Ft1-Adv-P1 Sol

1
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JEE(Advanced)-2015
ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(PAPER-1)
ALL INDIA TEST SERIES
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AITS-FT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
A, D
A, B, D
A, C
6.
B, D
A, B, C
A, B, C, D
7.
A, C
B, D
A, C, D
8.
B, C, D
B, C, D
A, B, C, D
9.
10.
11.
(A) (q)
(B) (p, q, s, t)
(C) (p, q, s, t)
(D) (r, s)
(A) (t)
(B) (q, s)
(C) (p, q, r)
(D) (t)
(A s, t)
(B p, q, r, t)
(C p, s)
(D q, s, t)
(A q)
(B p, t)
(C p, q)
(D s)
(A) (s)
(B) (q)
(C) (s)
(D) (p, r, t)
(A) (p)
(B) (q)
(C) (p)
(D) (r)
1.
2.
3.
4.
5.
6.
1.
2.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
SECTION A
3.
dp
50k N
Fnet
15i 20tj 50k = Freal Fpseudo and Freal mg(k)
dt
4.
= KA
dT
dx
Q
dx = K 0 (1 T)dT
A
0
Q
T2
x = K0 T
A
2 0
by solving
Q
T2
x K 0 T
A
2
So,
Q
(300)2
x0 K0 300
A
2
So, at x = 2x0 temperature T 425 K
5.
6.
m = V = A1 A 2 A1A 2 H
m
H
A1 A 2 A1A 2
A2 H
P1 = 1gH1
P2 = 2gH2 P1 > P2
F = mg FB = mg PA1
F1 = mg A1P1,
F2 = mg A1P2
2GMm
d2 y 2
2GMm
d2 y2
A2
F
mg
FB
A1
GM2
2d
2Gm2
2d
2
1
= 2Gm2

d2 y2 d
1
= U mv 2
2
3
7.
v = f =
8.
y 5e (
h E E
P
v

Particle
p h P 2m 2
a x b t )2
09-11. h = 160 m
2h
2 160
4 2 sec
g
10
Velocity of system after collision in vertical direction, v 10 = 30 m/s;
Velocity of system after collision in horizontal direction, v 20 40 = 10 m/s
t10
v120 900 + 2 10 80 v10 50 m/s
50 30
= 2 sec
10
4 sec
t 20
t10
SECTION - B
2.
Shape of sting at t = 0 is given by.

0
if x vt L
h(L x vt) / L if vt L x vt
y(x,t)
h(L x vt) / L if vt x vt L
0
if vt L x
O
y
O
x
((vt L), 0) (vt, 0) ((vt + L), 0)
SECTION C
2.
10gsin
= 5g sin
2
= 5 (2 sin /2 cos /2)

2
cos /2 = 1
10 sin
Ar
cycle
2A0
A0
2/3 s
3/4 s
5/6s
y1 = A sin 1t
y2 = A sin 2t
( 1 ) ( 2 1 )
yr = 2A cos 2
t sin
t
2
2
1/6 s
1/4 s
1/3 s
4.
1s
Resultant amplitude Ar = 2A|cos()t/2|

t
1
() t = s
2 2
4
t
1
( ) t = s
2 3
6
In one cycle of intensity of 1/2s, the detector remain idle for
1
1 1
2 s sec
6
4 6
4
1 1
In sec cycle, active time is = 1/3 sec
2 6
1/ 3
In 12 sec interval, active time is 12
= 8 sec
(1/ 2)
6.
V1
(2C)V 2
V
3C
3
1 4 2 2CV 2
C V
2 9
9
V
V2 =
3
U1
U2
1
V2
V 2 CV 2
(2C)
C
2
9
9
9
CV 2
3
1
Final total energy = (2C)V 2 CV 2
2
Initial total energy =
2
4
Charge flow through the battery 2CV CV CV
3
3
4
Wbattery CV 2
3
Heat dissipated
4CV 2 2CV 2 2
CV 2
3
3
3
Chemistry
PART II
SECTION A
1.
H3C
CH2
CH3 CH2 Cl
CaCN 2
H3C
H3C
H3C
C
H3 O
N
CH2
H3C
H3C
OH
CO
CH 2
CH3
CH2
N
CH 2
i 2CH3I
H
ii Moist Ag O
H3C CH2
CH 2
CH 2 CH3
OH
CH3
(A)
(B)
H
H2C
CH2 H3C
CH2 N
CH3 H2O
(C)
5
2.
CH3
H2 C
H2 C
CH3
O
CH2 CH2
CH3
OH
Anhydride AlCl
(minor)
O
i Zn Hg /HCl
ii SOCl2 /
CH2 CH2
OH
(major)
i Zn Hg / HCl
i SOCl2 /
Cl
CH3
O
Cl
Anhyd. AlCl3 / CS2
O
CH3
Anhyd. AlCl3 / CS2
CH3
O
(minor)
(major)
3.
N2O
C8H7OCl
287 m
Molar weight of C8H7OCl = 8 12 + 7 1 + 16 + 35.5

= 154.5 g
Molar weight of N2O = 2 14 + 16 = 44 g
According to Grahams Law of diffusion
rN2O
MC8H7OCl
154.5
3.5 1.87 : 1
rC8H7 OCl
MN2O
44
1.87
th
287 = 187 row from N2O side.
2.87
1.0
th
dC8H7OCl
287 = 100 row from weeping gas side.
2.87
Therefore, the spectator from the side of N2O in the 187th. Row will be laughing and weeping
simultaneously. Alternatively, the spectator from the side of weeping gas in 100th row will laugh
and weep.
The given orbital diagram has two radial nodes, i.e. n 1 2
The orbital, in which electron is present is 3s.
dN2O
4.
6
Cl
5.
H2C
(A)
Cl
CH
Cl H3C
CH
Cl
Cl
Cl
These occurs decrease in electron density and hence the ionization potential increases.
N
(B) Basic strength electron density over one N-atom
has lesser electron density over

N
one N-atom than in

N
(C) Heat of combustion
1
Stability
stability No. of H
and if no. of H of same stability ease of hyperconjugation.
(D) Conjugate acid of weaker base is stronger acid. Basic strength
NH2
NH2
NH2
CH3
CH3
6.
8.
B. pt. of CCl4 < that of SiCl4. The vapour must always be richer in more volatile component.
Hence, the upper curve represents the composition of the vapour and the lower curve represents
the composition of the solution at corresponding B. pt.
The correct basic order for (a) option
CH3O
CH3NH
>
(-ve) charge on most

electronegative atom
>
CH3CH2
(-ve) charge on least

electronegative atom
and it can also explain by its conjugate rest all option are correct.
Solution for the Q. No. 9 to 11.
M PbCO3
P Pb(NO3)2
B PbO
C CO2
D NO2
E O2
F CaCO3
G Ca(HCO3)2
Q PbSO4
R NaNO3
SECTION C
O
1.
14
14
14
14
OH
7
2.
ZB 4 2 2
ZA 4
ZC2 1
A 4B 2Z 1
x+y+z=7
o
3.
r2 = 5.49 A 2
o
2r = 83.05 A
o
then r = 13.22 A
0.529 n2
r
Z
0.529 n2
13.22 =
Z
n=5
Number of maximum lines possible = 3
CH3 COOH NaOH CH3 COONa H2O
4.
Int. No. of mole 106 V

at t t sec
10 6 V
0
0
6
10 V
CH3COONa
10 V
2V
= 5 107< 10-6.
Kw C
OH
Ka
=
104 107 5
1.9 105
= 2.63 108 < 106
so pOH = log (2.63 108 + 107)
pH = 7
pH
5
1.42
5.
Mn2 MnO2 2e
4e O2 2H2O
1 Eq of Mn+2 = 1 Eq of O2
(n = 2)
(n = 4)
mole of Mn+2 = 1 Eq. of O2
2 mole of Mn+2 = 4 Eq. of O2
8
6.
2C s O2 g
2CO g
Keq 103
C s O2 g Keq 10
CO2 g
C s CO2 g
2CO g
Keq 101 X
C s O2 g
2C s CO2 g Keq 1/ x 10
1
2CO g O2 g
2CO2 g Keq 10 Y
Hence X : Y = 1 : 1
Mathematics
PART III
SECTION A
1.
Let z1, z2 be the two roots with |z1| = 1

c
c 1
z 1z 2 =
z2
1
a
a z1
z1z1 z2 z2 1
b
and |b| = |a|
a
|z1 + z2|2 = 1
z1 z 2
1
1
(z1 + z2) z1 z2 1 z1 z2
1
z1 z2
(z1 + z2)2 = z1z2 b2 = ac
2.
For x [0, 1], f(x) f(1) ( f(x) is decreasing)

f 'x
f ' 1
2
2
f x 1 f x 1
1
f ' x
dx
f 2 x 1 dx f ' 1 f 2 x 1
0
dx
0 f x 1
tan1 f x f ' 1
0
tan1 f 1
dx
f 2 x 1 f ' 1
0
1
tan1 < > 0

1
dx
tan1 f 1
f ' 1
f 1
f ' 1
f 1
f 2 x 1 f ' 1
0
3.
P(x) = 0 has n real roots

x P(x) = 0 has n + 1 real roots
9
d
xP x 0
dx
x P(x) + P(x) = 0 has n real roots
x(x P(x) + P(x)) = 0 has n + 1 real roots
d 2
x P ' x xP x 0 has n real roots

dx
i.e. x2 P(x) + 3x P(x) + P(x) = 0 has n real roots (I) is true
Let one of the roots of P(x) = 0 is , and one root of Q(x) = 0 is as given,
P(x) Q(x) + P(x) Q(x) = 0
d
P x Q' x 0
dx
Consider f(x) = P(x) Q(x)
f() = 0, f() = 0
d
Hence, by Rolles theorem
P x Q' x 0 has at least one real root lying between and
dx
4.
Case-I:
a a
If a [0, 1], the curves intersect at , and (a, a). The bounded region is contained in the
3 3
1
1
triangle with vertices (0, 0), , 0 and (1, 1) with area =

4
2
1
Hence, area can not exceed
4
Case-II:
a a a
If a [1, 3]. In this case the bounded region is a quadrilateral with four vertices , , , 0 ,
3 3 2
1 a a 1 4 a
a
a2 4a
3 , 3 and (1, 1). In this case area bounded = 1 2 3 2 2 3 2 2
1 a 2
1
=
3
6
3
Case-III: If a [3, 4].
This case is symmetric with case-I
(2, 0)
a 1
, 0
2
5.
1 a
, 0
2
(2, 0)
a
, 0
2
Multiplying the first DE by gh, the second by fh and the third by fg, and adding the equations
gives
(fgh) = 6(fgh)2 + 6
Let f(x) g(x) h(x) = k(x)
We have k(x) = 6(k(x))2 + 6
Integrating and using k(0) = 1 gives
k(x) = tan 6x
4
10
Now 1st DE
f ' x
f x
2k x
1
k x
f ' x
2 tan 6x cot 6x
4
4
Integrating and using f(0) = 1 gives option A and C
6.
f x
By reflection property of ellipse PAF2 = QAF1

H1 is reflection of F1 QAH1 = QAF1
Now PH2 = PF2, PH1 = PF1
and F2H1 = F2A + AF1 = 2a
and F1H2 = F1B + BH2 = F1B + F2B = 2a
Hence, PF2H1 and PF1H2 are congruent as all three
sides are equal
This leads to all the options
P
H2
B
F2
7.
Let f(x) = a(x 1)(x 1)

f(x) f(x + 1) = a2(x 1)(x 1 + 1)(x 1)(x 1 + 1)
= a2(x2 + x 1x 1x + 11 1)(x2 + x 1x 1x + 11 1)
f(x) f(x + 1) = a2[(x2 (1 + 1 1) x + 11) 1] [(x2 (1 + 1 1) x + 11) 1]
Hence, g(x) = a2(x 1)(x 1) and h(x) = x2 (1 + 1 1) + 11
8.
Consider h(x) = x(1 + ln x), h: [1, ) [1, )

Clearly h(x) to increasing function in its domain
f() denotes the solution of x(1 + ln x) =
f: [1, ) [1, ), f is inverse function of h(x)
As lim h lim f
f '
H1
F1
1
h' x x f
f '

Now consider L lim
1
2 ln x
f ln
By LHospitals Rule L lim
lim
xf
1
2 ln f
f ln
f 1 ln f
= lim
ln
1 ln f
f
2 ln f
1/
lim
lim
f ' f f ' 1 ln f
ln f 1
1
L lim

1
ln f 1
9.
(I) holds true obviously

For (II): A B C a1, a2 b1 c 1, b2 c 2
= 2a1(b1 + c1) + a2(b2 + c2) + a1(b2 + c2) + a2(b1 + c1)

= (2a1b1 + a2b2 + a1b2 + a2b1) + (2a1c1 + a2c2 + a1c2 + a2c1)

= A B A C
Similarly it can be checked that (III) also holds true
10.

A B a1b1 a2b2 2 a2b1 2 a1b2
11
a b1 a2 b2
A B 1
2 2
3
A B
A B
2
11.
a2 b1 a1 b2 a1 a2 b1 b2
2

A B a1b1 a2b2 a3b3 B A
Hence, (I) holds true

A B C a1 b1 c1 a2 b2 c 2 a3 b3 c 3 a1b1 a2b2 a3b3 a1c1 a2c 2 a3c 3
a1b1 a2b2 a3b3 a1c1 a2c 2 a3 c 3

(II) Dont hold true
Similarly (III) can be checked
SECTION B
1.
Normal y + tx = at + 2at
at3 + (2a h)t k = 0
t1 + t2 + t3 = 0 t3 = (t1 + t2) .. (1)
2a h
t1t2 + t2t3 + t3t1 =
.. (2)
a
k
Also, t1t 2 t 3
..... (3)
a
ABC is equilateral
So, G H O
a
a
G t1t 2 t 2 t 3 t 3 t1 , t1 t 2 t 2 t 3 t 3 t1
3
3
G t1t 2 t 2 t 3 t 3 t1 , 0
..... (4)
3
H a, t1 t 2 t 3 t1t 2 t 3
..... (5)
3
Comparing (4) and (5), t1t2t3 = 0 and from (3), k = 0

2a h a
From equation (2), we get
a
a
3
2a h = 3a
h = 5a
O circumcentre of ABC = (a, 0)
Image of O will lie on circle
N (5a, 0)
One of the intersection point lie on vertex ( k = 0)
So, t2 = 0
at3 + (2a 5a)t = 0
t3 3t = 0 t(t2 3) = 0
t = 0, 3
P(t1)
N(h, k)
A
(a, 0)
Q(t2)
O
R(t3)
B
Intersection points P 3a, 2a 3 , Q (0, 0), R 3a, 2a 3
12
2.
(A) (f(x))2 + [f(x)]2 = h(x)

h(x) = 2f(x) f(x) + 2f(x) f(x)
= 2f(x) (f(x) + f(x))
= 2f(x) {x g(x) f(x)}
2
= 2x(f(x)) g(x)
So, h(x) < 0 of x > 0 and h(x) > 0 for x < 0
Then, x = 0 is a maxima
(B) f 2(x) + f(x) = g(x)
2f(x) f(x) + f(x) = g(x) and g(x) = f(x) {2f(x) + 1}
So, g(x) 0 as g(x) is increasing and for f(x) 0
2f(x) + 1 0
1
Hence, f x
2
x
(C) Let G x f t dt
0
G(x)
G' x 2f x f t dt and
h(x)
.. (1)
G' x
2
g x
and G(0) = 0 = g(0)

Also, g(x) is non-increasing
Hence, g(x) 0 x (, 0), g(x) 0 x [0, )
i.e., G(x) 0 for x 0, G(x) 0 for x 0 and G(0) = 0
But G(x) (from equation (1)) 0
Hence, G(x) = 0 x R
x
f t dt 0
xR
i.e., f(x) = 0 x R
Hence, f(1) = 0
x
(D) f x x 2 e t f x t dt
.. (1)
f x x 2 e x et f x x t dt
0
x
f x x 2 e x et f t dt
0
f ' x 2x e x e x f x e x et f f t dt
0
x t
f ' x 2x f x e f t dt = 2x + f(x) + x2 f(x)
0
f(x) = 2x + x
x3
2
f(x) = x +
c and from equation (1) f(0) = 0
3
Hence, c = 0
x3
i.e., f(x) = x 2
3
1 2 k 2
f 1 1 ,
k=2
3 3 3 3
13
SECTION C
/2
1.
Let f r
xr sin xdx
0
/2
Now,
xr cos xdx
/2
xr cos xdx
So, we have
x r 1
/2
cos x 0
r 1
/2
xr 1
sin xdx
r 1
f r 1
r 1
r C f r r 1
lim
L
r
f r 1
r 1
/2
Now, consider f r
Also as sin x

2
xr dx
r 1
2x
x

0, 2
r 1
/2

2
2
f r xr 1dx
r
2
0
r
2
r
r2
r 1
f r
r
r 1
r 1
2
r f r
f r
2 r 1
2
Hence, lim
=
lim
2
r f r 1
r
r
2
r 1 f r 1
f r
2
L lim r C r 1 L
Now, lim r C r 1
r
r
f r 1
For positive L we should have C = 1 and L =
2.
and y
2
2
f
f
2
2
Given equation f() f() = ( )
2
2
Let x + y = and x y = x
f x
x 2 k (k is some real constant)

x
f(x) = x3 + kx
f(1) = 2 k = 3, f(x) = x3 3x
f(x) = 3(x 1)(x + 1) on the interval x 3, 3 extreme value are 2 and 2
Hence,
3.
The given equation can be re-written as quadratic in y

y2 + (8x 2x2)y + (3x2 + 6x) = 0
Its discriminant to equal to
14
= (64x2 32x3 + 4x4) 4(3x2 + 6x) = 4x(x3 8x2 + 13x 6)

2
= 4x(x 6)(x 1)
For solutions in integers this discriminant should by perfect square this happens if and only if
z2 = x(x 6) = (x 3)2 9
9 = (x 3)2 z2 = (x + z 3)(x z 3) for name integer z
Checking all factorisations 9 = (9) (1) = (3) (3) = (1) (9) = 9 1 = 3 3 = 1 9
This gives all possible pairs (x, y) as (x, y) = (2, 0), (2, 24), (0, 0), (8, 4), (8, 60), (6, 12)
Therefore exactly three pairs of natural number (x, y) are possible
4.
As no multiple of nor any odd multiple of
satisfies the equation we can multiply both sides by

4
sin x cos 2x, which gives

sin 8x cos 5x = 2 sin 4x cos 4x cos 5x = 4 sin 2x cos 2x cos 4x sin 5x
= (sin x sin 2x)(8 cos x cos 4x cos 5x) = sin x cos 2x
sin 13x + sin 3x = sin 3x sin x
sin 13x = sin (x)
13x = n + (1)n (x)
5 7 11 2 3 4 5 6
Which gives 10 solutions
,
,
,
, ,
,
,
,
,
12 12 12 12 7 7 7 7 7 7
5.
Let Hi the event of getting a head on ith coin

H getting odd number of heads on throwing n coins once
Coin Number: 1 2 3 4 .. m
.. n
1 1 1 1
1
1
P(Hi)
..
3 5 7 9
2m 1
2n 1
P Hi
2
3
4
5
6
7
8
9
..
2m
2n
..
2m 1
2n 1
.. (1)
.. (2)
Now, P(H) = sum of series which has each term consisting of product of an odd number of terms
from (1) and even number of terms from (2) such that total number of factors in each term is n
1
1
2 1 4 1 6 1 2n
Consider the product .....
2n 1
3
3
5
5
7
7
2n
1
2n
1
LHS = P H P H
2n 1

Also, P H P H 1
n
2n 1
= 1, = 2, = 1, + + = 4
P H
6.
(, ) and (, ) will lie on some line y = x +

Solving line and parabola (x + ) = ax bx2
bx2 (1 + a)x + = 0
.. (1)
Again, y = a( y) b( y)2
2
2
by + y(1 + a 2b) + (b a) = 0
.. (2)
Both (1) and (2) has same roots which are and
1 a
Hence, 1 + a 2b = (1 + a)
b
Now, for , to exist disc of (1) > 0
2
(1 + a) 4b > 0
(a 3)(a + 1) > 0
a (, 1) (3, )
(, )
(, )

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1

ALL INDIA TEST SERIES

So, at x = 2x0 temperature T 425 K

v120 900 + 2 10 80 v10 50 m/s

Shape of sting at t = 0 is given by.

= 5 (2 sin /2 cos /2)

Resultant amplitude Ar = 2A|cos()t/2|

Initial total energy =

Anhyd. AlCl3 / CS2

Molar weight of C8H7OCl = 8 12 + 7 1 + 16 + 35.5

(B) Basic strength electron density over one N-atom

has lesser electron density over

one N-atom than in

(C) Heat of combustion

(-ve) charge on most

(-ve) charge on least

Int. No. of mole 106 V

Let z1, z2 be the two roots with |z1| = 1

For x [0, 1], f(x) f(1) ( f(x) is decreasing)

tan1 < > 0

P(x) = 0 has n real roots

x P ' x xP x 0 has n real roots

triangle with vertices (0, 0), , 0 and (1, 1) with area =

This case is symmetric with case-I

Integrating and using f(0) = 1 gives option A and C

By reflection property of ellipse PAF2 = QAF1

Let f(x) = a(x 1)(x 1)

Consider h(x) = x(1 + ln x), h: [1, ) [1, )

Now consider L lim

By LHospitals Rule L lim

(I) holds true obviously

= 2a1(b1 + c1) + a2(b2 + c2) + a1(b2 + c2) + a2(b1 + c1)

Hence, (I) holds true

a1b1 a2b2 a3b3 a1c1 a2c 2 a3 c 3

Comparing (4) and (5), t1t2t3 = 0 and from (3), k = 0

Intersection points P 3a, 2a 3 , Q (0, 0), R 3a, 2a 3

(A) (f(x))2 + [f(x)]2 = h(x)

and G(0) = 0 = g(0)

For positive L we should have C = 1 and L =

x 2 k (k is some real constant)

The given equation can be re-written as quadratic in y

= (64x2 32x3 + 4x4) 4(3x2 + 6x) = 4x(x3 8x2 + 13x 6)

As no multiple of nor any odd multiple of

satisfies the equation we can multiply both sides by

sin x cos 2x, which gives

Let Hi the event of getting a head on ith coin

(, ) and (, ) will lie on some line y = x +

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