L in Xe¥y, oxidation state and state of hybridisation of Xe and shape of the molecule are, respectively (a) +6, sp°d°, distorted octahedral ©) +4, sp*d?, square planar (© +6, sp’, pyramidal (@) +6, spd”, square pyramidal ‘2 The following species will not exhibit isproportionation reaction (2) Clo~ (b) Glo3 © clo5 @ Clo, 2. Relative stabilities of the following earbocations will be in the order cu, cuge, @H,0cH, A C ()C>B>A () CC>A @ C>A>B J. Which of the following species is aromatic? (@) Oo ) O © CS @ Cy 8 .._Benzalkonium chloride is a (a) cationic surfactant and antiseptic (b) anionic surfactant and soluble in most of organic solvents (©) cationic surfactant and insoluble in most of organic solvents (@) cationic surfactant and antimalarial Which factor/s will increase the reactivity of >c=0 group?10. 1. (i) Presence of a group with positive inductive effect (ii) Presence of a group with negative inductive effect (iii) Presence of large alkyl group (a) only @) (b) only (i) (© (@ and Gi) @ Gi and (i) In the following reaction, RCH,CH=CH, + Cl —> [A] Markownikoff’s product [A] is Rot ROCHA a 1 (© RCH—C=CH, (4) RCH=CH—CH,I 1 ‘Thermal decomposition of e 8 (ratsiesBi sie e onan @ (foe © (enon of po Which of the following aromatic acids is most acidic? [00H ‘COOH OH @ © COOH COOH © O @ ‘OH OH In the preparation of chlorobenzene from aniline, the most suitable reagent is (a) chlorine in the presence of ultraviolet light (b) chlorine in the presence of AICI, © nitrous acid followed by heating with CuCl, @ HCl and CuCl, ‘Comparing basic strength of NH, CH;NH and CgHsNHy it may be concluded that 12, 13, 14, (a) basic strength remains unaffected (b) basic strength of alky} amines is lowest (©) basic strength of aryl amines is lowest (@) basic strength of NH, is highest ‘The most suitable reagent A, for the reaction ° Ov,0 om Ore is/are (@) Os (b) H,0, (© NaOHHO, (@ m-chloroperbenzoic acid Mammals’ fats are hydrolysed to release fatty acids by (@) amylase (b) lactase © lipase @ insulin Which of the following represents neo-pentyi alcohol? (@) CH,CH(CH,)CH,CH_OH (b) (CH,),C—CH,OH (©) CHy(CH,),0H (@) CH.CH.CH(OH)C,H, ‘The most reactive compound towards electrophilic nitration is @ toluene (b) benzene (©) benzoic acid (@) nitrobenzene Arrange the following compounds in order of their decreasing reactivity with an electrophile, E (A) Chlorobenzene, (B) 2,4-dinitrochlorobenzene, (©) p-nitrochlorobenzene (a) C>B>A (b) B>C>A (©) A>C>B (@) A>B>Cc Sodium chloride is soluble in water but not = benzene because (2) AH yaion < AH ence in water ‘nydeation > AH wcice in benzene (©) Alf yaioe > 8H nyo mer A nydration < SH iartice energy in benzene (©) AA pydration = AF ance energy in water 404 ‘BH pin © AH never i ema (d) AH yyaration < AH atice energy in water 24 A pydration = AH iaice energy in benzene ‘The plot between concentration versus time fora zero order reaction is represented by(oc ne = — ==> é ! ~ © (@) — — 2. Which of the following reactions cannot be a base for electrochemical cell? (a) H, +0, —> H,0 (b) AgNO, +Zn —+ Zn(NO,), + Ag (©) AgNO, + NaCl —y AgCll + NaNO, (@) KMn0, + FeSO, + H,S0, —> K,S0, + Fe,(S0,); + MnSO, + Hj0 The strength of 10 volume of H,0, solution is (@) 10 (b) 68 © 60.70 @ 30.36 Which of the following species is non-linear? fa) Icy ® & ON; (@) ClO For the reaction, 24 + B > C+ D the order of reaction is {a) one with respect to [B] (b) two with respect to [4] (© three (@) cannot be predicted ‘The basic structural unit in silicates is fa) SiO, (®) [Si0,]* (©) SiO, tetrahedron (A) [Siz05]*" 1 which of the following reactions, H,0, is acting as a reducing agent? (@) SO, +H,0, —> H,S0, (>) 2KI+H,0, —+ 2KOH+1, (©) PbS + 410. —> PbSO, + 4H,0 @ Ag,0+H,0, —> 2Ag+H,0+0, ‘Which of the following oxides is most acidic in sarure? (2) Bed (b) Mgo (9 Cao (d) Bao The state of hybridisation of $ in SF, is (2) sp* and has a lone pair of electron (®) sp? and has tetrahedral structure 29. 30. 31. 33. (© sp’d and has a trigonal bipyramidal structure (d) sp°d? and has an octahedral structure 7. If two moles of glucose are oxidised in the body through respiration, the number of moles of ATP, produced are @ 19 (b) 38 © 57 (@) 76 The potential ofthe cell for the reaction, ‘M(s)+ 2H°(1M) —+ H,(g)( atm) +M*(0.1 M) is 1.500 V. The standard reduction potential for M** /M(s) couple is (@) 0.1470 ®) 1.470V © 14.70 (@) None of these The element with atomic number 117 if discovered would be placed in (a) noble gas family (b) alkali family (©) alkaline earth family (@) halogen family van't Hoff factor of ag. K,SO,, at infinite dilution has value eugal to f@1 (b) 2 ©,)3 (@) between 2 and 3 Which set of characteristics of ZnS crystal is correct? (@) Coordination number (4: 4): cep; Zn?* ion in the alternate tetrahedral voids (b) Coordination number (6 : 6); hep; Zn?* ion in all tetrahedral voids (©) Coordination number (6 : 4); hep; Zn" ion in all octahedral voids @ Coordination number (4 : 4); cep; Zn ion in all tetrahedral voids . When a radioactive substance is kept in vacuum, the rate of its disintergration per second (a) increases considerably () is not affected (©) suffers a slight decrease (@) increases only if the products are gaseous ‘An aqueous solution whose pH is zero will be called as (a) acidic (b) basic (©) neutral (@) amphoteric ‘Thebond angle and % of d-character inSF, are (a) 120°, 20% b) 90°, 33% (©) 109°, 25% d) 90°, 25%35. Which of the following species will be diamagnetic? (a) [Fe(CN),]* (b) [FeF,]* (©) [C0(C,0,)]* (4) [CoF]* 36, One component of a solution follows Raoult’s law over the entire range 0 < x, <1. The second component must follow Raoult’s law in the range when x, is (@) close to zero ——(b) close to © 0sx,505 (4) 0S x,51 37. Select wrong statement. (@) Ifa very small amount of AICI, is added to gold sol, coagulation occurs, but if a large quantity of AICI, is added, there is no coagulation. () Organic ions are more strongly adsorbed on charged surfaces in comparison to inorganic, ions, (©) Both emulsifier and peptising agents stabilise ‘colloids but their actions are different. 39. {@) Colloidal sohuons are thermodmnamicaly stable. An adiabatic process occurs in (a) open system (b) closed system (©) isolated system @ inall the given systems Approximate relationship between dissociation constant of water (K) and ionic product of water (Kk, is (a) K,=K () K, =55.6xK (© Ky=18xK —@) Ky =14xK For the reaction at 298 K A@)+ Bg) — Cg) =~Scal and AS =-10cal K? (a), AG=+ 2612cal_ (b) AG =-2612cal (Q AG=+261.2cal (4) AG=-261.2cal Answer — Key