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MOCK TEST
PART - I : PHYSICS
1.
2.
4.
(a)
Q
eo A
(b)
(c)
Q2
eo A
5.
V1
Q1 C1
10 W
D
10 W
C3
6.
10 W
(a) Q1 = Q2 = Q3 and V1 = V2 = V
(b) V1 = V2 = V3 = V
(c) Q1 = Q2 + Q3 and V = V1 + V2
(d) Q2 = Q3 and V2 = V3
A parallel plate condenser with oil between the
plates (dielectric constant of oil K = 2) has a
capacitance C. If the oil is removed, then
capacitance of the capacitor becomes
(c)
2C
C
2
10 W
(a)
10 W
V3
3.
10 W
10 W
V
Q2 2 C 2
Q3
10 W
(b) 2C
(d)
C
2
2V
3W
I B 3W
2
2
1
A
A (d)
A
(c)
3
9
8
Kirchhoffs first law, i.e. Si = 0 at a junction, deals
with the conservation of
(a) charge
(b) energy
(c) momentum
(d) angular momentum
The potential difference between the terminals
of a cell in an open circuit is 2.2 V. When a resistor
of 5W is connected across the terminals of the
(a) 1A
7.
8.
3W
C
(b)
2
cell, the potential difference between the
terminals of the cell is found to be 1.8 V. The
internal resistance of the cell is
(a)
9.
10.
11.
12.
13.
14.
10
7
W
W (b)
9
12
(c)
(b)
9
12
W (d)
W
10
7
qB
mp
(b)
qB
2pm
(c)
qBE
2pm
(d)
qB
2 pE
15.
16.
17.
18.
19.
20.
1
2
VI
(c) 1 VI
2
(d) VI
A magnetic field of 2 102 T acts at right angles
to a coil of area 100 cm2, with 50 turns. The
average e.m.f. induced in the coil is 0.1 V, when it
is removed from the field in t sec. The value of t
is
(a) 10 s
(b) 0.1 s
(c) 0.01 s
(d) 1 s
Two coils of self inductances 2 mH and 8 mH are
placed so close together that the effective flux
in one coil is completely linked with the other.
The mutual inductance between these coils is
(a) 6 mH
(b) 4 mH
(c) 16 mH
(d) 10 mH
Which one of the following electromagnetic
radiations has the smallest wavelength?
(a) Ultraviolet waves (b) X-rays
(c) g-rays
(d) Microwaves
Which one of the following phenomena is not
explained by Huygens constr uction of
wavefront?
(a) Refraction
(b) Reflection
(c) Diffraction
(d) Orgin of spectra
Two light waves having their intensities in the
ratio 16 : 9 interfere to produce interference
pattern. What is the ratio of maximum intensity
to minimum intensity in this pattern ?
(a) 4 : 3
(c) 25 : 7
(b) 625 : 49
(d) 49 : 1
A slab of thickness t and refractive index 1.5 is
placed in between point A and B as shown in the
figure given below. The optical path length
between A and B is
t
A
n = 1.5
21.
22.
23.
24.
(a)
x + + y
2
(b) (x + t + y)
(c)
x + t + y
2
(d)
x + t + y
2
Balmer series
1
1
1. v = R H 2 - 2
3
n
B.
Brakett series
1
1
2. v = R H 2 - 2
1
n
C.
Lyman series
1
1
3. v = R H 2 - 2
2
n
D.
Paschen series
1
1
4. v = R H 2 - 2
4
n
Codes :
A
B
C
D
(a) 3
2
1
4
(b) 3
4
2
1
(c) 4
3
2
1
(d) 2
3
1
4
A ruby laser using a flash lamp is
1. A pulse laser
2. A three level laser
3. Cooled effectively
Which of the above statements are correct ?
(a) 1, 2 and 3
(b) 2 and 3
(c) 1 and 2
(d) 1 and 3
The population inversion necessary for laser
action used in solid state lasers is
(a) electrical discharge
(b) inelastic atom-atom collision
(c) direct conversion
(d) optical pumping
2
2
3
1
1 H + 1 H 2 He + 0 n + 13 MeV
31.
7N0
8
(b)
N0
2
4
3N 0
N0
(d)
4
8
32. The diagram of a logic circuit is given below.
0.707 A max
(c)
W
X
A max
f1 f 2
W
Y
The output F of the circuit is represented by
(a) W + (X + Y)
(b) W + (X.Y)
(c) W, (X + Y)
(d) W, (X.Y)
33. NAND and NOR gates are called universal gates
primarily because they
(a) are available universally
(b) can be combined to produce OR, AND and
NOT gates
(c) are widely used in Integrated circuit packages
(d) are easiest to manufacture
34. Of the diodes shown in the following diagrams,
which one is reverse biased ?
37.
+10 V
(a)
(b)
R
+5 V
12 V
38.
5 V
(c)
R
10 V
+5 V
R
(d)
39.
35. The frequency response curve of RC coupled
amplifier is shown in figure. The band with of the
amplifier will be
f4 - f2
(d) f3 f1
2
I
In common emitter amplifier the c is 0.98. The
Ie
current gain will be
(a) 4.9
(b) 7.8
(c) 49
(d) 78
An antenna is a device
(a) that converts electromagnetic energy into
radio frequency signal
(b) that converts radio frequency signal into
electromagnetic energy
(c) that converts guided electromagnetic
waves into free space electromagnetic
waves and vice-versa
(d) none of these
Consider telecommunication through optical
fibres. Which of the following statements is not
true ?
(a) Optical fibres may have homogeneous core
with a suitable cladding
(b) Optical fibres can be of graded refractive
index
(c) Optical fibres are subject to electromagnetic
interference from outside
(d) Optical fibres have extremely low
transmission loss
What should be the maximum acceptance angle
at the aircore interface of an optical fibre if n 1
and n2 are the refractive indices of the core and
the cladding, respectively
(a) f3 f2
36.
f3 f 4
(b) f4 f2 (c)
(a)
sin -1 (n 2 n1 )
(b)
sin -1 n12 - n 22
(c)
-1 n 2
tan
n1
(d)
-1 n1
tan
n2
5
40.
What is a vidicon ?
(a) It is a type of camera
(b) It is a type of electric generator
(c) It is a type of heating device
(d) It is a type of optical device
PART - II : CHEMISTRY
(a) a = b = g 90
S 2 (s ) + 2 O 2 ( g )
2SO 2 ( g ) ; DG =544 kJ
(b) a = b = g =90
2 Zn (s ) + S 2 ( s )
2 ZnS (s ) ; DG = 293 kJ
2 Zn (s ) + O 2 ( g )
2 ZnO (s ) ; DG = 480 kJ
49.
2 ZnS (s ) + 3O 2 ( g )
2 ZnO (s ) + 2SO 2 ( g )
will be :
(a) 357 kJ
(b) 731 kJ
(c) 773 kJ
(d) 229 kJ
43. Considering entropy (S) as a thermodynamic
parameter, the criterion for the spontaneity of
any process is
(a) DSsystem + DSsurroundings > 0
50.
51.
52.
(d) a b g = 90
Which one of th e following will show
paramagnetism corresponding to 2 unpaired
electrons?(Atomic numbers : Ni = 28, Fe = 26)
(a) [Fe F6]3
(b) [Ni Cl4]2
3
(c) [Fe (CN)6]
(d) [Ni (CN)4]2
The most durable metal plating on iron to protect
against corrosion is
(a) Nickel plating
(b) Tin plating
(c) Copper plating
(d) Zinc plating
The most convenient method to protect the
bottom of ship made of iron is
(a) Coating it with red lead oxide
(b) White tin plating
(c) Connecting it with Mg block
(d) Connecting it with Pb block
Which of the following coordination compounds
would exhibit optical isomerism?
(a) pentamminenitrocobalt(III) iodide
(b) diamminedichloroplatinum(II)
(c) trans-dicyanobis (ethylenediamine)
chromium (III) chloride
(d) tris-(ethylendiamine) cobalt (III) bromide
6
53. Lanthanoids are
(a) 14 elements in the sixth period (atomic no. =
90 to 103) that are filling 4f sublevel
(b) 14 elements in the seventh period (atomic
no. = 90 to 103) that are filling 5f sublevel
(c) 14 elements in the sixth period (atomic no. =
58 to 71) that are filling 4f sublevel
(d) 14 elements in the seventh period (atomic
no. = 58 to 71) that are filling 4f sublevel
54. The radioactive isotope
60
27 Co
which is used in
59
28 Ni
(b)
59
27 Co
(c)
60
28 Ni
(d)
60
27 Co
Exp.
1
2
3
4
(c) 1.0 10 2
(d) 1.0 1010
63. In the silver plating of copper, K[Ag(CN)2] is used
instead of AgNO3. The reason is
(a) A thin layer of Ag is formed on Cu
(b) More voltage is required
(c) Ag+ ions are completely removed from
solution
(d) Less availability of Ag+ ions, as Cu cannot
displace Ag from [Ag(CN)2] ion
64. If 0.5 amp current is passed through acidified
silver nitrate solution for 100 minutes. The mass
of silver deposited on cathode, is (eq.wt.of silver
nitrate = 108)
(a) 2.3523 g
(b) 3.3575 g
(c) 5.3578 g
(d) 6.3575 g
C + D. The variation
65. For the reaction A + B
of the concentration of the products is given by
the curve
7
71. In a set of reactions acetic acid yielded a
product D.
Y
Z
SOCl
HCN
(a) Z
(b) Y
(c) W
(d) X
66. Acetamide and ethylamine can be distinguished
by reacting with
(a) Aqueous HCl and heat
(b) Aqueous NaOH and heat
(c) Acidified KMnO4
(d) Bromine water.
67. Aniline when diazotized in cold and when treated
with dimethyl aniline gives a coloured product.
Its structure would be
N=N
(a) CH3NH
(b) CH3
NHCH3
N=N
(c) (CH3)2N
N=N
(d) (CH3)2N
NH
NH2
Sn
COOH
(a)
CH2 C CH3
(c)
CH2 C CH3
OH
CN
(b)
OH
CN
X- stands for
(b) SnCl2
+
(d) NH 3 Cl
C CH3
OH
OH
(d)
C COOH
CH3
72. Ketones
[ R C R1 , where R = R1 = alkyl groups]
||
O
can be obtained in one step by
(a) oxidation of primary alcohols
(b) hydrolysis of esters
(c) oxidation of tertiary alcohols
(d) reaction of acid halides with alcohols
73. Phenylmethyl ketone can be converted into
ethylbenzene in one step by which of the
following reagents?
(a) LiAlH4
(b) Zn-Hg/HCl
(c) NaBH4
(d) CH3MgI
74. Ethanol and dimethyl ether form a pair of
functional isomers. The boiling point of ethanol
is higher than that of dimethyl ether, due to the
presence of
(a) H-bonding in ethanol
(b) H-bonding in dimethyl ether
(c) CH3 group in ethanol
(d) CH3 group in dimethyl ether
75. Propan - 1- ol may be prepared by the reaction of
propene with
(a) H3BO3
(b) H2SO4/H2O
(c) B2H6,NaOHH2O2
O
||
(d) CH 3 C - O - O - H
HCl
(c) Cl
H.OH
C D
Time
(a) NH 2
Benzene
Anhy.AlCl3
2
CH3COOH
A B
Conc
8
(c) CO2 and NaOH
(d) Sodium oxalate.
77. An ester (A) with molecular fomula, C9H10O2 was
treated with excess of CH3MgBr and the complex
so formed was treated with H2SO4 to give an
olefin (B). Ozonolysis of (B) gave a ketone with
molecular formula C 8H8O which shows +ve
iodoform test. The structure of (A) is
(a) C6H5COOC2H5
(b) C2H5COOC6H5
(c) H3COCH2COC6H5
(d) p H 3CO C 6 H 4 COCH 3
78. Self condensation of two moles of ethyl acetate
in presence of sodium ethoxide yields
(a) acetoacetic ester
(b) methyl acetoacetate
(c) ethyl propionate
(d) ethyl butyrate
79. Methanol is industrially prepared by
(a) Oxidation of CH4 by steam at 900C
(b) Reduction of HCHO using LiAIH4
(c) Reaction HCHO with a solution of NaOH
(d) Reduction of CO using H2 and ZnO Cr2O3.
80. Indicate which of the nitrogen compounds
amongst th e following would undergo
Hoffmanns reaction, i,e., reaction with Br 2 and
strong KOH to furnish the primary amine (R
NH2) ?
(a) R - CO - NHCH 3 (b) R CO ONH4
(c) R CO NH2
(d) R CO NHOH.
PART - III : MATHEMATICS
81. If sin (y + z x), sin (z + x y) and sin (x + y z) are
in A.P. (with x, y, z p /2), then tan x, tan y and tan
z are in
(a) A.P.
(b) G.P.
(c) H.P.
(d) none of these.
82. The number of roots of equation
p
is
4
(a) 0
(b) 1
(c) 2
(d) infinite
83. In order that the equation
tan -1 2x + tan -1 3x=
(b) (-, - 2)
(c) (2, )
(d) (-, )
84. The portion of a tangent to a parabola y2 = 4ax
cut off between the directrix and the curve
subtends an angle q at the focus, where q =
p
p
(a)
(b)
3
4
2p
p
(d)
3
2
85. There are 25 trees at equal distances of 5 meters
in a line with a well, the distance of the well from
the nearest tree being 10 metres. A gardener
waters all the trees separately starting from the
well and he returns to the well after watering each
tree to get water for the next. The total distance
the gardener will cover in order to water all the
trees is
(a) 3550 m
(b) 3434 m
(c) 3370 m
(d) 3200 m
2
2
2
86. If ax + by + cz - 1 = 0 and lx + my + nz = 0
then
(c)
(a)
dy
cly - anx
=
dx
bnz - cmx
(b)
dy
clz - anx
=
dx
bny - cmz
(c)
dz
amy - blx
=
dx
bny - cmz
(d)
dz
amz - blx
=
dx
bny - cmz
sin
(b) a n + c n > 2 b n
(d) none correct
Then
1
1
1
(a) A = , B = - , C = , D R
4
3
8
1
1
1
(b) A = , B = , C = , D R
8
4
3
1
(c) A = 0, B = - , C =
6
(d) none of these.
89. In a DABC, the area
2
b - (c - a )
1
, DR
8
of the triangle is
9
1
(a)
4
(b)
8
15
1
2
(d)
15
8
(c)
vertex is given by
(a) (a, 0)
(c) (a, 0)
96.
1
log5e
(d) loge5
e
91. If f(x) = xa log x and f(0) = 0, then the value of a
for which Rolles theorem can be applied in [0, 1]
is
(a) 2
(b) 1
(c) 0
(d) 1/2
(c)
p
2
sin 2 q d q
sin 4 q + cos 4 q
-1
(b) y = a tan ( x + y) + c
y
x
(c) y 1 - = tan + c
a
4
97. If
(b)
p
4
p
(d) p
2
94. Which of the following sums is correct?
(c)
(a)
(n + 1)! = e 1
n =1
(b)
(n + 2)! = e 2
n =1
(c)
n =1
(d)
1
e2 -1
=
(2n - 1)!
2e
1
(2n + 1)! =
n =1
e 2 - 2e
2e
(a) 1999
(c) 2001
is
(a) 0
dy
= a 2 is
dx
y+c
(a) x + y = a tan
a
(b) (0, a)
(d) None of these
98.
(b) 2000
(d) None of these
If sin -1 (1 - x ) = 2 sin -1 x +
(a) x = 0,
1
2
(b)
p
, then :
2
x=
1
2
(c) x = 0 only
(d) none of these
99. If a is a non-zero real number, then the vectors
uur
a = ai + 2aj - 3ak,
uur
10
101.
x 1 + x dx is equal to
(a)
21 3 4 8 / 7
+C
1 + x
32
(b)
32 3 4 8 / 7
+C
1 + x
21
(c)
7 3 4 8 / 7
+C
1 + x
32
1
[(n + 1)(n + 2)(n + 3)(n + 4) - 24]
5
(b)
1
(n + 1)(n + 2)(n + 3)(n + 4)(n + 5)
5
1
n(n + 1)(n + 2)(n + 3)(n + 4)
(c)
5
a2
2a 2
2a
(c) 2a
(b)
3a
(d)
5a
(a)
8
27
(b)
4
81
(c)
4
9
(d)
None
d2 y
dx
- 2a
dy
+ a 2 + b2 y =
dx
(a) 0
(c) a 2
110. The value of
(b) y
(b) b 2
p
2
p
2
p
log 2
2
is
(b) -
p
log 2
2
1
(c) p log
(d) none of these.
2
111. If A, B, C are the angles of a triangle then the
value of determinant
is
(a) p
(c) 2p
sin 2A
sin C
sin B
sin C
sin 2B
sin A
sin B
sin A
sin 2C
(b) 0
(d) None of these
11
112. The length of projection of the segment joining
P(1, 2, 0) and Q (1, 1, 2) on the plane
2x - y - 2z = 4 is
(a) 3
(b) 4
(c) 5
(d) 3 3
113. A square hole is punched out of a circular lamina
of diameter a. The diagonal of the square is equal
to the radius of the circle and one of the corners
is at the centre of the circle. The distance of the
C.G. of the remainder from the centre of the circle
is :
(a)
a
p+ 4
a
(c)
5p - 4
(b)
a
8p - 4
a
(d)
5p + 4
y2
+
= 1 with foci F and F . If A is the area
1
2
a 2 b2
of the triangle PF1F2, then the maximum value of
A is
(a) 2abe
(b) abe
1
abe
(d) None of these
2
117. Two cars started from a place, one moving due
north and the other due west with equal speed v.
The rate at which they were being separated from
each other is :
(c)
(a) 2v
(c)
(b)
2v
(d) v
2
118. Let A = {1,2,3,4,5,6,7,8} which of the following
relations from A to R is NOT a function?
(a) R1 = {( x, f ( x ) ) : x A, f ( x ) = 6 x + 7}
(b) R 2 = {( x, f ( x)) : x A, f ( x ) = | x | +9}
1
(c) R 3 = (x , f ( x )) : x A, f ( x ) =
2
x + 7
(d) R 4 = {( x, f ( x )) : x A, f ( x ) = 4x}
119. Let f : R R be such that f(1) = 3 and f ' (1) = 6.
1/ x
f (1 + x )
Then xlim
0
f (1)
equals
(a) 1
(b) e
(c) e 2
(d) e 3
120. The value of (2 w) (2 w2) (2 w10) (2 w11) is
(a) 49
(b) 16
(c) 16w
(d) 49w2
12
6.
R AB =
Q2
2Ae o
(c) C2 and C3 are parallel so V2 = V3
C1 and combination of C2 & C3 is in series.
So, V = V2 + V1 or V = V3 + V1
and also Q1 = Q2 + Q3
(d) When oil is placed between space of plates
2.
3.
C=
2 Ae 0
d
Ae 0
........(2)
d
on comparison both equation, weget
C' = C/2
(d) According to Gauss Law
4.
E.ds =
(c)
10W O 10W
10W
C
E
2
= = 1A
RAB 2
(a) We know from the Kirchhoff's first law that
the algebraic sum of the current meeting at
any junction in the circuit is zero (i.e. Si = 0)
or the total charge remains constant.
Therefore, Kirchhoff's first law at a junction
deals with the conservation of charge.
(b) E = V + ir
8.
9.
1.8
10
r r = W
5
9
(c) In the electrolysis of CuSO4 , oxygen is
liberated at anode and copper is deposited
at cathode.
10.
(b)
2.2 = 1.8 +
F 10W
10W
E
10W
11.
12.
2i i l
m
2 1 l l
F = 0 1 2 = 10 -7
4p
r
1
= 2 107 N/m.
[This relates to the definition of ampere]
(b) For circular path in magnetic field,
mrw2 = qvB
(a)
2
w =
10W
10W O
10W
10W
E 10W
= 10W +
n=
w
qB
n=
2p
2pm
L=
m Ni
Nf
; f = BA; B = 0
i
2R
10W
G
Equivalent
As v = rw
\ w2 =
F
A
qvB
mr
q(rw)B
qB
w=
mr
m
\ If n is frequency of roatation, then
Equivalent Circuit
10W
V 2 200 200
=
= 1000 W
P1
40
V 2 200 200
=
= 400 W
P2
100
\ R1 (for 40W) > R2 (for 100 W)
10W
G
R1 =
R2 =
= flux
7.
... (1)
KAe0
QC = d , if K = 2
3 6 18
=
= 2W
3+6 9
F=
Resistance of
circuit
20 20
+ 10 = 10 + 10 + 10 = 30W
20 + 20
13.
(c)
L=
m N2
N m 0 Ni
A L N2
A = 0
2R
i 2R
13
14.
20.
(b)
16.
NBA 50 2 10 2 10 2
t=
=
= 0.1 s
e
0. 1
(b) Mutual Inductance of two coils
21.
22.
18.
19.
Wavelength
[Range in m]
X-rays
1 1011 to 3 108
g-rays
6 1014 to 1 1011
Microwaves
103 to 0.3
Radiowaves
10 to 104
Wavelength of U.V. rays ranges from
6 108 to 4 107.
(d) Huygen's construction of wavefront does
not apply to origin of spectra which is
explained by quantum theory.
(d) Let the amplitude of the waves be a1, a2
and the intensities I1 and I2. The ratio of
this intensities is 16 : 9
1
1
v = RH 2 - 2
4
n
For Lyman series, electron jumps from
higher orbit to the first stationary orbit i.e.,
nf = 1
1
1
v = RH 2 - 2
1
n
For Paschen series, electron jumps from
higher orbits to third stationary orbit
(nf = 3)
I1 a12 16
Then I = 2 = 9
a2
2
23.
a1 4
=
a2 3
....(1)
24.
25.
1
1
v = RH 2 - 2
3
n
(a) All statements for ruby laser using flash
lamp is correct because it is a pulse laser,
three level laser as well as cooled effectively.
(c) A Febry Perot interferometer consists of two
plane parallel glass plates. With this
interferometer fringes of constant inclination
are obtained by transmitted light after
multiple reflection between the glass plate.
(b)
4a 2
3
I
\ max
I min
4a 2
+ a2
=
4a 2
- a2
I
49
\ max =
= 49 :1
Imin
1
Ek =
hc 1 1
(in eV)
e l l0
26.
2
13.6
= -3.4 eV
4
1
1
series v = R H 2 - 2
n
2
For Brackett series, the electron jumps from
higher orbits to fourth stationary orbit
(nf = 4)
(c) Rays
=-
17.
3
2
x + (t m) + y = x + (1.5t) + y = x + t + y
- (f 2 - f1 ) -( 0 - NBA ) NBA
=
=
t
t
t
15.
(b)
1
m n12 = 2 W0 - W0 = W0 and
2
1
m n 22 = 10 W0 - W0 = 9 W0
2
n
0
1
\ n = 9W = 3
2
0
14
27.
-13
28.
29.
30.
31.
= 1.6 10 Joules .
(d) Both are correct since the observers are
inertial. If they move with respect to each
other, they will always disagree.
(c) Forces between nucleons inside the
nucleus are
(i) attractive in nature
(ii) extremely short range
(iii) strongest forces in nature
(d)
300
=3
100
Now the number of atoms left after n halflives is
37.
38.
39.
40.
41.
42.
N
1
1
N = N0 = N0 = 0
2
2
8
Hence the number of nuclei which have
decayed in 300 years is
32.
(b) W
X
W
Y
33.
34.
35.
36.
7N0
N0 - N0 8 =
8
L1
(W + X)
L1
L
(W + Y) 3
(b)
(d) Positive terminal is at lower potential
(10V) and negative terminal is at higher
potential 0V.
(b)
(c) We know that for common base
a=
43.
44.
45.
46.
W + (X.Y)
i c collector current
=
= 0.98
i e emmiter current
a
0.98
0.98
=
=
= 49.
1 - a 1 - 0.98 0.02
(c) An antenna is a metallic structure used to
radiate or receive EM waves.
(c) Optical fibres are not subjected to
electromagnetic interference from outside.
(b) Core of acceptance angle
b=
2
2
3
1
1 H + 1 H 2 He + 0 n + 13 MeV
i c collector current
=
ib
base current
q = sin -1 n12 - n 22
(a) A vidicon is a type of camera.
(a) If DGsystem = 0 the system has attained
equilibrium is right choice.
In it alternative (d) is most confusing as
when DG > 0, the process may be
spontaneous when it is coupled with a
reaction which has DG < 0 and total DG is
negative, so right answer is (a).
(b) For the reaction
2 ZnS 2 Zn + S2 ; DG1 = 293 kJ ..........(1)
2 Zn + O2 ZnO ; DG2 = 480 kJ ..........(2)
S2 + 2 O2 2 SO2 ; DG3 = 544 kJ .........(3)
DG for the reaction
2 ZnS + 3 O2 2 ZnO + 2 SO2
can be obtained by adding equation (1),
(2) and (3)
DG = 293 480 544 = 731 kJ
Cr
4s0 3d4
Mn 4s0 3d5
Fe 4s0 3d6
For third Ionization enthalpy Mn has stable
configuration due to half filled d-orbital.
15
47.
(c)
56.
48.
49.
(b)
(b)
50.
(d)
51.
(c)
52.
(d)
N
Co
3+
en N
en
en
Co
53.
54.
Enantiomers
on both sides
55.
60
27
dx
st
1 order
log[a]
time t
59.
60.
Co +11 H
Thus X should be 60
28 Ni
(d) Age of geological formations (i.e. predicting
the age of the earth and rocks) is estimated
by U Pb method, also known as helium
dating.
(a , x) < k dt
i.e ln (a x) = kt + c or kt = ln a ln (ax)
or kt = 2.303 [log a log (a x)]
Thus if we plot a graph between log a & t
we get
l form
dx
< k(a , x)
dt
3+
1
[X ] +10 n 60
27 Co +1 H
60
1
28 X + 0
58.
[ B]3 .
N
N en
en
N
d form
en
57.
61.
Na +
+ l0
Cl -
= 126.45
....(1)
16
l0 + + l0
= 426.16 ...(2)
Cl-
l0
CH 3OO
67.
NaNO ,HCl
(c)
2
NH 2
0-5C
+ l0
= 91 ....(3)
Na +
NMe2
+ l0 +
Na
0(CH
3COOH)
62.
(d)
N 2 Cl
= 517.16 - 126.45
= 390.71ohm -1 cm 2
N=N
68.
0.0591
log 10 K
n
Here, n = 2, E = 0.295
E =
NO2
2 0.295
= 10 or K = 1010
0.0591
(d) In th e silver platin g of copper,
Aniline
65.
66.
NO2
Cu 2AgNO3
Cu(NO 3 ) 2 Ag
whereas in K[Ag (CN)2] solution a complex
anion [Ag(CN)2] is formed and hence Ag+
are less available in the solution and
therefore copper cannot displace Ag from
its complex ion.
(b) Given current (i) = 0.5 amp;
Time (t) = 100 minutes 60 = 6000 sec
Equivalent weight of silver nitrate (E) = 108.
According to Far aday's fir st law of
electrolysis
Eit
108 0.5 6000
=
= 3.3575 g.
96500
96500
(b) Order of reaction is independent of given
factors.
(b) Acetamide and ethylamine can be
distinguished by heating with NaOH
solution.Acetamide evolves NH3 but
ethylamine does not.
W=
CH 3CONH 2 + NaOH
CH 3COONa + NH 3
CH 3 CH 2 NH 2 + NaOH
No reaction.
NH2
Electrolytic reduction
(weakly acidic medium)
64.
NMe 2
\ log 10 K =
63.
NHOH
electrolytic
reduction in presence
of conc. H2SO4
NH2
rearrangement
OH
p-Hydroxyaniline
69.
70.
NO 2
Sn / HCl
Nitrobenzene
Aniline
Hence, option (a) is correct.
17
71.
SOCl
77.
(a)
OMgBr
|
CH3MgBr
C6 H5 COOC2 H5
C6 H5 - C - OC 2 H 5
|
CH3
O
||
- Mg(OC H )Br
Excess
2 5
C6 H5 - C - CH3
CH3MgBr
OMgBr
C6 H5
CH3
CH3
H2 O
C6 H5 C CH3
|
CH3
OH
CH3
|
Con. H 2SO 4
Ozonolysis
C 6 H 5 C = CH 2
D
'B'
C 6 H 5COCH 3 + HCHO
3I + 4 NaOH
78.
72.
(CH3)3 COH
8[O]
O
O
||
||
CH 3 C - OC 2 H 5 + H - CH 2 - C - OC 2 H 5
O
O
||
||
CH 3 - C - CH 2 - C - OC 2 H 5
CH3COCH3+CO2+2H2O
CH3COOH+2CO2+3H2O
(ethyl acetoaceta te )
79.
O
CH2CH3
CCH3
73.
(b)
Zn-Hg/HCl
Phenyl methyl
ketone
74.
75.
B 2H 6
CH3 CH=CH2
NaOH / H 2 O 2
B 2H 6
CH3CH2CH2OH
aOH / H 2 O 2
76.
(b)
2 3
CO + 2H 2
CH3OH
300C
ethyl
benzene
C 6 H 5 COCH 3 2
CHI 3
(a) It is an example of Claisen condensation.
The product is acetoacetic ester.
Propanol
COONa
2HCOONa |
360
COONa
sod.formate
+ H2
Compressed gas
80.
81.
Methyl alcohol
Br / KOH
(c)
R - CONH 2 2
RNH 2
This is known as Hoffmanns Bromamide
reaction.
(a) For the given A.P., we have
sin (z + x y) sin (y + z x) = sin
(x + y z) sin (z + x y)
2 cos z sin (x y) = 2 cos x sin (y z)
18
82.
(b)
tan -1 2x + tan -1 3x =
-1
tan
Now, slope of PS is m1 =
= 1 6x 2 + 5x - 1 = 0
1 - 6x 2
1
or 1
6
Now for x = 1, LHS of equation becomes
(6 x - 1)( x + 1) = 0 x =
85.
1
.
6
(a) The given equation is
negative, so x =
83.
at - a
2t
2
t -1
a ( t 2 - 1)
-0
( t 2 - 1)
t
==
-a -a
2t
Since m1m2 = 1, therefore PQ subtends a
right angle at the focus.
(c) Obviously the well (W) must be on one
side of the trees T1, T2,......., T25,
W
5m
T1
2a 2 x 2 + 2ancx + (n 2 - 2)c 2 = 0
It has real roots, So
5m
T2
T3...................T24
T25
D 0 (2anc) - 4 2a (n - 2)c 0
n 2 - 2(n 2 - 2) 0
= 10 + ( 2 10 + 5) + (2 15 + 5) + ............ + to 25 terms
[Q 4a 2 c 2 is positive]
n 2 - 4 0 (n + 2)(n - 2) 0
\ - 2 n 2 n [-2, 2]
+
2
ty = -a + at 2 y =
86.
24
[2 25 + ( 24 - 1) 10] = 10 + 12 [50 + 230 ] = 3370
2
2
2
2
(b) Let f (x, y, z) = ax + by + cz - 1 = 0 and
2 n 2
= 10 +
f( x, y, z ) = lx + my + nz = 0
df
df
= 0 and
=0
dx
dx
But
df f f dy f dz
=
+ . + .
dx x y dx z dx
or
0 = 2ax + 2by
or
ax + by
dy
dz
+ 2cz
dx
dx
dy
dz
+ cz
=0
dx
dx
Similarly from
2 at)
P (a t1 , 2
x+a=0
84.
2at - 0
and slope of QS is m2
2 x + 3x
= tan - 1 1
1 - 2 x.3x
5x
p
4
.....(1)
df
= 0,
dx
dy
dz
+n
=0
dx
dx
.....(2)
Solve (1) and (2) by the method of crossmultiplication,
we obtain, l + m
O
a ( t 2 - 1)
Q - a ,
dz
dy
1
dx
dx
=
=
bny - cmz c lz - anx amx - bly
dy c lz - anx
dz amx - bly
\ dx = bny - cmz and dx = bny - cmz
19
87.
1
B
2 = 2 = 8
\ tan B =
B 15 15
1 - tan 2
2 16
2 tan
ac
a +c
2
90.
(c)
a n + cn
> a n cn
Since A.M. > G.M.
2
a n + cn
>
2
( ac )n > b n
(Using (i))
(a) I =
91.
(t
- 2 t 5 + t 7 dt =
1
1 1
1
.
. =
log e 5 log e e e e log e 5
(d) For Rolles theorem in [a, b], f(a) = f(b), In
[0, 1] f(0) = f(1) = 0
Q the function has to be continuous in
[0, 1]
1 4 2 6 1 8
t - t + t +c
4
6
8
a
f (0) = lim f ( x ) = 0 lim x log x = 0
x 0+
1
1
1
sin 4 x - sin 6 x + sin 8 x + c
4
3
8
ALTERNATE :
lim
(1 - t
)t (- dt ) = (t
5
- t 5 dt =
1
1
cos 8 x - cos 6 x + c
8
6
[Not that this result is in terms of powers
of cos x]
89.
(b)
x -a
x 0
=0
x 0
lim
t
t
- +c
8
6
log x
x 0
1
1
1
.
. -0
log e 5 log e x x
j' (e) =
sin 3 x. cos 5 x dx
log e (log e x )
- log 5 (log e 3)
log e 5
\ j' ( x) =
a n + c n > 2b n
88.
loge x
If j(x) = log 5 log 3 x = log 5
log e 3
x 0
92.
(c)
93.
I=
tan
B 1
=
2 4
=0
2sin q cos q d q = dt
(s - a )(s - c) 1
B 1
=
tan 2 =
s(s - b)
16
2 16
- ax - a-1
- xa
= 0a >0
a
[b 2 - (c - a ) 2 = (b + c - a ) (b - c + a )
1/ x
dt
t 2 + (1 - t)2 2t 2 - 2t + 1
0
dt
1
dt
2 1 2 1 2
0 t
+
2 2
p
,t= 1
2
20
1
1
t-
1 1
-1
2 = tan -1 2t - 1
= . tan
1
1 0
2 1
2 0
2
94.
p p p
-- =
4 4 2
Tn = 1 + 3! + 5! + ...... = 2 (e - e -1)
97.
Tk = (k - 1)(k + 1)!+2(k )!
= (k + 2 - 3)(k + 1)!+ 2(k)!
= (k + 2)!- 3(k + 1)!+ 2(k)!
2
y1
- 2ax 1
or yy1 2ax =
Since it passes through the focus (a, 0)
2
0 2a2 = y1 - 2ax 1 or
2
y1
- 2a ( x 1 - a ) = 0
Thus, the locus of the mid point (x1, y1) is
y2 = 2a (x a), which is a parabola whose
vertex is (a, 0).
dy dz
=
(a) Put x + y = z 1 +
dx dx
The equation then becomes
dz
a 2 z2 + a 2
dz
z 2 - 1 = a 2
= 1+ 2 =
dx
z
z2
dx
dz = dx
z2 + a 2
Integrating we get
z2
z2 + a 2
dz =
dx + D
z
=z-x-D
a
z2
a2
z
tan - 1 = x + D
a
a
Tk = (k 2 + 1)k!= (k 2 - 1 + 2)(k )!
96.
] dz = x + D
y+c
x + y = a tan a , where c = -D
(a) The general term
e2 - 1
=
2e
(a) The equation of the parabola is y2 = 4ax...(1)
Let (x1, y1) be the mid point of a focal chord
of the parabola.
Equation of chord having (x1, y1) as its mid
point is
z2 + a 2
z
z-x-D
a = tan
a
n =1
95.
a2
-1
a tan
1
(c) We have, Tn = (2n - 1)!
[1 -
z-
Tk = T1 + T2 + T3 + ........... ..... + Tm
k =1
(c)
2 sin -1 x = sin -1 (1 - x ) -
p
p
2a = b 2
2
b = sin -1 (1 - x ) sin b = 1 - x
p
2
1 - 2 sin 2 a = sin b 1 - 2x 2 = 1 - x
1
2
Only x = 0 satisfies the given equation.
x (2x - 1) = 0 x = 0 or x =
21
99.
(d) We have
a
2a
- 3a
[ a b g ] = 2a + 1 2a + 3 a + 1
3a + 5
a +5
a+2
S (ae, 0) X
x=
31 1259
= 15a a + +
0
30
900
100. (c)
4/3
= x 7 x 1 / 3 dx =
21 6
z dz
4
21 z 8
7
21
3
x 1 + x 4 dx = z z 6 dz =
+C
4
4 8
21 3 4 8 / 7
+C
=
1 + x
32
= kx k +1
\ 5x k = kx k +1 - (k - 1)x k
= f( k + 1) f(k)
where f(k) = (k 1)xk
n
So, Sn =
k =1
1
xk =
5
[f (k + 1) - f (k)]
k =1
1
1
= [f (n + 1) - f (1)] = [nx n +1 - 0.x1 ]
5
5
x2
a
e
y2
x cos a + y sin a
= 0 ....(i)
2
2
p
a
2a
1 cos 2 a 1
sin 2 a
+ 2
=0
p 2 2a 2
p2
a
1
a
1
2a
1
p2
\ p 2 = 2a 2 p = 2 a
\ The equation of the chord is
x cos a + y sin a = 2a
Which is the equation of straight line always
2a .
cos x dx
d 2
x cos x dx dx
dx
= x 2 cos x dx -
22
= ( x 2 - 2) sin x + 2x cos x + c
f ( x ) = x 2 - 2, g( x ) = 2x
105. (c) Chord PQ is normal to the parabola at Q
and is equation is
y = mx 2am am3
...(1)
P
8
4
4 4 36 4
+ + +
=
= .
27 81 81 81 81 9
[Q The probability of winning the game if
2
2
=
1+ 2 3
and the probability of winning the game if
1
1
= ].
1+ 2 3
90
2am + am3
or m (2 + m2) y2 + 4xy 4mx2 = 0 ...(2)
p
, th e sum of the
2
coefficients of x2 and y2 in (2) must be zero.
m (2 + m2) 4m = 0 or m (m2 2) = 0
dx
= a (- sin q + sin q + q cos q) = aq cos q
dq
and
dy
= a (cos q - cos q + q sin q) = aq sin q,
dq
dy dy / dq
=
= tan q
dx dx / dq
So, the slope of the normal is
\
1
= - cot q, which varies as q.
dy / dx
The equation of the normal at any point is
y - a(sin q - q cos q)
-
Sin ce POQ =
As m 0, we get m2 = 2 or m = 2 .
x cos q + y sin q = a.
Clearly, it is a line at a constant distance | a
| from the origin.
Further, the equation x cosq +y sin q = a
represents the equation of a tangent to the
circle x2 + y2 = a2 for any value of q, which
is a fixed circle.
Thus, m = 2 .
106. (c) Let W stand for the winning of a game and
L for losing it. Then there are 4 mutually
exclusive possibilities
(i) W, W, W
(ii)
W, W, L, W
(iii) W, L, W, W
(iv)
L, W, W, W.
[Note that case (i) includes both the cases
whether he losses or wins the fourth game.]
By the given conditions of the question,
the probabilities for (i), (ii), (iii) and (iv)
respectively are
2 2 2 2 2 1 1 2 1 1 2
. . ; . . . ; . . .
3 3 3 3 3 3 3 3 3 3 3
and
1 1 2 2
. . . .
3 3 3 3
109. (a) If y = e
Then,
ax
sin(bx + c)
....(i)
dy
= ae ax sin( bx + c) + b cos( bx + c)e ax
dx
= ay + be ax cos( bx + c)
....(ii)
23
2
Again d y = a dy + b.aeax cos (bx + c)
dx
dx 2
- b2 eax sin(bx + c)
dy
dy
=a
dy
- (a 2 + b 2 )y
dx
= 2a
d2 y
dx
- 2a
2 sin A cos A
sin C
sin B
sin C
2 sin B cos B
sin A
sin B
sin A
2 sin C cos C
dy
+ (a 2 + b 2 )y = 0
dx
I = log sin x dx
cos A sin A 0
sin A cos A 0
p
2
110. (b)
...(i)
p
2
p
2
= log sin - x dx =
2
p
2
p/2
log
p
2
sin 2 x
dx
2
p
2
| MP |=
;
| NQ |=
p
2
| 2(-1) - 2 - 0 - 4 |
2 2 + (-1) 2 + (-2) 2
| 2.1 - (-1) - 2.2 - 4 |
2
2 + (-1) + (-2)
8,
3
5
3
Also
Put 2 x = t 2dx = dt
| PQ |= (1 + 1) 2 + (-1 - 2) 2 + (2 - 0) 2 = 17
2I =
p
1
log sin t dt - log 2
2
2
0
1
.2
2
p
2
1 2
1
113. (b) The area of the circle is p a = p a
4
2
\| NM |=| QR |= PQ 2 - RP 2 = 17 - 1 = 4 .
p
p
log 2 I = - log e 2
2
2
G2 O
G1
24
If x be side of square, then diagonal is
(x 2 + x 2 ) =
1
a given.
2
117. (b) Let the two cars move from O, one towards
north and the other
due west with equal speed v.
N
1
\ x = a 2 = area of square
8
2
Also OG1 =
11 1
a = a .
22 4
W B vt
1 2 1 2
Area of remainder = p a - a .
4 8
Taking moments about O, we get
dx
.
dt
From the right angled DAOB we have
AB2 = OA2 + OB2
a .
8p - 4
114. (a) The given quantity is of the form
nn (n + 1)n 1, where n = 1000
n
n (n + 1)
Now, nn (n + 1)n 1 = n n +1
\ OG 2 =
= nn -
n
1 +
n +1
or x 2 = (v.t) 2 + (v.t) 2 = 2v 2 t 2 ;
or x = 2v 2 t 2 = 2.v.t.
1
k
n
= n 1
n
n
+ 1
dx
= 2 v. which is constant.
dt
Hence the two cars separated from each
\
1
Where k = 1 + , which lies between 2
n
and 3
118. (d)
k
< 1 if n > 2
n +1
\ nn (n + 1)n 1 > 0 if n > 2
115. (a) a = 0, b = 1
a + b = Max (0, 1) = 1
116. (b) Let P (a cos q, b sin q)
P(acos q, bsin q)
1
2
a cos q b sin q 1
1
ae
0
1 = 2ae b sin q
2
- ae
0
1
= abe | sin q |
\
2 v.
In case of R1 , f ( x) = 6x + 7
clearly every element of A has a unique
image hence, R1 represents a function.
Similarly, R2 and R3 also represent
functions.
In case of R4, f (x) = 4x
\ every element of A has two unequal
images for example f(1) = 4, f(2) = 8, etc.
\ R4 is not a function
1/ x
119. (c)
F2 (-ae, 0) F1(ae, 0)
a2 a2
a a2 a
p
- .OG 2 = x 2 . =
.
4
8
4 8 4
A
vt
f (1 + x)
lim
x 0 f (1)
1 f (1+ x) -f (1)
lim
x
f (1)
x
0
=e
f '(1)
f (1)
=e
= e2
120. (a) w10 = w9.w = w, w11 = w9.w2 = w2
\ (2 w) (2 w2) (2 w10) (2 w11)
= (2 w)2 (2 w2)2
Now x3 1 = (x 1) (x w) (x w2),
dividing by x 1
\ x2 + x + 1 = (x w) (x w2)
or (x2 + x + 1)2 = (x w)2 (x w2)2.
Put x = 2, we get (2 w)2 (2 w2)2 = (7)2 = 49