Max Marks:360

KEY SHEET

Physics :
1) 3

2)

3)

4)

5)

6)

7)

11) 1

12) 2

13) 2

14) 2

15) 3

16) 2

17) 2

21) 2

22) 2

23) 4

24) 2

25) 3

26) 3

8)

9)

10) 1

18) 2

19) 4

20) 2

27) 4

28) 1

29) 2

30) 1

Mathematics :
31) 2

32) 2

33) 1

34) 1

35) 4

36) 4

37) 1

38) 3

39) 2

40) 1

41) 2

42) 2

43) 3

44) 3

45) 4

46) 2

47) 1

48) 4

49) 1

50) 2

51) 1

52) 3

53) 3

54) 3

55) 3

56) 2

57) 1

58) 2

59) 4

60) 1

61)1

62) 1

63) 1

64) 4

65) 3

66) 2

67) 4

68) 2

69) 3

70) 1

71) 1

72) 3

73) 1

74) 4

75) 3

76) 1

.i

Chemistry :
78) 3

79) 2

80) 1

81) 4

82) 1

83) 3

84) 1

85) 3

86) 1

87) 2

88) 2

89) 1

90) 1

te

ps

77) 1

SOLUTIONS
Assuming that ionization occurs as a result of a completely inelastic collision, we can write
mv0 m mH u

ud

1.

ys

PHYSICS

ww
w

.s
t

Where m is the mass of incident particle mH the mass of hydrogen atom v0 the initial velocity of
incident particle and u the final common velocity of the particle after collision. Prior to collision the
KE of the incident particle was
mv 2
E0 0
2
The total kinetic energy after collision
m mH u 2

m 2 v02
E

2
2 m mH
The decrease in kinetic energy must be equal to ionization energy.
mH
E1 E0 E
E0
m mH
E1
mH

E0 m mH
i.e, greater the mass m, the smaller the fraction of initial kinetic energy that be used for ionizartion.
PD 2V
q 10 C
In the first case

i.e,

2.
3.

Point P is an antinode i,e the string is vibrating in its second harmonic. Let f 0 be the fundamental
frequency. Then
2 f 0 100 Hz
f 0 50 Hz
Now P is an antinode (at length l / 4 from one end) so centre should be a node. So, next higher
frequency will be sixth harmonic or 6 f 0 which is equal to 300 Hz as shown below:

4.

Given that v1 v2

Therefore, if v1 makes an angle of with horizontal than v2 will make an

angle 900 900 with horizontal. Now horizontal component of velocity remains unchanged.
Therefore

ps

.i

v1 cos v2 sin
v
3
Or tan 1
v2 4

Now minimum kinetic energy will be

1
1
4
2
K min m v1 cos 2 3 5.76 J
2
2
5
Weins displacement law is

ww
w

6.

.s
t

ud

ys

te

Or 37 0

mT b ( b Weins constant)

b 2.88 106 nm K
m
T
2880 K
1000 nm
Energy distribution with wavelength will be as follows:
From the graph it is clear that
U 2 U1 (in fact U 2 is maximum)

7.

1 1 1

F f1 f 2
1
1
1 1
1
1 1 2 1

F
R
R
mv
v
r 0 0
B0 q B0

Or
8.

1 2
R

.i

will be
3B0

ps

Therefore, x, co-ordinate of particle at any time t

te

v
3 v0

3 v0

0
v0 t
0 t
cos 60

2 B0
2 B0 2 3B0
3B0
Free body diagram of the two bodies are as follows

.s
t

ud

ys

11.

R
1 2

x
3

sin
r
2
600
T

tOA
6 3B0

Or F

ww
w

Let acceleration of both the blocks towards left is a, then

f 2 20 f
a

Or 2 f 4 20 f
Or f 8 N
2
4
Maximum friction between the two blocks can be: m 2kg

f max mg 0.5 2 10 10 N

12.

13.

Now since f f max

Therefore, friction force between the two blocks is 8 N
In the circuit diode D1 is forward biased, while D2 is reverse biased. Therefore current i (through
6
0.02 A
D1 and 100 resistance) will be ; i
50 100 150
Here, 50 is the resistance of D1 in forward biasing.
Mi

d M di

d 4
2A
M 2
Further d M di 2 1 2Wb
During fusion binding energy of daughter nucleus is always greater than the total binding energy of
the parent nuclei. The difference of binding energies is released. Hence
Or di

14.

15.

In perfectly inelastic collision between two particles linear momentum is conserved. Let be the
angle between the velocities of the two particles before collision. Then
p 2 p12 p22 2 p1 p2 cos
2

v
2
2

Or 2m mv mv 2 mv mv cos
2

1
Or 1 1 1 2 cos
Or cos
2
16.

1
Here, Z1 R

V
V
i 0 and i2 0
Z1
Z2 ;
As Z 2 Z1 i1 i2
tan

1
And Z 2 R

2C
2

y 2 2

2
x
2

1
2

tan
2
1

cot
2
2
2
900

i.e, E is along positive y-axis.

k A k B Z B Z A

ps

Or cot

.i

17.

Or 1200

cut of

19.

cut of

ys

Let nth minima of 400 nm coincides with mth minima of 560 nm, then
2n 1 7 14
400
560
.....
Or
2n 1 2m 1
2m 1 5 10
2
2
i.e, 4th minima of 400 nm coincides with 3rd minima of 560 nm.
Location of this minima is
2 4 11000 400 106
Y1
14 mm
2 0.4
Next 11th minima of 400 nm will coincide with 8th minima of 560 nm
Location of this minima is
2 11 11000 400 106
Y2
42 mm
2 0.1
Required distance Y2 Y1 28 mm
Let the initial amplitude decreases to a1 to the other side i.e, after the first sweep;
Decreases in elastic potential energy Work done against friction
1
1
Or ka 2 ka12 mg a a1
2
2
1
Or k a a1 a a1 mg a a1
2

20.

ud

VA VB

.s
t

ww
w

18.

te

tan

Or a a1

2 mg
k

2 mg
k
.
2 mg
an 1 an
k
Adding all the above equations
2 n mg
a an
k
The block stops when
mg
mg kan or an
k
Substituting in the above equation we get:
20 0.3 15 n 7
ka
mg

2n 1
a Or 2n 1
mg 0.04 110
k
;
Let l be the end correction. Given that, fundamental tone for a length 0.1m first overtone for the
length 0.35 m.
v
3v

4 0.1 l 4 0.35 l
Solving this equation, we get
l 0.025m 2.5cm
The average speed of molecules of an ideal gas is given by
8 RT
v
i.e, v T for same gas.
M
Since, temperature of A and C are same average speed of O2 , molecules will be equal in A and C i.e,
v1 .
Linear acceleration of cylinder is zero i,e ,
mg sin Frictional force f upwards m mass of cylinder

24.

.s
t

ud

ys

22.

te

ps

.i

21.

Similarly a1 a1

Or

25.
26.

27.
28.

fR

2f
mR

ww
w

Angular acceleration about C is

R radius of

cylinder

Or

2mg sin 2 g sin

mR
R

1
mR 2
2
For no slipping between cylinder and plank
a R 2 g sin
In n-type semiconductors electrons are the majority charge carriers.
Current I can be independent of R6 only when R1 , R2 , R3 , R4 and R6 form a balanced Wheatstone
bridge.
R
R
Therefore, 1 3 or R1 R4 R2 R3
R2 R4
The average velocity in the first half of the distance v , while in the second half the average
velocity is v. Therefore t1 t2 . The work done against gravity in both halves is mgl / 2 .
The distribution of charge on the outer surface depends only on the charges outside and it
distribution itself such that the net, electric field inside the outer surface due to the charge on outer
surface and all the outer charges is zero. Similarly the distribution of charge on the inner surface
depends only on the charges inside the inner surface, and it distribution itself such that the net,

YAK
YA LK
m
K eq

m YA LK
YAK

ps

T 2

.i

29.

electric field outside the inner surface due to the charge on inner surface and all the inner charges is
zero.
Also the force on charge inside the cavity is due to the charge on the inner surface. Hence answer is
option.
YAK
K1 K 2
L
K eq

YA
K1 K 2
K
L

te

Note: Equivalent force constant for a wire is given by K

ys

YA
YA
F L and in case of spring F K .x . Comparing these two we find K of wire
L
L
1
2 mR 2 2 MR 2
2

4m 2m

8m
4m M

ww
w

.s
t

ud

30.

YA
. Because in case of a wire,
L

MATHEMATICS
31.

32.

z 2 , z 3 , z 4 2 10
Form an equilateral triangle
z 22 z32 z 24 z 2 z3 z3 z 4 z 4 z 2
z 22 z32 2z 2 2z 3 z 2 z 3 6 0
Numbers in the form 7k 14
7k 1 15
7k 2 15
7k 3 14
7k 4 14
7k 5 14
7k 6 14
to get maximum number of elements, one element from 7k, and all elements of the from , 7k+1,
7k+2, 7k+3

33.

Men can be seated 4! Ways, their wives can be seated in D 4 9 ways.

24x9 216
n

34.

ps

Given that coefficients of 2nd, 3rd & 4th terms is (a b) n are in A.P.
2n c2 n c1 n c3 n 7, n 2 (not possible)

te

36.

.i

35.

Pr 1 n Pr n Pr 1

a
b
c
a c
b2
1
1
1
c
b

&
n

b
a
b b
a(b c)
a(n r)n r 1) b(n r 1) c
1 .1
2 6
required probability =
5
1 . 1 1 . C2
2 6
2 25
= 8
23

& 3rd term = 84 7C2 .a 5 b 2 84

3r 3 (r 1)!

n 1

40.

(n 1)(n 1)!
(n 2)!

AP 2 PB2 (60) 2
2AP.PB
1 3h 2 3h 2 3600
h 20

2
3h 2 .2
line lies on the plane
cos120o

41.

(n 2)!

ww
w

n 1

.s
t

ud

ys

a 5 b 2 4 5log 2 a 2 log 2 b 2
5log 2 a 2 log 2 b
5log 2 a.2 log 2 b maximum value of 5 log 2 a.2 log 2 b 1
2
38. Conceptual.
(r 2)(r 2)! (r 1)(r 1)!
39.
(r 2 3r 3)(r 1)!

n 1 6

n5
7
n2

 (1, 2, a) lies on the plane 3x 4y 6z 7 0 a =3

& required plane, is nothing but plane, passing through (0,0,0) & the given line
x 1 4 2 z 9

1 is x+y+z=0
2
3
1
b
c

p.d 18 1 cos 2 d 18
0

b)

/2

2I

6sin d

6sin 36(1 sin 2 )

/2

sin d

sin cos

/2

1d I 4

ud

1
k ab sin C
2
1
k bc sin A
2
1
a 2 b2 c2
k acsin B Given expression becomes
2
2
In triangle APB
AP
sin B
2
AB

46.

47.

ww
w

.s
t

45.

.i

a)

P 36sin 2

x y
x2
y2
cos 1
1
1 0
2 3
4
9

9x 2 4y 2 12xy cos 36(1 cos 2 )

ps

44.

3 3
1 ab sin 75o
2
2

R 2

b 6

te

43.

y is Geometric mean of x & z

y 2 xz
a2
b
c

2R
o
o
sin 45
sin 60
sin 75o

ys

42.

a abc
xp xq y(pxq) yp yq z(pxq) p (pxq) 0

C AQ
In triangle AQC, Sin
2 AC
BI
AB
AI
In triangle ABI,

A B
A

C
sin Sin cos
2 2
2

2
CI
AC
& In triangle ACI,

A
B
Sin cos
2
2
AP AQ
A

cot
BI CI
2
1
1
1

w.k.t
2
2
PA CA
AD2

/2

cos d

sin cos
0

Where D is the point of intersection of PC & AB

AD 4 AB 8

48.

Y lt

1 tan 2 ln 1 x

1
ln(1 x )

cos x(1 x)

x 0

log e y lim

2 tan 2 ln 1 x

x 0

2 ln(1 x)

49.

50.

ye
Centroid divides the line segment, joining the points circumcentre & orthocenter in 1:2 ratio
circumcentre is P(2,3) & Image of orthocenter, with respect to any side of the triangle, lies on its
circumcircle (i.e) Q (8,5)
diameter = 2PQ 4 10

A 2t1 , t12 , B 2t 2 , t 22 P( 1, 0) are collinear points

ps

.i

t1 t 2 2t1t 2
& Centroid of triangle OAB
3
t1 t 2 & 3 t12 t 22
Is
2
(t1 t 2 ) 2 2t1t 2 3

52.

t tan x, dt sec 2 x dt

9t

ww
w

.s
t

ud

51.

ys

te

9 2 3

3
4
2
3x 2 2x 4y
cos x sin x
cos x x sin x x x
I
dx
dx
x(cos x x)
x(cos x x)
1
(sin x 1)
dx log x log(cos x x) log c
= dx
x
cos x x
log cx log(cos x x)
Cx
log
cos x x

7t 3 dt

(t 3 t)1/2

9t 8 7t 6
(t 9 t 7 )1/2 dt
y t9 t7
dy

2 y c
y
2

53.

1
e tan (sin x ) dx
I1
/2 e tan 1 (sin x) e tan 1 (cos x)
2

1
3
2I1 1 dx
/2
2

I1

3
4

1
I2

2I 2

54.

5
2

esin

tan 1 (sin x )

(sin x )

5
2

1dx I

I 1
sin 1

dx

tan 1 (cos x )

1
4

sin 1

2
1 (2sin ) 2n
lt
2
n (2sin ) 2n

x)dx ..... to n terms = since f (sin 4 x) is periodic

f (sin
0

function with period )

f (sin x)dx[1 3 5 ....to n terms] 2n

4

f (sin
0

Domain of y cos 1 (2x 5) 1 is [-3,-2]

1
Domain of y sin 1 (2x) sin 1
2
[2x]
Is 1 , 0 no solution
2
Let A (Ct1 , C / t 2 ) B (Ct 2 , C / t 2 )
C C
t1
t2
Slope of AB =
1 t 1 t 2 1
Ct1 Ct 2

x)dx

ww
w

.s
t

ud

57.

/2
2

ys

56.

.i

ps

I f (sin 4 x)dx f (sin 4 x)dx

te

55.

Equation of circle, AB as diameter is x 2 y 2 t1 t 2 c[x y] 8 0 .

x 2 y 2 8 (x y) 0 x y 0 and x 2 y 2 8 0

58.

59.
60.

circles pass through (2,2) & (-2,-2)

xi
5 x i 5n
n
xi
400
(x) 2 0
25 n=16.
n
n
Conceptual
Image of S(4,3), with respect to the tangent line x+y=3 is (0,-1) & the points (0,-1), (1,2) (6,a) are
collinear points a=17

CHEMISTRY
61. P4 N 2O P4O10 N 2
( A)

64.

67.

(B)

(C )

the electronic configuration of the given ion is as

Ca 2 1s 2 2s 2 2 p 6 3s 2 3 p 6 Mn 2 1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 5 Zn 2 1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 10
Thus the size of Zn 2 ion is smallest and of Ca 2 is largest among the three due to increase in effective
nuclear charge with increase in atomic number.Smaller the size of ion ,lighter is the hydration
enthalpy.Thus ,the order of hydration enthalpy is Zn 2 1 Mn 2 1 Ca 2 1 .
2047 kJ mol 1841kJ mol 1577 kJ mol
K 2Cr2O7 4 NaCl 6 H 2 SO4 2 CrO2Cl2 2 KHSO4 4 NaHSO4 3H 2O
red vapor ' p '

CrO2Cl2 2 NaOH Na2CrO4 HCl

yellowsolution

Na2CrO4 2 AgNO3 Ag 2CrO4

.i

Conceptual
A 2B C
t=0
Pi
0 0
at t
Pi -x 2x x
if t
0
2Pi Pi
Pt Pi 2x
P P
x t i
2
P
and P 3pi Pi
3
P
2.303
K
log i
t
Pi x
The base in which lone pairs are more available for donation,forms most stable adduct with the lewis
acid, B(CH 3 )3 .
Presence of electron releasing groups like ,Me makes the electron more available for donation,where
as an electron withdrawing group decreases the electron releasing tendency of the base.

ww
w

73.

.s
t

ud

ys

te

ps

70.
72.

red solid ' Q '

CH3

Thus

forms the most stable adduct with B(CH 3 )3 .

75.

and

both are crowded molecules so do not form adduct with Lewis

Acids.
H 3 PO 4 PO34 H 2 PO 4 HPO 42
Initial milli moles : 20 0.1 20 0.1
After reaction: - 2
2

2
Buffer solution of H 2 PO 4 (acid) and HPO 4 (Conjugate base) is formed

P P
H

=P

Due to lanthanide contraction, left to right atomic size decreases

0.1 F Liberates 0.1 equivalents of O 2 at anode and 0.1 equivalents of Ag at Cathode
Total loss = (0.1)8 + (0.1) 108 = 11.6g
Wt. of final solution = 108 11.6 96.4g
X is borazine.it is iso electronic with benzene.it reacts with hydrogen chloride to give an addition
product. B3 N3 H 6 3HCl B3 N3 H 9Cl3

Tf K f .m
0.93 1.86x

M 60
60
n
2
30
m.f CH 2 O 2
82.

36 1
x
M 1.2

81.

ka2

[Cu ( NH 3 ) 4 ](ClO4 ) 2 or [Cu ( NH 3 ) 4 ]2 contains Cu 2 ion

3d

4p

4s

Cu 2 [ Ar ]3d 9
4p

4s

te

3d

NH3

[Cu ( NH 3 ) 4 ]2 [ Ar ]

.i

79.

HPO 24
log
H 2 PO 4

ps

76.
78.

Ka2

ys

dsp2 square planar

NH 3 being a strong field ligand transfer the unpaired electron to 4d orbital.In

4p

sp3 tetra hedral

.s
t

4s

[Cu ( NH 3 ) 4 ] [ Ar ]3d 10

ud

[Cu ( NH 3 ) 4 ](ClO4 ) or [Cu ( NH 3 ) 4 ] ,Cu is present as Cu ion.

ww
w

Completely filled orbitals are highly stable, so NH 3 ligand occupy 4s and 4p orbitals.
85. Conceptual
x
87.
log tan(45o ) log p log 2
m
x
2p
m
4, at P 2 atm
88. Due to emulsification surface tension decreases.