7frwhl6 6 S~o SUtMntJf)e/!t!

) Au
~ t8tJLTS IW, ~y »IA<1lhMs:
1H6 -r.::S 3>1W;e/tN..S Plqr' 6/8 ~ L1/B A ~

~ V6JI&..n- IJO'I?ntkIJ M1lcr...t Wlhq} ~ 1twfI'I

W\rH 'TIff' N~ 70 ~ A n,Pf96Jr l»)9fRA-f
fis,2. 6ISIi 105SISlc! B,.vAL.~.

11~ 1)1~ Me A2.$O N~",A/JI«> "mt

«bPEK 70 "M£ ~f) ,~'s 6IGltJy--
p~~ ifJ,A1T),f' 11) rr, As rr IS atStz,z,y CIWI1
6t9r.i DrFi1f'Il~!s '1M'T NI£ crF JW111le-sr.
u
 d2 B = 860 cm-1 for V(lI!)
80, , iii i

40 3T2(t2e)

--7"'<~ 1Al
30

o 10 50
 (
.~,j
"~S<~~ ~
'-v 3 F 1fRIt\

_ ~LY
'~5~q.
aNt
wAY of ~flftNGJN6 e
Fbtl 'r.ifOtf S?Ir1E.
~ 6rrAut ) JhD 11i IS ~. OS. taw rl(i. 'N YI8l>s rn '"
57I1rCs VIA eQxec -4> A/(~~Al(l1" l:. ~~~;:~,~,~" 6

'-' J ~ -J --:J '?"" 6- 0""

- 11!"I! ~~£' A'S l)OJ!Q' t~/7f!D nt1f of : 3~ Z

a
U1) ~ 2 '~. • wlfd
= 'J
•

ft,oA-r uP "ro
jl,nJ : i tN ~.t.
Lr:tJ'-S ult£ c:lz.~') Az
_ S/~LY tXt: f1Q> "S7Ft1€: ~ ·
~ ~ ""'~ ~~ 1
dZ
 ~& lr,;
~1 X1J (' J: UI. OJ '" X1JD 'j
So 11j .
8
A-w~ ~~ of d 'S1A1O J'S IN ~6' f'F
~~!L Of ci~s?fK'ES ~ 1>tf &1I6J~ (sF)
U$)~ Irr -r:-S ~1~GiAM fN.. ~ ~ 10.,. ·
- oltf (tfJPfTCO '7f) d.' 'SI m.,JMJ,y ,
- ~ A'f,aJr d' 6- d'? (t8Jr1eO ~
s= )/2. d' (,0 S=~ d", 8cfi
..
V ~1
VS
".".

$: '/2.
L. ~ .
S'TflDJffR F/t7J)
 d8 B = 1080 cm-1 for Ni(ll)
80

Q:l 40
--.
~
I II A / / /
lAl
- - - - -

30

10___

20W
3 __
p
,
(
7'
<
IE

In/
10
1//
,., 3A2(t~e2)
3 _
F
0 10 20 30 40 50
/lIB
 o

o;t
~.
E... o;t~ I:.N..... N'-'"
-~
IDN
•
I.C'l

~ ..... o;t .... ..... E-.t ~ ~

'-' ~~~~N
_ (\J E... N N ~
!.O~ NO;;
~

8 .;;' " .. '\.. ~" --I", ,;;-

.E o;t "" o;t
.....I N
E
U
~
N
0
~

o
~ ~
II «:'l

I:tl ~N
V
~
"~

0
4
f""!""t """

o o
r-.... I.C'l
~ \ ??'/\\\\8
~ 0 Q..~c!)Q.,
N N"b N N N o;t

HI:£[
/

Ir------~------~------~------r_------r_------r_----_,r_----_,O
I I I I I I I • L{)

....
......
u
> .....
....
0
o
.......... "I-

o
..... I
I E ~
E u
u 0
c.o~
1.00
r-.... .-I
o
'--y---I
C\J

I:tl"
o
,......

o
00

fll'8.
@> fbe 4 N~~
..v, -= "A~ lt;j Itr hv = ~Q

• Va -= lAj= ~ ~ (')
~---~~-----;;.-
1·~8+),sA-~:l 22.'8&t(+)18D.
• '2,)3 = \A'j ~ '1j (P) kr
~~~~~ ....
,,·f8 +1·'4 +1.~:U$"~+A! +-J/SA.
~0Wt. A':I:P. JL~, 'f.e~. Li>oc. )~ (Jt1fIj 111---112.
\~V
~ It- \i~~ 2+ .. ,'
<i N(csH) BLIP IS s'nJ· ~811>P6J
5 -I &>1 I"t) I • b 1flArl~ 'f'T7ON I 'TO /~ <lit..
3. u~fP 'AI<\.
~ z>, ..J
J
'(;f,c
\~\
v··
... ("

· ~\i-t ~

. .J

-A
~01f LOW e-~~LlJf '\1lft$e' Atf -,$tc::. ~s f "'"
 -
A J¥J1E o.J . 1DnfA JIC-o$ 5YS'7zs.t s. .'.' -.'
-
e.j , d' ~ '1i " -- - - - - --

3F YltLDS./"'-' '-''-' 6&

'" -"".,#1
1Je
\JiA1 ~:r tF ~?
CtJ.) 1'f"S S = I) so 'l'bPL-tT-
(b) rn otc'~ l'l~~':~. 10 A.
6"-1f) 1M*r Cx€ = A I tALrE
AU, ~~81,cS C4. -d'. ():.s. = "A~
~~ '1He ~6-~o D11til~ /iR..
A ~ - at t\ ,(1IJ IS. :s~ *s .~
1'Ht ~ - d{IO-f\ J rmf-.
1; d J. - \JSG' ~ (;l' ; ~Ufl\.) ~ ~ t <: Lto
JlHfr /tOOUT' ~iSJ ~ IS /.D!J 'Sf ""'J ?
WHfrr -ro ~ fk. lA'\J -f~'~1
-r;J {JIJHtPJt5t.eJ?
 A Sl1VU6,. IJ/bvH.. lf4M1 Pte
w-(c.yaIrfA) U IS l.J.
=
1 ll. d1'-Y) = h'j
!L ht)
-~ .L dY1 :: l,j
Jl. L d,a I: 4.,
.!Uk U
- ~7E 1Ihtr a~:,0
d1Cl.~rJ'/,=eJ

~ 11tAWSt"~S 10 ~S'D~
. a fJtJ"wMJlt:

29-4

~O -~: Bj st._G* ) SOJola:} .

~~: B.&j '~It.M ') $() J BaJ .- ~ 1*e1
~/MG. faL 1ltc SlAI~te /KJlC.
S~MrA6~ A~I,6WCl)?