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0,6
0,5
0,4
amine A
0,3
amine B
0,2
MEA
0,1
0
5
1
0,8
0,6
0,4
amine D
0,2
amine E
0
0
10 15 20 25 30 35 40 45 50 55 60 65 70 75
Time (min)
Figure 2. Kinetics of reactions of di-amines with carbon dioxide
(2)
Experimental
All data were recorded under the same conditions: 1 atm of CO2 and
298 K. The kinetics was followed in tetrahydrofuran (THF) as
solvent. 8 mL of THF were saturated with CO2 in the absorption
flask, then the amine (0.90 mmol) was added. The uptake of CO2 was
followed using a gas burette.
Neat amines have been also used.
2 RNH2 + CO2
(1)
R = Benzyl
10 15 20 25 30 35 40 45 50 55 60 65 70 75
References
Time (min)
Figure 1. Kinetics of reactions of mono-amines with carbon dioxide
(1)
(2)
(3)
(4)
(5)