Jimbo

3M Scotchkote Epoxy Coating 172 (Part B)
Safety Data Sheet

Copyright, 2014, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior
written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the
intention of earning a profit thereon.
33-1665-0
Document group:
08/07/2014
Revision date:
Transportation version number: 3.00 (08/07/2014)
Version number:
Supersedes date:
4.00
07/07/2014
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Product Identification Numbers
GR-2001-4602-9
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Coating.
1.3. Details of the supplier of the substance or mixture
3M United Kingdom PLC, 3M Centre, Cain Road, Bracknell, Berkshire, RG12 8HT.
Address:
Telephone: +44 (0)1344 858 000
tox.uk@mmm.com
E Mail:
www.3M.com/uk
Website:
1.4. Emergency telephone number
+44 (0)1344 858 000
SECTION 2: Hazard identification

2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Acute Toxicity, Category 4 - Acute Tox. 4; H302
Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318
Skin Corrosion/ Irritation, Category 1A - Skin Corr. 1A; H314
Skin Sensitization, Category 1A - Skin Sens. 1A; H317
For full text of H phrases, see Section 16.
__________________________________________________________________________________________
Page: 1 of 16
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Indication of danger
Harmful; Xn; R20/22
Corrosive; C; R35
Sensitizing; R43
For full text of R phrases, see Section 16.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
DANGER!
Symbols:
GHS05 (Corrosion) | GHS07 (Exclamation mark) |
Pictograms
Ingredient
Benzyl Alcohol
3-aminomethyl-3,5,5-trimethylcyclohexylamine
m-phenylenebis(methylamine)
3-morpholinopropylamine
3,6,9-Triazaundecamethylenediamine
HAZARD STATEMENTS:
H302
H312
H332
H314
H317
CAS Nbr
100-51-6
2855-13-2
1477-55-0
123-00-2
112-57-2
% by Wt
10 - 25
1 - 15
1 - 15
1 - 10
<1
Harmful if swallowed.
Harmful in contact with skin.
Harmful if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
PRECAUTIONARY STATEMENTS
Prevention:
P260
P280D
Response:
P303 + P361 + P353
P305 + P351 + P338
P310
P333 + P313
Do not breathe dust/fume/gas/mist/vapours/spray.

Wear protective gloves, protective clothing, and eye/face protection.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
Immediately call a POISON CENTRE or doctor/physician.
If skin irritation or rash occurs: Get medical advice/attention.
59% of the mixture consists of components of unknown acute oral toxicity.

83% of the mixture consists of components of unknown acute dermal toxicity.
63% of the mixture consists of components of unknown acute inhalation toxicity.
Contains 63% of components with unknown hazards to the aquatic environment.
__________________________________________________________________________________________
Page: 2 of 16
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbol(s)
Corrosive
Contains:
Benzyl Alcohol; 3-aminomethyl-3,5,5-trimethylcyclohexylamine; m-phenylenebis(methylamine)
Risk phrases
R20/22
R35
R43
Safety phrases
S23C
S51
S36/37/39B
S26
S28C
S45
Harmful by inhalation and if swallowed.

Causes severe burns.
May cause sensitisation by skin contact.
Do not breathe vapour or spray.
Use only in well ventilated areas.
Wear suitable protective clothing, gloves, and eye and face protection.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After contact with skin, wash immediately with plenty of water for 15 minutes.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
Notes on labelling
Industrial Label.
2.3. Other hazards
Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. May cause
chemical gastrointestinal burns.
SECTION 3: Composition/information on ingredients

Ingredient
2-Propenenitrile, reaction products with
ethylenediamine, hydrogenated, reaction
products with benzaldehyde,
diethylenetriamine and triethylenetetramine,
hydrogenated
Benzyl Alcohol
3-aminomethyl-3,5,5trimethylcyclohexylamine
CAS Nbr
EU Inventory % by Wt
1173092-7410 - 50
4
Classification
100-51-6
Xn:R20-22 (EU)
2855-13-2
EINECS 202859-9
EINECS 220666-8
10 - 25
1 - 15
Acute Tox. 4, H332; Acute Tox.

4, H302 (CLP)
C:R34; Xn:R21-22; R43; R52/53
(EU)
4, H302; Skin Corr. 1B, H314;
Skin Sens. 1A, H317; Aquatic
Chronic 3, H412 (CLP)
1,3-Benzenedimethanamine, N-(2-
404362-22-7
1 - 15
__________________________________________________________________________________________
Page: 3 of 16
phenylethyl) derivs.
1477-55-0
EINECS 216032-5
1 - 15
T:R23; C:R35; Xn:R22; R43;

R52/53 (Self Classified)
4, H302; Skin Corr. 1A, H314;
Skin Sens. 1, H317; Aquatic
Chronic 3, H412 (Self
Classified)
Fatty acids, tall-oil, reaction products with

tetraethylenepentamine
68953-36-6
123-00-2
112-57-2
EINECS 273201-6
EINECS 204590-2
1 - 10
1 - 10
EINECS 203- < 1

986-2
C:R34 (Vendor)
Xn:R21 (Self Classified)
Skin Corr. 1B, H314 (Vendor)
Acute Tox. 4, H312 (Self
Classified)
C:R34; Xn:R21-22; N:R51/53;
R43 (EU)

4, H302; Skin Corr. 1B, H314;
Skin Sens. 1, H317; Aquatic
Chronic 2, H411 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate
medical attention. Wash clothing before reuse.
Eye contact
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.
If swallowed
Rinse mouth. Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures

__________________________________________________________________________________________
Page: 4 of 16
5.1. Extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance
Carbon monoxide.
Carbon dioxide.
Oxides of nitrogen.
Condition
During combustion.
During combustion.
During combustion.
5.3. Advice for fire-fighters

No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and
could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Place in a metal container approved for use
in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum
liner made of polyethylene. Clean up residue with an appropriate solvent selected by a qualified and authorised person.
Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Seal the
container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage

7.1. Precautions for safe handling
For industrial or professional use only. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on
clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing
should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse.
Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Store away from strong bases. Store away from oxidising
agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
__________________________________________________________________________________________
Page: 5 of 16
personal protection recommendations.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full face shield.
Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Polymer laminate
Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective
clothing material(s) are recommended: Coveralls - Disposable, laminate
Rubber boots.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Liquid.
Physical state
Viscous liquid
Specific Physical Form:
ammoniacal odour, Amber, N/A
Appearance/Odour
__________________________________________________________________________________________
Page: 6 of 16
Odour threshold
pH
Boiling point/boiling range
Melting point
Flammability (solid, gas)
Explosive properties
Oxidising properties
Flash point
Autoignition temperature
Flammable Limits(LEL)
Flammable Limits(UEL)
Vapour pressure
Relative density
Water solubility
Solubility- non-water
Solubility- non-water
Partition coefficient: n-octanol/water
Evaporation rate
Vapour density
Decomposition temperature
Viscosity
Density
9.2. Other information
Volatile organic compounds (VOC)
Percent volatile
No data available.
No data available.
200 C [Test Method:Estimated]
No data available.
Not applicable.
Not classified
Not classified
100 C [Test Method:Closed Cup]
350 C [Test Method:Estimated]
No data available.
No data available.
1.3 Pa [Test Method:Estimated]
1.01 g/cm3 [Test Method:Tested per ASTM protocol] [Ref
Std:WATER=1]
Negligible
No data available.
Not applicable.
No data available.
No data available.
No data available.
No data available.
No data available.
1.01 g/ml
1.4 g/l [Details:(On Part A and B mix)]
0%
SECTION 10: Stability and reactivity

10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Avoid curing large quantities of material to prevent a premature reaction (exotherm) with production of intense heat and
smoke.
10.5 Incompatible materials
Amines.
Strong bases.
Strong oxidising agents.
10.6 Hazardous decomposition products
Substance
None known.
Condition
Refer to section 5.2 for hazardous decomposition products during combustion.

__________________________________________________________________________________________
Page: 7 of 16
SECTION 11: Toxicological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Harmful if inhaled. Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache,
hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Skin contact
May be harmful in contact with skin.
Corrosive (skin burns): Signs/symptoms may include localised redness, swelling, itching, intense pain, blistering, ulceration,
and tissue destruction. Allergic skin reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering,
and itching.
Eye contact
Corrosive (eye burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.
Ingestion
Gastrointestinal corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and
diarrhea; blood in the faeces and/or vomitus may also be seen. May cause target organ effects after ingestion.
Target Organ Effects:
Single exposure may cause:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Additional information:
Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name
Overall product
Route
Dermal
Overall product
InhalationDust/Mist(4
hr)
Ingestion
InhalationDust/Mist
(4 hours)
Ingestion
Overall product
Benzyl Alcohol
Benzyl Alcohol
Species
Value
No data available; calculated ATE2,000 - 5,000
mg/kg
No data available; calculated ATE1 - 5 mg/l
Rat
No data available; calculated ATE300 - 2,000 mg/kg

LC50 8.8 mg/l
Rat
LD50 1,230 mg/kg
__________________________________________________________________________________________
Page: 8 of 16
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Dermal
Ingestion
Dermal
Rat
Rat
LD50 > 2,000 mg/kg

LC50 estimated to be 1 - 5 mg/l
Rat
Rabbit
Rat
LD50 1,030 mg/kg

LD50 > 2,000 mg/kg
LC50 0.8 mg/l
Rat
Rabbit
Rat
LD50 980 mg/kg

LD50 1,214 mg/kg
LD50 3,560 mg/kg
LD50 estimated to be > 5,000 mg/kg
Ingestion
Dermal
Ingestion
LD50 estimated to be 2,000 - 5,000 mg/kg

Rabbit
Rat
LD50 660 mg/kg

LD50 2,140 mg/kg
Species
Multiple
animal
species
official
classifica
tion
Rat
Value
Mild irritant
Species
Rabbit
Rabbit
Rabbit
Value
Severe irritant
Corrosive
Corrosive
Species
Human
and
animal
Guinea
pig
Guinea
pig
Value
Some positive data exist, but the data are not
sufficient for classification
Species
Value
Name
Benzyl Alcohol
Benzyl Alcohol
Route
In vivo
In Vitro
In Vitro
In vivo
In Vitro
In vivo
Value
Not mutagenic
Some positive data exist, but the data are not
sufficient for classification
Not mutagenic
Not mutagenic
Not mutagenic
Not mutagenic
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name
Benzyl Alcohol
Corrosive
Corrosive
Serious Eye Damage/Irritation

Name
Benzyl Alcohol
Skin Sensitisation
Name
Benzyl Alcohol
Sensitising
Sensitising
Respiratory Sensitisation
Name
Germ Cell Mutagenicity
Carcinogenicity
Name
Benzyl Alcohol
Route
Ingestion
Species
Multiple
animal
species
Value
Not carcinogenic
__________________________________________________________________________________________
Page: 9 of 16
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name
Route
Value
Species
Test result
Benzyl Alcohol
Ingestion
Not toxic to development
Mouse
Ingestion
Not toxic to female reproduction
Rat
Ingestion
Not toxic to male reproduction
Rat
Ingestion
Rat
Ingestion
Not toxic to female reproduction
Rat
Ingestion
Not toxic to male reproduction
Rat
Ingestion
Rat
NOAEL 550
mg/kg/day
NOAEL 160
mg/kg/day
NOAEL 160
mg/kg/day
NOAEL 250
mg/kg/day
NOAEL 450
mg/kg/day
NOAEL 450
mg/kg
NOAEL 450
mg/kg/day
Exposure
Duration
during
organogenesis
90 days
90 days
during
gestation
1 generation
1 generation
1 generation
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name
Route
Target Organ(s)
Value
Species
Benzyl Alcohol
Inhalation
Benzyl Alcohol
Inhalation
central nervous
system depression
respiratory irritation
Benzyl Alcohol
Ingestion
mphenylenebis(methylamine
)
Inhalation
central nervous
system depression
May cause drowsiness or

dizziness
Some positive data exist, but the
data are not sufficient for
classification
May cause drowsiness or
dizziness
May cause respiratory irritation
Inhalation
Test result
Exposure
Duration
NOAEL Not
available
NOAEL Not
available

classification
Not
available
NOAEL Not
available
LOAEL
0.002 mg/l
NOAEL Not
avaliable
Rat
2 weeks
Specific Target Organ Toxicity - repeated exposure

Name
Route
Target Organ(s)
Value
Species
Test result
Benzyl Alcohol
Ingestion
NOAEL 400
mg/kg/day
Ingestion
Mouse
NOAEL 645
mg/kg/day
8 days
Ingestion

classification
classification
classification
Rat
Benzyl Alcohol
endocrine system |
muscles | kidney
and/or bladder
nervous system |
respiratory system
Rat
NOAEL 160
mg/kg/day
13 weeks
mphenylenebis(methylamine
)
Ingestion

classification
Rat
NOAEL 600
mg/kg/day
28 days
hematopoietic
system | liver |
kidney and/or
bladder
endocrine system |
blood | bone
marrow
Exposure
Duration
13 weeks
Aspiration Hazard
Name
Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information

__________________________________________________________________________________________
Page: 10 of 16
The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.
12.1. Toxicity
No product test data available.
Material
3,6,9Triazaundecam
ethylenediamin
e
3,6,9Triazaundecam
ethylenediamin
e
3,6,9Triazaundecam
ethylenediamin
e
3,6,9Triazaundecam
ethylenediamin
e
3,6,9Triazaundecam
ethylenediamin
e
3aminomethyl3,5,5trimethylcyclo
hexylamine
hexylamine
hexylamine
hexylamine
Fatty acids,
tall-oil,
reaction
products with
CAS Nbr
112-57-2
Organism
Ricefish
Type
Experimental
Exposure
96 hours
Test endpoint Test result

LC50
>70 mg/l
112-57-2
Green Algae
Experimental
72 hours
EC50
0.12 mg/l
112-57-2
Water flea
Experimental
48 hours
EC50
13 mg/l
112-57-2
Green Algae
Experimental
72 hours
NOEC
0.018 mg/l
112-57-2
Water flea
Experimental
21 days
NOEC
0.14 mg/l
2855-13-2
Green algae
Experimental
72 hours
EC50
50 mg/l
2855-13-2
Water flea
Experimental
48 hours
EC50
17.4 mg/l
2855-13-2
Golden Orfe
Experimental
96 hours
LC50
110 mg/l
2855-13-2
Water flea
Experimental
21 days
NOEC
3 mg/l
68953-36-6
Data not
available or
insufficient for
classification
__________________________________________________________________________________________
Page: 11 of 16
tetraethylenepe
ntamine
3123-00-2
morpholinopro
pylamine
1,3Benzenedimeth
anamine, N-(2phenylethyl)
derivs.
2Propenenitrile,
reaction
products with
ethylenediamin
e,
hydrogenated,
reaction
products with
benzaldehyde,
diethylenetria
mine and
triethylenetetra
mine,
hydrogenated
mphenylenebis(
methylamine)
mphenylenebis(
methylamine)
mphenylenebis(
methylamine)
mphenylenebis(
methylamine)
mphenylenebis(
methylamine)
Benzyl
Alcohol
Benzyl
Alcohol
Benzyl
Alcohol
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
404362-22-7
1173092-74-4
Data not
available or
insufficient for
classification
1477-55-0
Water flea
Experimental
48 hours
EC50
15.2 mg/l
1477-55-0
Green Algae
Experimental
72 hours
EC50
28 mg/l
1477-55-0
Ricefish
Experimental
96 hours
LC50
87.6 mg/l
1477-55-0
Green Algae
Experimental
72 hours
NOEC
9.8 mg/l
1477-55-0
Water flea
Experimental
21 days
NOEC
4.7 mg/l
100-51-6
Water flea
Experimental
48 hours
EC50
360 mg/l
100-51-6
Algae
Experimental
96 hours
EC50
640 mg/l
100-51-6
Fathead
minnow
Experimental
96 hours
LC50
460 mg/l
Study Type
BOD
Test result
0 % weight
Protocol
OECD 301D - Closed
bottle test
12.2. Persistence and degradability

Material
CAS Nbr
3,6,9112-57-2
Triazaundecam
ethylenediamin
e
Test type
Duration
Experimental 28 days
Biodegradation
__________________________________________________________________________________________
Page: 12 of 16
32855-13-2
aminomethyl3,5,5trimethylcyclo
hexylamine
Fatty acids,
68953-36-6
tall-oil,
reaction
products with
tetraethylenepe
ntamine
3123-00-2
morpholinopro
pylamine
1,3Benzenedimeth
derivs.
2Propenenitrile,
reaction
products with
ethylenediamin
e,
hydrogenated,
reaction
products with
benzaldehyde,
diethylenetria
mine and
triethylenetetra
mine,
hydrogenated
mphenylenebis(
methylamine)
Benzyl
Alcohol
Biodegradation
BOD
0 % weight
OECD 301C - MITI

test (I)
Data not
N/A
available or
insufficient for
classification
N/A
N/A
N/A
Data not
N/A
available or
insufficient for
classification
Data not
N/A
available or
insufficient for
classification
N/A
N/A
N/A
N/A
N/A
N/A
1173092-74-4
Data not
N/A
available or
insufficient for
classification
N/A
N/A
N/A
1477-55-0
Biodegradation
CO2 evolution 49 % weight
OECD 301B Modified sturm or CO2
100-51-6
Biodegradation
BOD
94 % weight
OECD 301C - MITI

test (I)
Test type
Duration
Data not
N/A
available or
insufficient for
classification
BCF-Carp
Study Type
N/A
Test result
N/A
Protocol
N/A
Bioaccumulati <3.4
on factor
Other methods
Data not
available or
N/A
N/A
404362-22-7
12.3 : Bioaccumulative potential

Material
3,6,9Triazaundecam
ethylenediamin
e
hexylamine
Fatty acids,
tall-oil,
CAS Nbr
112-57-2
2855-13-2
68953-36-6
N/A
N/A
__________________________________________________________________________________________
Page: 13 of 16
reaction
products with
tetraethylenepe
ntamine
3morpholinopro
pylamine
1,3Benzenedimeth
derivs.
2Propenenitrile,
reaction
products with
ethylenediamin
e,
hydrogenated,
reaction
products with
benzaldehyde,
diethylenetria
mine and
triethylenetetra
mine,
hydrogenated
mphenylenebis(
methylamine)
Benzyl
Alcohol
insufficient for
classification
123-00-2
Estimated
Bioconcentrati
on
Data not
N/A
available or
insufficient for
classification
Bioaccumulati 2.34
on factor
Estimated:
Bioconcentration factor
N/A
N/A
N/A
1173092-74-4
Data not
N/A
available or
insufficient for
classification
N/A
N/A
N/A
1477-55-0
Experimental
BCF-Carp
Bioaccumulati <2.7
on factor
100-51-6
Experimental
Bioconcentrati
on
404362-22-7
42 days
Log Kow
1.10
OECD 305E Bioaccumulation flowthrough fish test

Other methods
12.4. Mobility in soil

Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during
incineration processes. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
__________________________________________________________________________________________
Page: 14 of 16
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of
3M, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/EC
and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are
complied with and always use a licensed waste contractor.
EU waste code (product as sold)
08 01 11*
Waste paint and varnish containing organic solvents or other dangerous substances
SECTION 14: Transportation information

GR-2001-4602-9
ADR/RID: UN2735, POLYAMINES, LIQUID, CORROSIVE, N.O.S., LIMITED QUANTITY, (ISOPHORONE
DIAMINE), (M-PHENYLENEBIS(METHYLAMINE), 8, III, (E), ADR Classification Code: C7.
IMDG-CODE: UN2735, POLYAMINES, LIQUID, CORROSIVE, N.O.S., (ISOPHORONE DIAMINE), (MPHENYLENEBIS(METHYLAMINE), 8., III, IMDG-Code segregation code: 18- ALKALIS, EMS: FA, SB.
ICAO/IATA: UN2735, POLYAMINES,LIQUID,CORROSIVE,N.O.S., (ISOPHORONE DIAMINE), (MPHENYLENEBIS(METHYLAMINE), 8., III.
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact 3M for more information. The components of this product are in compliance with the chemical notification
requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information

List of relevant H statements
H302
H311
H312
H314
H317
H331
H332
H411
H412
Toxic in contact with skin.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Toxic if inhaled.
Harmful if inhaled.
Toxic to aquatic life with long lasting effects.
Harmful to aquatic life with long lasting effects.
List of relevant R-phrases

R20
Harmful by inhalation.
R20/22
Harmful by inhalation and if swallowed.
R21
R22
R23
Toxic by inhalation.
R34
Causes burns.
R35
Causes severe burns.
__________________________________________________________________________________________
Page: 15 of 16
R43
R51/53
R52/53
May cause sensitisation by skin contact.

Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Revision information:
Revision Changes:
Section 14: Transportation classification information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
3M United Kingdom MSDSs are available at www.3M.com/uk
__________________________________________________________________________________________
Page: 16 of 16

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3M Scotchkote Epoxy Coating 172 (Part B)

Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the

SECTION 2: Hazard identification

3M Scotchkote Epoxy Coating 172 (Part B)

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Do not breathe dust/fume/gas/mist/vapours/spray.

59% of the mixture consists of components of unknown acute oral toxicity.

3M Scotchkote Epoxy Coating 172 (Part B)

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Harmful by inhalation and if swallowed.

SECTION 3: Composition/information on ingredients

Acute Tox. 4, H332; Acute Tox.

3M Scotchkote Epoxy Coating 172 (Part B)

T:R23; C:R35; Xn:R22; R43;

Fatty acids, tall-oil, reaction products with

EINECS 203- < 1

Acute Tox. 3, H311; Acute Tox.

SECTION 4: First aid measures

SECTION 5: Fire-fighting measures

3M Scotchkote Epoxy Coating 172 (Part B)

5.1. Extinguishing media

5.3. Advice for fire-fighters

SECTION 6: Accidental release measures

SECTION 7: Handling and storage

3M Scotchkote Epoxy Coating 172 (Part B)

personal protection recommendations.

SECTION 8: Exposure controls/personal protection

SECTION 9: Physical and chemical properties

3M Scotchkote Epoxy Coating 172 (Part B)

SECTION 10: Stability and reactivity

Refer to section 5.2 for hazardous decomposition products during combustion.

3M Scotchkote Epoxy Coating 172 (Part B)

SECTION 11: Toxicological information

No data available; calculated ATE300 - 2,000 mg/kg

LD50 1,230 mg/kg

3M Scotchkote Epoxy Coating 172 (Part B)

LD50 > 2,000 mg/kg

LD50 1,030 mg/kg

LD50 980 mg/kg

LD50 estimated to be 2,000 - 5,000 mg/kg

LD50 660 mg/kg

ATE = acute toxicity estimate

Serious Eye Damage/Irritation

Germ Cell Mutagenicity

3M Scotchkote Epoxy Coating 172 (Part B)

Not toxic to development

Not toxic to female reproduction

Not toxic to male reproduction

Not toxic to development

Not toxic to female reproduction

Not toxic to male reproduction

Not toxic to development

May cause drowsiness or

Some positive data exist, but the

Specific Target Organ Toxicity - repeated exposure

Some positive data exist, but the

Some positive data exist, but the

SECTION 12: Ecological information

3M Scotchkote Epoxy Coating 172 (Part B)

Test endpoint Test result

3M Scotchkote Epoxy Coating 172 (Part B)

12.2. Persistence and degradability