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Crystalline-Metallic
CrystallineStructures :
Examples:
Body-Centered Cubic
Face-Centered Cubic
Magnesium
Body-Centered Cubic
Face-Centered Cubic
Nonmetallic Materials
In contrast to metallic materials, nonmetallic materials such as glass, plastics and elastomers
have a noncrystalline structure. The atoms making up these materials do not possess the
periodicity of a crystal, i.e., they have no long-range order.
Ceramics, which are also classified as nonmetallic materials, can exhibit a crystalline structure.
An example of a ceramic material is aluminum oxide (Al2O3).
Plastics
The American Society for Testing and Materials (ASTM) defines a plastic as a material that
contains as an essential ingredient an organic substance of large molecular weight, is solid in its
finished state, and at some stage in its manufacture or in its processing into finished articles can
be shaped by flow.
There are two types or classes of plastics:
Thermoplastics soften with increasing temperature and return to their original hardness when
cooled.
Thermosetters cannot be softened by heat and will char or burn as the temperature is increased.
Plastics do not corrode like metals. Among the types of plastic deterioration are loss in
mechanical properties, swelling, softening, hardening, and color change.
Elastomers
Elastomers, such as natural and synthetic rubbers, have good elastic, resilience, and flexibility
properties. Certain elastomers have good chemical and abrasion resistance and are used in
corrosive environments.
Principle uses for hard materials include:
Hoppers handling coke are lined or constructed of hard, erosion resistant materials to minimize
the abrasive action of coke fines.
Shafts for pumps, turbines, compressors and valve stems are made of materials hardened by heat
treatment.
Strength at Low or Elevated Temperatures
Examples of items of equipment include pressure vessels, heat exchangers, valves and items of
rotating machinery such as pumps, compressors and turbines.
Corrosion and Erosion Resistance
Heat treatments which increase hardness are often used to increase a materials erosion resistance.
In general, materials that exhibit high hardness are usually more erosion resistant than soft
materials.
M-P
P-M
M-G
M-G
M-G
M-G
M-G
M-G
P-M
P-M
M-G
P-M
P-M
M-G
M-G
Characteristics of Plastics
Thermoplastics
Thermoplastics such as fluorocarbons (teflon, KEL-F), polyethylene, and polypropylene have
good resistance to many corrosive media, but limited service temperature range compared to
many metals. Uses include buried raw water piping and associated valves, valve seals and
gaskets, tape, valve diaphragms, and linings.
Elastomers
Elastomers such as Nitrile (Buna-N), Styrene-butadiene (Buna-S), Chloroprene (Neoprene),
Fluorocarbon (Viton), etc. have good resistance to many corrosive media. In the oil and
petrochemical industries they are used in the form of hose, tubing, seals, O-Rings, gaskets,
and occasionally tank linings. A significant limitation associated with these materials is that
they are not suitable for elevated temperature service. Neoprene, Buna-N, and Buna-S are
limited to temperatures below about 121 C (250 F). Viton, which is a fluoroelastomer can
be used at tempertures up to 260 C (500 F). Elastomers exhibit poor strength, and
consequently should never be used to fabricate pressure-retaining components, unless the
material is reinforced.
Thermosettin gPlastics
Thermosetting plastics such as epoxies, phenolics and polyesters are resistant to various
corrosive media and have relatively good mechanical properties. Fiber-reinforced plastics
(FRP) are thermosetting resins that are filled or reinforced with cloth, mat or chopped fibers.
FRP material is fiberglass reinforced epoxy. FRP materials are used for the fabrication of
underground storage tanks, pressure vessels, pipes, ducts, and small water or chemical injection
pumps.
Titanium
Titanium exhibits good strength-to-weight ratio, excellent corrosion resistance to brackish
water and certain very corrosive process media. Titanium uses include heat exchangers (all
components), and piping.
Plastics:
Thermoplastic
Thermosetting
Fiber-Reinforced Plastics
Elastomers
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GLOSSARY
atoms
characteristics
corrosion resistance
crystalline
ductility
erosion resistance
hardness
structure
tensile strength
toughness
yield strength
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