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SINHA’s I. I.T.

CHEMISTRY -1-

Unstable functional groups in organic chemistry and their stable products.

Enols. en-oxy, gem-diols, gem triols, hemiacetals ,ol-amines of the following


kinds are unstable and rearranges to more stable products as shown.
O
OH
1. H3C H3C + H2O
OH H

OH O
2. H3C
+ H3C + H2O
OH
HO OH

OH O

H3C + H3C OH
3. H3C
H
O CH3

OH O

4. H2C H3C

H
H

O
OH

H3C
5. H2C
CH3
CH3

HO O
O
6.
OH
H

OH
O CH3

7. CH3
HN
H3C N +
H3C H CH3

CH3

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