MATHEMATICS

1.

If f : R R, g : R R are defined by f x 5 x 3, g x x 2 3, then gof 1 3

(1)

25
3

(2)

111
25

(3)

9
25

(4)

et
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KEY: 2
f x 5x 3
HINT:
x3
f 1 x
5
g x x2 3

25
111

6 111
gof 1 3 g f 1 3 g
5 25

2.
If A x R
x and f x sin x x, then f A
4
3

3 1
1 3
(2)
(1)
,

,

3 2 4
2 4 2 3
2

(3) ,
(4) ,

3 4
4 3
KEY: 1
f x sin x x
HINT:

x
4
3

w
w

.n

Which is decreasing function in ,
4 3

f f x f
4
3

1
3
f x

2 3
2 4

3
1
f A
,

2
3
4
2

3.

The value of the sum 1.2.3 2.3.4 3.4.5 ....upto n terms

1
1 2
n 1 2n 1 2n 3
(1) n 2 2n 2 1
(2)
6
6
1
1
(3) n 2 1 n 2 5
(4) n n 1 n 2 n 3
8
4

KEY: 4
1.2.3+2.3.4++upto n terms
HINT:

tn n n 1 n 2
1
n n 1 n 2 n 3
4

b 2 ab b c

bc ac

The value of the determinant ab a a b b 2 ab

bc ac c a ab a 2

4.

et
ba
di
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S n tn

(1) abc
(2) a b c
KEY: 3
b 2 ab b c bc ac
ab a 2 a b b 2 ac 0
HINT:
bc ac c a ab a 2
Put a=b=c=1

(4) ab bc ca

(3) 0

If A is a square matrix of order 3, then Adj AdjA2

(1) A

(2) A

KEY: 3

(3) A

(4) A

w
w

HINT:

adj adj A2

.n

5.

Q A2

312

A2 A

The system 2 x 3 y z 5,3x y 5 z 7, x 4 y 2 z 3 has

(1) Unique solution
(2) Finite number of solutions
(3) Infinite solutions
(4) No solution
KEY: 4
Rank of A Rank of AB
HINT:

6.

No solution.
6

2k
2 k
i cos

7
7
k 1
(1) -1
(2) 0
KEY: 4

7.

sin

(3) i

(4) i

16

6
2k
2k

i cos
i sin

7
7
HINT: k 1

i 1 2 .... 6 1 i 0 1 i

If ' ' is a complex cube root of unity, then

(1) 1
(2) -1
(3)
KEY: 2
1 2 4

...... infinte G.P.
HINT: 3 9 27
S

(4) i

et
ba
di
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8.

1 3 9

....
2 8 32

1 2 4

....
3 9 27

a
1
1 r

1 3 9
....... infinte G.P.
2 8 32
S

a
2
1 r

1 2 1

The common roots of the equations z 3 2 z 2 2 z 1 0, z 2014 z 2015 1 0 are

9.

w
w

.n

(1) , 2
(2) 1, , 2
(3) 1, , 2
KEY: 1
Clearly , 2 are the roots of given equations.
HINT:

10.

1 cos 8 i sin 8

1 cos i sin
8
8

(1) 1

(4) , 2

(2) -1

(3) 2

(4)

1
2

KEY: 2
8

cos

i
sin

8
8 1

HINT: 1 cos i sin

8
8

11.

If a, b, c are distinct and the roots of b c x 2 c a x a b 0 are equal, then a, b, c

are in
(1) Arithmetic progression
(2) Geometric progression

(3) Harmonic progression

KEY: 1
Clearly x 1 is a solution
HINT:
Product of the roots

ab
bc

ab
bc

11

(4) Arithmetico-Geometric progression

et
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bc ab

2 b a c a, b, c are in A.P.

If the roots of x 3 kx 2 14 x 8 0 are in geometric progression, then k

(1) -3
(2) 7
(3) 4
(4) 0
KEY: 2
a
Let , a, ar be the roots
r
HINT:

12.

a
. a . ar 8
r

a3 8

a2

a 2 is a root of given equation

13.

.n

8 4k 28 8 0 k 7

If the harmonic mean of the roots of

w
w

(1) 2
(2) 3
KEY: 3
Let , be the roots
HINT:

2 82 5

2
4

2 82 5

b 4 5

2
b
2

2 x 2 bx 8 2 5 0 is 4, then the value of b

(3) 4 5

(4) 4 5

et
ba
di
.i

x2 2 x 1
14.
For real values of x , the range of 2
is
x 2x 1
1
(1) , 0 1,
(2) , 2
2
2

(3) , 1,
(4) , 6 2,
9

KEY: 1
x2 2x 1
Let y 2
x 2x 1
HINT:

yx 2 2 xy y x2 2 x 1

y 1 x 2 2 x y 1 y 1 0

B2 4 AC 0 & y 1, y 0
15.

The number of Four digit numbers formed by using the digits 0, 2, 4,5 and which are not
divisible by 5, is
(1) 10
(2) 8
(3) 6
(4) 4
KEY: 2
No. of four digit numbers divisible by 5 = 6+4=10
HINT:

.n

_ _ _ 0 3! = 6

w
w

_ _ _ 0 3!-2! = 4

Total No. of four digit numbers = 4!-3! =18

Required = 18-10=8

Tm denotes the number of Triangles that can be formed with the vertices of a regular
polygon of m sides. If Tm1 Tm 15, then m
(1) 3
(2) 6
(3) 9
(4) 12
KEY: 2

16.

HINT:

Tm 1 T m 15

m 1

C3 m C3 15

By verification m=6 by solve.

17.

If x 1 then the coefficient of x 5 in the expansion of

(1)

33
32

(2)

33
32

(3)

3x
is
x 2 x 1

31
32

(4)

31
32

KEY: 2

32
3 1 3
2 ; B

1
2 1
1 2 3

et
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3x
A
B

HINT: x 2 x 1 x 2 x 1

3x
2
1

x 2 x 1 x 2 x 1

2 1 x

1
1 x
2
x 1

1 x

2
5

x x
x
1 ..... .... 1 x x 2 x3 x 4 x 5 ....
2 2

1
33
1
32
32
n
9
10
If the coefficients of x , x , x11 in the expansion of 1 x are in arithmetic progression then

.n

Coefficient of x 5

18.

w
w

n2 41n
(1) 398
(2) 298
KEY: 3
n
C9 , n C10 , n C11 are in A.P.
HINT:
2 n C10 n C9 n C11 2

10
n 10

n9
11

w
2

(3) -398

(4) 198

C9 n C11

n
C10 n C10

110 n 2 19n 90
11n 99

n 2 41n 398

1 1.3
1.3.5

......, then 3 x 2 6 x
If x
5 5.10 5.10.15
(1) 1
(2) 2
(3) 3
KEY: 2

19.

(4) 4

1 1.3 1 1.3.5 1
1 x 1


5 2! 5
3! 5
HINT:

1 x

p
q

p p q x
1
.......
2!
q

x 1

q 5

q 2

5 5

5
We get 1 x
3
x2 2x 1

5
3

3x 2 6 x 2

If sin cos p and tan cot q then q p 2 1

(1)

1
2

(2) 2

KEY: 2

p2

w
w

HINT:

sin cos

.n

20.

et
ba
di
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p 1, p q 2, q 2

1 sin 2 p 2
1
q
Tan

Tan

sin 2 p 2 1

Tan 2 1 q

2Tan
2
cos ec 2

q
2

1
q

2 p 2 1 q
p 1 2
2

(3)1

(4) 3


2
4
2 tan
4 cot

5
5
5

2
3
4
(1) cot
(2) cot
(3) cot
(4) cot
5
5
5
5
KEY: 1
cotA - tanA = 2 cot2A
HINT:
22.
If sin A sin B sin C 0 and cos A cos B cos C 0, then
cos(A B) cos(B C) cos(C A)
(3) 1
(4) 0
(1) cos ( A B C) (2) 2
KEY: 4
x = cisA, b = cis B, z = cis C
HINT:
1
, then =
23.
If tan .tan(1200 ).tan(1200 )
3
n
n
n
n
,n Z
,n Z
,n Z
,n Z
(2)
(3)
(4)
(1)
3 18
3 12
12 12
3 6
KEY: 1
tan tan(120 ) tan(120 ) tan 3
HINT:
x2 x3

x 4 x6
24.
If sin1 x .............. + cos1 x 2 .............. and 0 < x < 2 then x =
2 4
2 4

2
1
1
(1)
(2) 1
(3)
(4) -1
2
2
KEY: 2
x 2 x3
x4 x6
x ...... x 2 ......
2 4
2 4
HINT:
tan

w
w

.n

et
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21.

(4)

1
1 a2

25.

x x2 x 1
a
1 x
If 2sin h 1
log

then x =
2
1 x
1 a
1
(1) a
(2)
(3) 1 a 2
a

KEY: 1
sinh 1 x log( x 1 x 2 )
HINT:
In a ABC, (a b c)(b c a) bc, then
(1) 6
(2) 6
(3) 0 4
KEY: 3

0 1
4
HINT:

26.

(4) 4

If in a ABC, r1 2r2 3r3 , then the perimeter of the triangle is equal to

(1) 3a
(2) 3b
(3) 3c
(4) 3(a b c)
KEY: 2

2
3
1

HINT: S a S b S c K
In a ABC,

(1) 2r
KEY: 4
a = b = c = 1,
HINT:

a
b
c

tan A tan B tan C

(2) r + 2R

A = B = C = 60
29.

(3) 2r + R

(4) 2 (r + R)

et
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28.

27.

If m1 , m2 , m3 , m 4 , are respectively the magnitudes of the vectors

a1 2i j k, a 2 3i 4j 4k, a 3 i j k, a 4 i 3j k, then the correct order of

m1 ,m2 ,m3 , m4 is
(1) m3 m1 m4 m2
(3) m3 m4 m1 m2

(2) m3 m1 m2 m4

(4) m3 m4 m2 m1

w
w

.n

KEY: 1
Find magnitudes
HINT:
30.
If a, b, c, are unit vectors such that a b c 0, then the a.b b.c c.a
3
3
1
1
(1)
(2)
(3)
(4)
2
2
2
2
KEY: 2
S.O.B.S
HINT:
31.
If a 2i k, b i j k, c 4i 3 j 7k, then the vector r satisfying r b c b and r.a 0 is

(1) i 8 j 2k
KEY: 4
r b c b
HINT:

r b c b 0

(r c ) b 0

r c // b
r c tb

(2) i 8 j 2k

(3) i 8 j 2k

(4) i 8 j 2k

r c tb

r a c .a t (b .a )
(c .a )
t
b .a

c .a
r c
b .a

If a, b , c are three vectors such that a =1, b =2, c =3, and a.b b.c c.a 0, then a b c
(1) 0
(2) 2
(3) 3
(4) 6
KEY: 4
a .a a .b a .c
2
a b c b .a b .b b .c
HINT:
c .a c .b c .c

et
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32.

If a b b c c a a b c , then =
(1) 0
(2) 1
(3) 2
(4) 3
KEY: 2
2
a b b c c a a b c
HINT:
34.
The Cartesian equation of the plane passing through the point (3,-2,-1) and parallel to the
vectors b i 2 j 4k and c 3i 2 j 5k is
(1) 2x 17y 8z + 63 = 0
(2) 3x + 17y + 8z - 36 = 0
(3) 2x + 17y + 8z + 36 = 0
(4) 3x 16y + 8z - 63 = 0
KEY: 3
x x1 y y1 z z1

w
w

.n

33.

a1
b1
c1 0
a2
b2
c2
35.
The arithmetic mean of the observations 10, 8, 5, a, b is 6 and their variance is 6.8. then ab=
(1) 6
(2) 4
(3) 3
(4) 12
KEY: 4
10 8 5 a b
6,
5
HINT:

HINT:

1
2
xi x 6.8

36.

If the median of the data 6, 7, x-2, x, 18, 21 written in ascending order is 16, then the
variance of that data is
1
1
1
1
(1) 30
(2) 31
(3) 32
(4) 33
5
3
2
3

KEY: 2
M

HINT:

x2 x
16
2

Variance =

1
2
xi x

Two persons A and B are throwing an unbiased six faced die alternatively, with the
condition that the person who throws 3 first wins the game. If A starts the game, the
probabilities of A and B to win the same are respectively.
6 5
5 6
8 3
3 8
(1) ,
(2) ,
(3) ,
(4) ,
11 11
11 11
11 11
11 11
KEY: 1
A p pq 2 pq 4 .......
HINT:
= p(1 + q2 + q4 + )
=

p
1 q2

The letters of the work QUESTION are arranged in a row at random. The probability
that there are exactly two letters between Q and S is
1
5
1
5
(1)
(2)
(3)
(4)
14
7
7
28
KEY: 4
HINT:

.n

38.

et
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37.

n E 6 P2 2! 5!

w
w

n S 8!

1 3p 1 2p
,
are probabilities of two mutually exclusive events, then p lies in the interval
3
2
1 1
1 1
1 2
1 2
(1) ,
(2) ,
(3) ,
(4) ,
3 2
2 2
3 3
3 3
KEY: 1
1 3P
1 2P
0
1, 0
1
3
2
HINT:
If

39.

40.

The probability that an event does not happen in one trial is 0.8. The probability that the
event happens atmost once in three trails is
(1) 0.896
(2) 0.791
(3) 0.642
(4) 0.592
KEY: 1
p = 0.2, q = 0.8, n = 3
HINT:

41.

The probability distribution of a random variable is given below :

X=x
P(X = x)

0
0

1
K

2
2K

3
2k

4
3K

5
K2

6
2K2

Then P 0 X 5
1)

1
10

2)

3
10

3)

8
10

4)

7
10

KEY: 3

P X xi 1

et
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HINT:
9 K 10 K 2 1
10 K 2 9 K 1 0
10 K 2 10 K K 1 0

10 K K 1 1 K 1 0
K

1
10

P 0 X 5 P X 1 P X 2 P X 3 P X 4 8K
42.

8
10

If the equation to the locus of points equidistant from the points (-2, 3), (6, -5) is
ax by c 0 where a > 0 then, the ascending order of a,b,c is
2) c,b,a

w
w

.n

1) a,b,c
KEY: 2
A 2,3 ; B 6, 5
HINT:

3) b,c,a

4) a,c,b

P x, y

PA2 PB 2
2

x 2 y 3

x 6 y 5

4 x 4 9 6 y 12 x 36 10 y 25
16 x 16 y 48 0
x y3 0
ax by c 0

a 1; b 1; c 3
Ascending order : c, b, a

43.

The point (2,3) is first reflected in the straight line y = x and then translated through a
distance of 2 units along the positive direction x-axis. The coordinates of the transformed
point are
1) (5, 4)
2) (2, 3)
3) (5, 2)
4) (4, 5)

7
7K2+k

 3 1 2
2 1 1

et
ba
di
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KEY: 3
HINT: Reflection of (2,3) in y=x is (3,2)
Required point (3+2,2) = (5,2)
44.
If the straight lines 2x 3 y 1 0 , x 2 y 1 0 and ax by 1 0 form a triangle with
origin as
ortho centre, then (a, b) =
1) (6, 4)
2) (-3, 3)
3) (-8, 8)
4) (0, 7)
KEY: 3
HINT:

3
2

x
y 1

1 1 1

w
w

.n

Verification
45.
The point on the line 4x y 2 0 which is equidistant from the points (-5, 6) and (3, 2) is
1) (2, 6)
2) (4, 14)
3) (1, 2)
4) (3, 10)
KEY: 2
Verification (or) Solving
HINT:

2x y 6 0 & 4x y 2 0
46.
If the lines x 2ay a 0 , x 3by b 0 , x 4cy c 0 are concurrent, then a,b,c are in
1) Arithmetic progression
2) Geometric progression
3) Harmonic progression
4) Arithmetico-Geometric progression
KEY: 3
1 2a a

HINT:
47.

1 3b b 0
1 4c c

H.P
2

The angle between the straight lines represented by x 2 y 2 sin 2 x cos y sin is
1)

2)

3) 2

4)

KEY: 3
cos cos 2
HINT:

m3 a
m3 m 6 3.m3 .6 63
a 2 19a 216 0

et
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di
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2
48.
If the slope of one of the lines represented by ax2 6 xy y 2 0 is the square of the other,
then the value of a is
1) -27 or 8
2) -3 or 2
3) -64 or 27
4) -4 or 3
KEY: 1
m m2 6
HINT:

Cp r

2Cp 2 10 20

The locus of centres of the circles which cut the circles x 2 y 2 4 x 6 y 9 0 and

w
w

50.

.n

a 27,8
49.
The sum of the minimum and maximum distances of the point (4, -3) to the circle
x 2 y 2 4 x 10 y 7 0 is
1) 10
2) 12
3) 16
4) 20
KEY: 4
Cp r
HINT:

x 2 y 2 5x 4 y 2 0 orthogonally is
1) 3x 4 y 5 0
2) 9 x 10 y 7 0
KEY: 2
S S1 0
HINT:

3) 9 x 10 y 7 0

4) 9 x 10 y 11 0

9 x 10 y 7 0
51.
The equation of the circle passing through (2,0) and (0,4) and having the minimum radius is
1) x2 y 2 20
2) x 2 y 2 2 x 4 y 0 3) x2 y 2 4
4) x 2 y 2 16
KEY: 2
x 2 x 0 y 0 y 4 0

HINT:

x2 2x y 2 4 y 0

If x 2 y 2 4 x 2 y 5 0 and x 2 y 2 6 x 4 y 3 0 are members of a coaxal system of

circles then centre of a point circle in the system is
1) (-5, -6)
2) (5,6)
3) (3,5)
4) (-8,-13)
KEY: 1
S L 0
HINT:

52.

r0

0,14

centre 5, 6

et
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4 2
centre
,

2
2

x2 y 2 4 x 2 y 5 x y 4 0

If x y 1 0 meets the circle x 2 y 2 y 1 0 at A and B then the equation of the circle

with AB as diameter is
1) 2 x 2 y 2 3 x y 1 0
2) 2 x 2 y 2 3x y 2 0

53.

3) 2 x 2 y 2 3 x y 3 0
KEY: 1
HINT:

.n

S L 0

4) x 2 y 2 3x y 1 0

x 2 y 2 y 1 x y 1 0

w
w

1
center
,

2
2

Centre lies on x y 1 0

32

Eq : x 2 y 2 y 1

3
x y 1 0
2

2 x2 y 2 3x y 1 0

An equilateral triangle is inscribed in the parabola y 2 8x , with one of its vertices is the
vertex of the parabola. Then, the length of the side of that triangle is
1) 24 3
2) 16 3
3) 8 3
4) 4 3
KEY: 2
54.

 3x x
, lies on y 2 8 x

2
2

HINT:
side x 16 3
55.
The point (3,4) is the focus and 2x 3y 5 0 is the directrix of a parabola. Its latus rectum is
2
4
1
3
1)
2)
3)
4)
13
13
13
13
KEY: 1
4a 2 distance from focus to directrix

56.

et
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HINT:
6 12 5
2
2

49
13

The radius of the circle passing through the foci of the ellipse

centre at (0,3) is
1) 6
KEY: 2
ae 7
HINT:

2) 4

r ae 2 b 2

3) 3

x2 y2

1 and having its

16 9
4) 2

1) 45
KEY: 3

.n

79 4
57.
The values that m can take so that the straight line y 4 x m touches the curve x2 4y2 4 is
2) 60

3) 65

4) 72

w
w

C a 2 m2 b2
HINT:

4 16 1 65

x2 y2
x2 y 2 1

1 and the hyperbola

coincide. Then, the value

58.
The foci of the ellipse
16 b 2
144 81 25
of b2 is
1) 5
2) 7
3) 9
4) 1
KEY: 2
For ellipse focus

HINT:

16 b 2 ,0

12
15

, 0 3, 0
5 12

For hyperbola focus is

16 b 2 3
b2 7

If (2,-1,2) and (K,3,5) are the triads of direction ratios of two lines and the angle between
them is 450 , then a value of K is
1) 2
2) 3
3) 4
4) 6
KEY: 3
1
2 K 3 10

HINT: 2 3 K 2 34
Verfication K 4
1 1 1
60.
The length of perpendicular from the origin to the plane which makes intercepts , ,
3 4 5
respectively on the coordinate axes is
1
1
1)
2)
3) 5 2
4) 5
10
5 2
KEY: 1
x y z
Equation of plane
1
a b c
HINT:
3x 4 y 5 z 1 0
1
1
distance from origin

50 5 2
61.
Match the following
I. The centroid of the triangle formed by
a) (2,2,2)
(2,3,-1), (5,6,3), (2,-3,1) is
II. The circumcentre of thetriangle formed by b) (3,1,4)
(1,2,3), (2,3,1),(3,1,2) is
III. The orthocenter of the triangle formed by c) (1,1,0)
(2,1,5), (3,2,3) , (4,0,4) is
IV. The incentre of the triangle formed by
d) (3,2,1)
(0,0,0), (3,0,0), (0,4,0) is
e) (0,0,0)
I
II
III
IV
1)
d
a
b
c
2)
a
b
c
d
3)
d
e
b
c
4)
d
a
e
c
KEY: 1
A 2, 3, 1 , B 5, 6,3 , C 2, 3,1
I
HINT:
x x x y y y3 z1 z2 z3
G 1 2 3, 1 2
,
3, 2,1
3
3
3

II.
ABC is a equilateral

w
w

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59.

G s 2, 2, 2

62.

If g x

g x g 2
x
for x 2 then lim

x 2
x 2
x

1) 1

2) 0

3)

1
2

4) 1

KEY: 3
Lt
x2

s x g 2
x2

x
1
1
Ltx2 2

x2 2
2x
Lim

x cos x

63.

1) 0

HINT:

x
2

et
ba
di
.i

S x

2)

KEY: 3
L.H.R
HINT:
Ans : -2

1
2

3) 2

4) 5

x, for 0 x 1
If f is defined by f x
, then at x = 1, is
2 x, for x 1
1) Continuous and differentiable
2) Continuous but not differentiable
3) Discontinuous but differentiable
4) Neither continuous nor differentiable
KEY: 2

w
w

.n

64.

F is centime but not differentable

HINT:

f x Ltx1 f x f 1

f x f 1 Lt
f x f 1
x1
x 1
x 1

Lt
x 1

Lt
x 1

1
1
dy

If x 2 y 2 t and x 4 y 4 t 2 2 then
t
t
dx
y
x
1)
2)
y
x
KEY: 2

65.

3)

x2
y2

4)

y2
x2

x2 y 2 t

HINT:

2 2

1
t

1
t
t

1
2
t2

x4 y 4 2 x2 y 2 t 2

x2 y 2 1
66.

et
ba
di
.i

2x2 y 2 2

Let D be the domain of a twice differentiable function f. For all x D, f '' x f x 0 and
2

f x g x dx constant . If h x f x g x and h 0 5 then h 2015 h 2014

1) 5
KEY: 3

2) 3

3) 0

4) 1

f x is constant function

HINT:

h 2015 h 2014 5 5 0

1
d2y
at t is
2
dx
2
4
2)
a

.n

67.

If x at 2 and y 2at, then

2
a

w
w

1)

3)

8
a

4)

4
a

KEY: 4

dy 1

HINT: dx t

d 2 y 1 dy
1
1
2
2

2
dx
t dx t 2at 2at 3

Put t

1
2

d 2 y 4

dx 2
a
68.

The volume of a sphere is increasing at the rate of 1200 c.cm/sec. The rawte of increase in its
surface area when the radius is 10 cm is .

1) 120 sq.cm/sec
KEY: 2

2) 240 sq.cm/sec

3) 200 sq.cm/sec

4) 100 sq.cm/sec

4
V r3
3
HINT:

dy 4
dy
3r 2
dt 3
dx

et
ba
di
.i

dv
dx
4 x 2
dt
dt

69.

dt
at the point where x = 1 is
3
0 1 t

The slope of the tangent to the curve y

1)

1
4

1
3

2)

KEY: 3
dy
1

3
HINT: dx 1 x

1
2

4) 1

3) 4

4) 5

3)

.n

1
1
dy
m x 1

11 2
dx

If x 2 y2 25 , then log 5 Max 3x 4y is

1) 2
2) 3
KEY: 4

w
w

70

HINT:

log 5 52

2log5 5 2 1 = 2

71.

If f is defined in 1,3 by f x x 3 bx 2 ax, such that f 1 f 3 0 and f ' c 0 where

c 2

1
, then a, b
3

1) 6,11
KEY: 3

2) 2 1 , 2 1
3
3

3) 11, 6

4) 6,11

f 1 x 3x 2 2bx a

HINT:

f 1 c 0
3c 2 2bc a 0

x 1

x2 1

(c is a constant)
x 1
C
1)
x 1
KEY: 3
dx
x2 1
1
t

Put x 1

x2 1

e x 1

73.

ex
C
x 1

dx

x 1
C
x2 1

2)

e x
C
x 1

3)

x 1
C
x 1

x 1
3) e x
C
x 1

w
w

1)

2)

.n

HINT: x 1

et
ba
di
.i

dx

72.

a 11, b 6

KEY: 3

x 2 1
1

x 12 x 12 dx
HINT:

x 1
1
x 1
ex

dx e x
c
2
x 1 x 1
x

74.

x 1

x 1 xe dx 0
x

1) Log

1 xe x
C
xe x

3) Log xe x 1 xe x C

2) Log

xe x
C
1 xe x

4) Log 1 xe x C

4)

x2 1
C
x 1

4) e x

x 1 C
x 1

KEY: 2
e x x 1

HINT:

xe 1 xe dx
x

f x g ' x f ' x g x

f x g x

g x
1) Log
f x C

3)

g x
1
2) Log
C
2
f x

g x Log g x C

f x
f x

KEY: 2

g x g x
4) Log
C

f
x
f
x

Put log g x1 log f x1 t

76.

1)

sin x cos x
dx
3 sin 2 x

1
Log 3
2

KEY: 4

2) Log 2

3) Log 3

.n

HINT:

Log g x Log f x dx

et
ba
di
.i

75.

Put xe x t

4)

1
Log 3
4

Put sin x cos x t

w
w

HINT:

1 x x2 1 x x2

dx
2
2
1

x
1
3

1)
2)
2
2
KEY: 3

3) 0

77.

4) -1

Odd function

HINT:

78.

The area of the region described by

1)

2 3

2)

2 3

x, y / x

y 2 1 and y 2 1 x is

3)

2 3

4)

2 3

KEY: 3
Solve x 2 y 2 1
HINT:

Area

dy 1 e y

is
dx x x 2
1) 2 x 1 Cx 2 e y

2) x 1 Cx 2 e y

3) 2 x 2 1 Cx 2 e y

4) x 2 1 Cx 2 e y

The solution of

KEY: 1
Dividing with e y
HINT:
1 dy
1
1
y 2
y
e dx xe
x

80.

et
ba
di
.i

79.

2 3

y2 1 x

The differential equation

.n

1) Linear in y
3) Linear in both x & y
KEY: 2

dy
1

where a, b, c are all non zero real numbers, is

dx ax by c
2) Linear in x
4) Homogeneous equation

w
w

dx
ax by c
HINT: dy

dx
ax by c
dy

Linear in x

PHYSICS
81.
The pressure on a circular plate is measured by measuring the force on the plate and the
radius of the plate. If the errors in measurement of the force and the radius are 5% and 3%
respectively, the percentage of error in the measurement of pressure is
1) 8
2) 14
3) 11
4) 12
KEY: 3

P
HINT:

F
F

A R2

P
F
R
100
100 2
100
P
F
R

5 2(3) 5 6 11
P
100 11%
P
A body is projected vertically from the surface of the earth of radius R with a velocity
equal to half of the escape velocity. The maximum height reached by the body is
R
R
R
R
1)
2)
3)
4)
2
3
4
5
KEY: 2
V KVe ( K 1) then
HINT:

et
ba
di
.i

82.

1
R
RK
R 4 R
4
h

2
1 K
1 4 3 3
1
4
2

R
3

A particle aimed at a target, projected with an angle 150 with the horizontal is short of the
target by 10m. If projected with an angle of 450 is away from the target by 15m, then the
angle of projection to hit the target is
1
1
1
1
1
3
9
7
2) sin 1
3) sin 1
4) sin 1
1) sin 1
2
2
2
2
10
10
10
10
KEY: 4

w
w

.n

83.

HINT:

R1 R 10

R2 R 15

R 10 sin 21 sin 30 1

R 15 sin 2 2 sin 90 2

2R 20 R 15
R 35

R max

u2
g

u 2 sin 2
R
g

50 g sin 2
g
35 7

50 10

7
2 sin 1
10
1
7
sin 1
2
10

A man running at a speed of 5kmph find that the rain falls vertically. When he stops
running, he finds that the rain is falling at an angle of 600 with the horizontal. The velocity
of rain with respect to running man is
5
5 3
4 3
kmph
2)
kmph
3)
kmph
4) 5 3kmph
1)
2
5
3
KEY: 4

.n

84.

sin 2

u 2 50 g

et
ba
di
.i

35

u2
50
g

w
w

HINT:

Tan300

5
1

= 5 3 kmph

Vrm

Vm
Vrm

85.

A horizontal force just sufficient to move a body of mass 4kg lying on a rough horizontal
surface, is applied on it. Coefficients of static and kinetic frictions are 0.8 and 0.6
respectively. If the force continues to act even after the body has started moving, the
acceleration of the body is g 10ms 2

1) 6ms 2
KEY: 3

2) 8ms 2

3) 2ms 2

4) 4ms 2

HINT:

a s k g (0.8 0.6) 10

0.2 10

a 2ms 2

A force 2i j k N acts on a body which is initially at rest. At the end of 20 sec the

86.

velocity of the body is 4i 2 j 2k ms 1 , then the mass of the body is

2) 10 kg

F 4 1 1 6
HINT:

V 16 4 4 24

v u
F m

24 0
6 m

20

6 20 20

10
2
24

w
w

m 10kg

4) 4.5 kg

.n

3) 5 kg

et
ba
di
.i

1) 8 kg
KEY: 2

A man of weight 50kg carries an object to a height of 20m in a time of 10sec. The power used
by the man in this process is 2000W, then find the weight of the object carried by the man
[ assume g 10 ms-2 ]
1) 100kg
2) 25 kg
3) 50 kg
4) 10 kg
KEY: 3

87.

P ( M x) gh / t

HINT:

2000

(50 x) 10 20
10

1000 500 10x

10 x 500 x 50kg

88.

A ball ' P ' moving with a speed of v ms -1 collides directly with another identical ball 'Q'

moving with a speed 10ms-1 in the opposite direction. P comes to rest after the collision. If
the coefficient of restitution is 0.6, the value of v is
1) 30ms-1
2) 40 ms -1
3) 50ms-1
4) 60 ms-1
KEY: 2

m(v 10) mV2

v2 (v 10)
v2 v1 (v 10) 0

u1 u2
(v 10)

0.6

v 10
v 10

0.6v 6 v 10
0.4v 16

v 40ms 1

et
ba
di
.i

HINT:

A particle of mass m = 5 units is moving with uniform speed V = 3 2 units in the XY plane
along the line Y= X+4. The magnitude of the angular momentum about origin is
1) zero
2) 60 units
3) 7.5 units
4) 40 units
KEY: 2

.n

89.

L mvb cos

w
w

HINT:

5 3 2 4 cos 45

L 60kg m2 s 1

The kinetic energy of a circular disc rotating with a speed of 60 r.p.m. about an axis passing
through a point on its circumference and perpendicular to its plane is (mass of circular disc
=5kg, radius of disc = 1m) approximately.
1) 170 J
2) 160 J
3) 150 J
4) 140 J
KEY: 3

90.

KE
HINT:

1 2 1 3 2 2 2
I mr 4 f
2
2 2

3mr 2 2 f 2 3 5 1 10 1

KE 150 J

The amplitude of a simple pendulum is 10cm. When the penduclum is at a displacement of 4

cm from the mean position, the ratio of kinetic and potential energies at that point is
1) 5.25
2) 2.5
3) 4.5
4) 7.5
KEY: 1
1
mw2 ( A2 x 2 )
K .E 2

1
HINT: P.E
mw2 x 2
2

K .E A2 x 2

P.E
x2
=

102 42
42

84
16

K .E 21

5.25
P.E
4

A satellite revolving around a planet has orbital velocity 10 km/s. The additional velocity
required for the satellite to escape from the gravitational field of the planet is
1) 14.14 km/s
2) 11.2 km/s
3) 4.14 km/s
4) 41.4 km/s
KEY: 3
Ve = ( 2 1)V0
HINT:

w
w

.n

92.

et
ba
di
.i

91.

= (1.414 1)V0= 0.414 10= 4.14 km/s

The length of a metal wire is l1 when the tension in it is F1 and l 2 when the tension is F2 .
Then original length of the wire is
l F l F
l -l
l F -l F
l F -l F
2) 2 1
3) 1 2 2 1
4) 1 1 2 2
1) 1 1 2 2
F1 F2
F2 F1
F2 F1
F2 F1
KEY: 3
F1 e1
HINT:

93.

F1 l1 l
F2 l2 l
F1 l1 l

F2 l2 l

F1l2 F1l F2l1 F2l

( F2 F1 )l F2l1 Fl
1 2
F2 l1 F1l2
F2 F1
The average depth of Indian ocean is about 3000m. The value of fractional compression
V

of water at the bottom of the ocean is (given that the bulk modulus of water is
V
2.2 109 Nm 2 , g 9.8 ms 2 , PH 2 O 1000 kg.m 3 )
l

et
ba
di
.i

94.

1) 3.4 102
2) 1.34 102
KEY: 2
v h g 3 103 103 9.8

k
22 108
HINT: v
=

3) 4.13 102

4) 13.4 102

3
147
103 98
103 1.34 102 m
22
11

The ratio of energies of emitted radiation by a black body at 600 k and 933 k when th e
surrounding temperature is 300 k
5
7
3
9
1)
2)
3)
4)
16
16
16
16
KEY: 3
E1 T14 TS4
4
4
HINT: E2 T2 T2

(600)4 (300)4 3

(900) 4 (300)4 16

w
w

.n

95.

The specific heat of helium at constant volume is 12.6 Jmol1 k 1 . The specific heat of helium

96.

at constant pressure in Jmol1k 1. is about (Assume the termperatrue of the gas is moderate,
4) 21

universal gas constant, R 8.314Jmol1k 1 )

1)12.6
2) 16.8
3) 18.9
KEY: 4
CV = 12.6
HINT:
R

= 8.314

CP = CV + R= 12.6 + 8.314= 21
97.

A gas does 4.5 J of external work during adiabatic expansion. If its temperature falls by 2K,
then its internal energy will be
1) increased by 4.5 J
2) decreased by 4.5 J
3) decreased by 2.25 J
4) increased by 9.0 J

KEY: 2
dQ= 0
HINT:
dU = -dW
dU = -4.5 J
The relation between efficiency ' ' of a heat engine and the co-efficient of performance ' '
of a refrigerator is
1
1
2)
3) 1
4) 1
1)
1
1
KEY: 2
1

1
HINT:

et
ba
di
.i

98.

99.

A flask contains argon and chlorine in the ratio of 2 : 1 by mass. The temperature of the
mixture is 270 C . The ratio of average kinetic energies of two gases per molecule is
1) 1 : 1
2) 2 : 1
3) 3 : 1
4) 6 : 1
KEY: 1
Independent of nature K.E1 : K.E2 = 1 : 1.
HINT:

A transverse wave is represented by the equation y 2 sin 30t 40 x and the measurements
of distances are in meters, then the velocity of propagation is
1) 15ms 1
2) 0.75ms 1
3) 3.75ms 1
4) 300ms 1
KEY: 2
y = 2sin (30t 40x)
HINT:

w
w

.n

100.

= Asin (wt kx)

w 30

0.75m / sec
k 40
101. Two closed pipes have the same fundamental frequency. One is filled with oxygen and the
other with hydrogen at the same temperature. Ratio of their lengths respectively is
1) 1 : 4
2) 4 : 1
3) 1 : 2
4) 2 : 1
KEY: 1
V
n
4l
HINT:

V=

VH lH 4

VO lO 1

VH
M2
32

4
VO
M1
2

R 20cm

103.

et
ba
di
.i

1.5
1
1.5 1

100 100
R

VO : VH 1: 4
102. An image is formed at a distance of 100 cm from the glass surface when light from point
source in air falls on a spherical glass surface with refractive index 1.5. The distance of the
light source from the glass surface is 100 cm. The radius of curvature is.
1) 20 cm
2) 40cm
3) 30 cm
4) 50 cm
KEY: 1
2 1 2 1

V U
R
HINT:

Two coherent sources of intensity ratio 9 : 4 produce interference. The intensity ratio of
maxima and minima of the interference pattern is
1) 13 : 5
2) 5 : 1
3) 25 : 1
4) 3 : 2
KEY: 3
I1 9

I2 4
HINT:
2

w
w

.n

Imax I1 I 2 9 4
25

1
I min I1 I 2 9 4
104. The energy of a parallel plate capacitor when connected to a battery is E. With the battery
still in connection, if the plates of the capacitor are separated so that the distance between
them is twice the original distance, then the electrostatic energy becomes.
E
E
1) 2E
2)
3)
4) 4E
4
2
KEY: 3
1
1 c1 d 2 2d
E cv 2 c

2
2
d c2 d1
d
HINT:
E1 C1
C
2

E2 C 2 C 2 1
E 2

E2 1
E2

E
2

Two point charges +8 c and +12 c repel each other with a force of 48N. When an
additional charge of -10 c is given to each of these charges (the distance between the
charges is unaltered) then the new force is
1) Repulsive force of 24N
2) Attractive force of 24N
3) Repulsive force of 24N
4) Attractive force of 2N
KEY: 4
q1 8 c q2 12c

105.

HINT:

q11 2 c q12 2 c

F1 q1q2

F2 q11q12

F2 2 N
106.

et
ba
di
.i

F 48 N

4
, then the electric susceptibility e is
3
4
3
3) 0
4) 0
3
4

If the dielectric constant of a substance is K

1)

0
3

2) 30

KEY: 1
r 1

K 1

w
w

1
3
0

.n

HINT:

0 3
0
3

107.

In a region of uniform electric field of intensity E, an electron of mass me is released from

rest. The distance travelled by the electron in a time t is
2met 2
m gt 2
eEt 2
1)
2)
3) e
e
eE
2me

KEY: 2
S

HINT:

1 2
at
2

1 eE 2
t
2 m

4)

2 Et 2
eme

108.

A constant potential difference is applied between the ends of the wire. If the length of the
wire is elongated 4 times, then the drift velocity of electrons will be
1) increases 4 times
2) decreases 4 times
3) increases 2 times
4) decreases 2 times
KEY: 2
1
Vd
l
HINT:
l2 4l

l1
l

Vd 2

Vd1 : Vd2 4 :1

et
ba
di
.i

Vd1

In a metre bridge, the gaps are enclosed by resistances of 2 and 3 . The value of shunt to
be added to 3 resistor to shift the balancing point by 22.5 cm is
1) 1
2) 2
3) 2.5
4) 5
KEY: 2
2 3 x 62.5

3x
37.5
HINT:

109.

On simplifying x 2

Two long straight parallel conductors 10 cm apart, carry equal currents of magnitude 3A in
the same direction. Then the magnetic induction at a point midway between them is
1) 2 105 T
2) 3 105 T
3) zero
4) 4 105 T
KEY: 3
At the midpoint two conductors B1 B2 B
HINT:

w
w

.n

110.

BR B1 B2 0

In a crossed field, the magnetic field induction is 2.0T and electric field intensity is 20 x 103
V/m. At which velocity the electron will travel in a straight line without the effect of electric
and magnetic fields ?
20
1)
103 ms 1
2) 10 103 ms 1
3) 20 103 ms 1
4) 40 103 ms 1
1.6
KEY: 2

111.

QvB QE

HINT:
V

E
B

A material of 0.25 cm2 cross sectional area is placed in a magnetic field of strength (H) 1000
Am1. Then the magnetic flux produced is (Susceptibility of material is 313) (Permeability of
free space, 0 4 10 7 Hm 1 )
1) 8.33 x 10-8 weber 2) 1.84 x 10-6 weber 3) 9.87 x 10-6 weber 4) 3.16 x 10-6 weber
KEY: 3

112.

X 1
BA = HA X 1 A

The magnitude of the induced emf in a coil of inductance 30 mH in which the current
changes from 6A to 2A in 2 sec is
1) 0.06 V
2) 0.6 V
3) 1.06 V
4) 6V
KEY: 1
L

HINT:

di
dt

114.

et
ba
di
.i

113.

HINT:

i
t

In an AC circuit V and I are given below, then find the power dissipated in the circuit

V 50sin 50t V
I 50 sin 50t mA
,
3

1) 0.625 W
2) 1.25 W
3) 2.50 W
4) 5.0 W
KEY: 1

HINT:

i0
cos
2

w
w

Here 0 50

.n

i0 50

Light with an energy flux of 9 Wcm2 falls on a non-reflecting surface at normal incidence.
If the surface has an area of 20 cm2. The total momentum delivered for complete absorption
in one hour is
1) 2.16 104 kgms 1 2) 1.16 103 kgms 1 3) 2.16 103 kgms 1 4) 3.16 104 kgms 1
KEY: 3

115.

IA
p t
C
HINT:

116.

The ratio of the deBroglie wave lengths for the electron and proton moving with the same
velocity is ( m p -mass of proton, me -mass of electron)

2) m p 2 : me 2

1) m p : me

3) me : m p

4) me 2 : m p 2

KEY: 1
mV

HINT:

The ratio of longest wavelength lines in the Balmer and Paschen series of hydrogen
spectrum is
5
7
7
5
1)
2)
3)
4)
36
20
144
27
KEY: 2

1
1
1
R 2 2
A2 3
HINT: B
1
1 1
r 2 2
p
3 4

b 7

p 10

et
ba
di
.i

117.

In the following nuclear reaction ' x ' stands for

n p e x
1) -particle
2) positron
3) nutrino
KEY: 4

4) Antinutrino

w
w

Conceptual

.n

118.

HINT:

In the following circuit the output Y becomes zero for the input combinations

119.

1) A = 1, B = 0, C = 0
3) A = 0, B = 0, C = 0
KEY: 4

HINT:

Y AB C
= A B C
Y 0 A 1, B 1, C 0

2) A = 0, B = 1, C = 1
4) A = 1, B = 1, C = 0

120.

The maximum amplitude of an amplitude modulated wave is 16V, while the minimum
amplitude is 4V. The modulation index is
1) 0.4
2) 0.5
3) 0.6
4) 4
KEY: 3
M

HINT:

AB
AC

et
ba
di
.i

Amin AC As

Amax AC As

CHEMISTRY

w
w

.n

121.Which of the following sets of quantum numbers is correct for an electron in 3d orbital
1
1
1) n = 3, l = 2, m = -3, s = +
2) n = 3, l = 3, m = +3, s = 2
2
1
1
3) n = 3, l = 2, m = -2, s = +
4) n = 3, l = 2, m = -3, s = 2
2
KEY: 3
1
for 3d, n 3, l 2, m 2 to 2, s
2
HINT:
122. If the kinetic energy of a particles is reduced to half, Debroglie wave length becomes
1
1) 2 times
2)
times
3) 4 times
4) 2 times
2
KEY: 4
1
KE2

KE1
HINT: 2

1
KE

2
2 KE

2 2 1

123. Identify the most acidic oxide among the following oxides based on their reaction with
1) SO3
2) P4O10
3) Cl2O7
4) N2O5
KEY: 3
Acidic nature of oxides increases from left to right in period. (or) Oxide of more EN atom is more
HINT:
acidic in nature.

B
III
I

1)
3)
KEY: 2
1. Rubedium HINT:
2. Platinum

C
II
IV

D
I
III

2)
4)

B
IV
III

C
I
I

s-block element

D
II
II

Atomic number:78

3. EkaSilicon -

Ge

4. Polonium

Radio active chalcogen

A
III
IV

A
IV
II

List II
I) Germanium
II) Radio active chalcogen
III) S-block element
IV) Atomic number 78

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124. Match the following

List-I
A) Rubedium
B) Platinum
C) Ekasilicon
D) Polonium

125. Which of the following does not have triple bond between the atoms ?
1) N2
2) CO
3) NO
4) C22KEY: 3
Iso electronic species have same properties. NO molecule has 15 electrons. Its bond order = 2.5
HINT:

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126. In which one of the following pairs the two species have identical shape but differ in
hybridization
1) I 3 , BeCl2
2) NH3 , BF3
3) XeF2 , I 3
4) NH 4 , SF4
KEY: 1
Both I 3 and BeCl2 have same structure (linear) and but differ in hybridization ( sp3d and sp ) .
HINT:

127. On the top of a mountain water boils at

1) High temperature 2) Same temperature 3) High Pressure
KEY: 4
Low temperature
HINT:

4) Low temperature

128. Which one of the following is the wrong statement about the liquid ?
1) It has intermolecular force of attraction
2) Evaporation of liquids increases with the decrease of surface area
3) It resembles a gas near the critical temperature
4) It is an intermediate state between gaseous and solid state
KEY: 2
Evaporation of liquids increases with increase in surface area.
HINT:

129. A carbon compound contains 12.8% of carbon, 2.1% of hydrogen and 85.1% of bromine. The
molecular weight of the compound is 187.9. Calculate the molecular formula of the
compound. (Atomic wts: H = 1.008, C = 12.0, Br = 79.9)
1) CH3Br
2) CH2Br2I
3) C2H4Br2
4) C2H3Br3
KEY: 3
Element
%
At. wt
relative number
simple ratio
HINT:
12.8

12

12.8
1.06
12

106
1
1.06

2.1

2.1
2.1
1

2.1
2
1.06

Br

85.1

80

85.1
1.06
80

1.06
1
1.06

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EF= CH 2 Br

Wt. of EF = 12 2 80 94
n

M .W
187.9

2
wt of EF
94

MF EF n CH 2 Br 2

= C2 H 4 Br2
130. 3.011 10 atoms of an element weights 1.15 gm. The atomic mass of the element is
1) 23
2) 10
3) 16
4) 35.5
KEY: 1
3.0111022 1.15g
HINT:

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22

6.023 1023 ?

1.15
6.023 1023 23
22
3.01110
131. Which one of the following is applicable for an adiabatic expansion of an ideal gas?
1) E 0
2) W E
3) W E
4) W 0
KEY: 2
Since E q W
HINT:

for an adiabatic reaction q 0

So E W .
132. On increasing temperature, the equilibrium constant of exothermic and endothermic
reactions, respectively
1) Increases and decreases
2) Decreases and increases
3) Increases and increases
4) Decreases and decrease

KEY: 2
As the temperature increases the reaction proceeds towards endothermic direction.
HINT:

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POH = 2, PH = 12

133. What is the pH of the NaOH solution when 0.04 gm of it dissolved in water and made to 100
ml solution ?
1) 2
2) 1
3) 13
4) 12
KEY: 4
0.04 1000
OH

10 2
40
100
HINT:

134. Which of the following methods is used for the removal of temporary hardness of water?
1) Treatment with washing soda
2) Calgon metod
3) Ion-exchange method
4) Clarks method
KEY: 4
Refer text book Memory based
HINT:

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135. Assertion (A): Alkali metals are soft and have low melting and boiling points.
Reason (R): This is because interatomic bonds are weak.
1) Both (A) and (R) are not true
2) (A) is true but (R) is not correct explanation of (A)
3) (A) is true but (R) is true
4) Both (A) and (R) are true and (R) is correct explanation of (A)
KEY: 4
Refer text book Memory based
HINT:

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136. Identify the correct statement

1) Lead forms compounds in +2 oxidation state due to inert pair effect
2) All halogens form only negative oxidation
3) Catenation property increases from boron to oxygen
4) Oxygen oxidation state is -1 in ozonides
KEY: 1
Refer text book Memory based
HINT:
137. Assertion (A): Noble gases have very low boiling points.
Reason (R) : All noble gases have general electronic configuration of ns 2 np6 (except He)
1) Both (A) and (R) are true but (R) is correct explanation of (A)
2) (A) is false but (R) is true
3) (A) is true but (R) is false
4) Both (A) and (R) are true but (R) is not the correct explanation of (A)
KEY: 4
Refer text book Memory based
HINT:

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138. Which of the following statements are correct ?

A) Ocean is sink for CO2.
B) Green house effect causes lowering of temperature of earths surface.
C) To control CO emission by automobiles usually catalytic convertor are fitted into exhaut
pipes.
D) H2SO4, herbicides and insecticides from mist.
1) (C) & (D)
2) (A) & (B)
3) (B) & (D)
4) (A) & (D)
KEY: 4
Refer text book Memory based
HINT:

C bond in methoxy methane is

139. The bond angle of C
1) 111.7
2) 109
3) 108.9
KEY: 1
Refer text book Memory based
HINT:

4) 180

140. Which of the following compounds has zero Dipolemoment ?

1) 1, 4 Dichlorobenzene
2) 1, 2 Dichlorobenzene
3) 1, 3 Dichlorobenzene
4) 1 chloro 2 methyl benzene
KEY: 1
Refer text book Memory based
HINT:

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141. Which of the following reagent is used to find out carbon-carbon multiple bonds ?
1) Grignard reagent
2) Bayers reagent
3) Sandmayers reagent
4) Gatterman reagent
KEY: 2
Conceptual
HINT:

2) p-type semiconductor
4) Insulator

142. Pure silicon doped with phosphorus is

1) Amorphous
3) n-type semiconductor
KEY: 3
Conceptual
HINT:

143. 18gm of glucose is dissolved in 90gm of water. The relative lowering of vapour pressure of the
solution is equal to
1) 6
2) 0.2
3) 5.1
4) 0.02
KEY: 4
Po Ps w M

m W
HINT: Po

0
E Ag

0
0.80V and EZn
2
Ag

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145. Calculate G for the following cell reaction

Zn( s ) Ag 2O( s ) H 2O(l ) Znn2( aq ) 2 Ag ( s ) 2OH ( aq )

144. A gas X is dissolved in water at 2 bar pressure. Its mole fraction is 0.02 in solution. The
mole fraction of water when the pressure of gas is doubled at the same temperature is
1) 0.04
2) 0.98
3) 0.96
4) 0.02
KEY: 3
P P0 X
HINT:
P1 X 1

P2 X 2
Xsolute Xsolvent 1

0.76V

Zn

1) -305 kJ/mol
2) -301 kJ/mol
KEY: 2
E 0 cell E 0 R E 0 L
HINT:
G 0 nFE 0 cell

3) 305 kJ/mol

4) 301 kJ/mol

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146. The time required for a first order reaction to complete 90% is t. What is the time required
to complete 99% of the same reaction
1) 2t
2) 3t
3) t
4) 4t
KEY: 1
100
log

t90%
10 1

HINT: t99% log 100 2

1
t99% 2t

147. Which of the following is the most effective in causing coagulation of ferric hydroxide sol?
1) KCl
2) KNO3
3) K2SO4
4) K3[Fe(CN)6]
KEY: 4
Conceptual
HINT:

148. Which of the following process does not involve heating ?

1) Calcination
2) Smelting
3) Roasting
KEY: 4
HINT: Conceptual

4) Levigation

149. Which one of the following is correct with respect to basic character ?
1) P(CH3)3 > PH3
2) PH3 > P(CH3)3
3) PH3 > NH3
4) PH3 = NH3
KEY: 1
HINT: Conceptual

150. When AgNO3 solution is added in excess to 1M solution of CoCl3 X NH3 one mole of AgCl is
formed ? What is the value of X ?
1) 1
2) 4
3) 3
4) 2
KEY: 2
From the given data the possible complex is
HINT:
Co NH 3 4 Cl2 Cl

So x is 4

x 3
2) 4 6 1 x 0

x2 0
x 2

x0

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3) x 0 0

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151. In which of the following coordination compounds, the central metal ion is in zero oxidation
state
1) [Fe(H2O)6]Cl3
2) K4[Fe(CN)6]
3) Fe(CO)5
4) [Fe(H2O)6]Cl2
KEY: 3
1) x 6 0 3 1 0
HINT:

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4) x 6 0 2 0

x 2

152. The percentage of lanthanides and iron, respectively, in Misch metal are
1) 50, 50
2) 75, 25
3) 90, 10
4) 95, 5
KEY: 4
Conceptual
HINT:
153. Sea divers use a mixture of
1) O2, N2
2) O2, H2
3) O2, He
4) N2, H2
KEY: 3
Conceptual
HINT:
154. The polymer obtained with methylene bridges by condensation polymer
1) PVC
2) Buna-S
3) Poly acrylo nitrile 4) Bakelie
KEY: 4
HINT:

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155. The amino acid containing Inhole part is

1) Tryptophan
2) Tyrosine
3) Proline
4) Methionine
KEY: 1
Conceptual
HINT:
156. The drug used as post operative analgesic in medicine is
1) L-Dopa
2) Amoxycilin
3) Sulphapyridine
4) Morphine
KEY: 4
Conceptual
HINT:
157. C2H5OH + 4I2 + 3Na2CO3 X + HCOONa + 5NaI + 3CO2 + 2H2O.
In the above reaction X is
1) Di iodo methane 2) Tri iodo methane 3) Iodo methane
4) Tetra iodo methane
KEY: 2
X CHI 3 Tri Iodomethane
HINT:
158. Phenol on oxidation in air gives
1) Quinone
2) Catechol
3) Resorsinol
4) O-Cresol
KEY: 1
HINT:

159. Identify the reagents A and B respectively in the following reactions

A
B
CH3COOH
CH3COCl
CH3CHO
1) SOCl2, H2/pd-BaSO4
2) H2/pd-BaSO4, SOCl2
3) SOCl2, H2O2
4) SOCl2, OsO4
KEY: 1
SOCl2
H 2 / Pd BaSO4
CH 3COOH
CH 3COCl
CH 3CHO
HINT:
160. Predict respectively X and Y in the following reactions

X
Y
Ar NH 2
Ar N N Cl
Ar Cl Ar NH2 A
1) NaNO3 & Cl2
2) NaNO3 HCl & HCl
3) NaNO2 HCl & Cu/HCl
4) NaNO2 HCl & NaNH2
KEY: 3

HINT:

NaNO2 HCl
Cu / HCl
Ar NH 2

Ar N2Cl
Ar Cl