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Chemical Corrosion
Corrosion is the surface disintegration of
metals/alloys within specific environment.
Some metals basically exhibit high
corrosion resistance than others and this
can be attributed to several factors like
their chemical constituents, the nature of
electrochemical reactions itself and
others. The corrosion resistance of metals
can be defined in terms of its ability to
withstand aggressive conditions. This determines to a large extent the
operational lifetime of components in service. It is realized that the most
widely used definition of corrosion is the degradation of material by its reaction
with its environment. The fact that corrosion needs to be controlled cannot be
overemphasized in view of the colossal amount of money that is expended on
it annually. Materials are protected from corrosion through a wide variety of
methods.
By retarding either the anodic or
cathodic reactions the rate of
corrosion can be reduced. This can be
achieved
in
several
ways:
Conditioning the Metal or Conditioning
the
Corrosive
Environment.
Conditioning the Metal can be subdivided into two main groups which is
Coating the metal, in order to
interpose a corrosion resistant coating
between metal and environment or Alloying the Metal. Again the coating may
consist of another metal, e.g. zinc or tin coatings on steel, a protective coating
derived from the metal itself, e.g. aluminium oxide on anodised aluminium,
organic coatings, such as resins, plastics, paints, enamel, oils and greases.
The action of protective coatings is often more complex than simply providing
a barrier between metal and environment. Paints may contain a corrosion
inhibitor.