Ft1-Adv-P2 Sol

1
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JEE(Advanced)-2015
ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(Paper-2)
ALL INDIA TEST SERIES
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AITS-FT-I (Paper-2)-PCM(Sol)-JEE(Advanced)/15
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
A, B
A, B
A, B, C
6.
B, D
B, D
A, CD
7.
A, D
A, D
A, B, C, D
8.
A, D
A, C, D
A, B, C
9.
10.
11.
(A) (p, r, s)
(B) (p, q, r, s, t)
(C) (p, s, t)
(D) (p, s)
(A) (p, q, r, s, t)
(B) (p, q, r, s, t)
(C) (p, q, r, s, t)
(D) (p, q, r, s, t)
(A p, q, r, s)
(B p, q)
(C p, q, r, s, t)
(D q)
(A p, q, t)
(B p, q, s, t)
(C q, r, t)
(D p, q, t)
(A) (r, s)
(B) (p, q)
(C) (r)
(D) (s)
(A) (q, s, t)
(B) (p, r)
(C) (s, t)
(D) (q, s)
1.
2.
3.
4.
5.
6.
1.
2.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
SECTION A
7.
-radiation being neutral is not deflected by magnetic field & particle may follow helical path or
straight line depending upon velocity of particle & magnetic field.
8.
Comparing the eqn. with velocity of projectile
v ucos i u2 sin2 2gy j
k 22
, ax 0
2
Motion will be projectile motion and hence the result.
m k 22
Force acting on particle will be constant & equal to
2
2
m k2
<F>=
2
Acceleration of particle a y
9.
(h11g)A = (h22g)A
h1 2
h2 1
10.
(h1 + x1)1g = (h2 + x2)2g

x1/x2 = 2
x1 + x2 = 3
x1 = 2 m
(i)
(ii)
11.
W1 dW1 (p0 x1g)Adx = 260 J

2
2
W2 dW2 (p0 x2 g)Adx = 130 J

1
W = W 1 + W 2 = 390 J
SECTION C
4.
L
RC = L/R i.e. time constants of RC & LR
C
circuit are same.
After switching from 1 to 2
i0
2R
from loop rule,
(i0 i1) R + /2 + i1 R = 0
2i R
i1 0
0
4R
R
3
5.
mgx 2
1 2 1 2
kx 2 kx 2
2
2
1 3mg
3mg
k
mg
2 k
k
Reference level
9m2 g2 3m2 g2 3m2g2

mgx 2
2k
k
2k
2 2
2 2
2k x 2 2mgkx 2 3m g 0
Natural position of springs 2 and 1
x0 = mg/k
kx12
x2
Velocity is zero
x2
x2/2
x1 = 3mg/k
New equilibrium position
equilibrium position
2mgk 4m2 g2k 2 24m2 g2k 2
4k 2
2mgk 2mgk 7 mg
=
[ 7 1]
2k
4k 2
x
mg 7
10 7
1
A 0 x2
m 5cm
2
2k
20
2 100 7
6.
0 Vst = x1
0 + V s t = x 2
x2 x1
x x2
Vs =
= 60 m/s & 0 = 1
= 1.1 m
2T
2
Speed of sound V = n 0 = 330 m/s
Frequency detected at point Q
V
n=
300Hz 330Hz
V Vs
Chemistry
PART II
SECTION A
2.
H2 C
CH3
CH3
CH3
CH3
H3 C
OH
O
O
OH
CH3
CH 2
CH3
CH3
4
3.
Ph
PhNHNH
Ph
Oet
Oet
Ph
O
N
HN
N
Ph
Ph
4.
XeOF4 is square pyramidal in shape

O
F
F
Xe
Due to lone pair-bond pair repulsion the four F atoms move away from lone pair resulting in the
movement of Xe towards lone pair.
F
Cl
Cl
P
Cl
F
The most electronegative substituent lies at the axial position to minimize bond pair-bond pair
repulsion.
Cl
Cl
Cl
P
Cl
Cl
PCl5 shows sp3d hybridisation with the involvement of axial dz2 orbital. Since the axial Cl is at 90
hence suffers relatively greater repulsion increasing the axial bond length.
The size of F is smaller than Cl leading smaller CF bond length decreasing the dipole moment.
5.
Surface tension of lyophilic aquasols is lower than that due to force of attraction between
dispered phase and dipersion medium.
Its viscocity is higher due to force of attraction between phase and disperesion medium.
8.
White salts or ions giving colourless beads do not give borax bead test.
9.
Cu2+ + 2e Cu
2
+
Hence SO4 ions are left which form H2SO4 with H from H2O.
11.
At anode:
2OH
H 2 O
Equivalent volume Ve =
1
O 2 2e
2
22.4
5.6 litre
2 2
5
ItVe
1 965 5.6 10 3
= 56 ml.
96500
96500
SECTION C
1.
At equilibrium relative lowering of vapour pressure of both the solution is same. Then
1 0.01 0.014
60
60
(1 + ) = 1.4
= 0.4
so
10 = 4
2.
Consider the unit cell face

So, atoms on face will be
1 1 1
= 1 1 atom
8 4 2
1
th
8
1
th
2
contribution
No. of atoms at one face of crystal

1
= 6 1030 1030 atm
6
No. of unit cells at one face of crystal = 6 1030 / 6
So no. of unit cells at edge of crystal = 1030 = 1015
4
Now edge length of one unit cell =
50 1015 n
2
4
So area of face of crystal =

50 1015 nm2
2
16
=
25 102 1030
2
= 2 1034 nm2
= 2 1018+34 m2
= 2 1016 m2
3.
Given P = 1.56 atm, V = 10 L

T = 317 K, R = 0.083 L
PV
1.56 10
Total moles (n) =
0.6 mol
RT 0.082 31%
Let CxH8 be a mol, therefore moles of CxH12 = (0.6 a) mol. Mass of C in a mol of CxH12 = 129 x
gm.
Mass of C in (0.6 a) mol of CxH12 = 12 (0.6 a) gram
Total mass of C in mixture = 12ax + 12x (0.6 a)g
= 41.4 g
6
7.2x
100
41.4
Given % of C = 87%
Or
720x
87
41.4
x=5
% of C in mixture =
4.
For A B
AB
AB
A B
When 2A 2B
2AB
Now eq. conc. will be 2 times of AB

5.
SrF2
Sr aq 2F aq
Ksp Sr 2 F
Sr 2
Ksp
2
7.9 1010
2
4.938 107 M
F
4.0 102

This concentration of Sr+2 ions should also satisfy the other expression for SrCO3
2

SrCO3 s
Sr aq CO3 aq
Ksp Sr 2 CO3
10
CO3 Ksp 7.0 10
Sr 2 4.938 10 7
= 1.4 103
6.
O
CH2
Mathematics
H2C
CH
CH2
H
N
PART III
SECTION A
1.
x x
Write the functional equation as f x f
2 2
x
x
x

f f
2 4 4
x x x
f f
4 8 8
7
x x
f n1 f n
2 2
x
n
2
x
Adding up we obtain f x f n
2
x
Hence, lim f x f n x
n
2
1
1 1 1
x ..... n
2
2 4 8
2.
Differentiating the given equation 2014 (f(x))2013 f(x) = f(x)

2014 (f(x))2012 f(x) = 1
2013
2014
Integrate
f x
xc
2013
2014
f(0) = 1 c
2013
2013
2013
Hence, f x
x 1
2014
(f(2014))2013 = 2013 + 1 = 2014
3.
Let Ai the event that student correctly solves exactly i of the three proposed problems
(Where i = 0, 1, 2, 3)
Required probability = P(A) = P(A2 A3) = P(A2) + P(A3)
Student know how to solve exactly half the problem
P(A0) = P(A3) and P(A1) = P(A2)
Also, P(A0) + P(A1) + P(A2) + P(A3) = 1
1
P(A) = P(A2) + P(A3) =
2
4.
Let r to in-radius and r1, r2, r3 are ex-radii of circle touching the sides BC, CA and AB respectively
of ABC
If is area of triangle and s is semi-perimeter, = rs = r1(s a) = r2(s b) = r3(s c)
1 1 1 s a sb sc s 1

r1 r2 r3
r
So, that r is the smallest term in G.P. Suppose that A B C
A
B
C
then r1 s tan r2 s tan r3 s tan
2
2
2
Hence, there is a number t > 1 for which r1 = tr, r2 = rt2, r3 = rt3
and (s b) = t(s c), (s a) = t2(s c), s = t3(s c)
By Herons formula t3r(s c) = r3(s c) = rs = =
Hence, r = s c, and so tan
5.
s s a s b s c t 6 s c t 3 s c
C
r
1 C = 90
2 s c
dy
= slope of line
dx
joining P and Q as P is always moving towards Q
Let Q (0, ) and P(x, y), (0 x)2 + ( y)2 = k2
If the curve traced by P is y = f(x) then
y=
K 2 x2
dy y
K 2 x2
dx 0 x
x
Solving the differential equation with initial condition f(K) = 0 gives
Q
K
P
(K, 0)
8
K K2 x2
y K ln
K 2 x2
6.
Differentiating the given equation 2f(x) f(x) = (f(x))2 + (f(x))2 (f(x) f(x))2 = 0
x
f(x) = f(x) f(x) = ce
f(0) = K c K f x Kex
7.
Point of intersection of P1 and L is given by mx + x + n = 0
2
Line is tangent if = 4mn m, , n are in G.P.
2
p
If point of intersection is rational (let x ) where p and q are co-prime
q
2
2
Then mp + lpq + nq = 0
.. (1)
Now, if one of p and q is even and other is odd then (1) can not hold as sum of an even and an
odd integer cant be zero
If p, q are odd then (1) can not hold true as sum of three odd numbers cant be zero
Common tangent to P1 and P2 is 2x y 1 = 0
Common chord of P1 and P2 is 2x + y = 0
8.
The sequence of two horses reaching the finishing line can be 2 or 1 + 1

Number of ways = 1 + 2! = 3
The sequence of three horses reaching the finishing line and number of ways are shown below
3 1 way
2 + 1 3C2 = 3 ways
1 + 2 3C2 = 3 ways
1 + 1 + 1 3! = 6 ways
Hence H3 = 1 + 3 + 3 + 6 = 13
The sequence of 4 horses reaching the finishing line and number of ways are shown below
4 1 way
4!
2+1+1
3! ways
2!
1!
1!
2!
3 + 1 4C3 ways
1 + 3 4C1
2 + 2 4C2
1 + 1 + 1 + 1 4!
Hence, H4 = 1 + 4 + 4 + 6 + 36 + 24 = 75
9.-11.
Equations of lines L1 and L2 can be obtained in symmetric form

x yb z
L1:
0
b
c
xa y z
L2:

a
0 c
x y b z
Equation of plane p: 0
a
c 0
x y z
1 0
a b c
Lines L1 and L2 in vector form
L1 r p1 q1 r bj bj ck and L2 r p2 q2 r ai 4 ai ck
9

p1 p2 q1 q2
Shortest distance =

q1 q2
2abc
bc
ca ab
a b 0
0 b c
a
bc
c
2
ac ab
1
4
1
1
1
1
2 2 2 64
4
a
b
c
SECTION B
1.
(A) f(x) = x[x]

f(x) is continuous at x = 0, but not differentiable at x = 0
f(x) is discontinuous at integers
(B) f(x) = x|x|
x 2
, x0
f x 2
x , x 0
f(x) is continuous and differentiable everywhere
2x , x 0
(C) f(x) = x + |x| =
0 , x 0
f(x) is continuous everywhere but not differentiable at x = 0
(D) f(x) = x = [x]
f(x) is discontinuous at integers
2.
(A) Given lines are

3x 4y + 5 = 0
.. (1)
4x + 3y 10 = 0
.. (2)
x+y+5=0
.. (3)
Radical centre of three circles described on sides of as diameter = orthocentre
As two lines are perpendicular to each other
So, orthocentre is point of intersection of (1) and (2)
Solving (1) and (2) x = 1, y = 2
So, radical centre (1, 2)
4x ky + 1 = 0 is the given line (0, 0) 0 + 0 + 1 > 0
So, for radical centre to be on opposite side 4 2k + 1 < 0
5 2k < 0
5
k
2
2
2
(B) x + 2xy + 2y = 0
x2 y2 xy
Equation of angle bisectors
.. (1)
1
(1 + )x2 8xy + y2 = 0
x2 y 2 xy
Equation of angle bisectors
.. (2)
4
For equally inclined lines (1) and (2) must represent same
1
So,
2 = 4, = 2
4
(C) y2 5x + 6y + 15 = 0
10
y 2 6y 9 5 x
5
6
2
y 3 5 x
5
5
2
Y = 4aX, a
4
6
Xx
5
For three normals to be distinct
X 2a > 0
6 5
x
5 2
5 6
x
2 5
37
x
10
(D) x2 + y2 6x = 0
x2 + y2 + 2x = 0
The triangle formed by common tangents
is ABC
CD 1
C
Let C (h, k),
CE 3
33
h
3
2
k=0
So, C (3, 0)
Equation of line thru Q, y = m(x + 3)
mx y + 3m = 0
This represents two tangents with two
difference values of m
m 3m
1
Length of perpendicular from D = Radius
m2 1
4m2 = m2 + 1
2
3m = 1
1
m
3
x
x
So, equation of tangents y
3 and y
3
3
3
A
3
1
D(1, 0)
E(3, 0)
B
1 : 3
D
(1, 0)
C
(h, k)
C
(3, 0)
A 0, 3 , B 0, 3 , C (3, 0)
AB = BC = CA = 2 3
So, P 6 3 , A
P
3
6,
A
3
3
2 3
4
3 3
11
SECTION C
1.
f(x) = x + 3x
f(x) = x 1 + 3x 1
f(x) > 0 x (0, 1)
f(x) = ( 1)x 2 + 3( 1)x 2 x (0, 1)
f(x) > 0 x (0, 1)
Hence, f(x) is monotonically increasing and concave upwards curve
0 1
B
,A=1
2
2.
Tr
r2
1 r
r
2r 1 2r 1 4 2r 1 2r 1
1 500 r
r
4 r 1 2r 1 2r 1
500
1 1 2 2 3 3 4
500 500
r
r
4S
= .....
2r 1
1 3 3 5 5 7 7
999 1001
r 1 2r 1
r
r 1
1
2r 1 2r 1
500 501000
Combining all such terms, we get 4S 1 499
1001
1001
125250
S
[S] = 125
1001
Number of divisors = 4
3.
I a a2 x 2 x dx 2a x x sin xdx sin2 xdx

0
Ia
a 8a
30
2
2
Ia
5
120
480
a 5 5
30
2

Hence, I(a) is minimum for a

4.
120
= 1, = 5
5
Dividing P(x) by Q(x) gives P(x) = Q(x)(x 2 + 1) + x2 x + 1

2
then
4
4
P
z
2
z
z
i i i j zi 4
i 1
i 1
i1
4
Use the formula for sum and products of the roots to obtain
P zi 1 2 1 4 6
i 1
B C xA yB zC

Taking dot product with B C

B2 C 2 B C

B C B C x A B C x

A B C
12

BC C A

Similarly taking dot with C A gives y

A B C

BC A B

and dot with A B gives z

A B C

A B C 12

B2 C2 B C 12
x=1
1
1
y and z
2
2
6
|aw + b| = 1
|aw + b|2 = 1 (aw + b) aw b a2 ab + b2 = 1

(a b)2 + ab = 1
When (a b)2 = 0 and ab = 1 then (1, 1), (1, 1)
When (a b)2 = 1 and ab = 0 then (0, 1), (1, 0), (0, 1), (1, 0)
Hence, total six ordered pairs

Ft1-Adv-P2 Sol

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1

ALL INDIA TEST SERIES

Comparing the eqn. with velocity of projectile

v ucos i u2 sin2 2gy j

(h1 + x1)1g = (h2 + x2)2g

W1 dW1 (p0 x1g)Adx = 260 J

W2 dW2 (p0 x2 g)Adx = 130 J

9m2 g2 3m2 g2 3m2g2

Natural position of springs 2 and 1

2mgk 4m2 g2k 2 24m2 g2k 2

XeOF4 is square pyramidal in shape

Consider the unit cell face

No. of atoms at one face of crystal

So area of face of crystal =

Given P = 1.56 atm, V = 10 L

Now eq. conc. will be 2 times of AB

Differentiating the given equation 2014 (f(x))2013 f(x) = f(x)

If the curve traced by P is y = f(x) then

Point of intersection of P1 and L is given by mx + x + n = 0

The sequence of two horses reaching the finishing line can be 2 or 1 + 1

Equations of lines L1 and L2 can be obtained in symmetric form

(A) f(x) = x[x]

(A) Given lines are

I a a2 x 2 x dx 2a x x sin xdx sin2 xdx

Hence, I(a) is minimum for a

Dividing P(x) by Q(x) gives P(x) = Q(x)(x 2 + 1) + x2 x + 1

|aw + b|2 = 1 (aw + b) aw b a2 ab + b2 = 1

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