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NATIONAL
CHEMISTRY OLYMPIAD
NATIONAL EXAM PART I
Prepared by the American Chemical Society Chemistry Olympiad Examinations Task Force
Property of ACS USNCO Not for use as USNCO National Exam after April 28, 2014
Distributed by the American Chemical Society, 1155 16 th Street, N.W., Washington, DC 20036
All rights reserved. Printed in U.S.A.
amount of substance
ampere
atmosphere
atomic mass unit
Avogadro constant
Celsius temperature
centi prefix
coulomb
density
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
n
A
atm
u
NA
C
c
C
d
E
Ea
H
S
K
CONSTANTS
M
mol
h
P
k
Q
s
c
T
t
VP
V
V
R = 8.314 Jmol 1K 1
R = 0.0821 Latmmol 1K 1
1 F = 96,500 Cmol 1
1
1 F = 96,500 JV mol 1
EQUATIONS
E Eo
1
1A
1
H
RT
ln Q
nF
k E 1 1
ln 2 a
k1 R T1 T2
H 1
ln K
constant
R T
18
8A
2
He
3
Li
2
2A
4
Be
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
1.008
4.003
10
Ne
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Cn
113
115
118
(Uup)
116
Lv
117
(Uut)
114
Fl
(Uus)
(Uuo)
(223)
(226)
(227)
(261)
(262)
(271)
(270)
(277)
(276)
(281)
(280)
(285)
(284)
(289)
(288)
(293)
(294)
(294)
Page 2
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(262)
Property of ACS USNCO Not for use as USNCO National Exam after April 28, 2014
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
(B) 10
(C) 15
(D) 16
(B) C14H10O4
(C) C13H6O4
(D) C15H14O3
(B) 69.7 g
(C) 57.2 g
(D) 113 g
(B) chloride.
(C) oxide.
(D) sulfide.
(B) colloid.
(C) emulsion.
(D) solution.
(A) 0.015 ng
(B) 0.015 g
(C) 0.015 mg
(D) 0.015 g
(B) NaBr
(C) KNO3
(D) MgSO4
(B)
(C)
(D)
1
1
(B) Ne
(C) Ar
(D) Rn
Property of ACS USNCO Not for use as USNCO National Exam after April 28, 2014
Page 3
Hf, kJmol
(D) viscosity
14. A 0.180 g sample of liquid H2O is injected into a 5.00 L
flask at 25 C. What will be present in the flask when
equilibrium is established?
(Vapor pressure H2O at 25 C = 23.8 mm Hg)
(A) H2O vapor at a pressure of 186 mm Hg
(B) H2O vapor at a pressure of 37.2 mm Hg
(D) liquid H2O and H2O vapor at a pressure of 23.8 mm Hg
15. The atmospheric pressure on the summit of Mt. Everest is
0.333 atmospheres. At what temperature (in C) does
(C) 96 C
(D) 98 C
Hf, kJmol 1
S, kJmol 1K-1
(A) 162 K
(B) 509 K
O2(g)
0.205
(C) 1060 K
(B) cis-2-butene
(C) trans-2-butene
(D) cyclobutane
Ga
H2O
0.371
4.184
melting point
C
30.0
(B) 38.1 C
(C) 41.8 C
(D) 52.6 C
5.576
(D) ReO3
Page 4
Hfus, kJmol
(A) 35.0 C
(B) Re2O3
(D) 1540 K
(A) 1-butene
(A) ReO
SO3(g)
395.7
0.257
Cp, Jg 1K
H2O(l)
285.8
CO2(g)
393.5
(A) 71 C
CH3CHOHCH3(l)
318.2
(B) +57.2 J
(C) 114 J
(D) 57.2 J
Property of ACS USNCO Not for use as USNCO National Exam after April 28, 2014
molL 1
in molL 1s 1
1
0.060
0.040
3.6 10 4
2
0.060
0.080
7.2 10 4
3
0.030
0.12
5.4 10 4
What is the rate law for the reaction?
26.
27. What are the units for the rate constant of a zero-order
reaction?
1
(A) time
(B) time
(C) Mtime
(D) Mtime
(slow)
A + M C + D (fast)
(C) B M
(slow)
M+AN
(fast)
N + A C + D (fast)
(B) A + A M
(fast)
B + M C + D (slow)
(D) B M
(fast)
M+AN
(slow)
N + A C + D (fast)
(B) 37.5 mL
(C) 25.0 mL
(D) 50.0 mL
2 OF2(g), Kp = 41.0.
32. For the reaction, O2(g) + 2 F2(g)
If PO2(g) = 0.116 atm and PF2(g) = 0.0461 atm at
equilibrium, what is the pressure of OF2(g)?
(A) 0.101 atm
(D) 36 hours
(A) 12.34
(B) 12.14
(C) 12.04
(D) 11.84
(B) 7.4 10
3
5
Property of ACS USNCO Not for use as USNCO National Exam after April 28, 2014
(B) 5.4 10
(D) 1.6 10
4
5
Page 5
2+
(B) 2
(C) 4
(D) 6
(B) Si
(C) P
(D) S
47. What are the two most common oxidation states for
antimony?
(A) I only
(B) II only
(A) 1 and 3
(B) 1 and +2
(C) +3 and 3
(D) +3 and +5
39. Given the reactions and data below, what is the K value
for this electrochemical cell?
Cu|CuNO3(1.0 M)|| I(1.0 M),I2(1.0 M)|Pt at 25 C
Reaction
E (V)
Cu+ + e Cu
0.518
I2 + 2 e 2 I
0.534
(B) 1.86
g)
2+
(A) 0.288
28
(C) 2.23
(D) 3.48
48. For which pair of species are the radii most similar?
(A) Li and Na
(B) Na and Mg
(C) Mn and Fe
(B) Cr
(C) Ni
(D) Zn
[Fe2+]
1104 M
(B) 0.45 V
[Mn2+]
1.0 M
[Fe3+]
1.0 M
(C) 0.64 V
pH
3.00
(D) 1.28 V
Page 6
(B) 2
(C) 3
(D) 4
51. How many stable resonance forms can be written for the
oxalate ion, C2O42?
(A) two
(B) three
(C) four
(D) five
(C) tetrahedral
(D) T-shaped
(B)
(C) 1
(D) 1
Property of ACS USNCO Not for use as USNCO National Exam after April 28, 2014
I.
II.
(A) I only
(B) II only
60. Which type of dietary fat is the least healthy for humans?
increase
(from 0.15 to 0 nm)
(B) K+
(C) Mg2+
(D) Ca2+
END OF TEST
When you have finished answering this examination or time has
been called by the Examiner, please provide responses to the
following 4 items. Your answers will not affect your score on the
exam but will help with a study being conducted by the U.S.
National Chemistry Olympiad (USNCO) Subcommittee.
61. The amount of time I spend doing experiments in the
laboratory per week on average during my chemistry course
was/is?
(A) less than hour
(B) between and 1 hour
(C) between 1 and 2 hours
(D) more than 2 hours
The following questions should be answered using the scale
(A) Strongly agree
(B) Agree
(C) Disagree
(D) Strongly disagree
62. As a result of my participation in the USNCO program,
I plan to study more chemistry.
63. As a result of my participation in the USNCO program,
I plan to major in chemistry in college.
64. As a result of my participation in the USNCO program,
I have a more positive view of chemistry than I did before
participating.
Property of ACS USNCO Not for use as USNCO National Exam after April 28, 2014
Page 7
Olympiad 2014
USNCO National Exam Part I
KEY
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
D
B
A
C
D
A
C
A
C
D
D
C
C
D
A
D
B
D
A
C
D
A
B
B
A
C
D
C
B
C
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Answer
B
A
A
B
B
B
C
C
D
B
B
A
B
C
C
C
D
C
B
B
C
B
A
A
A
B
B
A
B
D