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NATIONAL
CHEMISTRY OLYMPIAD
NATIONAL EXAMPART I
Prepared by the American Chemical Society Olympiad Examinations Task Force
60 questions
8 questions
2 lab problems
single-answer multiple-choice
problem-solving, explanations
laboratory practical
1 hour, 30 minutes
1 hour, 45 minutes
1 hour, 30 minutes
A periodic table and other useful information are provided on page 2 for student reference. Students should be permitted to use nonprogrammable calculators.
DIRECTIONS TO THE EXAMINEEPART I
DO NOT TURN THE PAGE UNTIL DIRECTED TO DO SO. Answers to questions in Part I must be entered on a Scantron
answer sheet to be scored. Be sure to write your name on the answer sheet; an ID number is already entered for you. Make a record
of this ID number as you will use the same number on both Parts II and III. Each item in Part I consists of a question or an
incomplete statement which is followed by four possible choices. Select the single choice that best answers the question or completes
the statement. Then use a pencil to blacken the space on your answer sheet having the same letter as your choice. You may write on
the examination, but the test booklet will not be used for grading. Scores are based on the number of correct responses. When you
complete Part I (or at the end of one hour and 30 minutes), you must turn in all testing materials, scratch paper, and your Scantron
answer sheet. Do not forget to turn in your U.S. citizenship statement before leaving the testing site today.
Not valid for use as an USNCO National Exam after April 16, 2000.
Distributed by the ACS DivCHED Examinations Institute, Clemson University, Clemson, SC. All rights reserved. Printed in U.S.A.
amount of substance
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi- prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
CONSTANTS
m
m
M
mol
h
P
k
Rf
s
c
T
t
V
R = 8.314 Jmol1K1
R = 0.0821 Latmmol 1K1
1 F = 96,500 Cmol1
1 F = 96,500 JV1mol1
N A = 6.022 1023 mol1
h = 6.626 1034 Js
c = 2.998 108 ms1
2
He
1.008
4.003
3
Li
4
Be
5
B
6
C
7
N
8
O
9
F
10
Ne
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
181.0
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
111
112
(223)
226.0
227.0
(261)
(262)
(263)
(262)
(265)
(266)
(269)
(272)
(277)
Page 2
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
237.0
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(260)
Not valid for use as a USNCO National Exam after April 16, 2000.
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
Make no marks on the test booklet. Do all calculations on scratch paper provided by your instructor.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
(A) I only
(B) lithium
(C) mercury
(D) phosphorus
(B) H2
(C) NH3
(D) N2
0.0
2.0
4.0
6.0
8.0
10.0
(B) 10%
0.40
Absorbance
0.30
0.20
0.10
0
0
(C) 15%
(D) 20%
(B) 7.20%
(C) 8.27%
(D) 10.8%
9. A 0.200 g sample of
benzoic acid, C6H5COOH, Substance Molar Mass
is titrated with a 0.120 M
C 6H5COOH 122.1 gmol1
Ba(OH)2 solution. What
volume of the Ba(OH)2 solution is required to reach the
equivalence point?
(A) 6.82 mL
(B) 13.6 mL
(C) 17.6 mL
(D) 35.2 mL
12.0 cm
(B) 0.75
(C) 0.67
(D) 0.60
Not valid for use as an USNCO National Examination after April 16, 2000.
Page 3
(A) 5.15 g
(B) 14.3 g
(C) 19.4 g
(D) 26.4 g
(B) 0.24 M
(C) 0.48 M
(D) 0.70 M
2.53
1
34.0 1.38
3
(D) 2.50 10
1.38
2.53
34.0
(C) 300 mL
740 mmHg
740 mmHg 20 mmHg
(D) 300 mL
740 mmHg
740 mmHg + 20 mmHg
1.0
A B C
T, C
(A) A
(B) metallic
(C) molecular
Page 4
(B) 300 mL
34.0
2.50
2.53
3
(C) 2.50 10
(A) 4
16. Hydrogen is
Compound
Vapor Pressure
collected over water
at 22 C
at 22 C and a
H2O
20. mmHg
barometer reading
of 740 mmHg. If 300. mL of hydrogen is collected,
which expression will give the volume of dry hydrogen
at the same temperature and pressure?
740 mmHg 20 mmHg
(A) 300 mL
740 mmHg
P,atm
(B) 6
(C) 8
(D) 12
(B) B
(C) C
(D) D
19. Consider this equation and the associated value for Ho.
2H2(g) + 2Cl2(g) 4HCl(g)
Ho = 92.3 kJ
Which statement about this information is incorrect?
(A) If the equation is reversed, the Ho value equals
+92.3 kJ.
(B) The four HCl bonds are stronger than the four bonds
in H2 and Cl2.
(C) The Ho value will be 92.3 kJ if the HCl is
produced as a liquid.
(D) 23.1 kJ of heat will be evolved when 1 mol of
HCl (g) is produced.
Not valid for use as an USNCO National Examination after April 16, 2000.
(A) 1074.0 kJ
(B) 22.2 kJ
(C) +249.8 kJ
(D) +2214.6 kJ
0.40
Molarity
0.30
0.20
0.10
0
0
(A) zero.
(B) first.
(C) second.
(D) third.
Bond
Bond Energy
HH
OO
O=O
HO
436
142
499
460
(A) 127 kJ
(B) 209 kJ
(C) 484 kJ
(D) 841 kJ
60
20 40
Time, sec
kJmol1
kJmol1
kJmol1
kJmol1
(B) 3.5 Ci
(C) 7.1 Ci
(D) 12 Ci
0.010
0.010
0.020
0.010
0.010
0.010
0.010
0.020
1
2
2
4
Not valid for use as an USNCO National Examination after April 16, 2000.
Page 5
15
(C) 1.7 10 s
2
(B) 5.8 10 s
(B) H2PO4(aq)
(C) H3O+(aq)
(D) PO43(aq)
HCO3
2.4 108
tablet is to be determined
by dissolving the tablet in water and titrating the
resulting solution with hydrochloric acid. Which
indicator is the most appropriate for this titration?
(A) methyl orange, pKin = 3.7
(B) bromothymol blue, pKin = 7.0
(C) phenolphthalein, pKin = 9.3
(D) alizarin yellow, pK in = 12.5
38. How many moles of
Acid
Ka
NaOCl must be added to
HOCl
2.8 108
150 mL of 0.025 M HOCl
to obtain a buffer solution with a pH = 7.50?
(A) 2.6 105
(A)
0.10
0.10
0.10
(B)
1.0
1.0
1.0
(C)
1.0
0.10
0.10
(D)
1.0
1.0
0.10
Acid
HOCl
Ka
2.8 108
(D) 4 only
(B) H3PO4
(C) H2SO3
(D) HClO3
Page 6
Not valid for use as an USNCO National Examination after April 16, 2000.
Cu (aq) + 2e Cu(s)
Eo = 0.34 V
(B) 2
(C) 4
(D) 6
(A) Mg
(B) Al
(C) Si
(D) P
salt bridge
Ag
Cu
Ag+ (aq)
Cu2+ (aq)
(B) 88.8 kJ
(C) 243 kJ
(D) 374 kJ
(B) B, N, O
2+
(C) Mg, Mg , Mg
49. When the atoms Li, Be, B, and Na are arranged in order
of increasing atomic radius, what is the correct order?
(A) B, Be, Li, Na
(A) SO3
(B) SO32
(C) ClF3
(D) ClO 3
N N O
mass of Ag
44. In the galvanizing process, iron is coated with zinc. The
resulting chemical protection is most similar to that
provided when
(A) a magnesium bar is connected to an iron pipe.
(B) an iron can is plated with tin.
(A) +1
(B) 0
(C) 1
(D) 2
52. How many bonding pairs and lone pairs surround the
central atom in the I 3 ion?
Bonding Pairs
Lone Pairs
(A)
(B)
(C)
(D)
Not valid for use as an USNCO National Examination after April 16, 2000.
Page 7
53. The nitrogen atoms in NH3, NH2, and NH4+ are all
surrounded by eight electrons. When these three species
are arranged in order of increasing HNH bond angle,
what is the correct order?
(B) C 3H6
(C) C 3H8
(D) C 4H6
O
H3C C C N
1 2 3
(A) sp , sp, sp
(B) sp , sp , sp
(C) sp , sp , sp
(D) sp , sp , sp
(C) 4
(D) 5
(B) alcohol
(C) aldehyde
(D) alkene
(B) 2 only
(A)
H3C
(B)
(B) 3
CH3
O
C CH3
(C)
CH3
(A) C 10H12
(B) C 10H14
(C) C 12H12
(D) C 12H14
CH3
(D)
O
C O CH3
END OF TEST
Page 8
Not valid for use as an USNCO National Examination after April 16, 2000.
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
Answer
C
D
C
A
B
B
B
C
A
B
D
C
B
C
D
A
B
D
C
B
Number
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
Answer
A
A
C
A
A
A
C
D
C
C
B
D
C
A
D
B
A
C
D
B
Number
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Answer
B
D
B
A
C
B
C
D
A
A
A
B
D
C
D
C
D
B
A
D