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National School of Public Health, Department of Sanitary Engineering and Environmental Health, Athens, Greece
Tel. +30 (210) 6466064; Fax+30 (210) 6400198; email: skoyz2002@yahoo.gr
b
School of Civil Engineering, cSchool of Chemical Engineering,National Technical University of Athens, Greece
Abstract
One of the most important tasks at any water treatment plant is safeguarding the quality of drinking water.
Worldwide, the drinking-water sector is increasingly aware of the limitations of end-product testing for ensuring
safety. One limitation is the steady increase in the number of potentially occurring pathogens and chemicals that
need to be monitored. A further limitation is the delayed availability of results in relation to the timing of interventions
needed to maintain the safety of a supply. Ensuring the safety of a supply requires monitoring not only of the
finished drinking-water, but particularly of parameters which indicate whether the key control measures in a given
process are functioning correctly. Preventative measures have therefore become very important. The Hazard Analysis
Critical Control Points system (HACCP) is a food safety management system which uses the approach of controlling
critical points in food and drink production, and the framework of its concept consists of 7 principles. According to
the Council Directive 93/43/EEC and the recent Regulation (EC) No 852/2004 on the hygiene of foodstuffs, the
application of HACCP in food production is obligatory. In the present work, the HACCP principles were applied to
the Aspropyrgos Water Treatment Plant. The critical control points identified include filtration and chemical
disinfection.
Keywords: HACCP; Drinking water
1. Introduction
Drinking water may be produced from a variety of sources, for instance, surface or groundwa*Corresponding author.
Presented at the 9th Environmental Science and Technology Symposium, September 13, 2005, Rhodes, Greece.
Organized by the Global NEST organization and prepared with the editorial help of the University of Aegean,
Mytilene, Greece and the University of Salerno, Fisciano (SA), Italy.
0011-9164/07/$ See front matter 2007 Published by Elsevier B.V.
doi:10.1016/j.desal.2006.05.039
139
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ing system, the critical limits of CCPs monitoring parameters as well as the necessary corrective actions.
Critical limits have been set according to legislation (The Council Directive on the Quality of
Surface Water intended for the abstraction of
drinking water 75/440/EEC [13] and the Current
Drinking Water Directive 98/83/EC [1]), operating procedures and performance targets of the
plant.
3. Results and discussion
In hazard analysis emphasis was given to
events, incidents or situations that could lead to
hazards being introduced into or not being removed from the water [5]. Risk assessment is the
key to the entire process -identifying risks, assessing their significance and the controls in the
system that manage those risks in a systematic
fashion- starting from the catchment and working down. A flow diagram of the Aspropyrgos
Water Treatment Plant was drawn up as depicted
in Fig. 1 [14]. At each step in the process, the
potential hazard to water quality and the controls
to prevent the hazard entering the water were identified [15]. A semi-qualitative risk assessment of
Aspropyrgos Water Treatment Plant was applied
and a simplified example is given in Table 1. It is
noted that the water treatment plant is not responsible for the quality of water coming from the
catchment area. The CCPs are determined going
through the decision tree of the method [15]. The
conceptual approach is shown in Fig. 2. An application of the CCP decision tree on the catchment area and the post-chlorination process is
depicted in Table 2.
The application of preparatory activities and
the principles of HACCP resulted in the HACCP
plan, part of which is described in Table 3 [15].
The HACCP plan includes the process steps of
the treatment, the identified hazards, the preventative measures, the determined critical control
points, a monitoring system, the critical limits of
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CCPs monitoring parameters as well as the necessary corrective actions. In this case only the
CCPs are examined.
The catchment area, Mornos Lake, is itself
considered a CCP, in spite of the existence of preventative measures, for those microbiological and
chemical hazards which the plant cannot manage
[15]. During the pre-chlorination procedure, optimization of the dose of chlorine is necessary so
as to avoid the formation of THMs, without affecting the disinfectant efficiency. This is achieved
when trace levels of residual chlorine are present
at the filters outlet. Filtration is a CCP, because it
is the last step for the removal of inorganic sub-
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Table 1
Example of risk assessment
Microbiological
hazards from
catchments
D Controls in
catchment
Bacteria, viruses,
protozoa
D Risk
E.g. security of
protected
catchments
D Controls in water
supply system
D Residual risk
Coagulation/ filtration
(CCP) disinfection
(CCP)
Must be acceptable
prior to
consumption
Table 2
Application of CCP decision tree
Process step
Hazard
Q1
Q2
Q3
Q4
CCP
Catchment area
Post-chlorination
Microbiological
Microbiological
Yes
Yes
No
Yes
Yes
No
Yes
Yes
stances and small flocs, and since efficient filtration is dependent upon the procedures which precede it, in assessing the efficiency of the filtration process it is requisite/ desirable that the turbidity at the sedimentation tank outlet be no
greater than 1.5 NTU and at the filters outlet no
greater than 0.2 NTU. Post-chlorination is the last
step for the elimination of microorganisms and is
a preventative measure against recontamination
in the distribution network. The storage of treated
water and the distribution system are CCPs due
to the risk of recontamination and regrowth. Recontamination must be prevented by adequate
construction, by maintaining positive hydrostatic
pressure at all times and by hygiene precautions
due to the possibility of chemical and microbiological recontamination. During treatment and
storage, there are many on-line sensors with remote monitoring in a control room working continuously.
4. Conclusions
The HACCP system provides a mechanism for
ensuring that the appropriate corrective action is
taken in the event of any failure. This could range
Distribution
Storage of treated
water
Post-chlorination
Filtration
Coagulation/
flocculation/
sedimentation
Chemical
Microbiological
Regrowth, re-contamination
Chemical
Overdose, formation of THMs
Microbiological
Recontamination
Chemical
Poor floc formation and
removal of inorganic
substances
Chemical
Inorganic constituents, filter
defects
Microbiological
Survival of pathogens
Microbiological
Algae growth, pathogens,
bacteria, viruses, protozoa
Chemical
Heavy metals, pesticides,
PAHs, PCBs, solvents,
fertilizers
Chemical
Overdose, formation of
disinfection by-products
(THMs)
Microbiological
Viruses, protozoan oocysts
Catchment area
(Mornos Lake)
Pre-chlorination
Hazards
Process step
In accordance with
75/440/EEC
In accordance with
75/440/EEC
Total coliforms
Residual chlorine Height of
water
Total coliforms Pressure in
system POPER >1bar
In accordance with
98/83/EEC
In accordance with
98/83/EEC
Rechlorination-Isolate part
of system
Isolate part of system
Replacement
Chemical analysis
Change of dose
Dilution
Isolate reservoir
Rechlorination
Optimization of
coagulation/ sedimentation
procedure
Emergency chlorination
after storage tank
Inspection
On-line measurements
Turbidity < 0,2 NTU at
filters outlet
Particle counts Pressure loss
On-line monitoring
Optimize dose and contact time Residual concentration of
chlorine: 0.45-0,6ppm
Bacteriological indicator
organisms
Careful chlorination
THMs < 100g/l
Frequent analysis
On-line measurements of
turbidity and pH
Optimizing coagulant,
coagulant-aid dose and mixing
conditions
Post chlorination
Measurement of flow
On-line residual chlorine at
filters outlet
On-line measurements of
turbidity and pH
Corrective actions
Monitoring procedure
Optimizing coagulant,
coagulant-aid dose and mixing
conditions
Preventive measures
Table 3
Principles of HACCP applied to Water Treatment Plant in Aspropyrgos
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