The methodology adopted for faunal survey involved : Random survey, Opportunistic observations, Diurnal bird
observation, active search for reptiles, faunal habitat assessment, active search for scats and foot prints and review
of previous studies, Desktop literature review was conducted to indentify the representative spectrum of threatened
species, population and ecological communities.
METHODS FOR DOCUMENTATION OF MICRO BIOTA
A) Collection of Plankton:
Samples were collected from the sampling sites considering the tidal cycle (during high tide) and weather condition.
Sampling of planktons was done by filtering 1 liter of water through plankton (bag) net of pore size 70m for
phytoplankton and 200m for zooplankton (Figure 2). A sieve was used on top of the bag net during filtration to
separate out debris and excess silt. The residue left in both the nets after filtration was then carefully washed with
distilled water and collectively conditioned in plastic containers with inert cap liners.

Figure 2: Standard Plankton Net with attached Collection Bottle


Page 5 of 7

EIA & EMP and Risk Assessment & DMP report


For proposed unit of Polyols & Polymer.
at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate,
Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India
SAMPLING AND ANALYTICAL METHODS ADOPTED
The samples were fixed in 2% Formaldehyde and Lugols Solution (0.3%) for 5 days. 10ml of this fixed sample was
then centrifuged at 1500 rpm for 10 minutes. Supernatant was discarded and the concentrated sample was taken for
further microscopic observations.
0.5 ml of the sample was taken on Sedgwick Rafter Counting Cell (Figure 3) and plankton number was counted. The
identification was done using a Stereo-microscope under 45X or 100X magnification. The planktons were then
compared with the descriptive and/or photographic identification keys given by Desikachary, 1959; Prescott, 1959;
Sournia, 1974; Boltovskoy, 1981; Matsumura Tundisi, 1986; Round et al., 1990; Santhanam, 1993 etc. The
plankton were identified as much possible up to species level.

Figure 3: Sedgwick Rafter Counter for counting the Plankton


B) Collection of Benthos:
The benthic fauna can be broadly grouped into two categories namely micro-benthos and macro-benthos. Sampling
of macro-benthos involved sampling of a portion of the sediment, from which the macro-invertebrates as well as the
vertebrates could be separated. Grabs or Dredges of various types are employed for this purpose. However, in the
current study Ekman Dredge, one of the simple dredge was been used extensively (Figure 4). It is been reported
that this dredge might not work accurately in some specific situations, e.g., for accurate investigation of the sediment
microlayer. The Liebman Core Sampler is suitable for hard bottom but as the substratum here was muddy Ekman
Dredge served the purpose. As the study area essentially included coastal wetland, samples were collected from the
coast as shown in figure 1, and were analyzed for their benthic fauna.
A total of 3 stations were selected for the sampling, i.e. upstream, midstream and downstream of the entire focal
study area. Three samples were collected from each of site and the distance between each sample was 500 m or
more.

Page 6 of 7

EIA & EMP and Risk Assessment & DMP report


For proposed unit of Polyols & Polymer.
at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate,
Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India
SAMPLING AND ANALYTICAL METHODS ADOPTED

Figure 4: Ekman Dredge used for sampling Benthic Fauna


C) Handling and Preservation:
The samples were first sieved and then washed from the sediment. From this, the samples were transferred along
with some water to a coarse sieve with a mesh size of 0.5 to 0.6 mm and a fine one with a mesh width of less than
0.2 mm, one over the other. Sieving yields a residue mixture of animals and sediment. The organisms were either
hand-picked or picked using forceps from this mixture. After sorting, macro-invertebrates were identified to the
lowest practical identification level (LPIL) which in most cases was to the species level unless the organism was a
juvenile, damaged, or otherwise unidentifiable. Macro-invertebrates were preserved in 10% formalin. Use of 70%
Ethyl Alcohol solution is recommended if organisms are having calcareous shells or exoskeleton.
D) Identification:
Identification of the organisms was done using a stereo-microscope. Pennak (1978), Tonapi (1980) Ward and
Whipple (1992) and other monographs were used as standard reference as identification manuals.

Page 7 of 7

Guidelines issued by GPCB for coal handling units and proposed compliance actions by proponent
Polyols & Polymers for coal handling at proposed new unit at D-II, Ta. Vagra, Dist. Bharuch, Gujarat,
India.

GUIDE LINES FOR COAL HANDLING UNITS:Guideline


(A) Location criteria:
1. Coal handling unit/Agency shall not use any agriculture
land and shall be located at a minimum distance of 250
meters away from the surrounding agriculture land.
2. Government waste land not suitable for any agriculture
purpose meeting with the requisite siting / distance
criteria shall be preferred for establishing coal handling
units.
3. Coal handling unit/Agency shall be minimum 500
meters away from the residential area, school/colleges,
Historical Monuments, Religious Places, Ecological
sensitive area as well as forests area.
4. Coal handling unit/Agency shall be located at a
minimum 500 meters away from the Railway line, Express
ways, National Highways, State ways and District Roads
and from water bodies like River, Nala, Canal, Pond etc.
5. In case of coal handling activities at the ports and
jetties or extension thereof, the distance and land use
criteria may be relaxed and compensated by
advanced/sophisticated pollution control measures and
mechanization & thick plantation, however all such ports
and jetties, where coal handling is carried out, shall
provide closed conveyor belt and mechanization for
handling of coal.
(B) Storage and handling criteria:
6. Coal handling unit/Agency shall store coal in such a way
that coal heap should not be higher than 5 meter and
clear distance between two adjoining heaps at G.L. should
be 5 meters, so that in case of fire, approach is available.
7. There should be mechanized loading/ unloading system
from the loading /unloading area to the stacking yards
and in to the vehicles.
8. Coal handling unit/Agency shall take all corrective steps
to resolve the issue of air pollution at permitted coal
storage/handling area where coal is being stored.
(C) Transport criteria:
9. Coal handling unit/Agency shall ensure that all trucks
before leaving the storage yard shall be showered with
water with adequate system, Shall be covered with
tarpaulin or any other effective measure/device
completely and also that trucks are not over loaded as
well as there is no spillage during transportation.
10. The vehicle carrying the coal should not be overloaded
by raising the height of carriage. Weigh scale shall be
provided within the loading area only and port / coal park
authority shall ensure that no overloading is done.
11. The top of the vehicle should be covered with fixed
cover instead of tarpaulin cover to avoid spillage or
dusting of coal.
12. Coal handling unit/Agency shall obtain transport
permission from the local Administration under the
relevant rules.
(D) Pollution prevention criteria:

Proposed action
Complied, plot land is acquired by GIDC
Complied, plot land is acquired by GIDC

Complied, plot is > 500 m away from residential area,


school/colleges, Historical Monuments, Religious Places,
Ecological sensitive area as well as forests area.
Complied, plot is > 500 m away from Railway line, Express
ways, National Highways, State ways and District Roads
and from water bodies like River, Nala, Canal, Pond etc.
Not applicable

Shall be complied

Shall be complied
Shall be complied

Shall be complied

Shall be complied

Shall be complied
Transport permission shall be obtained from local
administration after grant of EC

Page 1 of 3

Guidelines issued by GPCB for coal handling units and proposed compliance actions by proponent
Polyols & Polymers for coal handling at proposed new unit at D-II, Ta. Vagra, Dist. Bharuch, Gujarat,
India.
Guideline
13. Coal handling unit/Agency shall provide paved
approach with adequate traffic carrying capacity.
14. Coal handling unit/Agency shall construct compound
wall all along periphery of the premises with minimum 9
meters height.
15. Continuous water sprinkling shall be carried out on
the top of the heap at regular intervals to prevent dusting,
fire & smoke. To prevent fugitive emission during
loading/unloading, fixed pipe network with sufficient
water storage and pump shall be installed. Water
sprinkling shall be carried out at each and every stage of
handling to avoid generation of coal, dust or other dust
within premises.
16. Coal handling unit/Agency shall ensure regular
sweeping of coal, dust from internal and main road and
also ensure that there is adequate space for free
movement of vehicles.
17. The following adequate Air Pollution Control
Measures shall be
installed and to be operated
efficiently.
(a) Dust containment cum suppression system for the coal
stack, loading and unloading.
(b) Construction of effective wind breaking wall suitable
to local condition to prevent the suspension of particles
from the heaps.
(c) Construction of metal road & RCC Pucca flooring in the
plot area/ godown etc.
(d) System for regular cleaning and wetting of the floor
area within the premises.
(e) Entire coal storage area/ godown should be covered
with permanent weather shed roofing and side walls i.e.,
in closed shed, in case of crushing/sieving/grading activity
is carried out (i.e. G. I. Sheet) along with adequate
additional APCM should be installed.
18. Coal handling unit/Agency shall carryout three rows
plantation with tall growing tress all along the periphery
of the coal handling premises, inside & outside of the
premises along with road.
19. Proper drainage system shall be provided in all coal
storage area so that water drained from sprinkling &
runoff is collected at a common tank and can be reused
after screening through the coal slit or any other effective
treatment system.
20. All the engineering control measures and state of art
technology including covered conveyer belts, mechanized
loading and unloading, provision of silo etc. shall be
provided in addition to the measures recommended in
the environmental guidelines for curbing the pollution.
(E) Safety requirement:
21. Coal handling unit/Agency shall provide adequate fire
fighting measure to avoid any fire or related hazards
including adequate water storage facility, and the
premises shall be exclusively used for storage of the coal.
22. An onsite emergency plan shall be prepared and
implemented by coal handling unit.

Proposed action
10 m wide internal paved road shall be provided for
access to coal storage yard
Shall be complied
Shall be complied

Regular cleaning of floor area with wet mopping or


vacuum cleaning shall be done

There is no coal crushing or pulverizing involved, hence


dust containment and suppression system shall not be
required.
Shall be provided as and where required.
All internal roads and passages shall be RCC pucca flooring
Regular cleaning of floor area with wet mopping or
vacuum cleaning shall be done
Coal storage area shall be adequately covered

No mechanical crushing involved.

Garland drains shall be provided around the coal storage


area and water collected out of sprinkling shall be reused
after removal of coal silt.
Shall be provided as per requirement

Fire hydrant system and fire extinguishers shall be


provided at the coal storage area
Onsite emergency plan shall be prepared, hazards at coal
storage area and handling areas shall be included.

Page 2 of 3

Guidelines issued by GPCB for coal handling units and proposed compliance actions by proponent
Polyols & Polymers for coal handling at proposed new unit at D-II, Ta. Vagra, Dist. Bharuch, Gujarat,
India.
Guideline
(F) Legal criteria:
23. Necessary permission from all the applicable
regulatory authorities and adequate steps under the
provisions of applicable environmental acts/ rules shall be
taken.
24. Coal handling unit/Agency shall prepare EMP
(Environment Management Plan) and implement the
same in true spirit and thus maintain overall environment
of that area.
25. Coal handling unit/Agency shall not carry out the
operation of loading/unloading of coal/coal dust at any
place, till adequate air pollution control equipment for
dust control/suppression are installed and efficiently
operated and the consent under the provisions of Air
(Prevention & Control of Pollution) Act, 1981 is obtained
by the coal yard owners/ Coal handling unit/Agency / coal
importers.
26. Coal handling unit/Agency shall operate continuous
Ambient Air Quality Monitoring Stations as per CPCB
guideline. The results of parameters like SPM, RSPM, and
SO2 and NOx shall be submitted to the SPCB every month.
27. In case of port which provides the facility to individual
developers an agreement /MoU shall be made between
port authority and developer for curtailment of pollution.
Port authority shall be responsible for supervising and
controlling the pollution control related activities and
implementation of the environmental guidelines.
28. The concentration of the following parameters in the
ambient air within the premises and a distance of 10
meters from the source (other than the stack/vent) shall
not exceed the following levels.

PARAMETERS
Particulate
Matter- 10 (PM10)
Particulate
Matter- 2.5
(PM2.5)
SO2
NOx

Proposed action
Shall be complied

EMP for entire unit shall be prepared and implemented

Shall be complied

Shall be complied

Not applicable

Shall be complied

PERMISSIBLE LIMIT
24 Hrs
Annual
Average
60
100
3
3
Microgram/M
Microgram/M
40
3
Microgram/M

60
3
Microgram/M

50
3
Microgram/M
40
3
Microgram/M

80
3
Microgram/M
80
3
Microgram/M

Page 3 of 3

EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic
Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch,
Gujarat State, India
Functional Area AP
Associate FAE :1. Ms. Bhumika Bhuva
Designation : Environment Engineer
Individual activities carried out : Preparation of study area maps
Prepare monitoring calendar for AAQM
Co-ordination with team members
Record keeping
Compilation of baseline AAQM monitoring results in tabular and graphical formats
Procurement of meteorological data of nearest station of IMD and compiling the statistics.
Compilation of hourly meteorological data of weather monitoring station (primary baseline monitoring of site specific meteorology)
Generating windrose plots
Collecting all technical details related to stack emissions :-sources, pollutants, stack details, details of APCD
Project Data Collection
Secondary data procurement
Verify completeness and correctness of information obtained from proponent
Data collection for Alternative Analysis
Filling up of salient features table and comparing with siting guidelines of MoEF
Under guidance of FAE : Identification of impacting activities of project w.r.t air pollution.
Identifying other sources of air pollution by studying each project activity at each phase
Prediction of impacts and scoring in impact-activity matrices
fugitive emission estimation on TANKS software
Post project monitoring plan for AP management
Assistance in report preparation
Team members :1. Mr. Vikram Gohil
Designation :- Field Supervisor & Lab Chemist
Baseline monitoring : Survey work for baseline sampling and monitoring. GPS measurements and photography of sampling sites.
Selecting Air quality monitoring stations, networking, scheduling, supervising equipment installation and sampling, recording
analysis results and evaluating baseline status.
Co-ordinating with client for monitoring schedules and visits
Supervising equipment installations and arranging for necessary field support and supplies
guiding monitoring teams
troubleshooting while monitoring and sampling
Supervising sample storage and transport procedures
Inhouse lab analysis and compilation of analytical data
Verification of sampling results and assessment of baseline status
Collecting all technical details related to stack emissions :-sources, pollutants, stack details, details of scrubber systems already
installed and operational.
2. Mrs. Femida Kundawala Designation : Environment Engineer
Preparation of study area maps
Prepare monitoring calender.
Compilation of baseline AAQM monitoring results in tabular and graphical formats
Estimating the emission loads from material balance and reactions
Calculation flue gas emission factors

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 1 of 5

EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic
Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch,
Gujarat State, India
Functional Area WP
Associate FAE :1. Mrs. Khushbu Patel
Designation : Environment Engineer
Individual activities carried out : Preparation of study area maps
Co-ordination with team members
Record keeping
Collection of analytical data for SW and GW analysis and compilation in tabular format for data review, authentication and
verification
Conducting ion balancing for SW and GW samples
Collecting secondary baseline data from Govt. publications and websites and compilation of the same for comparison
Final drafting of GW and SW baseline results
Carrying out Water balance calculations for process and utilities and assessment of effluent generation sources, quantification of
effluent streams
Identifying and segregating the effluent streams
Identification of impacting activities of project w.r.t water pollution.
Prediction of impacts and scoring in impact-activity matrices
Estimating the rainwater harvesting potential
Assist in report preparation
Under guidance of FAE
Estimation of boiler blowdown
Hydraulic calculations for capacity rating of proposed ETP unit
Suggestions for water conservation measures
2. Mrs. Femida Kundawala Designation : Environment Engineer
Under guidance of FAE : Preparation of study area maps
Collecting secondary baseline data from Govt. publications & comparison of primary data with secondary data.
Carrying out Water balance calculations for process and utilities and assessment of effluent generation sources, quantification of
effluent streams
Identifying and segregating the effluent streams
Hydraulic calculations for capacity rating of proposed ETP units
Team Members
1. Mr. Vikram Gohil
Designation : Field Supervisor and Lab Chemist
- Survey work & field visit for baseline sampling for SW & GW. GPS measurements and photography of sampling sites.
- Sampling preparation work
- guiding monitoring teams
- troubleshooting while sampling
- Inhouse lab analysis
- Verification of analytical data for authenticity, completeness, relevance and accuracy
- Identify impacting activities and their significance through impact matrices
- Review proposed treatment scheme for adequacy based on treatability results and make suggestions
- Review adequacy of contingency storage proposed
- Prediction of impacts and assessment of required mitigation measures and finalization
- Propose Post-project environment monitoring plan w.r.t WP
- Identification and prediction of construction phase impacts on water and proposed mitigation measures
- Suggest additional mitigative measures if required
2. Dr. Vinod B. Gaur
Designation : Laboratory Manager
- Guide for Laboratory preparations for surfacewater and ground water sampling, collection, preservation and transport etc.
- Conduct QC/QA procedures for checking errors and flaws
- Execute instrument calibration procedures and intermediate checks
- Supervise analytical work and record-keeping
- Participate in review of results and interpretation
- Participate in preparation of Post project monitoring plan
3. Ms. Neha H. Solanki
Designation :
Lab Chemist
Individual activities
Selection of parameters for Environmental Analysis of baseline survey samples of GW, SW, marine samples, soil etc.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 2 of 5

EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic
Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch,
Gujarat State, India
Analysis of samples of GW, SW, marine samples, soil etc.
Calibration and intermediate check of instruments
Under guidance of FAE :- QA/QC activities as per QMS and SOPs
- Participate in data interpretation for SW and GW baseline results and conclusion
FA - Hazardous Wastes Management
Associated FAE :1. Ms. Bhumika Bhuva
Designation : Environment Engineer
Individual activities
Site Visit and study area visit
Identification of project activities
Identification of impacts from project activities
Evaluating the types of solid wastes to be generated from each project activity during each phase of the project.
Quantifying the industrial wastes generated from material balance.
Categorization of industrial wastes as per HW rules
Determining the segregation of the wastes, method of collection and disposal of each waste in compliance with the applicable HW
rules.
Collecting status of common TSDF and incineration facilities proposed for disposal.
Details of management of the hazardous wastes to be generated from the project stating detail of storage area for each type of
waste, its handling, its utilization and disposal etc.
Collecting information on proposed methodology of de-contamination and disposal of discarded containers and its record keeping
and assessing its suitability and feasibility as well as effectiveness
Impact assessment of waste generation during construction phase.
Assess measures proposed for hazardous waste management, quantity generated, storage facilities, treatment facilities
Assess disposal methods proposed are in compliance with applicable rules and whether the receiving bodies have the capacity to
accept the wastes
Impact assessment of waste generation during commissioning & operation phase.
Under guidance of FAE : EMP for construction phase under FAE guidance.
Measures for waste minimization
Possibilities of co-processing of incinerable wastes
Management of non-hazardous wastes
Assigning scores in impact activity matrices under guidance of FAE.
Assist in Report preparation.
EMP for commissioning & operation phase.
2. Mrs. Femida Kundawala Designation : Environment Engineer
Under guidance of FAE : Identification of project activities
Identification of impacts from project activities
Evaluating the types of solid wastes to be generated from each project activity during each phase of the project.
Quantifying the industrial wastes generated from material balance.
Categorization of industrial wastes as per HW rules
Determining the segregation of the wastes, method of collection and disposal of each waste in compliance with the applicable HW
rules.
Details of management of the hazardous wastes to be generated from the project stating detail of storage area for each type of
waste, its handling, its utilization and disposal etc.
Assigning scores in impact activity matrices under guidance of FAE.
Assist in Report preparation.
FA SE
Associated FAE :1. Mr. MahendraSinh K. Rathod
Designation : Executive Socio economic studies(Proposed FAE for SE)
Primary data collection for socio economic survey within study area.
Photography of survey.
Compilation of survey information gathered in questionnaires
Secondary data collection of Govt. publications, census & comparison of primary data with secondary data.
Verification of legal aspects of the project related socio-economics with prevailing policies and regulations in India
Participate in CSR planning and need assessment review

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Page 3 of 5

EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic
Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch,
Gujarat State, India

FA EB
Associate FAE
1. Priti D. Raval
Designation : Environment Engineer
Study area visit for ecological survey
Collecting secondary ecological data and verifying it through surveys
determining status of endangered species of animals and plants
Identification of nearest ecologically sensitive areas around project site
Verification of applicability of prevailing policies and regulations in India
Assisting FAE for assessment of impact of the various project activities on the ecology and biodiversity of the project area during all
phases of the project.
Assistance in Report drafting for EIA
Assisting FAE in recommending species suitable for pollution abatement and ecological conservation as suggested in CPCB
guidelines and SEAC guidelines for the given agroclimatic zone of the region

2. Mrs. Khushbu Patel


Designation : Environment Engineer
Study area visit for ecological survey
Collecting secondary ecological data and verifying it through surveys
Sampling for aquatic studies and analysis of plankton
determining status of endangered species of animals and plants
Identification of nearest ecologically sensitive areas around project site
Verification of applicability of prevailing policies and regulations in India
Assisting FAE for assessment of impact of the various project activities on the ecology and biodiversity of the project area during all
phases of the project.
Assistance in Report drafting for EIA
3. Mrs. Twinkle H. Modi
Designation : Technical Manager and Microbiologist
Planning & Scheduling for baseline ecological survey for EIA studies
determining status of endangered species of animals and plants
organizing the baseline data collection
Sampling for aquatic studies and analysis of plankton
Identification of impacting activities of project w.r.t ecology and biodiversity of the study area
Review of Greenbelt development requirement of the project
Lab management activities, Laboratory analysis & identify species and Lab QMS implementation
FA HG
Associate FAE
1. Mr. Vikram Gohil
Designation : Field Supervisor and Lab Chemist
selection of locations for soil sampling within the study area
Arrangements for collection of soil samples
Supervision of Soil Analysis and characterization
Survey work & field visit for baseline sampling for soil. GPS measurements and photography of sampling sites.
guiding monitoring teams
troubleshooting while sampling
Inhouse lab analysis and compilation of analytical data
Team member
1. Ms. Neha H. Solanki
Designation : Lab Chemist
- Environmental Analysis of baseline survey samples of soil
Verification of sampling results and assessment of baseline status
Submit the outcomes in form of report
FA AQ
Associate FAE
1. Mrs. Femida Kundawala
Designation : Environment Engineer
- Collecting input data related to meteorological and stack emission for GLC simulation
FA Noise
FAE :1. Mr. Vikram Gohil
Designation: Field Supervisor and Lab Chemist
Planning and scheduling of noise measurement at selected locations of study area
GPS & photography during monitoring.

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

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EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic
Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch,
Gujarat State, India
Review of baseline noise levels, sources and their compliance with permissible limits
Identify sources of noise generation from the project and predict resultant increase in noise levels of sensitive receptors of the study
area
Collection and compilation of analytical data
Calculating equivalent noise levels from measured noise
Associate FAE
1. Ms. Priti D. Raval
Designation: Environment Engineer
Planning and scheduling of noise measurement at selected locations of study area
sampling and monitoring jobs and guiding monitoring teams
Collection and compilation of analytical data
Calculating equivalent noise levels from measured noise levels and compilation in tabular form
determine status of noise environment, existing sources of major noise generation
To predict noise levels of different project activities and anticipate the increase in the baseline noise levels in residential, industrial
and commercial zones as well as noise due to increase in road traffic
Compilation of the outcomes of the assessment in report form and submission to EIA Co-coordinator
Team Member
1. Mr. Ajit Parmar
Designation: Lab Assistant
Noise monitoring within study area, GPS & photography during monitoring.
Assist team during monitoring
2. Mr. Moshin Mansuri
Designation: Lab Assistant
Noise monitoring within study area, GPS & photography during monitoring.
Assist team during monitoring.
3. Mr. MahendraSinh K. Rathod
Designation: Executive Socio economic studies
Noise monitoring within study area, GPS & photography during monitoring.
Assist team during monitoring.
FA LU
Associate FAE
1.Ms. Bhumika Bhuva
Designation : Environment Engineer
Reference map preparation for classification and determine baseline LULC of the area.
Identification of impacts, Prediction of impacts on land use pattern and land cover.
Identification of talukas and villages as well as major landforms covered in the study area using google earth, wikimapia, census
datasheets
2. Mrs. Khushbu Patel
Designation: Environment Engineer
Reference map preparation for classification and determine baseline LULC of the area.
Identification of impacts, Prediction of impacts on land use pattern and land cover.
Identification of talukas and villages as well as major landforms covered in the study area using google earth, wikimapia, census
datasheets.
FA RH
Associate FAE
1. Ms. Bhumika Bhuva
Designation: Environment Engineer
Identification of hazardous chemical w.r.t haz. Chemical schedules & their antidotes.
Hazardous chemical Consequence analysis using ALOHA, mapping of threat zones and plot affected areas of study area and plant
sections.
Collecting data regarding fire-fighting arrangements and occupational safety measures
2. Mrs. Khushbu Patel
Designation: Environment Engineer
Identification of hazardous chemical w.r.t haz. Chemical schedules & their antidotes.
Hazardous chemical Consequence analysis using ALOHA, mapping of threat zones and plot affected areas of study area and plant
sections

Siddhi Green Excellence Pvt. Ltd., Ankleshwar

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