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INTRODUCTION
CHEMICAL
REACTION??
Reaction occurred.
How??
Color change
Formation of a solid (precipitate) within
a clear solution
Evidence of a gas
Evolution or absorption of heat
Reaction type??
Combination reaction A + B AB
Decomposition reactions AB A + B
Displacement reactions
AB + C AC + B
be
very,
very
slow
i.e.
Sewage
CONCENTRATION
OVER TIME
RATE LAW/
RATE OF EQUATION
dCi
rate Unit SI is mol L-1s-1
dt
aA +bB cC + dD
For relative rate of reactions, various species that involved in
reaction can be obtained from stoichiometric coefficient:
rA rB rC rD
a
b
c
d
A+ 2B C + D
4 moles of A reacted with 8 moles of B to produce 4
moles of C and 4 moles of D
HOMOGENEOUS
HETEROGENEOUS
ELEMENTARY
NONELEMENTARY
A+ B R
The rate of disappearance of A is given by
-rA = kCA CB
Such reaction is called ELEMENTARY REACTION
CHE594: CHEMICAL REACTION ENGINEERING
Rate of
expression
Consistent unit!!
Change temp. in
Kelvin
Insert EQ. 1
and 2
1 dN A
V dt
dN A rAVdt
rA
NA
dN
N A0
rA2
rA1
t
N A 1
rA
V
t
1
rA C A0 C A
t
A0
t1
2
A0
CA
t1
N A0 rAVt
A0
CA
rAV dt
1
C A0 C A
rA2
t2
1
rA1
C A0 C A
t1
rA2
rA1
t1
t2
rA kCA
k k0 e
rA2
k 2 k0 e RT2
rA1 k1 k e E RT1
0
RT
rA2
rA1
rA2
rA1
k 2C A
k1C A
k2
k1
rA2
ln
rA
1
rA2
ln
rA
1
RT2
E RT2 E RT1
e
ln
E RT1 ln e
ln e
E
E
RT2
RT1
rA2
ln
rA
1
E 1 1
R T1 T2