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NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Olympiad Examinations Task Force
Not valid for use as an ACS Olympiad Local Section Exam after March 28, 2007. STOCK CODE OL07
Distributed by the ACS DivCHED Examinations Institute, University of Wisconsin - Milwaukee, Milwaukee, WI.
All rights reserved. Printed in U.S.A.
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
CONSTANTS
m
M
M
mol
h
P
k
Rf
s
T
t
V
R = 8.314 Jmol1K1
R = 0.0821 Latmmol1K1
1 F = 96,500 Cmol1
1 F = 96,500 JV1mol1
NA = 6.022 1023 mol1
h = 6.626 1034 Js
c = 2.998 108 ms1
0 C = 273.15 K
1 atm = 760 mmHg
EQUATIONS
E = Eo !
1
1A
1
H
RT
ln Q
nF
"k % E " 1 1 %
ln$$ 2 '' = a $$ ( ''
# k1 & R # T1 T2 &
18
8A
2
He
3
Li
2
2A
4
Be
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
1.008
4.003
10
Ne
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Uun
111
Uuu
112
Uub
114
Uuq
116
Uuh
118
Uuo
(223)
(226)
(227)
(261)
(262)
(263)
(262)
(265)
(266)
(269)
(272)
(277)
(2??)
(2??)
(2??)
Page 2
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(262)
Not for use as a USNCO Local Section Exam after March 28, 2007
DIRECTIONS
When you have selected your answer to each question, make sure your answer is clearly legible on the answer sheet using a soft,
#2 pencil. For Scantron style sheets, make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the
unwanted answer very carefully.
There is only one correct answer to each question. Any questions for which more than one response is indicated will not be
counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
(B) Ag2CO3
(C) BaCl2
(D) BaCO3
(D) NH3
(B) 2
(D) 25 mL beaker
(B) H2
(A) Cl2
(C) 3
(D) 4
(B) KMnO4
(C) Na2Cr2O7
(D) ZnCl2
Not for use as a USNCO Local Section Exam after March 28, 2007
(B) 1.54/1
(C) 1/1
(D) 0.276/1
(B) 0.130 M
(C) 0.0800 M
(D) 0.0500 M
Page 3
(A) 2.0010-3
(B) 4.010-3
(C) 8.010-3
(D) 1.610-2
(A) 1 only
(B) 2 only
(D) 1, 2 and 3
(B)
(A) 360
(B) 623
(C) 831
(D) 1440
(D)
(D) viscosity
(A) Ne
(B) Ar
(B) 46.1 kJ
(C) 46.1 kJ
(D) 92.2 kJ
(A) 92.2 kJ
(D) Rn
(B) 0.032
(C) 0.14
(D) 7.1
(B) II only
(C) H2O(l)
(D) PbO2(s)
Page 4
(B) H 0
(C) G < 0
(D) S > 0
Not for use as a USNCO Local Section Exam after March 28, 2007
(B) 818.5
(C) 1766.2
(D) 3661.6
(B)
28.
(B) 2 min
(C) 4 min
(D) 8 min
(C)
(D)
26.
(B) 0.016
(C) 0.032
(D) 0.064
27. What are the units of the rate constant for a second order
reaction?
(A) s-1
(B) mol.L-1.s-1
(C) L.s.mol-1
(D) L.mol-1.s-1
Not for use as a USNCO Local Section Exam after March 28, 2007
Page 5
(A) 0.48 V
(B) 6.920
(C) 7.000
(D) 7.084
Ka
CH3COOH
1.8105
HCN
5.81010
(B) 1.16 V
(C) 1.84 V
(D) 2.52 V
(B) Sn2+
(C) Mn
(D) Sn
(A) I only
(A) 3
(B) 5
(C) 9
(D) 15
(B) 8.810-9
(C) 1.710-6
(D) 3.410-6
(A) Br
(B) K
(C) Mg
(D) Na
(B) Mg and Si
(C) P and As
(D) Ti and V
(A) B and Ge
(A)
56
26 Fe
and
58
28 Ni
(B)
(C)
57
27 Co
and
57
28 Ni
(D)
58
26 Fe
57
28 Ni
and
and
56
2+
26 Fe
58
28 Ni
(B) Cl
(C) ClO2
(D) ClO4
Page 6
(B) +4
(C) +6
(D) +12
Not for use as a USNCO Local Section Exam after March 28, 2007
49. In which species does the central atom have one or more
lone pairs of valence electrons?
(A) AlCl4
(B) CO2
(C) PCl4+
(D) SO2
(B) two
(C) three
(A) NH4Br(s)
(B) KI(s)
(A) alcohol
(B) aldehyde
(C) CH2Cl2(l)
(D) SiF4(g)
(C) amide
(D) amine
(B) HCl
(C) HBr
(D) HI
52. The ONO bond angle in the nitrite ion, NO2, is closest
to
(A) 180.
(B) 150.
(C) 120.
(D) 109.
(D) four
(B) two
(C) three
(D) four
(C) polystyrene
I.
II.
(A) I only
(B) II only
(B) see-saw
(C) tetrahedral
(A) 1, 2, 2
(B) 1, 3, 3
(C) 1, 1, 4
(D) 2, 4, 2
END OF TEST
(B) C8H14
(C) C8H16
(D) C8H18
Not for use as a USNCO Local Section Exam after March 28, 2007
Page 7
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
C
C
D
A
D
B
D
B
A
A
B
C
A
A
D
B
C
C
D
C
A
B
C
A
D
C
D
B
D
D
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Not for use as a USNCO Local Section Exam after March 28, 2007
Answer
A
D
D
C
D
B
A
D
B
C
B
C
C
B
A
A
B
A
D
A
A
C
B
C
D
C
D
B
B
A