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INTRODUCTION
In order to emphasize the effects of the bio-phyto-modulators on composite materials,
a layered fiber reinforced composite material was investigated. Such materials, increasingly
used for manufacturing strength structures, are made of a matrix (polymer) and reinforcement,
chosen depending on the characteristics and service conditions of the designed product.
For the matrix one uses polyesters, acrylates, polyamides, etc. Such materials have to
fulfill several conditions in order to be able to replace metals in strength structures: high
mechanical strength and stiffness, stability, resistance to high temperatures, thermal stability,
resistance to corrosion, humidity and chemical factors, high dielectric resistance, resistance to
flaming arc, etc.
Fibers or other reinforcements are introduced in the matrix to obtain materials with better
mechanical properties, compared to the base material. The influence of the reinforcements on
the plastic material differs as a function of the material, the arrangement, proportions, and the
possibility of obtaining a good adherence between the polymer and the reinforcement. The
choice of the reinforcement is made based on the knowledge of the conditions that the
material should fulfill: ultimate tensile, bending and shock strength and Youngs modulus
higher than those of the matrix, chemical resistance with respect to the matrix, shape
according to the functional role and surface with good adherence with the matrix.
Materials most used for reinforcement are: glass fibers, carbon fibers, asbestos fibers,
silica fibers, quartz fibers, boron fibers, graphite fibers [1].
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Layered fiber reinforced composites are the most used worldwide. Owing to their
configuration and the reduced number of elastic constants necessary for their characterization,
the analysis of structures made of such materials can be made with high precision. Such
materials are among the very few for which strength calculations can be made regardless the
complexity of the structure.
The fibers can be: continuous (uni- or bi-directional, woven, and multi-directional) or
discontinuous (uni-directional or randomly oriented).
A layered fiber reinforced composite is obtained by gluing several laminae (layers)
with different fiber orientations. If two or more laminae have the same orientation, a group of
laminae is formed.
The disposal of the fibers in laminae or groups of laminae is made depending on the
necessary mechanical performances for the designed structure.
The layered composite is characterized by the number of laminae and the orientation
angle of the fiber in the lamina.
Each lamina has assigned a local system of axes Olt, in which the axis Ol is parallel to
the direction of fibers, and the axis Ot is normal to the direction of fibers and in the plane of
the lamina [2].
z
l
x
>0
h/2
3
2
1
y
Each lamina is characterized by the angle between the direction of fibers (axis Ol)
and the axis Ox).
The setting of the laminae can be described starting from the surface of the material,
located at z = - h/2 and ending at z = h/2. For a group of laminae, a subscript denoting the
number of laminae in the group is used. A layered [0/903/0/45] contains six laminae with
fibers oriented at 0, 90 and 45 with respect to Ox, the 90 laminae being three.
A layered composite has mirror symmetry if identical laminae (as type and
orientation) are symmetrical with respect to the xOy plane. An example is the composite
[90/02/-45/45]S, made of 10 laminae symmetrically disposed with respect to the middle plane
(see subscript S). The fibers are oriented as follows with respect to the Ox axes: 90 (two
laminae), 0 (four laminae), 45 (two laminae) and 45 (two laminae).
The study of a certain structure made of layered fiber reinforced composites should
consider five elastic constants [3]:
- El - elastic modulus of the lamina on the fiber direction (direction of Ol axis);
- Et - elastic modulus of the lamina on a direction normal to the fiber (direction of Ot
axis);
- Glt - shear modulus of the lamina (in the Olt plane);
- lt Poissons ratio in the Olt plane;
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The first set of three specimens, which were not subjected to the influence of modulators,
were tested in order to obtain the characteristic curve of the material and the mechanical
characteristics.
In order to quantify the influence of the bio-phyto-modulators on the mechanical
characteristics of composite materials, the specimens were tested after being put in contact
with the modulators for 50 hours (two specimens), 91 hours (four specimens), 139 hours (four
specimens) and 312 hours (three specimens).
RESULTS AND DISCUSSION
The characteristic curves of the materials are shown in Figs. 4 to 8.
Specimen 1 to 3
140
120
100
Specimen #
80
1
2
3
60
40
20
0
0
Fig. 4. Characteristic curves of the composite material without the influence of modulators
Specimen 1 to 3
140
120
100
Specimen #
80
1
2
3
60
40
20
0
0
Fig. 5. Characteristic curves of the composite material influenced by modulators for 50 hours
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Specimen 1 to 4
140
120
100
Specimen #
80
1
2
3
4
60
40
20
0
0
Fig. 6. Characteristic curves of the composite material influenced by modulators for 91 hours
Specimen 1 to 4
120
100
Specimen #
80
1
2
3
4
60
40
20
0
0
Fig. 7. Characteristic curves of the composite material influenced by modulators for 139 hours
Specimen 1 to 3
140
140
120
100
Specimen #
80
1
2
3
60
40
20
0
0
Fig. 8. Characteristic curves of the composite material influenced by modulators for 312 hours
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For a birds eye view and a comparative study about the influence of the modulators
on the elastic constants and mechanical characteristics of composites, graphs from Figs. 9-12
were plotted. In these plots, the characteristics are represented as a function of the number of
hours in contact with the modulator.
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CONCLUSIONS
The abovementioned behavior can be explained by:
- the anisotropy of the material, that is modulators have different influence on the
materials from which the composite is manufactured;
- the fact that the fibers have micrometric dimensions and are flawless, with high
tensile strength, and the influence of the modulators is insignificant;
- the appearance and favoring of the debonding fiber-matrix phenomena, following the
action of the modulators, due to the influence of the modulators on matrix (practically, the
modulators modify only the characteristics of the plastic material);
- following a higher exposure time in the field generated by the modulators, the
material becomes more fragile, losing the elasticity given by the matrix; this can be explained
by the fact that the adherence fiber-matrix decreased and the material did not behave as a
composite, the fibers being those that make resistance.
In order to clarify the complexity of phenomena both at the interface fiber-matrix and
in the bulk of the material, a microscopic experimental study should be undertaken.
BIBLIOGRAPHY
1. Gheorghiu, H., A. Hadr and N. Constantin (1998). Analiza structurilor din materiale
izotrope i anizotrope, Printech Publishing House, Bucharest.
2. Gay, D. (1991). Matriaux composites. Ed. Hermes, Paris.
3. Hadr, A. (2002). Structuri din compozite stratificate Publishing House of the Romanian
Academy and AGIR, Bucharest.
4. Constantinescu, I. N., C. Picu, A. Hadr and H. Gheorghiu (2006). Rezistena materialelor
pentru ingineria mecanic. BREN Publishing House, Bucharest.
5. Hadr, A., Fl. Baciu, H. Gheorghiu and A. Dinc (2010). Influena modulatorilor bio-fitodinamici de tip AD asupra caracteristicilor mecanice ale unor materiale plastice. The Informative
Bulletin of the Center of Biosynergetic Studies and Researches Dinc Ancu Bucharest, Ed.Tipolex.
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