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u = 0
CHEM 520
Derivation of N-S
Derivation based on force balance about a fluid element:
Net force = sum of forces
Convective force (convective transport of
momentum), uu
Viscous stress forces (viscous forces),
Pressure forces, p
z
External forces, e.g. gravity, g
u = uu p + F
t
u = uu p + g
t
z
x
CHEM 520
Derivation of N-S
= u
( )
( )
xx yx zx
xy
yy
zy
xz yz zz
xx = 2 + 2 3 u
x
yy = 2 + 2 3 u
y
3-D
zz = 2 + 2 3 u
z
u v
xy = yx = +
y x
( )
1-D
yx
u
=
y
v w
+
z y
yz = zy =
w u
+
x z
zx = xz =
CHEM 520
Derivation of N-S
Viscous stress (recap)
Stress has unit of pressure.
It describes the local variation in velocity.
Viscous force = Stress x area
Force balance using stress:
Viscous forces balance (1) convective force,
(2) pressure force, and (3) external force.
A = ugrad(u) A + P A + F A
yx
u
=
y
0
CHEM 520
Derivation of N-S
From force balance:
Constant and :
Navier-Stokes eqt.
Inviscid flow, = 0 :
Eulers eqt.
D u = p + F
Dt
ur
D ur = ur p + F
Dt
ur
r
r
D
2
u = u p + F
Dt
D u = p + F
Dt
CHEM 520
Convective
+
force
u = 0
Viscous
force
Pressure
force
External
force
u + u u = 2u p + F
t
u = u u + 2u p + F
t
Rate of change Convective
force
of momentum;
net acceleration
CHEM 520
u + u = 2 u dp + Fx
t
dx
x
x
Rate of change of
momentum; net
acceleration
External force
e.g. gravity
Convective
force
Viscous
force
Pressure
force
CHEM 520
Dimensional Analysis
Why?
Reduction of information,
Parameters and variables in a typical fluid system: P, D, U, ,
.
Parameters and variables in a typical reactive transport system
without effects due to electrical field: T, U, c, , , k, Dab, P, ra,
,
How about with electric field effects? Like electrochemical
systems?
Simplify problem and focus on important physical phenomena.
An art that depends on physical insights of problem at hand.
As a check to your solution when you can simplify the physics
CHEM 520
Dimensional Analysis
1-D, viscous forces dominant
2
u
u + u = 2 u dp + Fx
t
x
dx
x
*
*
*
2
u
u
dp
*
DU
*
*
u
u
+
F
+
=
x
*
2
*
*
*
t
x
dx
*
*
*
2
u
dp
u
*
*
*
Re
u
+
F
+u
=
x
2
*
*
*
*
t
dx
x x
Drop *
u
u
Re + u = 2 u dp + Fx
x x
t
dx
u* = u / U
x* = x / D
p * = p /( U / D )
Fx* = Fx /( U / D)
t * = Ut / D
Re =
Du
CHEM 520
Dimensional Analysis
3-D case, we have
u
Re + u u = 2u p + F
u + u u =1/ Re2u p + F
t
2
u
dp + F
1
u + u =
u
t x Re x 2 dx x
u* = u / U
x* = x / D
p * = p /( U 2 )
Fx* = Fx /(U 2 / D)
t * = Ut / D
CHEM 520
Reynolds Number
A ratio of inertial to viscous forces.
D = characteristic dimension.
U = magnitude of velocity.
Re =
Du
= fluid density.
= fluid viscosity.
CHEM 520
Reynolds Number
High, Re > 4000; turbulent
Inertial forces dominant
e.g. ocean waves, air flow past
wing, tornado.
Re =
Du
Low Re
Viscous forces
dominant
u + u u =1/ Re2u p + F
t
0 for large Re
u + u u = p + F
t
Re + u u = 2u p + F
0 for low Re
0 = 2u p + F
CHEM 520
High Re
Inertial forces
dominant
0 = 2u p + F
u + u u = p + F
t
Convective
force
Rate of
change of
momentum;
External
force
Viscous
force
Pressure
force
External
force
Pressure
force
CHEM 520
Need to specify:
t
Boundary Conditions
CHEM 520
u + u u = p + F
t
P = Ax 2
for all ys
near
surface
Flow
x
y
++Viscous
Viscous
effects
effects
P
y
x
CHEM 520
P = A(1 4 sin 2 )
P
P = Ax 2
CHEM 520
D u = 2u p + F
Dt
Re=10,000
CHEM 520
Low Re - example
Re + u u = 2u p + F
0 for low Re
0 = 2u p + F
3 U ( D / 2)
p p =
cos
2
r
2
P =
3 cos
4 r2
CHEM 520
CHEM 520
3 U ( D / 2)
cos
r2
2
P =
3 cos
4 r2
P
Re=0.04
CHEM 520
Creeping Flow
Uniqueness of flow
Many bodies interactions may become
important
Reversibility
e.g.:
Spermatozoan (p.235 Acheson)
Bacteria, protein molecules, polymer,
suspensions
CHEM 520
CHEM 520
Transport Analogies
Mode of transport
Transport
variable
Momentum
u + u u = 2u p + F
Energy
C T + u T = k2T p( u)
Mass
cA
DAB
c A
+ u c A = D 2c A + R
AB
A
t
CHEM 520