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INSTRUCTIONS
8.
9.
10.
11.
12.
13.
in
7.
s.
6.
ep
3.
4.
5.
st
2.
Immediately fill in the particulars on this page of the Test Booklet with Blue/Block Ball Point Pen,
Use of pencil is strictly prohibited.
The answer Sheet is kept inside this Test Booklet. When you are directed to pen the Test Booklet,
take out the Answer Sheet and fill in the particulars carefully.
The test is of 3 hours duration.
The Test Booklet consists of 90 questions. The maximum marks are 360.
There are three parts in the question paper A, B, C consisting of Chemistry, Physics and
Mathematics having 30 questions in each part of equal weight age. Each question is allotted 4
(four) marks for each correct response.
Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each
question (one fourth) marks will be deducted for indicating incorrect response of each question.
No deduction from the total score will be made if no response is indicated for an item in the answer
sheet.
There is only one correct response for each question. Filling up more than one response in each
question will be treated as wrong response and marks for wrong response will be deducted
accordingly as per instruction 6 above.
Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side1 and Side2
of the Answer Sheet. Use of pencil is strictly prohibited.
No candidate is allowed to carry any textual material, printed to written, bits of papers, pager,
mobile phone, any electronic device, etc., except the Admit Card inside the examination hall/room.
Rough work is to be done on the space provided for this purpose in the Test Booklet only. This
space is given at the bottom of each page and in 3 pages (Page 21 23) at the end of the booklet.
On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty
in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
The CODE for this Booklet is P. Make sure that the CODE printed on Side2 of the Answer Sheet is
the same as that on this booklet. In case of discrepancy, the candidate should immediately report
the matter to the Invigilator for replacement of both the Test Booklet and the answer sheet.
Do not fold or make any stray marks on the Answer Sheet.
dy
1.
tu
CHEMISTRY
ww
w
.s
1.
H3
2H
OH H
H
OH HO
4.
DNA
AIEEE-2011-CODE-P
OH
Br
8.
Br
Br2
Br
5.
E H + /H = EH + /H
2
PH
0.0059
log + 2 2
2
|H |
PH
0.59
log + 2 2
2
|H |
For the negative value of E H + /H
= 0
By
PH 2
+ 2
in
OH
st
ep
s.
10.
Sol.: O
+
H
H
7.
ww
w
sp3
.s
tu
O = N = O sp
dy
Cl
Cl
C
Cl
O
C
Cl
Cl
C
Cl
Cl
Cl
C
Cl
Cl
Cl
C
Cl
OH
O
C
OH
OH
O
Cl
Cl
C
Cl
O
C
CCl3 C O
CCl3 CH2 OH
AIEEE-2011-CODE-P
s.
13.
tu
dy
st
ep
in
ww
w
.s
14.
18.
Identify
the
compound
that
exhibits
tautomerism :
(1) 2-butene
(2) Lactic acid
15. Which of the following facts about the complex
(3) 2-Pentanone
(4) Phenol
[Cr(NH3)6]Cl3 is wrong?
Key:
(3)
O
O H
(1) The complex involves d2sp3 hybridisation
Tautomerisation
H3C C CH2 CH2 CH3
H3C C CH CH2 CH3
and is octahedral in shape.
(2) The complex is paramagnetic.
Keto form
enol form
Sol.:
(3) The complex is an outer orbital complex
O
OH
(4) The complex gives white precipitate with
silver nitrate solution.
Key: (3)
enol
keto
4
AIEEE-2011-CODE-P
A vessel at 1000 K contains CO2 with a Sol.: Cl is a weak field ligand and therefore d8 ion
pressure of 0.5 atm. Some of the CO2 is
will have two unpaired electron.
converted into CO on the addition of graphite.
= n ( n + 2)
2 4 = =8 = 2.82 B.M.
= 1.8 atm.
in
( 0.6 )
25.
ww
w
.s
tu
dy
st
ep
s.
0.2
(4) a for Cl2 > a for C2H6 but b for Cl2 < b for
C2H6
Key: (4)
28.
Sol.: Compressible gases have greater force of
attraction and hence value of a should be
greater and reduced volume b should be less.
The magnetic moment (spin only) of [NiCl4]2
is :
(1) 1.82 BM
(2) 5.46 BM
(3) 2.82 BM
(4) 1.41 BM
Key: (3)
23.
AIEEE-2011-CODE-P
Key. (3)
O
||
Sol.: CH 3CH 2 O Na + + CH 3 C Cl
Sol.
O
||
CH3 C OCH2 CH3 + NaCl
Nucleophilic acyl substitution.
29.
i 1
(2) =
x + y +1
x + y 1
(3) =
i 1
x + y +1
(4) =
i 1
Key: (1)
Sol.: AxBy
xA y + + yBx
x
A1
is
A2
(1)
M
M+m
(2)
1
in
M
(3)
M+m
Key. (4)
M+m
M
1
M+m 2
(4)
.
M
k
= (M m)V
M
k
.
M+m
ep
st
Also V = A 2
ww
w
.s
tu
dy
30.
PHYSICS
35.
100 g of water is heated from 30C to 50C.
Ignoring the slight expansion of the water, the
change in its internal energy is (specific heat of
water is 4184 J/Kg/K)
(1) 4.2 kJ
(2) 8.4 kJ
(3) 84 kJ
(4) 2.1 kJ.
Key. (2)
Sol.
U = 0.1 4184
20 8.4
kJ .
(2).
32.
20 min= .
ratio of
31.
T=1
s.
e t1
=2
e t 2
ln2
t 2 t1
(3).
(4).
y(x, t) = e (ax + bt 2 ab xt )+
This represents a
(1) wave moving in +x direction with speed
a
b
(2) wave moving in +x direction with speed
b
a
The half life of a radioactive substance is 20
(3)
standing
wave of frequency b
minutes. The approximate time internal (t2 t1)
1
2
.
(4) standing wave of frequency
between the time t2 when
of it had decayed
b
3
Key. (2)
is
2
(1) 7 min
(2) 14 min
Sol.
y(x, t) = e ( a bt ) +
(3) 20 min
(4) 28 min.
(2).
2
AIEEE-2011-CODE-P
Sol.
V = V0 1 e RC
6
120 = 200 1 e R 210
6
R = 2.7 10 .
(3)
36.
Sol.
(2) 2 s
(4) 8 s.
d
v
t=2s
(2)
6.25
40.
s.
st
ep
38.
Key.
Sol.
39.
ww
w
.s
tu
Sol.
r r q encl
Now, E ds =
A current I flows in a infinitely long wire with
0
sphere
cross section in the form of a semicircular ring
4
of radius R. The magnitude of the magnetic
r 3
induction along its axis is
2
2ar 4 r
3
=
0 I
0 I
0
(2)
(1)
2 R
22 R
6a
= 0 .
0 I
0 I
(4).
(3)
(4)
.
2R
4R
(1)
41. A car is fitted with a convex sideview mirror
I
0
0 I .
0 =
3
v dt u 2 dt
(1) 372 K and 310 K
2
dv
1
280
(2) 372 K and 330 K
m/s
= 15
dt
15 280 15
(3) 330 K and 268 K
(4) 310 K and 248 K.
(2).
(1)
T
42. If a wire is stretched to make it 0.1% longer, its
=1 2
resistance will
T1
(1) increase by 0.05%
(1).
(2) increase by 0.2%
(3) decrease by 0.2%
An object, moving with a speed of 6.25 m/s, is
(4) decrease by 0.05%.
decelerated at a rate given by
Key. (2)
dv
= 2.5 v
l
l 2
Sol.
R =
=
dt
A (Volume)
where v is the instantaneous speed. The time
dy
Key.
= 2.5 d t
in
37.
(1) 1 s
(3) 4 s
Key. (2)
R l2
AIEEE-2011-CODE-P
R
l
=2
R
l
(2).
(4)
Fe=
x3 =
(2) v x 1
(3) v x
Key. (3)
Sol.
1
2
Kq 2
x2
T cos = mg
T sin =
(4) v x .
(i)
(ii)
Tsin
x
2
x
2
kq 2 l
mg
(i)
vx
(3)
1
2
st
dy
tu
ep
45.
ww
w
44.
l -4x
2
x3 q2
dx
dq
3x 2
2q
dt
dt
2
x vq
.s
n
Number of moles of second gas = 2
NA
n3
Number of moles of thirst gas =
NA
If no loss of energy then
P1V1 + P2V2 + P3V3 = PV
n
n1
n
RT1 + 2 RT2 + 3 RT3
NA
NA
NA
n1 + n 2 + n 3
RTmix
=
NA
n T + n 2 T2 + n 3T3
.
Tmix = 1 1
n1 + n 2 + n 3
(2).
mg
n1
NA
x
kq 2
= 2
l x mg
Key. (2)
Sol. Number of moles of first gas =
Kq
x
l
in
(3)
Tcos
l 4x
2
s.
43.
Tan =
= 4 0.03 16 104 2
= 4 0.48 104 2
= 1.92 104 2
= 3.94 104 = 0.394 mJ 0.4 mJ.
(4).
46.
LC
(1) LC
(2)
4
(3) 2 LC
(4)
LC .
Key. (2)
q 02 q 2 Li 2
Sol.
=
+
2C 2C
2
differentiating w.r.t. t
di
q
=
dt
LC
d2q
1
=
q
2
dt
LC
8
AIEEE-2011-CODE-P
d2 x
= 2 x
dt 2
1
=
LC
So, q = q0 cost (Q at t = 0, q = q0)
q
For half energy q = 0
2
q0
So,
= q 0 cos t
2
t =
4
=
t=
LC .
4 4
(2).
Comparing
) (
dy
st
ep
s.
in
49.
ww
w
.s
tu
x
(r n)
Gm
4Gm
=
(r / 3) (2r / 3)
9Gm
.
=
r
(4).
48.
50.
(1)
(2)
2
3
(3)
(4)
.
4
6
Key. (2)
AIEEE-2011-CODE-P
53.
Direction :
The question has a paragraph followed by two
statements, Statement 1 and Statement 2.
Of the given four alternatives after the
statements, choose the one that describes the
statements.
ww
w
.s
tu
dy
st
ep
s.
in
10
AIEEE-2011-CODE-P
and T R = mR 2
(ii)
2
59. A pulley of radius 2 m is rotated about its axis
and a = R
(iii)
by a force F = (20t 5t2) Newton (where t is
2
Solving a = g .
measured in seconds) applied tangentially. If
3
the moment of inertia of the pulley about its
(3)
axis of rotation is 10 kg m2, the number of
rotations make by the pulley before its direction
57. A water fountain on the ground sprinkles water
of motion if reversed, is
all around it. If the speed of water coming out
(1) less than 3
of the fountain is v, the total area around the
(2) more than 3 but less than 6
fountain that gets wet is
(3) more than 6 but less than 9
v2
v4
(4)
more than 9.
(2) 2
(1)
Key. (2)
g
g
v4
v2
Sol.
= = 4t t 2
(3)
(4)
.
I
2 g2
g2
d
Key. (2)
= 4t t 2
dt
4
v
Sol.
A = R 2max = 2 .
t3
2t=2
g
3
(2)
is zero at t = 0s and t = 6s
d
t3
58. Direction :
= = 2t 2
Now
dt
3
The question has Statement 1 and Statement
2 3 t4
2. Of the four choices given after the
t=
ww
w
.s
tu
dy
st
ep
s.
in
56.
11
AIEEE-2011-CODE-P
MATHEMATICS
61. Let , be real and z be a complex number. If
z2 + z + = 0 has two distinct roots on the
line Re z = 1, then it is necessary that:
64.
(1) (0, 1)
(2) (-1, 0)
(3) || = 1
(4) (1, )
Key: (4)
Sol.: Let roots be 1 + ia and 1 - ia
So (1 + ia) + (1 - ia) = -
and (1 + ia) (1 - ia) =
= 1 + a2
(1, )
8log(1 + x)
dx is
1 + x2
0
(2) log 2
8
The value of
(1) log 2
(3)
log 2
2
(4) log 2
Key: (1)
/ 4
8log(1 + tan ) d
log(1 + tan 4
0
/ 4
log 1 + tan d
tu
=8
) d
63.
d2x
equals
dy 2
d2 y
(1) 2
dx
d 2 y dy
(2) 2
dx dx
d 2 y dy
(3) 2
dx dx
Key: (4)
Sol.:
d 2 y dy
(4) 2
dx dx
1
d 2 x d dx d dy
=
=
dy 2 dy dy dy dx
d dy
dx dx
ww
w
/ 4
I = 4 log 2d = log 2
.s
/ 4
= 8 ( log 2 log(1 + tan ) ) d
0
st
I=8
dy
0
/ 4
dy
dx
ep
I=
s.
8log(1 + x)
dx
1 + x2
0
Let x = tan dx = sec2 d
1
Sol.: I =
dy
.
dx
in
62.
d2 y
= 2
dx
t sin t dt
f (x) =
x sinx
Sol.: f(x) =
12
AIEEE-2011-CODE-P
69.
+
5/2
y=x
x=e
in
s.
1
3
+ ln | x | =
2
2
1
ep
is
f(x)
=
q
, x=0
2
x+x x
, x>0
x 3/ 2
continuous for all x in R, are
1
3
5
1
(2) p = ,q =
(1) p = , q =
2
2
2
2
3
1
1
3
(4) p = ,q =
(3) p = , q =
2
2
2
2
Key: (3)
sin(p + 1)x + sin x
, x<0
Sol.: f(x) =
q
, x=0
x + x2 x
, x>0
x 3/ 2
sin(p + 1) x + sin x
lim f (x) = lim+
=p+2
x 0
x 0
x
1
1
lim f (x) = p + 2 = q =
x 0+
2
2
3
1
p= ,q=
2
2
ww
w
.s
tu
dy
st
68.
71.
2 2
P(-2, -2)
R
13
O (0, 0)
x
Q(-1, -2)
y 1 z 3
=
2
5
and the plane x + 2y + 3z = 4 is cos-1 14 ,
then equals
(1) 2/3
(2) 3/2
(3) 2/5
(4) 5/3
(1)
x 0 y 1 z 3
=
=
1
2
x + 2y + 3z = 4
Angle between the line and plane will be
= sin-1
1 + 4 + 2
cos-1
= sin 1
1 +4 +
1.1 + 2.2 + .3
5 3
14 5
+2
5
(5 + 3 ) 2
1
= cos 1
14(5 + )
14
(given)
= 2/3.
The domain of the function f(x) =
(1) (-, )
(3) (-, 0)
Key: (3)
1
| x | x
(2) (0, )
(4) (-, ) - {0}
is
AIEEE-2011-CODE-P
Sol.: f(x) =
| x | x
f(x) is define if |x| - x > 0
|x| > x
x<0
So domain of f(x) is (-, 0).
the value of
y
7
r r
r r
r r
2a b . a b a 2b is
+
2
(t , t)
(1) - 5
(2) -3
x
(3) 5
(4) 3
Key: (1)
+
Sol.: ( 2a b ) . ( a b ) ( a 2b )
75.
) (
)(
ep
s.
in
dy
tu
.s
ww
w
74.
= ( 2a b ) . ( a b ) a
st
3 2
8
73. A man saves Rs. 200 in each of the first three
months of his service. In each of the subsequent
months his saving increases by Rs. 40 more
than the saving of immediately previous month.
His total saving from the start of service will be 77.
Rs. 11040 after.
(1) 18 months
(2) 19 months
(3) 20 months
(4) 21 months
Key: (4)
Key:
Sol.: Let it happened after m months
m3
Sol.:
(2 240 + (m - 4) 40))
2 300 +
2
= 11040
m2 + 5m - 546 = 0
(m + 26) (m - 21) = 0 m = 21.
So shortest distance between them is
(
= ( 2a b )( b 0
2( a+ b) b
= 4a.a b.b = 5 .
dy
= y + 3 > 0 and y(0) = 2, then y(ln 2) is
If
dx
equal to
(1) 7
(2) 5
(3) 13
(4) -2
(1)
dy
=y+3
dx
dy
= dx
y+3
On integrating
ln |y + 3| = x + c
ln (y + 3) = x + c
Since y(0) = 2
c = ln 5
ln (y + 3) = x + ln 5
put x = ln 2
y = 7.
Equation of the ellipse whose axes are the axes
of coordinates and which passes through the
point (-3, 1) and has eccentricity 2 / 5 is
(1) 3x2 + 5y2 - 32 = 0
14
AIEEE-2011-CODE-P
2
(2) 5x + 3y - 48 = 0
(3) 3x2 + 5y2 - 15 = 0
(4) 5x2 + 3y2 - 32 = 0
Key: (1)
x 2 y2
Sol.: Let the ellipse be 2 + 2 = 1
a b
9 1
It passes through (-3, 1) so 2 + 2 = 1 ... (i)
a b
Also, b2 = a2 (1 - 2/5)
5b2 = 3a2 ... (ii)
32 2 32
,b =
Solving we get a2 =
3
5
So, the ellipse is 3x2 + 5y2 = 32.
ww
w
.s
tu
dy
st
ep
s.
in
x 2
x2
83. Consider 5 independent Bernoulli's trails each
AIEEE-2011-CODE-P
r
r
1
87. The vectors a and b are not perpendicular and
].
r
r r r
r
2
c and d are two vectors satisfying: b c = b d
2
2
84. The two circles x + y = ax and
r
rr
and a.d = 0. Then the vector d is equal to
x2 + y2 = c2 (c > 0) touch each other if
r
rr
r b.cr r
(1) 2|a| = c
(2) |a| = c
r a.c r
r
(2)
b
c
(1)
+
c
r
r r b
(3) a = 2c
(4) |a| = 2c
a.b
a.b
Key: (2)
rr
rr
r b.c r
r a.c r
Sol.: If the two circles touch each other, then they
(3) b + r r c
(4) c r r b
must touch each other internally.
a.b
a.b
|a|
|a|
Key: (4)
=c
So,
rr
2
2
Sol.: a.b 0
|a| = c.
rr
a.d = 0
r r r r
85. Let A and B be two symmetric matrices of
b c = b d
r r r
order 3.
b (c d) = 0
Statement-1:
r
r r
b is parallel to c d
A(BA) and (AB)A are symmetric matrices.
r r r
Statement-2:
c d = b
r
AB is symmetric matrix if matrix multiplication
Taking dot product with a
of A and B is commutative.
r
rr
r
a.c 0 = a.b
(1) Statement-1 is true, Statement-2 is true;
rr
Statement-2 is correct explanation for
a.c
r
=
r
Statement-1.
a.b
rr r
(2) Statement-1 is true, Statement-2 is true;
r r a.c
Statement-1.
(3) Statement-1 is true, Statement-2 is false.
88. Statement-1:
(4) Statement-1 is false, Statement-2 is true.
The point A(1, 0, 7) is the mirror image of the
Key: (2)
x y 1 z 2
Sol.: Given, A = A
point B(1, 6, 3) in the line =
=
B = B
1
2
3
Now (A(BA)) = (BA)A = (AB)A = (AB)A
Statement-2:
= A(BA)
x y 1 z 2
bisects the line
=
=
The line :
Similarly ((AB)A) = (AB)A
1
2
3
So, A(BA) and (AB)A are symmetric matrices.
segment joining A(1, 0, 7) and B(1, 6, 3).
Again (AB) = BA = BA
(1) Statement-1 is true, Statement-2 is true;
Now if BA = AB, then AB is symmetric matrix.
Statement-2 is a correct explanation for
statement-1.
86. If C and D are two events such that C D and
(2) Statement-1 is true, Statement-2 is true;
P(D) 0, then the correct statement among the
Statement-2 is not a correct explanation for
following is
Statement-1.
(3) Statement-1 is true, Statement-2 is false.
(1) P(C|D) = P(C)
(2) P(C|D) P(C)
(4) Statement-1 is false, Statement-2 is true.
P(D)
(3) P(C|D) < P(C)
(4) P(C|D) =
Key:
(2)
P(C)
Sol.: The direction ratio of the line segment joining
Key: (2)
points A(1, 0, 7) and B(1, 6, 3) is 0, 6, -4.
C P(C D) P(C)
The
direction ratio of the given line is 1, 2, 3.
P(C)
=
Sol.: P =
P(D)
P(D)
Clearly 1 0 + 2 6 + 3 (-4) = 0
D
So, the given line is perpendicular to line AB.
(Since 0 < P(D) 1
Also , the mid point of A and B is (1, 3, 5)
P(C)
P(C) )
So,
which lies on the given line.
P(D)
So, the image of B in the given line is A,
because the given line is the perpendicular
bisector of line segment joining points A and B.
ww
w
.s
tu
dy
st
ep
s.
in
89.
AIEEE-2011-CODE-P
(1)
3
A1
4
(3) 1 A 2
13
A1
16
3
13
(4) A
4
16
(2)
Key: (1)
Sol.: A = sin2x + cos4x
= sin2x + cos2x. (1 - sin2x)
1
sin22x
=14
Since; 0 sin22x 1
3
A 1.
So,
4
90. The number of values of k for which the linear
equations
4x + ky + 2z = 0
kx + 4y + z = 0
2x + 2y + z = 0
posses a non-zero solution is:
(1) 3
(2) 2
(3) 1
(4) zero
Key: (2)
Sol.: For the system to have non-zero solution
4 k 2
k 4 1 =0
2 2 1
k2 - 6k + 8 = 0
k = 2 or 4.
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