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1, When the electron of a hydrogen atom jumps from n=4 to n=1 state, the number of spectral lines emitted is (a) 15 9 6 @3 x» . Which of the following is an appropriate set of reactants for the preparation of ‘-methoxy-4-nitrobenzene? Br Na 0 + CH,ONa 0) + CH3Br ae eg Jbi Sig (© BothAandB (d of these }. Consider the decomposition of NO; as N,Os NO; +50, » The rate of reaction is given by “-AIN,03) _1 dINO,) _ tape carih +d ee 70 =2kIN-03] = KIN-Os] son i ghINsOs]=KINDs] Choose the correct ae @ k=K=K () ky =2k =k © 4k, =k = 2k Re 4k 25k =k ithm of the equilibrium constant of fe cell reaction corresponding to the cell Bee (aq)||¥*(aq)|¥(s) with standard cell potential, £2 =1.2V is given by (a) 12.5 (b) 21.5 (© 405 @ 47.2 5. If the half cell reactions are given as @ Fe**(aq)+ 2e > Fe(s); E°=-0.44V i) 2H" (aq) + 4ox8) +26 + H,0(D E°=+1.23V The E° for the reaction Fe(s) + 2H" + $0.) > Fe™ (aq) + H,0( is (a) +167V (b) -167V (c) +079V (d) -0.79V 6. The most adsorbed gas on activated charcoal is (a) N, (b) Hy (© CO, @ cH, 7. Which of the following represents the arrangement in increasing order of bond order and bond dissociation energy? (a) 03 @) INi(CN),]> 10. The maximum number of PH bonds are contained in which of the following molecules ? (a) H;PO, (b) H;PO, (© HPO, (@) H,P,0, 11. The bond order of the N—O bonds in NO; ion is (a) 033 (b) 1.00 (c) 1.33 (d) 1.50 17. 18. Among the following the third ionisation energy is highest for (a) magnesium (b) boron (©) beryllium @ aluminium The highest lattice energy corresponds to (a) MgO. (b) CaO (© sro (@ Bao ‘The change of energy on freezing 1.00 kg of liquid water at 0°C and 1 atm is (a) 236.7kIkg? —(b) 333.4 kJ kg? (© -333.4kJ kg? (d) -236.7 ki kg? The degree of hardness of water is usually expressed in terms of (a) ppm by weight of MgSO, (b) g/L of CaCO, and MgCO, present (© ppm by weight of CaCO, irrespective of whether it is actually present (@) ppm of CaCO, actually present in water 0.1 M NaCl and 0.05 M BaCl, solutions are separated by a semipermeable membrane in a container. For this system, choose the correct answer. (a) There's no movement of any solution Dea: membrane lows from BaCl, solution towards NaCl solution (© Water flows from NaCl solution towards BaCl, solution (d) Osmotic pressure of 0.1 M NaCl is lower than the osmotic pressure of BaCl (Assume complete dissociation) If W is the amount of work done by the system and q is the amount of heat supplied to the system, identify the type of the system. (@) Isolated system (b) Closed system © Open system (@) System with thermally conducting walls The charge balance equation of species in 0.100 M acetic acid solution is given by © n=! (@) 2{"]=[0H"] + (CH,COO™)] [OH] + [CH,COO"] 19. 20. 21. 22. 24. 25, . Which of the following Total number of voids in 0.5 mole of a ‘compound forming hexagonal closed packed structure are (@) 6.022x10% — (b) 3.011 10 (©) 9.033% 10% — (d) 4.516x 10” Four solutions of K,SO, with the following concentration 0.1 M, 0.01 m, 0.001 m and 0.0001 m are available. The maximum value of van't Hoff factor, i, corresponds to (a) 0.0001 m solution (b) 0.001 m solution (© 0.01 msolution (4) 0.1 m solution The pH of a solution prepared by mixing 2.0 mL of HC! solution of pH 3.0 and 3.0 ml. of NaOH of pH 10.0 is (@) 25 () 3.5 (© 5.5 (d) 6.5 The set of quantum numbers that represents the highest energy of an atom is @ n=41=0.m=05=+3 (b) n= (n= (d) n=3,1=0,m=0,s= sets of quantum, numbers represents the 19th electron in chromium? (Z = 24 for Cr) 1 1 @ lise () ee {0:3:225 @ 32-25 The number of molecules in 100 ml. of 0.02 N H.S0, is (a) 6.02x 107 (© 6.02 10” For the reaction AB(g) —+ A(g) + B(g), AB is 33% dissociated at a total pressure of p. Therefore, p is related to K,, by one of the (b) 6.02% 10" (@) 6.02% 10" following options @ (© p= 0) p=3K, (a) p=8K, 26. 27. 28. 29. 31. 32. SY When subjected to acid catalysed hydration, the order of reactivity of the alkenes; (CH,),C=CH,(), CH,CH=CH,(11) CH, =CH, (IID) is (a) I> M>1 (© I> I> mL and (b) I> > (a) U>1> mr Name the reagent used to bring about the following transformation : But-2ene to ethanal (a) K,Cr,0, in acidic medium (b) CrO,Cl,/ H,0* (@ Pec (@) 0,/H,0-Zn dust Arrange the following in increasing order of their basic strength : CHNH,(D, (CH3)2NHD, (CH,);N(ID, CH,CH,NH, (IV) @ W H,S,0, > Na,S,0,>Sg (b) H,SO, >SO,>H,S>H,S,05 (©) SO} >SO} >S0} > HSO; (@) H,S0, > H,S0, >SCl, > HS 49. 50. ‘The pH of a solution obtained by mixing equal volumes of NaOH and © Hcl is 10 20 (@) 13.4 (b) 12.4 © 76 @ 16 The solubilities of Na,SO,, BeSO,, MgSO, 1d BaSO gill follow the order MgSO, > Na,SO, > BaSO, Na,SO,, > MgSO, > BaSO, (©) MgSO, > BeSO, > Na,SO, > BaSO, (@) Na,SO, > BeSO, > MgSO, > BaSO, following compounds in increasing order of their reactivity in nucleophilic addition reactions. Ethanal (D, Propanal (11), Propanone (II), Butanone (IV) @) M

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