41. 42. An electronic transition in hydrogen atom results in the formation of H, line of hydrogen in Lyman series, the energies associated with the electron in each of the orbits involved in the transition (in kcal mol“) are (a) -313.6, - 34.84 (b) -313.6, - 78.4 (© -78.4, - 34.84 (d) -78.4, - 19.6 The velocities of two particles A and B are 0.05 and 0.02 ms" respectively. The mass of Bis five times the mass of A. The ratio of their de-Broglie's wavelength is (a) 2:1 (b) 1:4 1:1 @4:t 43. If the mass defect of 5B" is 0.081 u, its average binding energy (in MeV) is (a) 8.60 (b) 6.85 (© 5.60 (d) 5.86 44, The atomic numbers of elements A, B, C and Dare Z~1,Z,Z + Land Z + 2, respectively If ‘B’ is a noble gas, choose the correc answers from the following statements (1)\A) has higher electron affinity (2) ‘C’ exists in +2 oxidation state (3) “D'is an alkaline earth metal “(@) (2) and (2) (b) (2) and (3) (©) (1) and (3) (d) (1), (2) and (3)47. 51. . The bond length of HCI molecule is 1.275 A and its dipole moment is 1.03 D. The ionie character of the molecule (in percent) (charge of the electron = 4.8 x 107" esu) is. (@) 100 (b) 67.3 (0) 33.66 (@) 16.83 . Which one of the following is a correct set ? (@) HO, sp®, angular (b) BCl,, sp®, angular (© NH}, dsp, square planar (d) CH,, dsp’, tetrahedral Ammonium carbamate decomposes as NH,COONH, (s) =—* 2NH,(g) +CO2(g) For the reaction, K, = 2.9 10° arm®. if we start with 1 mole of the compound, the total pressure at equilibrium would be (@) 0.766 arm ~—(b) 0.0582 atm (©) 0.0388 arm —(d) 0.0194 atm . What is the temperature at which the kinetic energy of 0.3 moles of helium is equal to the Kinetic energy of 0.4 moles of argon at 400 K? {a) 400 K (©) 533K (b) 873 K {d) 300K . When 25g of a non-volatile solute is dissolved in 100g of water, the vapour pressure is lowered by 2.25 x 107? mm. If the vapour pressure of water at 20°C is 17.5 mm, what is the molecular weight of the solute ? (a) 206 (b) 302 (© 350 (@) 276 ). 50 mL of H,0 is added to 50 mL of 1 x 10M barium hydroxide solution. Whatis the pH of the resulting solution ? (a) 3.0 b) 3.3 @ 1.0 (@) 11.7 Assertion (A) : The aqueous solution of CH,COONa is alkaline in nature. Reason (R) : Acetate ion undergoes anionic hydrolysis ‘The correct answer is (a) Both (A) and (R) are true and (R) is the correct explanation of (A). (b) Both (A) and (R) are true but (R) is not the correct explanation of (A). (c) (A) is true but (R) is not true. (@) (A) is not true but (R) is uve. 52. When same quantity of electricity is passed through aqueous AgNO, and H,S0, solutions connected in series, 5.04 x 10" g of H, is liberated. What is the mass of silver {in grams) deposited ? (Eq, wts. of hydrogen = 1.008, silver = 108) (a) 54 (b) 0.54 O54 @ 108 53. When electric current is passed through ¢} acidified water for © 1930 s, 1120 mL of Hy gas is collected (at STP) at the cathode What is the current passed in amperes ? (@) 0.95, (b) 0.50 ©5.0 @50 54. For a crystal, the angle of diffraction (26) is 90° and the second order line has ad value of 2.28 A. The wavelength (in A) of X-rays used Reaction coordinate for Bragg’s diffraction is fa) 1.612 (b) 2.00 © 2.28 (@) 4.00 55. Ina,500 ML flask, the degree of dissociation of POI, at equilibrium is 40% and the initial arhount is 5 moles, The value of equilibrium constant in mol L' for the decomposition of PC, is (a) 2.33 (b) 2.66 (¢) 5.32 (d) 4.66 56, For a reversible reaction A —* B, which one of the following statements is wrong from the given energy profile diagram ? (a) Activation energy of forward reaction is greater than backward reaction {b) The forward reaction is endothermic (¢) The threshoid energy is less chan that of activation energy (d) The energy of activation of forward reaction is equal to the sum of heat of reaction and the energy of activation of backward reaction 57. Caleulate AH in kJ for the following reaction C(g) + O2(g)-— CO,(g). Given that, HO(g) + C(g}-— CO(g) + Hols AH =+131k)©0¢g)+ 3.0464) —+ COL 5 AH =~ 28210 Hy(e)+30,(g)> HOG) AH =~ 24245 (a) -393 (b) +393 (©) +655 (d@) -655 58 Which one of the following graphs represents Freundlich adsorption isotherm ? OMe a wont - tis se ort . ser 2 om" L 59. Which one of the following reactions represents the oxidising property of H,0, ? (@ 2KMnO, + 3H,S0, + 5H,0, —> K,SO, + 2MnSO, + 8H,0+ 50, (b) 2K,[Fe(CN),] + 2KOH + 1,0,—> 2K ,{Fe(CN),] + 2H,0 +0, (© PbO, + 0, —> PbO+H,0+0, (@) 2KI+ #80, + H,0, —> K,SO, +1, + 2H,0 60. Which of' the following statements are, correct for alkali metal compounds ? @ Supenaiices are paramagnetic in (i) The basic strengths of hydrordes increases down the group. (iil) The conductivity of chlorides in their! aqueous solutions decreases down the group. (iv) The basic nature of carbonates in aqueous solutions is due to cationic hydrolysis. (@) (@, Gi and Gil) only (b) @ and Gi) only i) (@) Gi) and (iv) only 61. Boron halides behave as Lewis acids because Of their ...,..... nature. (@) proton donor —_(b) covalent (© electron deficient (4) ionising 62. Identify B in the following reaction 100°C H,SiO, args A -oee, B+CO (a) corundum ——(b) quartz (© silica (@) carborundum 63. The correct order of reducing abilities of hydrides of V group elements is (a) NH, < PH, < AsH, PH, > AsH > SbH, > BiH, (©) NH, < PH, > AsH, > SbH, > BiH, (d) SbH, > BiH, > AsH, > NH, > PH; 64. The number of sigma and pi bonds in peroxodisulphuric acid are, respectively (a) 9 and 4 (b) 11 and 4 (© 4and8 @ 4and9 65. Which one of the following reactions does not occur? (@) Ry + 2h — 2F +Cl, (b) Cl, + 27 — 2Cr + (© Bry + 27 —> 2B +1, @) Cl, + 2B —> 2Cr + Br, 66. The compound in which the number of dx-px bonds are equal to those present in clo; (a) Xek, (© Xe0, (©) Xe0, (@) XeF,7. (Co(NH,);S0,] Br and [Co(NH;);Br] SO, are a pair of ........ isomers. (@) ionisation (b) ligand (©) coordination (4) hydrate ©. Among the following compounds, which one 7, is not responsible for depletion of ozone layer ? (@) CH, (b) CFC, (© NO @ Cl, Which of the following compound(s) has ‘Z° configuration ? oS = a u/ "Ns “% CH; Gi) ye she (@) (@ only () Gii) only © Gi) only @) @ and Citi) According to Cahn-Ingold-Prelog sequence rules, the correct order of priority for. the given groups is (a) —COOH>—CH,OH>——OH> —cHO (b) —COOH>—cHO> —cH,OH > —oH (© —OH > —CH,OH > —CHO > —cooH (@) —OH>—COOH> —CcHO>—CH,OH What are XandY respectively in the following reaction ? Z-product *— 2-butyne 4 E-produet (a) Na/NH,(lig. ) and Pd/BaSO, + H (b) Ni/140°C and Pd/BaSO, +H, (©) Ni/140°C and Na/NH,(liq. ) (d) Pd/ BaSO, + H, and Na/NH,(liq.) In which of the following reactions, chlorine acts as an oxidising agent ? (i) CH;CH,OH + Cl, —» CH,CHO + HCI (ii) CH,CHO + Cl, —> CCl, CHO + HCI Gil) CH, + Cl, 5 CH,CL+ HCl The correct answer is (a) @ only ~ (b) Gi) only {c) G) and Gi) @ @, Gi) and Gii) 73. 74. 75. 76. 77. ‘The correct order of reactivity of hydrogen halides with ethyl alcohol is (@) HF > HCl > HBr > HI (b) HCl > HBr > HF > HI (©) HBr > HCl > HI > HE (d) Hi > HBr > HCl > HF ‘da The IUPAC name of CHs—O—CH Nau, is (a) ethoxy propane (b) 1,1-dimethyl ether (c) 2-ethoxy isopropane (@) 2-ethoxy propane Acetone on addition to methyl magnesium bromide forms a complex, which on decomposition with acid gives X and Mg(O¥)Br. Which one of the following is X? (a) CHyOH (b) (CH,),COH (© (CH,),CHOH (4) CH,CH,OH Identify A and B in the following reaction CH,—cH, <2 cu,coon —4s cH,cH,0H A B (@) Hi+redP —_LiAIH, b) Nia LiAIH, (© WalH, HI + red P (@) Pd-BasO, Zn+HCL The structure of the compound formed, when nitrobenzene is reduced by lithium aluminium hydride (LiAlH,) is 2 O--O) Tl HOH NHOH 9) -O--O NH, : (d)78. The energy released in an atomic bomb explosion is mainly due to (a) release of electrons (©) release of neutrons (©) lesser mass of products than initial material (@ greater mass of products than initial material IfM,, is the weight average molecular weight and M, is the number average molecular weight of a polymer, the poly dispersity index (PDI) of the polymer is given by My My (a) i, (b) i, aa 1 (© MxM, (d@) xm, 80. Hydrolysis of sucrose with dilute aqueous sulphuric acid yields (a) 1:1 D-(+)-glucose; D-(-)-fructose (b) 1: 2 D-(+)-glucose; D-(-)-fructose (©) 1: 1D+@)-glucose; D-(+)-fructose {d)_1 : 2 De(-)-glucose; D-(+)-fructose Answer — Key 4b [42 a [43 b [44 c [45 d [46 a [47 b [48% c [4% c |50 ¢ bia [52 c (53. c [54 a [55 b [56 c [57 a |58& c [59 d | 60. b 61 c (62 d (63. a |64 b |65. b 66 b |67. a |68 a 69. d (70 d 7a [7d [73.4 |74 d [7 b |76 c |” ¢ |7& c |79% b [80 a