Professional Documents
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in order to promote transparency and accountability in the working of every public authority,
and whereas the attached publication of the Bureau of Indian Standards is of particular interest
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timely dissemination of this information in an accurate manner to the public.
1 +, 1 +
01 ' 5
Jawaharlal Nehru
! $ ' +-
Satyanarayan Gangaram Pitroda
! > 0 B
BharthariNtiatakam
IS : 2520
- 1984
(Reaffirmed2005)
1!395)
(Reaffirmed
Indian Standard
SPECIl?ICATION FOR
ZINC STEARATE FOR COSMETIC INDUSTRY
( Second Revision )
First Reprint FEBRUARY 1999
UDC
661.847.753
: 665.58
Q Copyright 1984
BUREAU
MANAK
cl-4
OF
BHAVAN,
INDIAN
STANDARDS
9 BAHADUR
SHAH
NEW DELHI
110002
ZAFAR
MARG
November 1984
IS I2520-1984
Indian Standard
SPECIFICATION FOR
ZINC STEARATE FOR COSMETIC INDUSTRY
( Second Revision )
Cosmetics Sectional Committee, PCDC 19
RqWrsnling
Choirman
Directorate
DB S. S. GOTIWJSKAR
General
M&S
FoodBo~bsDyB
tt.W.ISTAWTDm~cxou
Administration,
Maharashtra
State,
DB P. D. PILANKAU ( Al&mate)
SEBJ B. S. BULVE
Ltd, Bombay
&
Research
Centre,
2 )
@ Ca@ri# 1984
BUREAU
OF INDIAN
STANDARDS
Manbm
Representmg
SERI P. ROY
Bengal chemical
Calcutta
SUNDABEEH
& Pharmaceutical
Works
Basic Chemicals
& Pharmaceuticals
&
Export Promotion Council, Bombay
Ltd,
Cosmetics
Alternate 1
Consumers
SHSI M. S. TRAXVB
SEUI N. G. IY~B ( Aftmutr
SEBI R. THANJAXU
Guidance
Society, Bombay
Alterwe )
Directorate
General
of Technical
Development,
New Delhi
SEBI S. N. AOABWAL ( Alternate )
SIERI M. S. SAIEIPA,
Director General, IS1 ( Ex-ofio Member )
Director(P&C)
SHRIYATI V~JAY MALIK
As&ant
Director ( P & C ), IS1
Raw Materials
DE G. L. MA~AX
PCDC
19 : 1
Members
.SEBI D.
CEHIsBA
Afternute to
Dr G. L. Madan )
~OXS~~~IO~R
AauumAler
Food
8 Drug
Bombay
Administration,
Maharashtra
State,
( 2zzz2xTm.m
omc!m
CnaesI(Cn~~)
(A&,)
LakmC Ltd, Bombay
SHBI B. S. BABVE
SBBI S. M. SlIAl?BHAQ ( Alterwe >
~~~m~~~oi;ip
14trl, Bofl~y
S-1 V. G. I)~~~HPANDE
Acinmutra~on,
Government
of
.g .
SEEI J. P. GANATBA
ularat, Alunadabad
S-1
R
D. DIEODEAR( Al&m&c )
Johnson h Johnson Ltd. Bombay
DBS.N.IYW
S-TX
USEA
R. JOSHI ( Ati
)
Swastik Household
h Industrial Products Pvt Ltd,
SW1 K. S. RAO
Bombay
S-I C. R. KB~SFRJAU~OO~TI~P( Al&n& )
Sudershan Chemical Industries Ltd, P~FM
SE& K. L. RATEI
&IBI U. N. LlYAYB
( dUR&
DF&. K:RoY?
DBP. C. BOSE ( Afrmrok )
DE N. D. !%k
D~M.h.Dortn
AlkrncrcI)
SEIU NA~OEAI~DBA 6 . SHAH
8~~1
VLIIODOHABIDBA K.
MmnTA(&m-)
8sNA4.8.Tl?AxuB
8~uxN.G.hxa(~)
Central
Drug Laboratory,
Calcutta
ISr2520.1984
Indian Standard
SPECIFICATION FOR
ZINC STEARATE FOR COSMETIC INDUSTRY
( Second Revision )
0.
FOREWORD
was adopted
by the
Indian Standards Institution on 16 August 1984, after the draft finalized
by the Cosmetics Sectional Committee had been approved by the
Petroleum, Coal and Related Products Division Council.
0.2 This standard was first published in 1963 and subsequently revised
in 1977. In the first revision of this standard, two sets of requirements,
namely, the essential and the optional requirements had been prescribed.
Subsequently this was found non-implementable for certification and
therefore the Sectional Committee after due consideration decided to
stipulate only a single set of requirement.
0.3 Zinc stearate is used in face powders, after-shave powders; baby
powders, foot powders etc, to which it is said to impart improved properties of smoothness and adhesion.
It has mild antisepticand astringent properties. It is also used as a local smoothing application in
inflammatory and irritating skin diseases and as a water-in-oil emulsifier
in hair-grooming preparations.
0.4 For the purpose of deciding whether a particular requirement of this
standard is complied with, the final value, observed or calculated,
expressing the result of a test or analysis, shall be rounded off in accordance with IS : 2-1960*. The number of significant places retained in
the rounded off value should be the same as that of the specified valuein
this standard.
1.SCOPE
1.1This standard prescribes the requirements and
the methods
sampling and test for zinc stearate for cosmetic industry.
*Rules for rounding
off numerical
values
( rcuiscd ).
of
IS : 2520 - 1984
2. REQUIREMENTS
2.1 Description
- The material shall be in the form of a fine white
bulky powder, free f.om rancid odour.
It shall be insoluble in alcohol,
water and ether.
2.2 The material shall also comply with the requirements given in
Table 1, when tested according
to the methods prescribed
in
Appendix A. Reference to the relevant clauses of Appendix A is given
in co1 4 of the table.
TABLE
REQUIREMBNTS
COSMETIC
SL
No.
FOR
METHODOBTEST
( REP TO CL No.
IN APF-J~NDIXA )
(1)
(2)
(3)
(4)
i)
130 to 15-5
A-2
ii)
T$;
54
A-3
of
separatedfatty acids ( C ),
A-4
10
A-5
As agreed to between
the purchaser and
the supplier
A-8
4-O
A-7
Shall not
differ
from zinc content
by more than 05
A-8
3.0
A-9
Frgafatty
1-O
A-10
xi)
PH, Ma.v
9'0
A-11
iv)
v)
vi)
vii)
Bulk density
1
Moisture, percent by mass, Max
ix)
3. PACKING
matter,
percent by mass,
AND MARRING
IS : 2529 - 1984
3.2.1 The product may also be marked with Standard
mark.
3.3 The use of the Standard Mark is governed by the provisions of the
Bureau of Indian Standards Act, 1986 and the Rules and Regulations
made
thereunder.
The details of conditions under which the licence for the use of
Standard Mark may be granted to manufacturers or producers may be obtained
from the Bureau of Indian Standards.
4. SAMPLING
41
Preparation
the material
of Test
4.2 Number
- Representative
as prescribed in Appendix
Samples
shall be prepared
test samples
B.
of
of Tests
4.3 Criteria
for Conformity
divided
by the
between
the
maximum
( R ) = the difference
minimum
value of the test results.
The lot shall be declared
to have
satisfied
number
and
of
the
the requirements
than
13.0, and
15.5.
43.2 For Composite Sample - The test results on the composite sample
shall meet the corresponding
requirements
specified in 2 and in Table 1.
5
II3 I 2520
- 1984
APPENDIX
( Claw? 2.2 )
AbfALYSIS OF ZINC STBARATE FOR
cosMETx
INDUSTRY
A-2. DETERMINATION
A-2.1
chemicals
that
do not
contain
impurities
OF ZINC
Reagents
A-21.1
A-2.1.2
percent.
A-2.1.3
A-21.4
of water.
See IS : 265-1962t.
Ethyl Alcohol -
10
percent
and
50 percent ( v/v ).
Dissolve
0.15 g of methyl
red in 500 ml
A-2.2 Procedure
- Weigh accurately
about 1 g of the material
into a
DO not heat
latinum dish and ignite to light grey ash at 600 to 650C.
Panger than necessary.
Cool and take up the ash in about 10 ml of
water.
Add methyl
red indicator
and neutralize
with concentrated
Bring to boil on a hot
h drochloric acid and make up to about 200 ml.
p rate and add 60 ml of ammonium
hydrogen phosphate solution ( 10 percent ) and continue to heat at just below boiling for 30 minutes.
Remove
from the hot plate and allow to cool to room temperature.
Filter
through a tared Gooch crucible. Wash with freshly prepared ammonium
hydrogen phosphate solution ( 1 percent ) and finally with 50 ml of ethyl
Place the crucible in a porcelain
crucible
alcohol.
Discard the filtrate.
Increase the temperature
and
of suitable size and dry over a low flame.
ignite at full heat to constant mass.
*Specification
f?Specification
).
A-2.3
Calculation
Zinc ( as Z,O
), percent
by mass = q
where
m 1M I
and
A-3. DETERMINATION
ACIDS
OF
taken
TlTItE
OF SEPARATab
FATTY
A-3.1 Reagents
A-3.1.1
1 : 3.
Ad.2 Procedure
- Heat 50 g of the material
with 400 ml of water
and 50 ml of dilute eulphuric acids until the fatty acidr have separated
a6 a layer.
Wabh the fatty acids with boiling
water until free of
sulphate.
Warm
the fatty acid6 on a steam-bath
until the water is
separated and the acid6 arc clear.
Allow the acid6 to cool, melt and
filter into a dry hot beaker and dry for 20 minutes
at 100C.
Thsre
the titre a6 directed
fatty acids are also ured for test in A*9. Determine
in 16 of IS : 266-1966*.
A-4. TEST
FOR
ARSENIC
A-4.1 Preparation
of Solutioa - Place 1000 g of the material
.in a
COOI
platinum
dish and incinerate
for about 2 hours at 525 to 550C.
and treat with a mixture
of 5 ml of concentrated
sulphuric acid and
5 ml of concentrated
nitric acid.
Take to fumes on a hot plate, cool
and make up the volume to exactly 100 ml.
A-4.2 Take 10 ml of the solution of the material
a6 obtained
in A-4.1
and carry out the test for arsenic as prescribed
in IS : 2088-1971t.
Corn are the stain obtained with that produced by 0000 2 mg of arsenic
triox Pde ( As606 ).
A-5. TEST
A-5.1
HEAVY
METALS
Apparatus
A&I.1
A-5.2
FOR
Nesster Cylindrrs -
50 ml capacity.
Reagents
A-3.2.1
Sor IS : 265.1962#.
A-5.2.3
Ammonium Chloride
A-5.2.4
Acetic Acid -
1 : 1.
1 N.
&&hide
Solution -
Freshly
prepared,
saturated
OF
SIEVE
ANALYSIS
AND
BULK
Sieve Analysis
(JFrsr reuision).
IS : 2520 - 1984
residue, carefully transfer it on to a tared watch-glass and dry to constant
mass at 105 f 2C.
NOTE I-Tap
water is usually sufficiently free from suspended particles to be utilized
directly as i&_comesfrom the faucet.
If the water is turbid, it is necessary to place a
large bottle of&&d
water above the working sink and to siphon the water through
a clean rubher tube to the level of the sieve. It is a good plan to insert a small rubber
stopper carrying a short glass tube about 5 cm in length and W6 cm in internal diameter in the faucet outlet.
A thin flexible piece of clean rubber tubing ( new tubing
should first be thoroughly washed ) about 60 cm in length is then attached to the glass
tube. The faucet is turned [on slowly until a thin stream of water is coming
through the rubber tube. By processing the end of the rubber tube between the fingers,
the steam of water can be varied in intensity and directed to any section of the sieve.
Experience has shown that the best practice is to alternately tip the sieve from one
side to another, washing the sample from the higher level of the sieve to the lower
and then reversing the sieve and repeating the operation.
NOTE 2 - In order to obtain comparable results, it is essential to continue washing
the residue on the sieve until one is satisfied that all the material fine enough to pas
through the sieve has been removed.
At least one-half hour of washing is essential in
most cases. It is a good plan to catch the last washes in a beaker.
By viewing the
contents of the beaker against a dark coloured background, it is possible to accurately
gauge the progress of the washing operations.
A-6.1.2 Calculation
Material retained on the specified sieve,
percent by mass
~ 1OOm
M
where
m = mass in g of the residue retained on the specified sieve,
and
M =- mass in g of the material taken for the test.
A-6.2 Bulk Density
A-6.2.1 Apparatus
A-6.2.1.1
Assemble the apparatus as shown in Fig. 1. The base of
measuring cylinder A shall be ground flat and the emply measuring
cylinder A together with the rubber bung shall weigh 250 f 5 g. It
shall be accurately calibrated to 250 ml with an error, if any, of less
than one millilitre. The distance between zero and 250 ml graduation
on the measuring cylinder A shall be not less than 220 mm and not more
than 250 mm. The distance between the flat-ground part of the base
of measuring clyinder A and the rubber base pad B, when the measuring
cylinder A is raised to full height shall be 25 f 2 mm.
A-6.2.1.2 Rubber base pad - The rubber base pad B shall have a
shore hardness of 42 to 50.
A-6.2.1.3 Balance - Pans of the balance shall be at least 10 cm in
diameter and the balance shall be sensitive to less than 0.1 g.
through
A-6.2.2 Procedure - Sieve about 40 g of the material
250 micron IS Sieve on to a tared glazed paper and weigh it accurately.
9
15:2520-1984
Slip the powder gently and smoothly into the measuring cylinder which
should be held at 45 to the vertical, without knocking or squeezing.
Assemble the apparatus as shown in Fig. 1. With the thumb and four
fingers of one hand, gently grasp the upper part of cylinder and within
one second, lift it about 25 mm ( takihg care not to jerk the cylinder by
knocking it against the upper stop ) and let it drop. Note the volume
after dropping it once. Continue lifting and dropping 50 complete
drops have been given to the cylinder.
During this operation, give a
gentle turn of about 10 in the clockwise direction to the cylinder afier
every two drops. As soon as 50 drops are completed, raise the cylinder
to eye level and read the volume of the material.
AI1dimensions in milHmetres.
APPARATUS
FOR DETERMINATIONOF BULK DENSITY
FIQ. 1
A-6.2.3, Calculation
Bulk density, g/ml:
a) After one tap -
1
b) After 50 taps -
-F
.n
where
m = mass in g of the material taken for the test,
Va = volume in ml of the material after one tap, and
Vg = volume in ml of the material after 50 taps.
10
IS : 2529 - 1984
A-7. DETERMINATION
OF MOISTURE
100 MI
-
M2
where
OF TOTAL
ASH
lOO&
M2
where
OF IODINE
OF SEPARATED
OF FREE FATlY
MATTER
A-10.1 Reagent
A-10.1.1 EthTl Ether -
set IS : 336-1973t.
IS : 2528 - 1984
.
and filter. Take the filtrate in a tared porcelain dish and evaporate
slowly on a steam-bath.
Cool and weigh the residue.
A-10.3
Calcolation
100 Ml
Ma
where
Ml = mass in g of the residue, and
Ma - mass in g of the material taken for the test.
A-11. $3 DETERMINATION
A-11.1 Apparatus
pH Meter
APPENDIX
( Clause 4.1 )
PREPARATION
B-I. GENERAL
STEARATE
OF SAMPLING
OF SAMPLING
of sampling
mentsand precautions.
chemicals
and
chemical
12
products:
Part 1 General
require-
IS:2520-1984
B-2.2 The number
depend
TABLE
NUMBEB
OF CONTAINERS
NO. OB COXTMNRRS TO
LOTSIZE
up
51
151
301
501
FOR SAMPLING
TO BE SELECTED
(1)
(2)
BE
SELECTED
3
4
5
7
IO
50
to 150
to 300
to 500
and above
to
TEST
SAMPLES
B-3.1 Preparation
AND REFEREE
SAMPLE
of Test Samples
lSt2520-19s4
The material in each such sealed bottle shall constitute an individual
test sample.
These individual samples shall be separated into three
identical sets of samples in such a way that each set has an individual
test sample representing each container selected.
One of these three
sets shall be sent to the purchaser, another to the supplier and the third
shall be used as referee sample.
B-3.2 Referee
Sample - The
referee sample shall
consist
of
the composite sample ( see B-3.1.2 ) and a set of individual samples
( SIC B-S.13) marked for this purpose and shall bear the seals of the
purchaser and the supplier.
These shall be kept at a place agreed to
between the purchaser and the supplier and shall be used in case of dispute
between the two.
14
BUREAU
OF INDIAN
STANDARDS
Telephone
Industrial
Area, SAHIBABAD
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AMENDMENT
NO. 1 DECEMBER
1995
TO
IS 2520 : 1984 SPECIFICATION FOR ZINC
STEARATE FOR COSMETIC INDUSTRY
( Second Revision )
[ Page 4, Table 1, SINo. (i), coZ3 ] -Substitute
Substitute
13.Oto 15.5.
the following
A-2.1 Reagents
A-2.1.1 Sulplluric Acid -
0.1 N.
0.05 M.
8.138xVx
where