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For an ideal gas not undergoing any chemical reaction or phase change
dS
dqrev.
T
dS
nC dT PdV
dU dw
T
T
m
V
nCVm dT
nRT
dV
V
Tf
Vf
S nCVm ln nR ln
Ti
Vi
Tf
S nC pm ln
Ti
Or
Pi
nR ln
Pf
These expressions are valid for both reversible & irreversible processes
CASE-II:
S fusion
H fusion
Tm. p.
&
Svap.
H vap.
Tb. p.
CASE-III:
( r S 2 r S1 ) r CP ln
T2
T1
(ii)
( r S 2 r S1 ) ng R ln
P1
P2
Q.1
Column-II
(A)
(P)
Ssystem > 0
(B)
(Q)
Ssystem < 0
(C)
(R)
Ssurounding < 0
(D)
(S)
Ssurounding = 0
Ans.
Q.2
When two equal sized pieces of the same metal at different temperatures Th (hot
piece) and Tc(cold piece) are brought into contact into thermal contact and isolated
from it's surrounding. The total change in entropy of system is given by
(T T ) 2
(T T ) 2
T T
T
(A) C ln C h
(B) C ln 2
(C) C ln C h
(D*) C ln C h
2TC
T1
2TCTh
4TCTh
Q.3
The normal boiling point of a liquid 'A' is 350 K. Hvap at normal boiling point is 35
kJ/mole. Pick out the correct statement(s). (Assume Hvap to be independent of
pressure).
(A*) Svaporisation > 100 J/Kmole at 350 K and 0.5 atm
(B) Svaporisation < 100 J/K mole at 350 K and 0.5 atm
(C*) Svaporisation < 100 J/K mole at 350 K and 2 atm
(D) Svaporisation = 100 J/K mole at 350 K and 2 atm
Q.4
Estimate enthalpy of vaporisation of ethane from its boiling point which is 88.6o C ?
Ans. 16KJmole-1
Q.5
Q.6
And
p
CNp2 30 JK 1mole1 , COp2 30 JK 1mole1 , CNO
40 JK 1mole1
2
Q.7
1000 K
200 K
400
500
S
Calculate:
(a)
(efficiency)
(b)
Work done
(c)
Heat given to
(d)
Heat taken from the source
Ans. (a) 0.8, (b) -8 104 J, (c) 20 KJ, (d) 100 KJ