Professional Documents
Culture Documents
H2 CHEMISTRY 9647
Ans: B
Paper 1
Multiple Choice Questions
Worked Solutions
1
0
m
1
2
2 1.0mol
M
2.0
V
22.4
nO2 2
2
2 2.0mol
Vm
22.4
A:
11
6
B:
111
53
C:
76
35
Br
76
36
D:
76
35
Br
75
35
I 111
52Te , is not a process of this sort
Ans: C
y
y
C x H y x O2 xCO2 H 2O
4
2
,
,x=3
nCx H y VCx H y
1 10
p 10 e
Ans: A
2
1
1
(expelled from
m 35.5
0.5mol
M 71.0
D: nO atoms
nucleus)
B: nCH3CO2 H c V 11 1.0mol
However, since ethanoic acid is a weak
acid, nH = nCH 3CO2 H
C: nCl2
,
4 45 ,
nCx H y
VCx H y
1
10
y
y
3 4.5 , 4.5 3 1.5
4
4
y 1.5 4 6
Ans: A
5
Page 1 of 23
C: False statement.
More energy is released when CaCl2(s) is
formed from its elements, and that is the
reason why CaCl2(s) will be formed
instead of CaCl(s).
D: True statement.
q q
Since L.E.
, the lattice energy
r r
energy
Ca(s) + Cl2(g)
Hf {CaCl(s)}
Hf {CaCl2(s)}
CaCl(s)
CaCl2(s)
(lower energy
more stable)
Ans: D
7
Ca2+(g) + 2Cl(g)
Ca+(g) + 2Cl(g)
Ca(g) + 2Cl(g)
Ca(g) + Cl2(g)
Ca(s) + Cl2(g)
H2nd ionisation(Ca)
2H1st E.A.(Cl)
Ca2+(g) + 2Cl(g)
H1st ionisation(Ca)
HB.E.{ClCl}
L.E.{CaCl2(s)}
Hatom{Ca(s)}
Hf {CaCl2(s)}
CaCl2(s)
A: Correct
Eo values should be measured under
standard conditions of 298 K, 1.0 atm
pressure, and using solutions containing
1.0 mol dm3 of the aqueous ions.
B: Correct
The cell e.m.f. should be measured using
a high resistance voltmeter, so as to
ensure that the electrical current flowing in
the circuit is essentially zero, and that the
voltmeter measures the maximum
potential difference.
C: Not correct
For the standard hydrogen electrode,
[H+] should be 1.0 mol dm3. In a solution
containing 1.0 mol dm3 of H2SO4, the [H+]
is 2.0 moldm3.
D: Correct
By comparing the Eo values of the two
half-reactions involved, it can be deduced
that Zn will be oxidised to Zn2+ in Cell 1.
Zn2+ + 2e Zn
2H+ + 2e H2
B: True statement.
Since less energy is required to ionise
Ca(g) to form Ca+(g), we would expect
Page 2 of 23
Eo = 0.00 V
Eo = 0.76 V
11
soln)
Cu2+ + e Cu+
I2
oxidised
+ 2e 2I
Eo = + 0.15 V
E = +0.54 V
13
Ans: A
10
(conjugate base)
D: Not correct
MgO is only slightly soluble in water (due
to its high lattice energy), to form a slightly
basic solution (rather than an acidic
solution).
MgO(s) + H2O(l) Mg2+(aq) + 2OH(aq)
Ans: D
14
15
isomers
H
Cl
Cl Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl Cl
20
Cl Cl
Ans: B
Cl
Cl
Cl
Cl
Cl
Ans: C
Cl
21
Cl Cl
Cl Cl
Cl
Cl
Cl Cl
benzene ring.
Structure of T is therefore:
Ans: C
I
18
3n 1
O2 nCO2 + (n+1)H2O
2
CnH2n+2 +
22
23
OH
Ans: B
Ans: B
19
Cl
Since halogenoarenes is unreactive, only the
Cl atom will be hydrolysed by NaOH(aq)
under reflux. Hence, the final product
obtained is:
O
OH
CH2OH
OH
B: False
Cortisone does not contain the COCH3
or CH(OH)CH3 structure
C: True
The three ketone functional groups in
cortisone will undergo reduction with
NaBH4 (methanol is the solvent) to form a
product with 5 hydroxyl (alcohol) groups.
OSO3H
CH3
HO
OH OH
CH3
CH2OH
C
H
HO
D: False
The primary alcohol functional group in
cortisone will be oxidised to a carboxylic
acid, while the alkene functional group will
undergo oxidative cleavage with hot
acidified KMnO4 to form a product with 4
carbonyl groups
CH3
OH O
C
CO2H
CH3
O
Ans: A
CO2H
O
25
OH O
CH3
Ans: A
24
CH3
A: False
Only the alkene functional group in
cortisone will undergo mild oxidation with
cold dilute KMnO4 to form a product with 4
hydroxyl (alcohol) groups.
Page 6 of 23
2: Correct
Evaporation causes the solvent to change
from liquid to gas. This change in state
increases the disorderliness in the system
(positive S).
Ans: A
28
3: Correct
The movement of solvent molecules from
the pure solvent through the semipemeable membrane to the solution
during osmosis increases the number of
ways of arranging solvent molecules in
the solution which will lead to an increase
in entropy (positive S).
29
Ans: A
33
Ans: C
nM
3.01 x 10 -3 3
1.00 x 10-3 1
O
N
Ans: D
31
Ans: A
30
1: Correct
Dissolving the solute in the solvent
Increases the number of ways of
arranging molecules in the solution which
will lead to an increase in entropy
(positive S).
1: Correct
Recall that for clock experiment, Rate 1/
t, and letting the rate equation be:
rate = k [L]a [M]b [N]c,
- Comparing expt 1 & 2, no change in rate
even though [L] is varied
zero order wrt L.
- Comparing experiment 2 & 3,
1
rate2 k [M ]2b [N ]2c 0.05b
176
b
c
b
1
rate3 k [M ]3 [N ]3
0.10
44
b2
1: Correct
At constant T, average K.E. remains
constant
2: Correct
pV = nRT Mr = mRT/pV
Since p, V and T are constant,
Mr(S) : Mr(T) = m(S) : m(T)
= 0.5 g : 2.5 g
=1:5
1
rate3 [N ]3c 0.05c
44
1
rate4 [N ]4c 0.10c
22
c 1
3: Wrong
Since n = pV/RT and p, V and T are
constant, n is constant and hence no. of
molecules is constant for X and Y.
Ans: B
Page 7 of 23
2: Correct
Rearranging the rate equation:
rate mol dm 3s 1
k
mol 2dm 6 s 1
[M ]2 [N ] (mol dm 3 )3
3: Wrong
Rate = k[M]2[N] = k[N] where k = k[M]2
t = ln 2 / k = ln 2 / k[M]2
Hence t of reaction is dependent on [M].
1: Correct
Hhyd of cation q+/r+
Since ionic radius of M2+ increases down
the group, Hhyd of M2+ becomes less
exothermic (decreases in magnitude).
2: Wrong
Reducing power of M Ease of removal
of electrons. Since atomic radius of M
increases down the group, valence
electrons are more easily removed
Down the group the elements are
stronger reducing agents
3: Wrong
The atomic radius of the elements
increases down the group due to the
increase in number of principal quantum
shell of electrons (the increase in
screening effect outweighs the increase in
nuclear charge)
2: Correct
Ethanol reacts with Na(s) to give H2 gas
3: Correct
Ethanoic acid reacts with Na2CO3(aq) to
give CO2 gas
Ans: C
40
Ans: D
36
1: Wrong
Phenol does not react with PCl5(s) to give
white fume of HCl due to partial double
bond character of C-O bond in phenol.
1: Correct
Only carboxylic acid in compound U will
react with NaOH(aq). Hence, 1 mol of U
(which has only one COOH group) will
react exactly with 1 mol of NaOH(aq).
2: Correct
LiAlH4 will reduce both ketone and
carboxylic acid in compound A to produce
a compound with 4 chiral centres. This will
give 24 = 16 stereoisomers.
38
1: Correct
The electron rich nucleophile, OH
substituted the Br-atom in the
bromoalkane.
2: Wrong
The type of reaction is reduction
3: Correct
The type of reaction is electrophilic
substitution
Ans: D
1: Correct
Two ions (formed by the reaction of
ethanol and sulfuric acid in step 1) are
reacting in the slow step which
corresponds to 2nd order reaction.
2: Correct
H2SO4 is used up in the first step, and
regenerated in the second step of the
mechanism - the characteristic of a
catalyst
3: Wrong
2-methylpropan-2-ol is a tertiary alcohol
and is more likely to undergo dehydration
Page 8 of 23
3: Correct
Oxidative cleavage of the two alkene
functional groups occurs with hot acidified
KMnO4 to give a product having four
CO2H groups
Ans: A
Page 9 of 23
Question 1
(a)
(b)(i)
2 0.05
100% 2.22%
4.50
The percentage error in the measurement of the titre volume is relatively significant / high, as
the volume of hydrochloric acid required to react with FA1 is too small, as the concentration of
hydrochloric acid in FA1 is too high.
(ii)
In the trial experiment, the amount of hydrochloric acid required to react completely with 25.0 cm 3
of FA1, nHCl 0.200 4.50 103 9.00 104 mol
Since the concentration and volume of Ca(OH) 2 used in the actual titration is the same as that in
the preliminary test, the amount of hydrochloric acid needed to neutralise Ca(OH) 2 is the same.
For a titre reading of about 30 cm3, [ HCl ]FA 2
9.00 104
0.0300moldm 3
30 103
7.50 103
0.0375dm3 37.5cm3
0.200
Or
Since the titre volume in the preliminary test is 4.5 cm 3, for a titre volume of around 27 cm 3 (= 4.5
cm3 x 6) in the actual titration, the concentration of hydrochloric acid in FA2 needs to be one-sixth
that of the stock solution.
[ HCl ]FA 2
1
0.200 0.0333moldm 3 .
6
1
250 41.67cm3
6
A. Preparation of FA2
1. Fill a burette with the stock solution of hydrochloric acid. Drain 37.50 cm3 of the hydrochloric
acid from the burette into a 250 cm3 volumetric flask. Top-up the volumetric flask up to the
mark with de-ionised water. Add the last few drops of de-ionised water using a dropper till the
bottom of the meniscus coincides with the mark.
2. Stopper the volumetric flask firmly and invert it 10 to 15 times to ensure complete mixing.
This is to ensure that a homogeneous solution is obtained.
B. Titration of FA1 against FA2
1. Fill a clean burette with FA2 solution. Pipette 25.0 cm3 of FA1 into a clean conical flask.
2. Add 2 or 3 drops of methyl orange / bromothymol blue / cresol red indicator and add
around 25 cm3 of the FA2 solution from the burette quickly to the contents in the conical flask
with constant swirling, and then drop-wise as the titration is near the end-point.
3. Stop the titration immediately when the first drop of FA2 solution added turns the solution from
yellow to orange / blue to green / reddish purple to yellow.
4. Repeat the titration until two accurate titre readings fall within 0.10 cm 3 of each other are
obtained
Page 10 of 23
(ii)
[Ca(OH ) 2 ]FA1 2
My mol dm 3
3
25.0 10
50
Since [Ca (OH ) 2 ]FA1
1
My mol dm 3 ,
50
1
1
1
My mol dm 3 and [OH ] 2 My My mol dm 3
50
50
25
2
1
1
5
3 3
3
9
Ksp = [Ca 2 ][OH ]2
My
My
3.2 10 M y mol dm
50
25
[Ca 2 ]
(e)
Both HCl and Ca(OH)2 are corrosive. Wear gloves / put on a laboratory coat / put on
goggles / use a dropper when handling the chemicals
Or
HCl is toxic. Use pipette filler when siphoning the required volume from the stock solution into
the pipette.
Or
HCl is corrosive. Wear goggles (when filling the burette) to prevent accidental spillage into the
eyes.
Question 2
Total Marks: 16, Average Mark: 6.8 (42.5%)
(a)
(b)(i)
(ii)
chemical parameters
Cl2(aq)
2.3
3.24 x 105
NH2Cl (aq)
2.0
3.88 x 105
PO43
0.012
1.26 x 107
0.006
1.08 x 107
50
360 180dm3
100
number of moles Cl2 present = 3.24 105 180 5.83 103 mol
number of moles NH2Cl present = 3.88 105 180 6.98 10 3 mol
number of moles of S2O32 to react with Cl2 =
1
5.83 103 1.46 103 mol
4
1.54dm3
0.010
0.010
Page 11 of 23
(d)(i)
(ii)
(e)(i)
Fe
Fe2+
In the presence of water ligands, the degenerate d-orbitals of Fe 2+ / Fe3+ are split into two sets of
different energy levels.
When light is shone on the complex, an electron from the lower energy d-orbital of Fe 2+ / Fe3+ will
absorb photons of wavelength / frequency in the visible light region and be promoted to the higher
energy d-orbital.
Colours not absorbed (complementary colour) will form the observed colour of the complex.
Cl2 is a stronger oxidising agent than Br2 and so it is able to displace Br from the solution to form
Br2.
(ii)
chlorine, Cl2
bromine, Br2
in water
in hexane
colourless
orange / reddish-brown
(iii)
(iv)
source
Al3+
Na+
(b)(i)
Al and Al+ have the same nuclear charge due to both having same number of protons but Al+ has a
lower shielding effect due to a lower number of electrons.
More energy is required to overcome the stronger net attractive force between the nucleus and
valence electron of Al+ than Al.
Hence the 2nd IE of Al is higher than the 1st IE.
Page 12 of 23
(c)(i)
pH
7
6.5
2
1
NaCl
(ii)
MgCl2
AlCl3
PCl5
SiCl4
(d)
Aluminium fluoride has a giant ionic lattice structure with strong electrostatic forces of
attraction between Al3+ and F ions while aluminium chloride has a simple molecular structure
with weak instantaneous dipole-induced dipole interaction between the molecules
More energy is required to overcome the stronger ionic bonds in aluminium fluoride, thus it has a
higher melting point than aluminium chloride.
(e)(i)
(ii)
109
(iii)
The lone pair of electrons on N of (CH3)3N was donated to the empty 3p orbital of Al in AlH3 to
form a dative bond.
(a)(i)
Initial (mol dm3)
Change
0.95y
0.05y
0.95
y
2
0.95
y
2
0.95
y
2
0.95
y
2
As given in the question, equilibrium concentration of NO 2+ and NO3 are both 0.100 mol dm3,
0.95
0.100 2
0.2105moldm 3
y = 0.100, y =
2
0.95
Page 13 of 23
[ NO2 ][ NO3 ]
[0.1][0.1]
0.01
(iii)
NO2+ will undergo electrophilic substitution with the benzene ring (of phenol) to form nitrophenol.
As a result [NO2+] will decrease.
By Le Chateliers principle, the position of equilibrium will shift to increase the [NO 2+]. Hence, position
of equilibrium will shift right, favouring the forward reaction or the forward reaction will occur to
a greater extent, increasing the yield of NO3.
(b)
C
O
O
+
C
O
(c)(i)
+ H
H +
OH
. OH
(ii)
Intramolecular hydrogen bonding exist between the OH group and NO2 of 2-nitrophenol, hence
2-nitrophenol forms less extensive intermolecular hydrogen bonding with surrounding water
molecules compared to 4-nitrophenol.
Lesser energy is released to overcome the hydrogen bonding between water molecules and the
hydrogen bonding / van der Waals forces of attraction between 2-nitrophenol molecules.
(iii)
Since the nitro group is electron-withdrawing (or the nitrogen atom is electronegative), the negative
charge on the conjugate base of 4-nitrophenol is more dispersed compared to that of phenol
the conjugate base of 4-nitrophenol is more stable than that of phenol
4-nitrophenol has a greater tendency to dissociate to produce H + ions
4-nitrophenol is a stronger acid than phenol
pKa of 4-nitrophenol is lower than that of phenol.
reagent
compound
W, X, Y or Z
PBr3
Br
H
2,4-dinitrophenylhydrazine
NO2
O2N
Page 14 of 23
(b)(i)
Fehlings
reagent,
heat
acidified
K2Cr2O7(aq),
heat
O
-
electrophilic addition
(ii)
(iii)
2-methyl-2-phenylbutanoic acid
(iv)
H3C
CH2CH3
CH2CH3
CO2H
CO2H
CH3
mirror plane
(c)
sp2 hybridised
p-orbitals
Page 15 of 23
Question 1
(a)(i)
(ii)
[ H ]2
(3.63 10 2 ) 2
Or
K a1
[ H ]2 (3.63 102 ) 2
(iii)
(iv)
The anion of the salt formed (at the second equivalence point), SO 32, is a weak base, and
undergoes hydrolysis in water to produce OH.
Hence. pH at point C is greater than 7.
SO32 + H2O HSO3 + OH
(b)
Both Oleum and sulfuric acid have simple molecular structure and they are held by hydrogen
bonding between their respective molecules.
Oleum has much more electrons than sulfuric acid and hence has stronger instantaneous dipole
induced dipole (id-id) attraction than sulfuric acid.
re heat energy is required to overcome the stronger id-id attraction in oleum
higher melting point
(c)(i)
Standard enthalpy change of neutralisation is the heat change when one mole of water is
formed when an acid neutralises a base under standard conditions of 298 K and 1 atm.
(ii)
(d)(i)
OH H
1.26
25.2kJmol 1
0.0500
OH
CO2H
CH3
Page 16 of 23
(iii)
Nucleophilic Addition
NaCN
Na+ + CN
..
+
CN
Question 2
(a)
Upon the initial addition of NH3(aq) to the (light) blue solution, a (light) blue ppt will be formed.
Upon addition of an excess of NH3(aq), the light blue ppt dissolves to give a dark blue solution.
(light) blue solution Cu2+(aq) or [Cu(H2O)6]2+(aq)
(light) blue ppt Cu(OH)2(s) or Cu(H2O)4(OH)2(s)
dark blue solution [Cu(NH3)4]2+(aq) or [Cu(NH3)4(H2O)2]2+(aq)
(b)
(Since O2 is acting as a Bronsted base, it will be able to abstract a proton from the solvent, in this
case, NH3).
O2 + NH3 OH + NH2 (or CuO + 5NH3 [Cu(NH3)4]2+ + OH + NH2)
The colour of the solution would be dark blue (due to the [Cu(NH3)4]2+ complex)
(c)
(d)
H2O
..
90o
HO:
HO :
Cr
..
H2O
.OH
.
: OH
: OH
Cr
Or
HO :
:OH
..
OH
109o
octahedral
tetrahedral
Page 17 of 23
COOH
(e)
NH3
V
CH=CH 2
NH2
U
CH2CH2OH
NH2
T
CH2COOH
+
NH3
S
O
C
H2C
NH
R
O
Question 3
(a)(i)
(ii)
Page 18 of 23
C N C C N
H
H C
C
H
H
C
H
H
H
H H
O
O
(iii)
..
Hydrogen bond
(b)(i)
The quaternary structure of a protein is the association of more than one polypeptide chains to
form a three-dimensional structure that confers the biological function to the protein. The
structure is stabilised by instantaneous dipole - induced dipole interactions between nonpolar R-groups, hydrogen bonds between polar uncharged R-groups, ionic interactions
between oppositely charged R-groups and disulphide linkages between SH groups of two
cysteine residues. Haemoglobin consists of 4 polypeptide chains, 2 -subunits and 2 subunits which are wound to give a spherical shape. Each polypeptide chain is linked noncovalently to a haem group containing Fe2+ ion.
(ii)
Valine contains a non-polar alkyl group that forms instantaneous dipole - induced dipole
interactions while glutamic acid contains a negatively charged COO group (at pH = 7) that
forms ionic interactions.
The hydrophobic side-chain of valine is able to interact with the non-polar patch on the surface
of another haemoglobin molecule, causing the haemoglobin molecules to aggregate.
(c)(i)
COOH
COOH
COOH
CONH2
(ii)
(iii)
(ii)
Fe + 2HCl FeCl2 + H2
Sn + 2HCl SnCl2 + H2
To precipitate out Fe2+ as Fe(OH)2(s) - precipitate R
Or
To facilitate the separation of Fe2+ and Sn2+ (as Sn2+ will form a soluble complex in excess NaOH)
(iii)
(iv)
nFe2O3
3.20
3.20
0.02005mol
2(55.8) 3(16.0) 159.6
0.36
100% 13.9%
2.60
Question 4
(a)
(b)(i)
(ii)
x
xx
x
x
or
x
x
x
N xx O
(iii) For N2(g) + O2(g) N2O(g), entropy decreases (or S < 0) as there is a decrease in number of
moles of gas (from 1 moles to 1 mole)
Using Go = Ho TSo, since H > 0 (given in question) and S < 0,
G > 0 at all temperatures
The reaction is not energetically feasible
(c)(i)
2N2O(g)
O2(g)
2N2(g)
pinitial / kPa
25.0
pchange / kPa
+x
+x
ptotal / kPa
25.0 x
Page 20 of 23
PT PN O PN PO
2
p 0.5x x
p 1.5x
p 1.5(2p 50.0)
75.0 2p kPa
(ii)
25.0
27.5
30.0
32.5
34.0
35.0
1030
2360
4230
5870
7420
25.0
20.0
15.0
10.0
7.0
5.0
partial
(iii) pressure of N2O / kPa
time / s
From the graph since 1st t = 3200 s = 2nd t, the order of reaction with respect to N2O is 1.
(must show 2 consecutive t on the graph)
(iv)
ln 2
2.17 10 4 s 1
t1
2
(d)(i)
H3NCH2CH2CH2CH2NH3+
The salt formed is ionic with strong electrostatic forces of attraction between the oppositely charge
ions. The salt is thus non-volatile and does not vapourise easily and is odourless.
Page 21 of 23
Question 5
(a)(i)
(ii)
(iii)
(iv)
(b)(i)
(ii)
(iii)
(iv)
Using z = 5,
ln K c
5 96500 0.73
142.23
8.31 298
As the value of the Kc is very large, the equilibrium lies towards the right and the reaction is
effectively complete.
Cathode: 2H2O + 2e H2 + 2OH or 2H+ + 2e H2
Q = 0.30 (20 60) = 360 C
No. of moles of e transferred = 360 96500 = 3.73 103 mol
No. of moles of OH liberated = 3.73 103 mol
[OH] = (3.73 103) 0.450 = 8.29 103 mol dm3
Page 22 of 23
High temperature
At high temperature, the gas particles possess high kinetic energy such that they have sufficient
energy to overcome the intermolecular forces of attractions between them. Hence, the
intermolecular forces between the gas particles are insignificant and negligible.
Low pressure
At low pressure, the gas particles are far apart from one another and so they have negligible
volume as compared to the volume of the container. (In addition, the intermolecular attractions
between the gas particles are also insignificant and negligible since they are very far apart.)
Page 23 of 23