51. 52. 53. 54. 55. Ethyl acetate is obtained when methyl ‘magnesium bromide reacts with (a) ethyl formate (b) ethyl chloroformate (©) acetyl chloride (qd) carbon dioxide ‘The most stable hydride is (a) NHy (b) PH, (© Ast, (@) SbHy The ratio of amounts of H,S needed to precipitate all the metal ions from 100 mL of 1 M AgNO, and 100 mL of 1M CuSO, will be covalent character in the cena is (a) 54% (b) 46% (©) 23% (@) 72% Which of the following reaction defines AH; ? @ Sea +03(g)—— C0,(g) ay n(g) +3 F,(g)}—> HF(g) (a) 1:1 (b) 1:2 () 2:1 (d) Ne Ite eleenegaiviy 56. 58. (©) N,(g)+ 3H;(g) —> 2NH,(g) (@) CO(g)+ 50.(@)—> COC) Formaldehyde polymerizes to form glu according to the reaction 6HCHO = GH,,0, The theoretically computed _ equilibri constant for this reaction is found to 6x 10”. If 1 M solution of glucose diss according to the above equilibrium, concentration of formaldehyde in the soluts will be (a) 1.6x 107M —(b) 1.6 104M (Gx 10°M — @) 1.6x10°M Peat: configuration of a dipositive Beai:: 14 and its mass number is 56. number of neutrons present is (a) 32 (b) 42 (© 30 (a) 34 If Xis the total number of collisions whick gas molecule register with others per unit under particular conditions, then the colli frequency of the gas containing N moles per unit volume is61. (a) X/N (b) NX (co) 2NX (d) Nx/2 Aypothecal eatin A+ By» 248 flows the mechanism as given below, a At ACH) 4+ By AB YB omy eB a8 The order of the overall reaction is (a) 2 (b) 1 it @o The mass of helium atom of mass number 4 is 4.0026 u, while that of the neutron and proton are 1.0087 and 1.0078 respectively on the same scale. Hence, the nuclear binding energy per nucleon in the helium atom is nearly (a) 5 Mev (b) 7 Mev (© 10Mev (@) 14 Mev Which of the following statements is correct ? Dielectric constant of H,0, (a) Increases with dilution (b) Decreases with dilution (©) Is unaffected on dilution (d) None of the above For the square 66. How many number of atoms are there in a cube based unit cell having one atom on each comer and two atoms on each body diagonal of cube ? @ 8 ©) 6 4 @o 67. Bleeding due to a cut can be stopped by applying ferric chloride solution in the laboratory. This is due to (a) coagulation of negatively charged blood articles by Fe” ions (b) coagulation of positively charged blood particles by Cl ions (©) reaction taking place between ferric ions and the haemoglobin forming a complex (@ common element, iron, in both FeCl, and haemoglobin. 68. Which one of the following solutions will have highest conductivity ? (a) 0.1 MCH,COOH (b) 01M NaCt (© 0.1 MKNO, @ 01 MHC! - One of thé following metals forms a volatile otis (i) and this property is taken [M(@)(b)(e)(@) Gwhere, M al ivan for its extraction. This metal is and a, b, cand d are monodentate ligands), the number of possible geometrical isomers are @)1 ) 2 ©3 @4 Potash alum dissolves in water to give a/an (a) acidic solution of H,S0, (b) alkaline solution (©) acidic solution of HCl (@) neutral solution The discovery of which of the following group of elements gave death blow to the Newland’s law of octaves ? (a) Inert gases (©) Rare earths (b) Alkaline earths (d) Actinides .van't Hoff factor more than unity indicates that, the solute in solution has (a) dissociated (b) associated (©) Both (a) and (b) (@) cannot say anything (a) iron (b) nickel (© cobalt (@) tungsten 70. If Na ion is larger than Mg™ ion and Sion is larger than Cl- ion, which of the following will be stable soluble in water ? (a) Sodium chloride (b) Sodium sulphide (© Magnesium chloride (@) Magnesium sulphide 71. Impurities of Cu and Ag from gold are removed by (a) boiling impure gold with dil. H,S0, (b) boiling impure gold with conc. H,S0, (© electrolytically (@) Both (b) and (c) 72. Which of the following salt would give SO. with hot and dil. H,SO, and also decolourises Br, water ? (a) Na,SO; (b) NaHsO, (©) Na,SO, (@) Nas73. 74. 75. 76. 77. 78. 79. 80. If two compounds have the same empirical formula but different molecular formulae, they must have (a) different percentage composition (b) different molecular weights (© same viscocity (@) same vapour density Among the following which one has weakest carbon-halogen bond ? (a) Benzyl bromide (b) Bromobenzene (©) Vinyl bromide (4) Benzyl chloride Petrochemicals can be used to prepare (a) synthetic fibres (b) pesticides © plastics (@) All of these tert-butyl methyl ether on heating with anhydrous HI in ether gives (a) CH,OH + (CHy),CL (b) CHyL + (CH,)sCOH (© CHL + (CHY)Cl (@) None of the above ‘The correctly reported answer of the addition of 4.523, 2.3 and 6.24 will have significant figures @) two (b) three (©) four (d) five) What happens if CCI, is treated with AgNO, ? (a) Awhite ppt. of AgCl will form (b) NO, will be evolved (© CCI, will dissolve in AgNO, (@) Nothing will happen Na is more stable isotope of Na. Find out the process by which j{Na can undergo radioactive decay (a) Br emission (b) o-emission (©) B* emission (@) K electron capture ‘The heat of combustion of solid benzoic acid at constant volume is ~321.30 kJ at 27°C. The heat of combustion at constant pressure is (a) - 321.30-300R (b) ~ 321.30+ 300R (© -321.30-150R @ ~321.30+ 900R 81. 82. 85. 87. In which of the following compounds —OH group is least reactive ? OH @ cHO {0 CHO (© HO ) 2and 3, (©) 1and3 @) 1,2and3 A fibrous mineral which can withstand red hot flames without any damage is (@) tale (b) glass wool (© soapstone __(d) asbestos When o- or p-phenolsulphonic acid is treated with bromine water, the product formed is (@) 2, 4-dibromophenol (b) 2, 4, 6-tribromophenol (©) 3-bromophenol boric acid (@) 3, 5-dibromophenolAnswer — Key 51. b 53. b | 54 55. 57. c | 58d | 59 c | 60 b 75. d | 76. r 7b | 78% d | 79%. a | 80. ¢ 35. d | 8a | 87a | sa | 8 b | 90 a a | %c | % c | Bb | 9% d | 100.b md | 7a | 73. b ala 82. b | 883. a 1c 2.4 | 9. b SER